On the Nature of Variations in Density and Composition Within TATB-based Plastic Bonded Explosives

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ISBN 13 :
Total Pages : 7 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis On the Nature of Variations in Density and Composition Within TATB-based Plastic Bonded Explosives by : J. H. Kinney

Download or read book On the Nature of Variations in Density and Composition Within TATB-based Plastic Bonded Explosives written by J. H. Kinney and published by . This book was released on 2006 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Initiation of insensitive high explosives is affected by porosity in the 100 nm to micron size range. It is also recognized that as-pressed plastic bonded explosives (PBX) are heterogeneous in composition and density at much coarser length scale (10 microns-100 microns). However, variations in density and composition of these explosives have been poorly characterized. Here, we characterize the natural variations in composition and density of TATB-based PBX LX-17 with synchrotron radiation tomography and ultra small angle x-ray scattering. Large scale variations in composition occur as a result of binder enrichment at the prill particle boundaries. The pore fraction is twice as high in the prill particle as in the boundary. The pore distribution is bimodal, with small pores of 50-100 nm in radius and a broader distribution of pores in the 0.5-1.5 micron size range. The higher pore density within the prill particle is attributed to contact asperities between the crystallites that might inhibit complete consolidation and binder infiltration.

A Literature Review of Shock Sensitivity Changes of TATB Due to Thermal Cycling

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ISBN 13 :
Total Pages : 39 pages
Book Rating : 4.:/5 (958 download)

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Book Synopsis A Literature Review of Shock Sensitivity Changes of TATB Due to Thermal Cycling by :

Download or read book A Literature Review of Shock Sensitivity Changes of TATB Due to Thermal Cycling written by and published by . This book was released on 2016 with total page 39 pages. Available in PDF, EPUB and Kindle. Book excerpt: Insensitive high explosives (IHEs) based on 1,3,5-triamino 2,4,6-trinitro-benzene (TATB) are the IHEs of choice for use in nuclear warheads over conventional high explosives when safety is the only consideration, because they are very insensitive to thermal or mechanical initiation stimuli. It is this inherent insensitivity to high temperatures, shock, and impact, which provides detonation design challenges when designing TATB explosive systems while at the same time providing a significant level of protection against accidental initiation. Although classified as IHE, over the past few years the focus on explosive safety has demonstrated that the shock sensitivity of TATB is influenced with respect to temperature. A number of studies have been performed on TATB and TATB formulations, plastic bonded explosives (PBX) 9502, and LX-17-01 (LX-17), which demonstrates the increase in shock sensitivity of the explosive after it has been preheated or thermally cycled over various temperature ranges. Many studies suggest the change in sensitivity is partly due to the decomposition rates of the temperature elevated TATB. Others point to the coefficient of thermal expansion, the crystalline structures of TATB and/or the combination of all factors, which create voids which can become active hot spots. During thermal cycling, TATB is known to undergo an irreversible increase in specific volume called ratchet growth. This increase in specific volume correlates to a decrease in density. This decrease in density and increase in volume, demonstrate the creations of additional void spaces which could serve as potential new initiation hot spots thus, increasing the overall sensitivity of the HE. This literature review evaluates the published works to understand why the shock sensitivity of TATB-based plastic bonded explosives (PBXs) changes with temperature.

Thermal Expansion of PBX 9501 and PBX 9502 Plastic-bonded Explosives

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Thermal Expansion of PBX 9501 and PBX 9502 Plastic-bonded Explosives by :

Download or read book Thermal Expansion of PBX 9501 and PBX 9502 Plastic-bonded Explosives written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Two applications of thermal expansion measurements on plastic-bonded explosive (PBX) composites are described. In the first dilatometer application, thermal expansion properties of HMX-based PBX 9501 are measured over a broad thermal range that includes glass and domain-restructuring transitions in the polymeric binder. Results are consistent with other thermal measurements and analyses performed on the composite, as well as on the binder itself. The second application used the dilatometer to distinguish the reversible and irreversible components of thermal expansion in PBX 9502, a TATB-based explosive. Irreversible expansion of the composite is believed to derive from the highly-anisotropic coefficient of thermal expansion (CTE) values measured on single T A TB crystals, although the mechanism is not well understood. Effects of specimen density, thermal ramp rate, and thermal range variation (warm first or cold first) were explored, and the results are presented and discussed. Dilatometer measurements are ongoing towards gaining insight into the mechanism(s) responsible for PBX 9502 irreversible thermal expansion.

On the Re-use of TATB in Plastic-bonded Explosives (PBX) (u).

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis On the Re-use of TATB in Plastic-bonded Explosives (PBX) (u). by :

Download or read book On the Re-use of TATB in Plastic-bonded Explosives (PBX) (u). written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preliminary Development and Characterization of a TATB/HMX Plastic-bonded Explosive

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Preliminary Development and Characterization of a TATB/HMX Plastic-bonded Explosive by :

Download or read book Preliminary Development and Characterization of a TATB/HMX Plastic-bonded Explosive written by and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Scientific and Technical Aerospace Reports

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ISBN 13 :
Total Pages : 578 pages
Book Rating : 4.:/5 (334 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1981 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.

LASL Explosive Property Data

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Publisher : Univ of California Press
ISBN 13 : 9780520040120
Total Pages : 471 pages
Book Rating : 4.0/5 (41 download)

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Book Synopsis LASL Explosive Property Data by : Terry R. Gibbs

Download or read book LASL Explosive Property Data written by Terry R. Gibbs and published by Univ of California Press. This book was released on 1980 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt:

European Scientific Notes

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ISBN 13 :
Total Pages : 68 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis European Scientific Notes by :

Download or read book European Scientific Notes written by and published by . This book was released on 1991 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energetic Materials

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Publisher : John Wiley & Sons
ISBN 13 : 3527604936
Total Pages : 643 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Energetic Materials by : Ulrich Teipel

Download or read book Energetic Materials written by Ulrich Teipel and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 643 pages. Available in PDF, EPUB and Kindle. Book excerpt: Incorporation of particular components with specialized properties allows one to tailor the end product's properties. For instance, the sensitivity, burning behavior, thermal or mechanical properties or stability of energetic materials can be affected and even controllably varied through incorporation of such ingredients. This book examines particle technologies as applied to energetic materials such as propellants and explosives, thus filling a void in the literature on this subject. Following an introduction covering general features of energetic materials, the first section of this book describes methods of manufacturing particulate energetic materials, including size reduction, crystallization, atomization, particle formation using supercritical fluids and microencapsulation, agglomeration phenomena, special considerations in mixing explosive particles and the production of nanoparticles. The second section discusses the characterization of particulate materials. Techniques and methods such as particle size analysis, morphology elucidation and the determination of chemical and thermal properties are presented. The wettability of powders and rheological behavior of suspensions and solids are also considered. Furthermore, methods of determining the performance of particular energetic materials are described. Each chapter deals with fundamentals and application possibilities of the various methods presented, with particular emphasis on issues applicable to particulate energetic materials. The book is thus equally relevant for chemists, physicists, material scientists, chemical and mechanical engineers and anyone interested or engaged in particle processing and characterization technologies.

High-Pressure Shock Compression of Solids II

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Publisher : Springer Science & Business Media
ISBN 13 : 1461223202
Total Pages : 496 pages
Book Rating : 4.4/5 (612 download)

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Book Synopsis High-Pressure Shock Compression of Solids II by : Lee Davison

Download or read book High-Pressure Shock Compression of Solids II written by Lee Davison and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume concerns the fracture and fragmentation of solid materials that occurs when they are subjected to extremes of stress applied at the highest possible rates. The plan for the volume is to address experimental, theoretical, and com putational aspects of high-rate dynamic fracture and fragmentation, with emphasis on recent work. We begin with several chapters in which the emphasis falls on experimental methods and observations. These chapters address both macroscopic responses and the microscopic cause of these re sponses. This is followed by several chapters emphasizing modeling-the physical explanation and mathematical representation of the observations. Some of the models are deterministic, while others focus on the stochastic aspects of the observations. Often, the ov\!rall objective of investigation of dynamic fracture and fragmentation phenomena is provision of a means for predicting the entire course of an event that begins with a stimulus such as an impact and proceeds through a complicated deformation and fracture pro cess that results in disintegration of the body and formation of a rapidly expanding cloud of debris fragments. Analysis of this event usually involves development of a continuum theory and computer code that captures the experimental observations by incorporating models of the important pheno mena into a comprehensive description of the deformation and fracture pro cess. It is to this task that the work of the last few chapters is devoted.

Unified Constitutive Equations for Creep and Plasticity

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Publisher : Springer Science & Business Media
ISBN 13 : 9400934394
Total Pages : 351 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Unified Constitutive Equations for Creep and Plasticity by : A.K. Miller

Download or read book Unified Constitutive Equations for Creep and Plasticity written by A.K. Miller and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: Constitutive equations refer to 'the equations that constitute the material response' at any point within an object. They are one of the ingredients necessary to predict the deformation and fracture response of solid bodies (among other ingredients such as the equations of equilibrium and compatibility and mathematical descriptions of the configuration and loading history). These ingredients are generally combined together in complicated computer programs, such as finite element analyses, which serve to both codify the pertinent knowledge and to provide convenient tools for making predictions of peak stresses, plastic strain ranges, crack growth rates, and other quantities of interest. Such predictions fall largely into two classes: structural analysis and manufacturing analysis. In the first category, the usual purpose is life prediction, for assessment of safety, reliability, durability, and/or operational strategies. Some high-technology systems limited by mechanical behavior, and therefore requiring accurate life assess ments, include rocket engines (the space-shuttle main engine being a prominent example), piping and pressure vessels in nuclear and non-nuclear power plants (for example, heat exchanger tubes in solar central receivers and reformer tubes in high-temperature gas-cooled reactors used for process heat applications), and the ubiquitous example of the jet engine turbine blade. In structural analysis, one is sometimes concerned with predicting distortion per se, but more often, one is concerned with predicting fracture; in these cases the informa tion about deformation is an intermediate result en route to the final goal of a life prediction.

Military Explosives

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Publisher : Legare Street Press
ISBN 13 : 9781016219969
Total Pages : 0 pages
Book Rating : 4.2/5 (199 download)

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Book Synopsis Military Explosives by : Ordnance Department

Download or read book Military Explosives written by Ordnance Department and published by Legare Street Press. This book was released on 2022-10-27 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work is in the "public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.

Nondestructive Characterization of Materials IV

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Publisher : Springer Science & Business Media
ISBN 13 : 1489906703
Total Pages : 506 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Nondestructive Characterization of Materials IV by : J.F. Bussière

Download or read book Nondestructive Characterization of Materials IV written by J.F. Bussière and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a great deal of interest in extending nondestructive technologies beyond the location and identification of cracks and voids. Specifically there is growing interest in the application of nondestructive evaluation (NOEl to the measurement of physical and mechanical properties of materials. The measurement of materials properties is often referred to as materials characterization; thus nondestructive techniques applied to characterization become nondestructive characterization (NDCl. There are a number of meetings, proceedings and journals focused upon nondestructive technologies and the detection and identification of cracks and voids. However, the series of symposia, of which these proceedings represent the fourth, are the only meetings uniquely focused upon nondestructive characterization. Moreover, these symposia are especially concerned with stimulating communication between the materials, mechanical and manufacturing engineer and the NDE technology oriented engineer and scientist. These symposia recognize that it is the welding of these areas of expertise that is necessary for practical development and application of NDC technology to measurements of components for in service life time and sensor technology for intelligent processing of materials. These proceedings are from the fourth international symposia and are edited by c.o. Ruud, J. F. Bussiere and R.E. Green, Jr. . The dates, places, etc of the symposia held to date area as follows: Symposia on Nondestructive Methods for TITLE: Material Property Determination DATES: April 6-8, 1983 PLACE: Hershey, PA, USA CHAIRPERSONS: C.O. Ruud and R.E. Green, Jr.

Explosive Effects and Applications

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Publisher : Springer Science & Business Media
ISBN 13 : 1461205891
Total Pages : 440 pages
Book Rating : 4.4/5 (612 download)

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Book Synopsis Explosive Effects and Applications by : Jonas A. Zukas

Download or read book Explosive Effects and Applications written by Jonas A. Zukas and published by Springer Science & Business Media. This book was released on 2013-12-01 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a broad-based text on the fundamentals of explosive behavior and the application of explosives in civil engineering, industrial processes, aerospace applications, and military uses.

The Preparatory Manual of Explosives

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Publisher : Independently Published
ISBN 13 : 9781790329137
Total Pages : 350 pages
Book Rating : 4.3/5 (291 download)

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Book Synopsis The Preparatory Manual of Explosives by : Jared Ledgard

Download or read book The Preparatory Manual of Explosives written by Jared Ledgard and published by Independently Published. This book was released on 2018-11-25 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Preparatory Manual of Explosives: Radical, Extreme, Experimental Explosives Chemistry Vol.1 is broken down into Section 1: a) Introduction; b) Dual bonding; c) The Element Nitrogen; d) The element oxygen; e) The element chlorine; f) Introduction to filtration; 1) Gravity filtration; a) Fluting Filter Paper for use in gravity filtration; 2) Vacuum Filtration (suction filtration); a) General Laboratory Techniques: Methods of heating; 1) Free flame; 2) Steam bath, or water bath; 3) Oil bath; 4) Electric Heating Mantles; 5) Hot Plates; a) Methods of Cooling; 1) Cold water bath; 2) Ice water bath; 3) Standard ice bath; 4) Salt/ice bath; 5) Dry ice/acetone bath; a) Cooling tricks of the trade; b) Recrystallization, and solid product recovery; c) Recrystallization; 1) General recrystallization utilizing heat only; a) Working example of recrystallization using heat only; 2) Recrystallization using seed crystals; 3) Recovering the product through low heat and vacuum; a) Washing liquids; b) Washing solids using non-vacuum techniques; c) Washing solids using vacuum techniques; d) Drying solids; e) Drying liquids to remove water; f) Laboratory safety; g) Laboratory glassware; h) Laboratory equipment; Section 2: Intermediates, Reagents, and Solvents; Section 3: Experimental Explosives Chemistry; Theoretical Preparation 1: 1,3,5-trinitrohexazinane; Azinane; Theoretical Preparation 2: trisodium hexazinane-1,3,5-triide; SOD; Theoretical Preparation 3: 3,3',3''-hexazinane-1,3,5-triyltris(triaza-1,2-dien-2-ium-1-ide); HEXAAZIDE; HTA; Theoretical Preparation 4: diammonium trioxidane-1,3-diide; diammonium trioxide; DATD; Theoretical Preparation 5: 3,3'-trioxidane-1,3-diylbis(triaza-1,2-dien-2-ium-1-ide); TDTD; Theoretical Preparation 6: benzene-1,3,5-triyltris(chlorane) nonaoxide; BTCN; Chlorane; Theoretical Preparation 7: 2,4,6-trinitro-1,3,5,2,4,6-trioxatriazinane; TNTOTA; oxatriazinane; Theoretical Preparation 8: (2,4,6-trinitrobenzene-1,3,5-triyl)tris(chlorane) nonaoxide; Chlorane; Theoretical Preparation 9: 1,3,5-triazido-2,4,6-trinitrobenzene; Nitrazide; TATNB; Theoretical Preparation 10: 1,3,5-trinitrohexasilinane; nitrosilane; 2-TNHS; Theoretical Preparation 11: 1,3,5-trinitro-1,3,5-tris(nitrooxy)hexasilinane-1,3,5-triium; TNNHS; Si-135; Theoretical Preparation 12: 1,3,5-trinitrohexaphosphinane; TNHP; High Explosive Phosphorus; Theoretical Preparation 13: pentanitro-l5-phosphane; 5-PNP; Theoretical Preparation 14: trinitroamine oxide; TNAOX; NITROXIDE; Theoretical Preparation 15: pentachloryl-l5-phosphane; Theoretical Preparation 16: Tetranitrodiborane; TNDB; Nitro Boron; Theoretical Preparation 17: 1,2,3,4,5,6-hexanitrocyclohexaborane; KNCHB; 6-Nitrocycloborane; Theoretical Preparation 18: N'-perchlorylperchloric hydrazide; N'PCPH, Perchloryl hydrazine; Theoretical Preparation 19: tetranitrohydrazine; TNH-X; Theoretical Preparation 20: hexaaza-1,2,4,5-tetraene-2,5-diium-1,6-diide; Hexazide; HTDD; Theoretical Preparation 21: hexaazidobenzene; HAAB; 6-Azide; Theoretical Preparation 22: 1,2,3,4,5,6-hexanitro-1l4,2l4,3l4,4l4,5l4,6l4-hexathiine; Nitro hexathiine; Gamma-HNH; Theoretical Preparation 23: pentakis(dioxidobromanyl)-l5-chlorane; Chlorane; pentabromate chloride; PDDBC; Theoretical Preparation 24: hexa-1,3,5-triyne-1,6-diyl dinitrate; HTDD; poly acetylene dinitrate; Theoretical Preparation 25: 1,2,3,4,5,6-hexanitrohexa-1,3,5-triene-1,6-diyl dinitrate; HNHTDD; Hexanitro-Triene; Triene dinitrate; Theoretical Preparation 26: (1Z,3E,5Z)-1,2,3,4,5,6-hexaazidohexa-1,3,5-triene-1,6-diyl dinitrate; EZ-Azido Triene; HAHTDN; Theoretical Preparation 27: 1,2,3,4,5,6-hexafluoro-1,2,3,4,5,6-hexaperchlorylhexane-1,6-diyl dinitrate; Fluoroperchlorylhexane; HFGPHDD; Theoretical Preparation 28: 3,3':4',3''-ter-1,2-dioxetane-4,4''-diyl dinitrate; Dioxetane; Dioxetane dinitrate; ter-DDD; Theoretical Preparation 29: 2H,3'H,3"H-2,2':3',2"-teraluminum-3,3"-diyl dinitrate; Aluminum-3H-dinitrate; Aluminum-3-3-dinitrate; 2H'3H'-Aluminum d

Chemical Rocket Propulsion

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Publisher : Springer
ISBN 13 : 3319277480
Total Pages : 1069 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Chemical Rocket Propulsion by : Luigi T. De Luca

Download or read book Chemical Rocket Propulsion written by Luigi T. De Luca and published by Springer. This book was released on 2016-08-19 with total page 1069 pages. Available in PDF, EPUB and Kindle. Book excerpt: Developed and expanded from the work presented at the New Energetic Materials and Propulsion Techniques for Space Exploration workshop in June 2014, this book contains new scientific results, up-to-date reviews, and inspiring perspectives in a number of areas related to the energetic aspects of chemical rocket propulsion. This collection covers the entire life of energetic materials from their conceptual formulation to practical manufacturing; it includes coverage of theoretical and experimental ballistics, performance properties, as well as laboratory-scale and full system-scale, handling, hazards, environment, ageing, and disposal. Chemical Rocket Propulsion is a unique work, where a selection of accomplished experts from the pioneering era of space propulsion and current technologists from the most advanced international laboratories discuss the future of chemical rocket propulsion for access to, and exploration of, space. It will be of interest to both postgraduate and final-year undergraduate students in aerospace engineering, and practicing aeronautical engineers and designers, especially those with an interest in propulsion, as well as researchers in energetic materials.

High Energy Materials

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Publisher : John Wiley & Sons
ISBN 13 : 3527802681
Total Pages : 499 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis High Energy Materials by : Jai Prakash Agrawal

Download or read book High Energy Materials written by Jai Prakash Agrawal and published by John Wiley & Sons. This book was released on 2015-11-20 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: Authored by an insider with over 40 years of high energy materials (HEMs) experience in academia, industry and defense organizations, this handbook and ready reference covers all important HEMs from the 1950s to the present with their respective properties and intended purposes. Written at an attainable level for professionals, engineers and technicians alike, the book provides a comprehensive view of the current status and suggests further directions for research and development. An introductory chapter on the chemical and thermodynamic basics allows the reader to become acquainted with the fundamental features of explosives, before moving on to the important safety aspects in processing, handling, transportation and storage of high energy materials. With its collation of results and formulation strategies hitherto scattered in the literature, this should be on the shelf of every HEM researcher and developer.