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Oxygen Atom Transfer Reactions
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Book Synopsis Oxygen Atom Transfer Reactions by : Robert Bakhtchadjian
Download or read book Oxygen Atom Transfer Reactions written by Robert Bakhtchadjian and published by Bentham Science Publishers. This book was released on 2023-01-11 with total page 137 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Book Synopsis Oxygen Atom Transfer Reactions by : Robert Bakhtchadjian
Download or read book Oxygen Atom Transfer Reactions written by Robert Bakhtchadjian and published by Chemical Reaction Mechanisms. This book was released on 2023-01-11 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Book Synopsis Oxygen Atom Transfer Reactions by : Anke Sieker
Download or read book Oxygen Atom Transfer Reactions written by Anke Sieker and published by . This book was released on 1994 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Computational Modelling of Oxygen Atom Transfer Reactions by : Mark Richard Bray
Download or read book The Computational Modelling of Oxygen Atom Transfer Reactions written by Mark Richard Bray and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Photo-initiated Oxygen-atom Transfer Reaction from Nitrogen Dioxide to Acetylene and Methyl Acetylene Under Matrix Isolation Conditions by : James Andrew Harrison
Download or read book Photo-initiated Oxygen-atom Transfer Reaction from Nitrogen Dioxide to Acetylene and Methyl Acetylene Under Matrix Isolation Conditions written by James Andrew Harrison and published by . This book was released on 1991 with total page 1146 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterisation and Oxygen Atom Transfer Reactions of a Series of Cis-dioxomolybdenum(VI) Complexes by : John Allison McEwan
Download or read book Synthesis, Characterisation and Oxygen Atom Transfer Reactions of a Series of Cis-dioxomolybdenum(VI) Complexes written by John Allison McEwan and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molybdenum and Tungsten Enzymes by : Russ Hille
Download or read book Molybdenum and Tungsten Enzymes written by Russ Hille and published by Royal Society of Chemistry. This book was released on 2016-09-29 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: There has been enormous progress in our understanding of molybdenum and tungsten enzymes and relevant inorganic complexes of molybdenum and tungsten over the past twenty years. This set of three books provides a timely and comprehensive overview of the field and documents the latest research. Building on the first volume that focussed on biochemistry aspects, the second volume in the set focusses on the inorganic complexes that model the structures and reactivity of the active sites of each major group of molybdenum and tungsten enzymes. Special attention is given to synthetic strategies, reaction mechanism and chemical kinetics of these systems. The introductory chapter provides a useful overview and places the topic of the book into a wider context. This text will be a valuable reference to workers both inside and outside the field, including graduate students and young investigators interested in developing new research programs in this area.
Book Synopsis Vanadium in Biological Systems by : N.D. Chasteen
Download or read book Vanadium in Biological Systems written by N.D. Chasteen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past several decades, vanadium has increasingly attracted the interest of biologists and chemists. The discovery by Henze in 1911 that certain marine ascidians accumulate the metal in their blood cells in unusually large quantities has done much to stimulate research on the role of vanadium in biology. In the intervening years, a large number of studies have been carried out to investigate the toxicity of vanadium in higher animals and to determine whether it is an essential trace element. That vanadium is a required element for a few selected organisms is now well established. Whether vanadium is essential for humans remains unclear although evidence increasingly suggests that it probably is. The discovery by Cantley in 1977 that vanadate is a potent inhibitor of ATPases lead to numerous studies of the inhibitory and stimulatory effects of vanadium on phosphate metabolizing enzymes. As a consequence vanadates are now routinely used as probes to investigate the mechanisms of such enzymes. Our understanding of vanadium in these systems has been further enhanced by the work of Tracy and Gresser which has shown striking parallels between the chemistry of vanadates and phosphates and their biological compounds. The observation by Shechter and Karlish, and Dubyak and Kleinzeller in 1980 that vanadate is an insulin mimetic agent has opened a new area of research dealing with the hormonal effects of vanadium. The first vanadium containing enzyme, a bromoperoxidase from the marine alga Ascophyllum nodosum, was isolated in 1984 by Viltner.
Book Synopsis Mechanistic Studies and Synthetic Applications of Oxygen Atom Transfer Reactions Catalyzed by Rhenium(V) Dithiolato Complexes and Methyltrioxorhenium (MTO) by : Ying Wang
Download or read book Mechanistic Studies and Synthetic Applications of Oxygen Atom Transfer Reactions Catalyzed by Rhenium(V) Dithiolato Complexes and Methyltrioxorhenium (MTO) written by Ying Wang and published by . This book was released on 2001 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the case of oxygen atom transfer reaction between tert-butyl hydroperoxide and sulfide catalyzed by Re(V) dithiolato compounds, an induction period is observed due to the slow ligand exchange step. Reaction schemes are proposed to interpret the kinetic data. In both cases, the active intermediates are Re(VII) dioxo species, which were detected at the low temperature. Organic disulfides with both alkyl and aryl substituents are oxidized by hydrogen peroxide when CH3ReO33 (MTO) is used as a catalyst. Thiosulfinate is formed in the first step about an hour with nearly quantitative yield. Kinetics studies of the first oxidation reaction established that two peroxorhenium compounds are the active forms of the catalyst. Rate constants were obtained and a mechanism was proposed in which the electron-rich sulfur attacks the peroxo oxygen of intermediates.
Book Synopsis Principles of Bioinorganic Chemistry by : Stephen J. Lippard
Download or read book Principles of Bioinorganic Chemistry written by Stephen J. Lippard and published by University Science Books. This book was released on 1994 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of unnatural metals - which have been introduced into human biology as diagnostic probes and drugs - is another active area of tremendous medical significance.
Book Synopsis Physical Inorganic Chemistry by : Andreja Bakac
Download or read book Physical Inorganic Chemistry written by Andreja Bakac and published by John Wiley & Sons. This book was released on 2010-04-22 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: This go-to text provides information and insight into physical inorganic chemistry essential to our understanding of chemical reactions on the molecular level. One of the only books in the field of inorganic physical chemistry with an emphasis on mechanisms, it features contributors at the forefront of research in their particular fields. This essential text discusses the latest developments in a number of topics currently among the most debated and researched in the world of chemistry, related to the future of solar energy, hydrogen energy, biorenewables, catalysis, environment, atmosphere, and human health.
Book Synopsis Peroxidases in Chemistry and Biology by : Johannes Everse
Download or read book Peroxidases in Chemistry and Biology written by Johannes Everse and published by CRC Press. This book was released on 1990-10-24 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second of two relatively independent volumes on the chemistry and biology of peroxidases. Volumes 2 covers the peroxidases isolated from plants and microorganisms, and includes detailed discussions of some of the unique reactions catalyzed by these enzymes. Volume one covered the peroxidases isolated from animal sources, as well as the "pseudo- peroxidase activity" of prostaglandin H synthase and of myoglobin and hemoglobin. Acidic paper. Annotation copyrighted by Book News, Inc., Portland, OR
Book Synopsis Advances in Inorganic Chemistry by : Rudi van Eldik
Download or read book Advances in Inorganic Chemistry written by Rudi van Eldik and published by Gulf Professional Publishing. This book was released on 2003-07-08 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Advances in Inorganic Chemistry series presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. This, the 54th volume in the series continues this tradition providing comprehensive reviews by leading experts in the field with the focus on inorganic and bioinorganic reaction mechanisms. The latest volume in this highly successful series is dedicated to inorganic and bioinorganic reaction mechanisms Comprehensive reviews written by leading experts in the field
Book Synopsis On Being Well-Coordinated by : Fred Basolo
Download or read book On Being Well-Coordinated written by Fred Basolo and published by World Scientific. This book was released on 2003-10-14 with total page 656 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry. Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance. Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature. Contents: Ligand Substitution Reactions of Transition Metal ComplexesApplication of Reaction Mechanisms to the Synthesis of Metal ComplexesCarbon Monoxide Substitution Reactions of Metal CarbonylsMetal Nitrosyl CarbonylsCatalysis of CO Substitution in Metal CarbonylsMigratory Insertion ReactionsOxygen Atom Transfer to Metal CarbonylsSynthetic Oxygen Carries of Biological Interestand other papers Readership: Researchers in the solution of metals, as well as bioinorganic, organometallic and solid state chemistry. Keywords:Coordination Chemistry;Metal Complexes;Transition Metals;Inorganic Chemistry;Biochemistry
Book Synopsis Advances in Inorganic Chemistry by :
Download or read book Advances in Inorganic Chemistry written by and published by Academic Press. This book was released on 1994-02-03 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Inorganic Chemistry
Book Synopsis Modern Gold Catalyzed Synthesis by : A. Stephen K. Hashmi
Download or read book Modern Gold Catalyzed Synthesis written by A. Stephen K. Hashmi and published by John Wiley & Sons. This book was released on 2012-05-21 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced both organic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology, self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis at the moment, with an increasing amount of research being carried out in this field. While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Following a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes and alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions. The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and technical chemists.
Book Synopsis Electron Transfer Reactions by : R. D. Cannon
Download or read book Electron Transfer Reactions written by R. D. Cannon and published by Butterworth-Heinemann. This book was released on 2016-07-29 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron Transfer Reactions deals with the mechanisms of electron transfer reactions between metal ions in solution, as well as the electron exchange between atoms or molecules in either the gaseous or solid state. The book is divided into three parts. Part 1 covers the electron transfer between atoms and molecules in the gas state. Part 2 tackles the reaction paths of oxidation states and binuclear intermediates, as well as the mechanisms of electron transfer. Part 3 discusses the theories and models of the electron transfer process; theories and experiments involving bridged electron transfer; optical electron transfer; and electron transfer in the solid state. The text is recommended for chemists who would like to know more about the principles and mechanisms behind electron transfer reactions.
