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Author : Vladimir Fomin
Publisher :
ISBN 13 : 9783330090781
Total Pages : 368 pages
Book Rating : 4.0/5 (97 download)
Download or read book Oxidation of Derivants of Ferrocene by Molecular Oxygen and Peroxides written by Vladimir Fomin and published by . This book was released on 2017-06-30 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Joshua M. Halstead
Publisher :
ISBN 13 :
Total Pages : 93 pages
Book Rating : 4.:/5 (17 download)
Download or read book Oxidation of Ferrocene Derivatives with Dibenzoyl Peroxide and Meta-chloroperoxybenzoic Acid written by Joshua M. Halstead and published by . This book was released on 2018 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemical oxidation of ferrocene and related derivatives (RFc) via organic peroxides solvated in acetonitrile was studied spectrophotometrically by varying concentration and temperature to determine kinetics and activation parameters. The reaction rate of ferrocene with dibenzoyl peroxide depends strongly on whether electron withdrawing or donating substituents are present. Products were analyzed and the effect of different solvents on reactivity were studied. The rate law was first order in both oxidant and reductant, and steric and solvent effects are consistent with outer sphere electron transfer (ET) as the rate-controlling step. B3YLP calculations were conducted to determine reorganization energies using Marcus theory and to examine molecular geometry and steric considerations.
Author : Refaat Khalid Abu-Saleh
Publisher :
ISBN 13 : 9781109988697
Total Pages : 165 pages
Book Rating : 4.9/5 (886 download)
Download or read book Oxidation of Ferrocene with Peroxides written by Refaat Khalid Abu-Saleh and published by . This book was released on 2007 with total page 165 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation of ferrocene was accomplished by reacting Fc with benzoyl peroxide (C6H5CO2OCOC6H5), hydrogen peroxide (H2O2), and tetranitromethane (TNM) to produce the ferricenium cation (Fc+). Ferrocene reacts with TNM instantaneously to produce Fc+, whereas the peroxides oxidize Fc to produce two moles of Fc+ per mole of peroxide. The blue ferricenium cation was stable to air, oxygen, and water in acidic aqueous acetonitrile solvent. The time dependence of oxidation of Fc to Fc+ depended linearly on the concentration of Fc and the concentration of the oxidants, but was independent of acid concentration, affording a rate expression d[Fc +]/dt = k[Fc] [peroxide]. Activation parameters obtained from the temperature dependence of the rate constants k were determined using the Eyring equation, d[ln(k/T)] = ln(kappakB/h) - DeltaH ‡/RT + DeltaS‡/R. For hydrogen peroxide, DeltaH ‡ = 11.0 +/- 1.9 kcal/mol and DeltaS‡ = -27.5 +/- 0.5 eu, and for benzoyl peroxide, DeltaH ‡ = 9.8 + 0.9 kcal/mol and DeltaS‡ = -28.1 + 0.2 eu. The energy DeltaG estimated for thermodynamic electron transfer from reported values of redox potentials (Eo ox = 0.56-0.62 V vs. NHE for oxidation of Fc and Eo red = -(0.63-0.68) V for reduction of hydrogen peroxide) and the Nerst equation is 13-14 kcal/mol, as compared to the observed activation energy DeltaG ‡ = 19.1 kcal/mol at 22°C.
Author : Ana Ison
Publisher :
ISBN 13 :
Total Pages : 250 pages
Book Rating : 4.:/5 (847 download)
Download or read book Hydrocarbon Oxidation Using Molecular Oxygen and Hydrogen Peroxide Catalyzed by Transition Metal Complexes written by Ana Ison and published by . This book was released on 2004 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Douglas E. Patton
Publisher :
ISBN 13 :
Total Pages : 216 pages
Book Rating : 4.:/5 (333 download)
Download or read book The Catalytic Oxidation of Organic Substrates Utilizing Molecular Oxygen and Peroxides written by Douglas E. Patton and published by . This book was released on 1993 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Katja A. Strohfeldt
Publisher : John Wiley & Sons
ISBN 13 : 1118695356
Total Pages : 290 pages
Book Rating : 4.1/5 (186 download)
Download or read book Essentials of Inorganic Chemistry written by Katja A. Strohfeldt and published by John Wiley & Sons. This book was released on 2015-01-30 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive introduction to inorganic chemistry and, specifically, the science of metal-based drugs, Essentials of Inorganic Chemistry describes the basics of inorganic chemistry, including organometallic chemistry and radiochemistry, from a pharmaceutical perspective. Written for students of pharmacy and pharmacology, pharmaceutical sciences, medicinal chemistry and other health-care related subjects, this accessible text introduces chemical principles with relevant pharmaceutical examples rather than as stand-alone concepts, allowing students to see the relevance of this subject for their future professions. It includes exercises and case studies.
Author : Karen Lorraine McCeney
Publisher :
ISBN 13 :
Total Pages : 100 pages
Book Rating : 4.:/5 (13 download)
Download or read book Kinetic Study of the Oxidation of Ferrocene and Ferrocenecarboxylic Acid by Hydrogen Peroxide in Acidic Media written by Karen Lorraine McCeney and published by . This book was released on 1983 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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ISBN 13 :
Total Pages : 690 pages
Book Rating : 4.:/5 (4 download)
Download or read book Journal of Research of the National Institute of Standards and Technology written by and published by . This book was released on 1991-10 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ole Hammerich
Publisher : CRC Press
ISBN 13 : 142008402X
Total Pages : 1706 pages
Book Rating : 4.4/5 (2 download)
Download or read book Organic Electrochemistry written by Ole Hammerich and published by CRC Press. This book was released on 2015-09-22 with total page 1706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Praise for the Fourth Edition"Outstanding praise for previous editions.the single best general reference for the organic chemist."-Journal of the Electrochemical Society"The cast of editors and authors is excellent, the text is, in general, easily readable and understandable, well documented, and well indexed those who purchase the book will be sa
Author : Sumio Sakka
Publisher : Springer Science & Business Media
ISBN 13 : 9781402079665
Total Pages : 716 pages
Book Rating : 4.0/5 (796 download)
Download or read book Handbook of sol-gel science and technology. 1. Sol-gel processing written by Sumio Sakka and published by Springer Science & Business Media. This book was released on 2005 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since Dr. Disiich of Germany prepared a glass lens by the sol-gel method around 1970, sol-gel science and technology has continued to develop. Since then this field has seen remarkable technical developments as well as a broadening of the applications of sol-gel science and technology. There is a growing need for a comprehensive reference that treats both the fundamentals and the applications, and this is the aim of "Handbook of Sol-Gel Science and Technology."The primary purpose of sol-gel science and technology is to produce materials, active and non-active including optical, electronic, chemical, sensor, bio- and structural materials. This means that sol-gel science and technology is related to all kinds of manufacturing industries. Thus Volume 1, "Sol-Gel Processing," is devoted to general aspects of processing. Newly developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, photocatalysts will be covered. Topics in this volume include: Volume 2, "Characterization of Sol-Gel Materials and Products, "highlights the important fact that useful materials are only produced when characterization is tied to processing. Furthermore, characterization is essential to the understanding of nanostructured materials, and sol-gel technology is a most important technology in this new field. Since nanomaterials display their functional property based on their nano- and micro-structure, "characterization" is very important. Topics found in Volume 2 include: Sol-gel technology is a versatile technology, making it possible to produce a wide variety of materials and to provide existing substances with novel properties. This technology was applied to producingnovel materials, for example organic-inorganic hybrids, which are quite difficult to make by other fabricating techniques, and it was also applied to producing materials based on high temperature superconducting oxides. "Applications of Sol-Gel Technology," (Volume 3), will cover applications such as:
Author : Antonio Joseph Ricco
Publisher : The Electrochemical Society
ISBN 13 : 9781566771474
Total Pages : 1126 pages
Book Rating : 4.7/5 (714 download)
Download or read book Chemical and Biological Sensors and Analytical Electrochemical Methods written by Antonio Joseph Ricco and published by The Electrochemical Society. This book was released on 1997 with total page 1126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Richard Monson
Publisher : Elsevier
ISBN 13 : 0323159974
Total Pages : 216 pages
Book Rating : 4.3/5 (231 download)
Download or read book Advanced Organic Synthesis written by Richard Monson and published by Elsevier. This book was released on 2012-12-02 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Organic Synthesis: Methods and Techniques presents a survey and systematic introduction to the modern techniques of organic synthesis. The book attempts to acquaint the reader with a variety of laboratory techniques as well as introduce chemical reagents that require deftness and care in handling. Chapters are devoted that discuss the techniques of organic synthesis; apparatus and terminology used in the description of synthetic procedures; the scope and mechanism of chemical reactions; and technical procedures on how to perform chemical experiments. The text will be of vital importance to advanced undergraduate student or beginning graduate student of chemistry.
Author : Christopher P. Price
Publisher : Springer
ISBN 13 : 1349112348
Total Pages : 665 pages
Book Rating : 4.3/5 (491 download)
Download or read book Principles and Practice of Immunoassay written by Christopher P. Price and published by Springer. This book was released on 1991-06-18 with total page 665 pages. Available in PDF, EPUB and Kindle. Book excerpt: Each chapter of this book aims to explore the basic physical and chemical principles involved in the immunoassay techniques discussed. The book also looks at the optimization and limitations of methodology and concludes with a brief overview of the application of the performance of the technology.
Author :
Publisher :
ISBN 13 :
Total Pages : 464 pages
Book Rating : 4.:/5 (318 download)
Download or read book Journal of Chemical Research written by and published by . This book was released on 2004 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
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ISBN 13 :
Total Pages : 1338 pages
Book Rating : 4.3/5 (243 download)
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1970 with total page 1338 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Akademii︠a︡ nauk SSSR.
Publisher :
ISBN 13 :
Total Pages : 670 pages
Book Rating : 4.3/5 (91 download)
Download or read book Doklady written by Akademii︠a︡ nauk SSSR. and published by . This book was released on 1987 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Allen J. Bard
Publisher : Springer Science & Business Media
ISBN 13 : 3642295517
Total Pages : 994 pages
Book Rating : 4.6/5 (422 download)
Download or read book Electrochemical Dictionary written by Allen J. Bard and published by Springer Science & Business Media. This book was released on 2012-10-02 with total page 994 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition of the highly successful dictionary offers more than 300 new or revised terms. A distinguished panel of electrochemists provides up-to-date, broad and authoritative coverage of 3000 terms most used in electrochemistry and energy research as well as related fields, including relevant areas of physics and engineering. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired. Almost 600 figures and illustrations elaborate the textual definitions. The “Electrochemical Dictionary” also contains biographical entries of people who have substantially contributed to electrochemistry. From reviews of the first edition: ‘the creators of the Electrochemical Dictionary have done a laudable job to ensure that each definition included here has been defined in precise terms in a clear and readily accessible style’ (The Electric Review) ‘It is a must for any scientific library, and a personal purchase can be strongly suggested to anybody interested in electrochemistry’ (Journal of Solid State Electrochemistry) ‘The text is readable, intelligible and very well written’ (Reference Reviews)
