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Non Aqueous Solvents
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Author :John R. Chipperfield Publisher :Oxford University Press on Demand ISBN 13 :9780198502593 Total Pages :86 pages Book Rating :4.5/5 (25 download)
Book Synopsis Non-aqueous Solvents by : John R. Chipperfield
Download or read book Non-aqueous Solvents written by John R. Chipperfield and published by Oxford University Press on Demand. This book was released on 1999 with total page 86 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solvents other than water are used in chemical analysis, chemical manufacturing, and in specialized syntheses. This book covers the principles and uses of non-aqueous solvents at a level suitable for first or second-year undergraduates. The book first discusses the general properties of solvents, and introduces the necessary concepts for making rational choices of solvents for different applications. There is a discussion of the various chemical interactions between solvents and the substances dissolved in them, and how solvents change the course of reactions. The chemistry of 16 common solvents is discussed, emphasizing the advantages and disadvantages of each. The book concludes with an account of the chemistry of molten salts and discusses the use of low melting temperature compounds as synthetic media. The book expands on the brief treatment of non-aqueous solvents given in many textbooks while avoiding the complexities introduced in research treatises. It is the only book currently available that provides an in-depth treatment accessible to undergraduates.
Book Synopsis Electrochemistry in Nonaqueous Solutions by : Kosuke Izutsu
Download or read book Electrochemistry in Nonaqueous Solutions written by Kosuke Izutsu and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Book Synopsis Inorganic Chemistry in Nonaqueous Solvents by : Arthur Kenneth Holliday
Download or read book Inorganic Chemistry in Nonaqueous Solvents written by Arthur Kenneth Holliday and published by Pergamon. This book was released on 1965 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents by : K. Burger
Download or read book Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents written by K. Burger and published by Elsevier. This book was released on 2012-12-02 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
Book Synopsis Coordination Chemistry in Non-Aqueous Solutions by : Victor Gutmann
Download or read book Coordination Chemistry in Non-Aqueous Solutions written by Victor Gutmann and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt: Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.
Book Synopsis Carbon Dioxide in Non-aqueous Solvents at Pressures Less Than 200 KPA by :
Download or read book Carbon Dioxide in Non-aqueous Solvents at Pressures Less Than 200 KPA written by and published by . This book was released on 1992 with total page 483 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Buffers for pH and Metal Ion Control by : D. Perrin
Download or read book Buffers for pH and Metal Ion Control written by D. Perrin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is intended as a practical manual for chemists, biologists and others whose work requires the use of pH or metal-ion buffers. Much information on buffers is scattered throughout the literature and it has been our endeavour to select data and instructions likely to be helpful in the choice of suitable buffer substances and for the preparation of appropriate solutions. For details of pH measurement and the preparation of standard acid and alkali solutions the reader is referred to a companion volume, A. Albert and E. P. Serjeant's The Determination of Ionization Constants (1971). Although the aims of the book are essentially practical, it also deals in some detail with those theoretical aspects considered most helpful to an understanding of buffer applications. We have cast our net widely to include pH buffers for particular purposes and for measurements in non-aqueous and mixed solvent systems. In recent years there has been a significant expansion in the range of available buffers, particularly for biological studies, largely in conse quence of the development of many zwiUerionic buffers by Good et al. (1966). These are described in Chapter 3.
Book Synopsis Enzymes in Nonaqueous Solvents by : Evgeny N. Vulfson
Download or read book Enzymes in Nonaqueous Solvents written by Evgeny N. Vulfson and published by Humana. This book was released on 2010-11-19 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Enzymatic catalysis has gained considerable attention in recent years as an efficient tool in the preparation of natural products, pharmaceuticals, fine chemicals, and food ingredients. The high selectivity and mild reaction con- tions associated with enzymatic transformations have made this approach an attractive alternative in the synthesis of complex bioactive compounds, which are often difficult to obtain by standard chemical routes. However, the maj- ity of organic compounds are not very soluble in water, which was traditi- ally perceived as the only suitable reaction medium for the application of biocatalysts. The realization that most enzymes can function perfectly well under nearly anhydrous conditions and, in addition, display a number of useful properties, e. g. , highly enhanced stability and different selectivity, has d- matically widened the scope of their application to the organic synthesis. Another great attraction of using organic solvents rather than water as a reaction solvent is the ability to perform synthetic transformations with re- tively inexpensive hydrolytic enzymes. It is worth reminding the reader that in vivo, the synthetic and hydrolytic pathways are catalyzed by different enzymes. However, elimination of water from the reaction mixture enables the “reversal” of hydrolytic enzymes and thus avoids the use of the expensive cofactors or activated substrates that are required for their synthetic count- parts.
Book Synopsis Chemistry in Non-Aqueous Solvents by : B. Trémillon
Download or read book Chemistry in Non-Aqueous Solvents written by B. Trémillon and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Arising no doubt from its pre-eminence as a natural liquid, water has always been considered by chemists as the original solvent in which very varied chemical reactions can take place, both for preparational and for analytical purposes. This explains the very long-standing interest shown in the study of aqueous solutions. In this con nection, it must be stressed that the theory of Arrhenius and Ostwald (1887-1894) on electrolytic dissociation, was originally devised solely for solutions in water and that the first true concept of acidity resulting from this is linked to the use of this solvent. The more recent development of numerous physico-chemical measurement methods has made possible an increase of knowledge in this area up to an extremely advanced degree of systematization. Thus today we have available both a very large amount of experimental data, together with very refined methods of deduction and of quantitative treatment of chemical reactions in solution which enable us to make the fullest use of this data. Nevertheless, . it appears quite evident at present that there are numerous chemical processes which cannot take place in water, and that its use as a solvent imposes 2 INTRODUCTION limitations. In order to overcome these limitations, it was natural that interest should be attracted to solvents other than water and that the new possibilities thus opened up should be explored.
Book Synopsis Diffusion and Electrophoretic NMR by : Peter Stilbs
Download or read book Diffusion and Electrophoretic NMR written by Peter Stilbs and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-08-19 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diffusion and Eletrophoretic NMR experiments resolve chemical compounds based on their molecular motion. This publication introduces the basics of these methods and explains how they can be used to measure the size of molecules and aggregates, to determine degree of polymerization and to solve other chemical problems. Supplied with many case studies, the book is a must-have for students and researchers who work with practical NMR measurements.
Book Synopsis Nonaqueous Electrochemistry by : Doron Aurbach
Download or read book Nonaqueous Electrochemistry written by Doron Aurbach and published by CRC Press. This book was released on 1999-07-27 with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt: An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.
Download or read book Acids and Bases written by Brian G. Cox and published by Oxford University Press. This book was released on 2013-01-31 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book seeks to enhance our understanding of acids and bases by reviewing and analysing their behaviour in non-aqueous solvents. The behaviour is related where possible to that in water, but correlations and contrasts between solvents are also presented.
Download or read book Ph Measurements written by C Westcott and published by Elsevier. This book was released on 2012-12-02 with total page 185 pages. Available in PDF, EPUB and Kindle. Book excerpt: pH Measurements is a seven-chapter simplified text on obtaining a high degree of accuracy in practical pH measurement. The introductory chapter of this book relates the principles of pH measurements to the actual measurement. This chapter specifically tackles the factors involved in the measurement and what magnitude of effect does each factor have on the measurement. These topics are followed by discussions on the components of pH equipment and technique, including the electrodes and buffers. A chapter considers the general approach of pH measurements and illustrates with examples of some common difficult samples. The concluding chapter shows the isolation and correction a pH equipment malfunction. pH equipment operators and users will find this book rewarding.
Book Synopsis Physical Chemistry of Organic Solvent Systems by : A. Covington
Download or read book Physical Chemistry of Organic Solvent Systems written by A. Covington and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 821 pages. Available in PDF, EPUB and Kindle. Book excerpt: We believe this to be the first monograph devoted to the physicochemical properties of solutions in organic solvent systems. Although there have 1 been a number of books on the subject of non-aqueous solvents - 4, they have been devoted, almost entirely, to inorganic solvents such as liquid ammonia, liquid sulphur dioxide, etc. A variety of new solvents such as dimethylformamide, dimethylsulphoxide and propylene carbonate have become commercially available over the last twenty years. Solutions in these solvents are of technological interest in connection with novel battery systems and chemical synthesis, while studies of ion solvation and transport properties have fostered academic interest. This monograph is primarily concerned with electrolytic solutions although discussion of non-electrolyte solutions has not been excluded. We have deliberately omitted consideration of the important area of solvent extraction, since this has been adequately covered elsewhere. Our contributors were asked to review and discuss their respective areas with particular reference to differences in technique necessitated by use of non-aqueous solvents while not reiterating facts well-known from experience with aqueous solutions. We have striven to build their contributions into a coherent and consistent whole. We thank our con tributors for following our suggestions so ably and for their forebearance in the face of our editorial impositions.
Book Synopsis Organic Synthesis with Enzymes in Non-Aqueous Media by : Giacomo Carrea
Download or read book Organic Synthesis with Enzymes in Non-Aqueous Media written by Giacomo Carrea and published by John Wiley & Sons. This book was released on 2008-04-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Closing a gap in the literature, this comprehensive book examines and discusses different non-aqueous systems from organic solvents to ionic liquids for synthetic applications, thus opening the door to new successful methods for biocatalytic reactions. It gathers into one handy source the information otherwise widely spread throughout the literature, combining useful background information with a number of synthetic examples, including industrial scale processes for pharmaceutical and fine chemicals. Extremely well structured, the text introduces the fundamentals of non-aqueous enzymology, before going on to new reaction media and synthetic applications using hydrolases and non-hydrolytic enzymes. The one-stop reference for everyone working in this hot field.
Book Synopsis Titrations in Nonaqueous Solvents by : Huber Walter
Download or read book Titrations in Nonaqueous Solvents written by Huber Walter and published by Elsevier. This book was released on 2012-12-02 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: Titrations in Nonaqueous Solvents discuss the theory, practice, and data on acidic and basic strength of nonaqueous solvents. This book is organized into three parts encompassing six chapters. The first part considers the general principles of acids and bases and methods of end-point determination. This part also covers the fundamentals, advantages, and limitations of titration instruments, such as potentiometers, burets, titration vessels, and electrodes. The classification of titration solvents according to their functions as color indicators and titrant solutions is provided in this part. The remaining parts describe the analytical procedures for acidity and basicity of nonaqueous solvents. These parts also provide a tabulated data on the acidic and basic strengths, stability, and dissociation constants of various titration solvents. Analytical chemists, and analytical chemistry teachers and students will find this book invaluable.
Book Synopsis Chemistry in Non-aqueous Solvents by : Harry Hall Sisler
Download or read book Chemistry in Non-aqueous Solvents written by Harry Hall Sisler and published by . This book was released on 1961 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:
