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Organometallic Compounds The Main Group Elements Pt 2 Groups Iv And V
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Book Synopsis Organometallic Compounds by : B. J. Aylett
Download or read book Organometallic Compounds written by B. J. Aylett and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Book Synopsis Organometallic Chemistry by : R. C. Mehrotra
Download or read book Organometallic Chemistry written by R. C. Mehrotra and published by New Age International. This book was released on 2007 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Book Is A Revised Edition Of A Lucid And Stimulating Introductory Account Of Organometallic Chemistry, An Exciting And Rapidly Developing Interdisciplinary Branch Of Science.A Characteristic Feature Of This Book Is The Presentation Of An Integrated (Covering Different Facets Usually Dealt With Either In Organic Or/And Inorganic Texts) View Of The Rapidly Developing Field Of Organometallic Chemistry. Attempts Have Been Made To Choose The Latest Examples To Illustrate The Fundamental Properties As Well As The Synthetic Procedures Of Organometallic Chemistry. Other Features Include: (A) An Interesting Brief Historical Background Of The Subject Including Some Quotations From Relevant Nobel Lecture Accounts Of Epoch Making Advances By The Discoverers Themselves, (B) The Adoption As Far As Possible Of The Iupac Rules Of Nomenclature, (C) A Brief Account Of The Rapidly Emerging Organometallic Chemistry Of The F-Elements, And (D) Inclusion Of Study Questions At The End Of Each Chapter.During The Revision Of The Book, The Latest Examples Have Replaced The Older Ones Wherever Feasible. The Book Would Be Extremely Useful As A Basic Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.
Book Synopsis Pb Organolead Compounds by : Friedo Huber
Download or read book Pb Organolead Compounds written by Friedo Huber and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is exclusively devoted to tetramethyllead. Owing to the recent large-scale use as an antiknock agent, its application, toxicological, biological, and environmental aspects are given much attention besides its chemical and physical properties. - Literature coverage up to 1986.
Book Synopsis Basic Organometallic Chemistry by : Ionel Haiduc
Download or read book Basic Organometallic Chemistry written by Ionel Haiduc and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Syntheses by : John Eisch
Download or read book Organometallic Syntheses written by John Eisch and published by Elsevier. This book was released on 2012-12-02 with total page 209 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nontransition-Metal Compounds is the second volume in the series Organometallic Syntheses and presents various procedures for the nontransition-metal compounds. Topics also covered in this volume include sensitive liquids, sample transfer, and inert atmosphere provision. The text is divided into two major parts. Part I is mostly procedural as it offers directions and suggestions in different processes such as (a) establishment of an inert atmosphere and solvent medium; (b) evaluation of purity, mode of mixing, and solvent type; and (c) isolation and purification of reaction products. Organometallic products, particularly its physical and chemical characteristics, are also tackled. In Part II, around 85 nontransition-metal organometallic compounds and the reliable procedures used for their synthesis are presented. This particular volume will be of help to students both in the fields of chemistry and biology.
Book Synopsis GeR4 Compounds and Ge(CH3) 3R Compounds up to Cyclic Alkyl Groups by : Frank Glockling
Download or read book GeR4 Compounds and Ge(CH3) 3R Compounds up to Cyclic Alkyl Groups written by Frank Glockling and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume opens the Gmelin series on organogermanium compounds, that is, those compounds containing at least one germanium-to-carbon bond. This whole series is being coordinated by Professor J. Satge of the Universite Paul Sabatier in Toulouse. Germanium is of historical interest because its existence was predicted by Newlands in 1864 and by Mendeleeff in 1871 although it was not isolated until1887 by Winkler. Mendeleeff's predictions of the properties of germanium and its compounds by comparison with what was known of the chemistry of its neighbors, silicon and tin, proved remarkably accurate and included predictions of the existence of organic derivatives GeR and of their properties. 4 Although significant applications are as yet lacking for organogermanium compounds in contrast to organo-silicon, -tin, and -lead compounds there has been considerable interest in the parallel development of its chemistry. Up to 1983 about 1500 publications have appeared on organogermanium chemistry. The material of the present series will be grouped in a similar way as for the organotin series beginning with compounds containing only one germanium atom (mononuclear com pounds) and continuing with binuclear up to polynuclear compounds. Within each group the compounds are arranged by the kind of non-carbon substituents rather than by following the usual Gmelin principle of the last position using the Gmelin system of elements.
Book Synopsis Organotin Chemistry by : Alwyn G. Davies
Download or read book Organotin Chemistry written by Alwyn G. Davies and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: At long last: The second, completely revised edition of this comprehensive standard reference. Alwyn G. Davies has updated the contents of his book to reflect the current state of research into organotin chemistry. He covers all aspects in detail, such as its synthesis, characterization, structures and applications, while also devoting space to such hot topics as environmental issues. This new edition also includes a CD-ROM with more than 5,000 references, making this database an invaluable tool for everyone working in the field. "The text is well written, extremely accessible and very comprehensive: particularly impressive is the inclusion of up-to-the-minute references in these areas...." - Advanced Materials, 13 (1998) "The standard of production is very good, with well-structured tables and an abundance of clear formula schemas, which enable the reader to quickly grasp the essence of the text." - Angewandte Chemie 16, 1997
Book Synopsis Spectroscopic Properties of Inorganic and Organometallic Compounds by : N N Greenwood
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by N N Greenwood and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Book Synopsis Physical Chemistry, Series Two by : Amyand David Buckingham
Download or read book Physical Chemistry, Series Two written by Amyand David Buckingham and published by . This book was released on 1975 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Compounds of Germanium, Tin and Lead Including Biological Activity and Commercial Application by : Richard W. Weiss
Download or read book Compounds of Germanium, Tin and Lead Including Biological Activity and Commercial Application written by Richard W. Weiss and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 1139 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Inorganic Reactions and Methods, The Formation of Bonds to Group VIB (O, S, Se, Te, Po) Elements (Part 1) by : A. P. Hagen
Download or read book Inorganic Reactions and Methods, The Formation of Bonds to Group VIB (O, S, Se, Te, Po) Elements (Part 1) written by A. P. Hagen and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 601 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.
Book Synopsis The British National Bibliography by : Arthur James Wells
Download or read book The British National Bibliography written by Arthur James Wells and published by . This book was released on 1979 with total page 1388 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Organometallic Chemistry by : Geoffrey Wilkinson
Download or read book Comprehensive Organometallic Chemistry written by Geoffrey Wilkinson and published by . This book was released on 1982 with total page 1592 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Physical Chemistry by : Amyand David Buckingham
Download or read book Physical Chemistry written by Amyand David Buckingham and published by . This book was released on 1976 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Surface Chemistry and Colloids by : Milton Kerker
Download or read book Surface Chemistry and Colloids written by Milton Kerker and published by . This book was released on 1975 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Alicyclic Compounds by : David Ginsburg
Download or read book Alicyclic Compounds written by David Ginsburg and published by . This book was released on 1976 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Aliphatic Compounds by : Norman Bellamy Chapman
Download or read book Aliphatic Compounds written by Norman Bellamy Chapman and published by . This book was released on 1975 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: