Natural Rubber Biosynthesis

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Publisher :
ISBN 13 :
Total Pages : 218 pages
Book Rating : 4.:/5 (883 download)

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Book Synopsis Natural Rubber Biosynthesis by : Cheng Ching Kurt Chiang

Download or read book Natural Rubber Biosynthesis written by Cheng Ching Kurt Chiang and published by . This book was released on 2013 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural Rubber (NR) is an important strategic raw material for manufacturing a wide variety of industrial products. NR has been mainly obtained from Hevea brasiliensis. The USA is self-sufficient in the production of synthetic rubber while NR supply in USA is mainly imported from Southeast Asia. However, synthetic rubber cannot match the performance of imported Hevea NR. It is a matter of great concern that the USA is highly vulnerable to disruptions of NR supply because of a possible introduction of leaf blight into plantations as none of the trees in plantations across Southeast Asia have resistance to blight. Puskas et al. postulated that the biosynthesis of polyisoprenoids in general, and that of NR in particular, may proceed by a living carbocationic polymerization process. "Natural living carbocationic polymerization" (NLCP) mechanism was proposed in terms of accepted polymer chemical formalism, i.e., initiation, propagation, and equilibria between active and dormant species. This thesis studied the fundamental steps of NR biosynthesis in two ways: 1) characterization of NR from stabilized latex and in vitro biosynthesis; 2) addition of isoprene (IP) and other derivatives to shift the enzymatic equilibrium of the terpenoid biosynthesis lifecycle. Synthetic initiators to be used in in vitro NR biosynthesis system were prepared and characterized. For the first portion of this thesis, in vitro NR biosynthesis was studied using high resolution size exclusion chromatography (HR-SEC). Then, various compounds such as isoprene (IP) and amylene were introduced to the in vitro NR biosynthesis system. The rationale behind these studies was based on the terpenoid biosynthesis lifecycle. HRSEC, gravimetric analysis, in situ Raman spectroscopy and NMR spectroscopy were used to study scenarios where the equilibrium was disrupted by the introduction of foreign chemical compounds. The second goal of this research was to design and synthesize a synthetic initiator for the future synthesis in vitro of a novel polyisobutylene-block-cis-1,4-polyisoprene (PIB-b-NR) diblock copolymer. Two feasible synthetic pathways were developed to yield the target synthetic initiator: one by conventional syntheses and the other through an enzymatic pathway. The ultimate purpose of this synthetic initiator is to explore if the cis-prenyltransferase enzyme will recognize the compound and eventually apply this concept to novel terpenoids/NR in vitro. A seven-step synthetic strategy for the preparation of the PIB-NPP synthetic initiator is proposed and presented.

Chemistry, Manufacture and Applications of Natural Rubber

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Publisher : Woodhead Publishing
ISBN 13 : 0128188448
Total Pages : 508 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Chemistry, Manufacture and Applications of Natural Rubber by : Shinzo Kohjiya

Download or read book Chemistry, Manufacture and Applications of Natural Rubber written by Shinzo Kohjiya and published by Woodhead Publishing. This book was released on 2021-03-24 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry, Manufacture and Applications of Natural Rubber, Second Edition presents the latest advances in the processing, properties and advanced applications of natural rubber (NR), drawing on state-of-the-art research in the field. Chapters cover manufacturing, processing and properties of natural rubber, describing biosynthesis, vulcanization for improved performance, strain-induced crystallization, self-reinforcement, rheology and mechanochemistry for processing, computer simulation of properties, scattering techniques and stabilizing agents. Applications covered include natural rubber, carbon allotropes, eco-friendly soft bio-composites using NR matrices and marine products, the use of NR for high functionality such as shape memory, NR for the tire industry, and natural rubber latex with advanced applications. This is an essential resource for academic researchers, scientists and (post)graduate students in rubber science, polymer science, materials science and engineering, and chemistry. In industry, this book enables professionals, R&D, and producers across the natural rubber, tire, rubber and elastomer industries, as well as across industries looking to use natural rubber products, to understand and utilize natural rubber for cutting-edge applications. Explains the latest manufacture and processing techniques for natural rubber (NR) with enhanced properties Explores novel applications of natural rubber across a range of industries, including current and potential uses Discusses resources and utilization, and considers sustainable future development of natural rubber

Carbocationic Polymerization

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ISBN 13 :
Total Pages : 552 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Carbocationic Polymerization by : Joseph P. Kennedy

Download or read book Carbocationic Polymerization written by Joseph P. Kennedy and published by . This book was released on 1982-02-22 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents a new and unified, view of carbocationic polymers, demonstrating the prodigious promise and unexploited possibilities in the field. Clarifies the tremendous advances made in the past decade in the elucidation of cationic polymerization, and the exploitation of new mechanistic information in terms of new products and processes in the laboratory.

The Rubber Tree Genome

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Publisher : Springer
ISBN 13 : 9783030422608
Total Pages : 175 pages
Book Rating : 4.4/5 (226 download)

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Book Synopsis The Rubber Tree Genome by : Minami Matsui

Download or read book The Rubber Tree Genome written by Minami Matsui and published by Springer. This book was released on 2021-05-04 with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the first comprehensive compilation of genome research on the Hevea brasiliensis rubber tree. The genomes of Hevea tree clones (cultivars) are described by three major international groups. Chapters on omics-driven investigations address a broad range of topics including genome annotation and utilisation, transcriptome and gene family analysis, genetic mapping, metabolic pathways in latex and molecular breeding. Additionally, an overview of fundamental rubber biology, especially on laticifers, provides a historical background that is relevant to rubber genome analysis. The book concludes with several perspectives on the future needs of rubber investigations and prospects of rubber genomics. Given the scope of topics, this book will appeal to researchers and university students working in genomics and biotechnology of the rubber tree, and to rubber breeders with an interest in non-conventional approaches to trait analysis, selection and breeding.

The Role of Small Rubber Particle Proteins in Rubber Biosynthesis

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Publisher :
ISBN 13 :
Total Pages : 224 pages
Book Rating : 4.:/5 (662 download)

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Book Synopsis The Role of Small Rubber Particle Proteins in Rubber Biosynthesis by : Jillian E. Collins

Download or read book The Role of Small Rubber Particle Proteins in Rubber Biosynthesis written by Jillian E. Collins and published by . This book was released on 2009 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of natural rubber is evident by the fact that it is a natural commodity that is necessary in the manufacturing of thousands of products. Natural rubber (cis -1,4-polyisoprene) is produced in a side branch of the isoprenoid mevalonate pathway, and in all rubber producing plants, it is synthesized in cytosolic vesicles known as rubber particles. Because the proteins that are involved are membrane bound, classic biochemical methods have failed to identify the exact proteins needed for rubber biosynthesis. The rubber transferase is a membrane bound enzyme responsible for elongation of the polymer molecule. Several proteins thought to be the rubber transferase, or proteins associated with the rubber particle membrane and thought to be involved in the rubber transferase complex have been assessed over the past 20 years, including the small rubber particle protein (SRPP). However, there has been a lack of in vivo evidence corroborating in vitro results that have suggested a function in rubber biosynthesis for most of these candidates. The aim of this study is to develop a system to functionally identify and characterize genes/proteins responsible for rubber biosynthesis. Taraxacum kok-saghyz, or Russian dandelion, provides a strong system to study rubber biosynthesis because it produces rubber of similar quality to Hevea brasiliensis, and it is amenable to transformation and greenhouse work and study. Several Russian dandelion SRPPs have been identified in a dandelion root cDNA library. Three of the five SRPPs were also tightly associated with dandelion rubber particles. Transgenic Russian dandelion lines were generated by over-expressing and knocking down the most abundant dandelion SRPP, TKS SRPP1. Results presented here show that SRPP not only influences rubber content in dandelion root, but also has an effect on rubber molecular weight. Broader impacts include using this knowledge to genetically engineer an ideal domestic source of natural rubber.

Natural Rubber Biosynthesis and Physic-Chemical Studies on Plant Derived Latex

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Publisher :
ISBN 13 : 9789533071794
Total Pages : pages
Book Rating : 4.0/5 (717 download)

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Book Synopsis Natural Rubber Biosynthesis and Physic-Chemical Studies on Plant Derived Latex by : Christian Schulze Gronover

Download or read book Natural Rubber Biosynthesis and Physic-Chemical Studies on Plant Derived Latex written by Christian Schulze Gronover and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Magnesium Regulation of Rubber Biosynthesis

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Publisher :
ISBN 13 :
Total Pages : 398 pages
Book Rating : 4.:/5 (35 download)

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Book Synopsis Magnesium Regulation of Rubber Biosynthesis by : Bernardo Moura Torres Da Costa

Download or read book Magnesium Regulation of Rubber Biosynthesis written by Bernardo Moura Torres Da Costa and published by . This book was released on 2006 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Investigating the Biosynthesis of Natural Rubber Through the Characterisation of Rubber Associated Proteins

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ISBN 13 :
Total Pages : 344 pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Investigating the Biosynthesis of Natural Rubber Through the Characterisation of Rubber Associated Proteins by : Daniel Brown (Researcher in life sciences)

Download or read book Investigating the Biosynthesis of Natural Rubber Through the Characterisation of Rubber Associated Proteins written by Daniel Brown (Researcher in life sciences) and published by . This book was released on 2016 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Biology of Hevea Rubber

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Publisher : Springer
ISBN 13 : 331954506X
Total Pages : 252 pages
Book Rating : 4.3/5 (195 download)

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Book Synopsis Biology of Hevea Rubber by : P.M. Priyadarshan

Download or read book Biology of Hevea Rubber written by P.M. Priyadarshan and published by Springer. This book was released on 2017-06-09 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the second edition of this book, the origin, upkeep and latex harvest from the Hevea rubber tree are dealt with succinctly. New chapters have been included on Propagation Systems and Genetic Resources. The importance of Heterozygosis and Breeding is a new theme for the section on Breeding. A new chapter on Genomics and Molecular Breeding that focuses on the latest advancements on gene mapping, marker assisted selection and stimulation has been added. Lastly, ‘textboxes’ that highlight points and topics of significant interest are included in the new addition. Natural rubber has been an essential commodity not only for the tire industry but also for more than 50,000 products that holds elasticity as an attribute. The prime source of natural rubber worldwide is Hevea brasiliensis. Hevea rubber tree is an excellent example of how a soil-tree-atmosphere system can work in tandem. The retrieval of rubber through ‘injuring’ the tree on alternate days or once in three days or once in seven days, is indeed a unique arrangement followed universally that ensures income to the planter almost throughout the year. Every molecule of rubber is the end result of meticulous biochemical changes. Therefore the biology of Hevea rubber tree itself is a subject that aggregates science and technology for the realization of its industrial utility.

Review of Natural Rubber Biosynthesis and Synthesis of Model Intermediates for the Preparation of a Macroinitiator for the in Vitro Synthesis of Polyisobutylene-polyisoprene Diblock Copolymer

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Publisher :
ISBN 13 :
Total Pages : 136 pages
Book Rating : 4.:/5 (294 download)

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Book Synopsis Review of Natural Rubber Biosynthesis and Synthesis of Model Intermediates for the Preparation of a Macroinitiator for the in Vitro Synthesis of Polyisobutylene-polyisoprene Diblock Copolymer by : Emilie Gautriaud

Download or read book Review of Natural Rubber Biosynthesis and Synthesis of Model Intermediates for the Preparation of a Macroinitiator for the in Vitro Synthesis of Polyisobutylene-polyisoprene Diblock Copolymer written by Emilie Gautriaud and published by . This book was released on 2006 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: "A detailed review of the biochemical literature concerning the biosynthesis of polyisoprenes, including natural rubber (NR, cis-1,4-polyisoprene cPIP) by rubber producing plants, and the polymer chemical literature on biomimetic and related syntheses, was made. It led us to postulate that the biosynthesis of polyisoprenoids in general, and that of NR in particular, may proceed by a living carbocationic polymerization process. Our analysis led to the formulation of a 'natural living carbocationic polymerization' (NLCP) mechanism in terms of accepted polymer chemical formalism, i.e., initiation, propagation, and equilibria between active and dormant species. A thorough analysis of the intermediates known to be involved in the biosynthesis of NR is consistent with our postulate. This review of the biochemical literature also inspired the concept of producing new block copolymers utilizing this process and a synthetic macroinitiator. A feasible synthetic pathway was developed to yield the target macroinitiator by combining conventional syntheses and natural rubber biosynthesis. This macroinitiator will consist of a polyisobutylene (PIB) chain carrying a neryl pyrophosphate functional group (PIBNPP) that will be synthesized from PIB-OH made by 'traditional' living carbocationic polymerization. The ultimate purpose is to explore if the cis-prenyltransferase enzyme involved in NR biosynthesis would recognize this new synthetic molecule as an initiator of cis-1,4-polyisoprene, such that this synthetic PIB-NPP macroinitiator would induce NR biosynthesis in vitro, and if so, could be used to produce PIB-b-NR block copolymer. A six-step synthetic strategy for the preparation of the PIB-NPP macroinitiator was proposed. The first three steps were successfully completed. The others were studied by carrying out experiments using model compounds, and the results obtained were extremely promising. In particular, a model molecule was successfully linked to the PIBOH starting material."--Abstract.

The Biosynthesis of Natural Rubber and Other Hydrocarbon Polymers

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Publisher :
ISBN 13 :
Total Pages : 458 pages
Book Rating : 4.:/5 (613 download)

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Book Synopsis The Biosynthesis of Natural Rubber and Other Hydrocarbon Polymers by : K. R. Hirschbuehler

Download or read book The Biosynthesis of Natural Rubber and Other Hydrocarbon Polymers written by K. R. Hirschbuehler and published by . This book was released on 1979 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Biochemistry and Molecular Biology of Plants

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Publisher : John Wiley & Sons
ISBN 13 : 0470714220
Total Pages : 1280 pages
Book Rating : 4.4/5 (77 download)

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Book Synopsis Biochemistry and Molecular Biology of Plants by : Bob B. Buchanan

Download or read book Biochemistry and Molecular Biology of Plants written by Bob B. Buchanan and published by John Wiley & Sons. This book was released on 2015-08-31 with total page 1280 pages. Available in PDF, EPUB and Kindle. Book excerpt: With over 1000 original drawings and 500 photographs, this work offers complete coverage of cell biology, plant physiology and molecular biology.

Medicinal Natural Products

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Publisher : John Wiley & Sons
ISBN 13 : 9780471496410
Total Pages : 524 pages
Book Rating : 4.4/5 (964 download)

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Book Synopsis Medicinal Natural Products by : Paul M. Dewick

Download or read book Medicinal Natural Products written by Paul M. Dewick and published by John Wiley & Sons. This book was released on 2002-01-03 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: This guide covers classes of natural products in medicine, whether derived from plants, micro-organisms or animals. Structured according to biosynthetic pathway, it is written from a chemistry-based approach.

Plant-derived Natural Products

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Publisher : Springer Science & Business Media
ISBN 13 : 0387854983
Total Pages : 588 pages
Book Rating : 4.3/5 (878 download)

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Book Synopsis Plant-derived Natural Products by : Anne E. Osbourn

Download or read book Plant-derived Natural Products written by Anne E. Osbourn and published by Springer Science & Business Media. This book was released on 2009-07-07 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plants produce a huge array of natural products (secondary metabolites). These compounds have important ecological functions, providing protection against attack by herbivores and microbes and serving as attractants for pollinators and seed-dispersing agents. They may also contribute to competition and invasiveness by suppressing the growth of neighboring plant species (a phenomenon known as allelopathy). Humans exploit natural products as sources of drugs, flavoring agents, fragrances and for a wide range of other applications. Rapid progress has been made in recent years in understanding natural product synthesis, regulation and function and the evolution of metabolic diversity. It is timely to bring this information together with contemporary advances in chemistry, plant biology, ecology, agronomy and human health to provide a comprehensive guide to plant-derived natural products. Plant-derived natural products: synthesis, function and application provides an informative and accessible overview of the different facets of the field, ranging from an introduction to the different classes of natural products through developments in natural product chemistry and biology to ecological interactions and the significance of plant-derived natural products for humans. In the final section of the book a series of chapters on new trends covers metabolic engineering, genome-wide approaches, the metabolic consequences of genetic modification, developments in traditional medicines and nutraceuticals, natural products as leads for drug discovery and novel non-food crops.

Natural Rubber

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Publisher : Elsevier
ISBN 13 : 0444597808
Total Pages : 623 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Natural Rubber by : M.R. Sethuraj

Download or read book Natural Rubber written by M.R. Sethuraj and published by Elsevier. This book was released on 2012-12-02 with total page 623 pages. Available in PDF, EPUB and Kindle. Book excerpt: No other book on natural rubber covers such a broad spectrum of subjects as this unique publication. Subjects related to the biology, cultivation and technology of natural rubber are dealt with, along with such important aspects as its history, production and processing, through to its sophisticated engineering applications. Every chapter follows a monograph style of presentation, with comprehensive citations and depth of treatment. Contributions from highly experienced, and still active, renowned scientists reflect the truly international effort to the development of this commodity. In addition to the wealth of information presented, most of the chapters contain elaborate lists of earlier contributions in the respective fields; one chapter each has been included on rubber wood, ancillary products and guayule.

Physiology of Rubber Tree Latex

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Publisher : CRC Press
ISBN 13 : 1351092596
Total Pages : 920 pages
Book Rating : 4.3/5 (51 download)

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Book Synopsis Physiology of Rubber Tree Latex by : J. d'Auzac

Download or read book Physiology of Rubber Tree Latex written by J. d'Auzac and published by CRC Press. This book was released on 2018-01-18 with total page 920 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present work is based on the study of the laticiferous system in Hevea. It therefore covers anatomical, histological, and cytological research on laticifers and latex, together with biochemical and enzymological investigation of latex in vitro. Integration of all these studies led to the investigation of the physiology of the laticiferous function. The work described includes the most important results obtained over a period of nearly a century and the most recent work which has yet to be published.

Structural Characterization of Natural Rubber Analysis of Biosynthesis Mechanism and Non-rubber Components Associated with Rubber Chain

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Publisher :
ISBN 13 :
Total Pages : 358 pages
Book Rating : 4.:/5 (88 download)

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Book Synopsis Structural Characterization of Natural Rubber Analysis of Biosynthesis Mechanism and Non-rubber Components Associated with Rubber Chain by : Porntip Rojruthai

Download or read book Structural Characterization of Natural Rubber Analysis of Biosynthesis Mechanism and Non-rubber Components Associated with Rubber Chain written by Porntip Rojruthai and published by . This book was released on 2009 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: