Nanomaterials via Single-Source Precursors

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Publisher : Elsevier
ISBN 13 : 0128203447
Total Pages : 630 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Nanomaterials via Single-Source Precursors by : Allen W. Apblett

Download or read book Nanomaterials via Single-Source Precursors written by Allen W. Apblett and published by Elsevier. This book was released on 2022-02-19 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials via Single-Source Precursors: Synthesis, Processing and Applications presents recent results and overviews of synthesis, processing, characterization and applications of advanced materials for energy, electronics, biomedicine, sensors and aerospace. A variety of processing methods (vapor, liquid and solid-state) are covered, along with materials, including metals, oxides, semiconductor, sulfides, selenides, nitrides, and carbon-based materials. Production of quantum dots, nanoparticles, thin films and composites are described by a collection of international experts. Given the ability to customize the phase, morphology, and properties of target materials, this "rational approach to synthesis and processing is a disruptive technology for electronic, energy, structural and biomedical (nano)materials and devices. The use of single-source chemical precursors for materials processing technology allows for intimate elemental mixing and hence production of complex materials at temperatures well below traditional physical methods and those involving direct combination of elements. The use of lower temperatures enables thin-film deposition on lightweight polymer substrates and reduces damage to complex devices structures such as used in power, electronics and sensors. - Discusses new approaches to synthesis or single-source precursors (SSPs) and the concept of rational design of materials - Includes materials processing of SSPs in the design of new materials and novel devices - Provides comprehensive coverage of the subject (materials science and chemistry) as related to SSPs and the range of potential applications

Nanoparticles as Reactive Precursors

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (662 download)

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Book Synopsis Nanoparticles as Reactive Precursors by : John C. Bauer

Download or read book Nanoparticles as Reactive Precursors written by John C. Bauer and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Alloys, intermetallic compounds and multi-metal oxides are generally made by traditional solid-state methods that often require melting or grinding/pressing powders followed by high temperature annealing (> 1000 degrees C) for days or weeks. The research presented here takes advantage of the fact that nanoparticles have a large fraction of their atoms on the surface making them highly reactive and their small size virtually eliminates the solid-solid diffusion process as the rate limiting step. Materials that normally require high temperatures and long annealing times become more accessible at relatively low-temperatures because of the increased interfacial contact between the nanoparticle reactants. Metal nanoparticles, formed via reduction of metal salts in an aqueous solution and stabilized by PVP (polyvinylpyrrolidone), were mixed into nanoparticle composites in stoichometric proportions. The composite mixtures were then annealed at relatively low temperatures to form alloy and intermetallic compounds at or below 600 degrees C. This method was further extended to synthesizing multi-metal oxide systems by annealing metal oxide nanoparticle composites hundreds of degrees lower than more traditional methods. Nanoparticles of Pt (supported or unsupported) were added to a metal salt solution of tetraethylene glycol and heated to obtain alloy and intermetallic nanoparticles. The supported intermetallic nanoparticles were tested as catalysts and PtPb/Vulcan XC-72 showed enhanced catalytic activity for formic acid oxidation while Pt3Sn/Vulcan XC-72 and Cu3Pt/y-Al2O3 catalyzed CO oxidiation at lower temperatures than supported Pt. Intermetallic nanoparticles of Pd were synthesized by conversion chemistry methods previously mentioned and were supported on carbon and alumina. These nanoparticles were tested for Suzuki cross-coupling reactions. However; the homocoupled product was generally favored. The catalytic activity of Pd3Pb/y-Al2O3 was tested for the Heck reaction and gave results comparable to Pd/y-Al2O3 with a slightly better selectivity. Conversion chemistry techniques were used to convert Pt nanocubes into Ptbased intermetallic nanocrystals in solution. It was discovered that aggregated clusters of Pt nanoparticles were capable of converting to FePt3; however, when Pt nanocubes were used the intermetallic phase did not form. Alternatively, it was possible to form PtSn nanocubes by a conversion reaction with SnCl2.

Precursor Chemistry of Advanced Materials

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540016052
Total Pages : 240 pages
Book Rating : 4.0/5 (16 download)

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Book Synopsis Precursor Chemistry of Advanced Materials by : Roland A. Fischer

Download or read book Precursor Chemistry of Advanced Materials written by Roland A. Fischer and published by Springer Science & Business Media. This book was released on 2005-09-29 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Material synthesis by the transformation of organometallic compounds (precursors) by vapor deposition techniques such as chemical vapor deposition (CVD) and atomic layer deposition (ALD) has been in the forefront of modern day research and development of new materials. There exists a need for new routes for designing and synthesizing new precursors as well as the application of established molecular precursors to derive tuneable materials for technological demands. With regard to the precursor chemistry, a most detailed understanding of the mechanistic complexity of materials formation from molecular precursors is very important for further development of new processes and advanced materials. To emphasize and stimulate research in these areas, this volume comprises a selection of case studies covering various key-aspects of the interplay of precursor chemistry with the process conditions of materials formation, particularly looking at the similarities and differences of CVD, ALD and nanoparticle synthesis, e.g. colloid chemistry, involving tailored molecular precursors.

Inorganic Nanoparticles

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Publisher : CRC Press
ISBN 13 : 1351833960
Total Pages : 885 pages
Book Rating : 4.3/5 (518 download)

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Book Synopsis Inorganic Nanoparticles by : Claudia Altavilla

Download or read book Inorganic Nanoparticles written by Claudia Altavilla and published by CRC Press. This book was released on 2017-12-19 with total page 885 pages. Available in PDF, EPUB and Kindle. Book excerpt: Among the various nanomaterials, inorganic nanoparticles are extremely important in modern technologies. They can be easily and cheaply synthesized and mass produced, and for this reason, they can also be more readily integrated into applications. Inorganic Nanoparticles: Synthesis, Applications, and Perspectives presents an overview of these special materials and explores the myriad ways in which they are used. It addresses a wide range of topics, including: Application of nanoparticles in magnetic storage media Use of metal and oxide nanoparticles to improve performance of oxide thin films as conducting media in commercial gas and vapor sensors Advances in semiconductors for light-emitting devices and other areas related to the energy sector, such as solar energy and energy storage devices (fuel cells, rechargeable batteries, etc.) The expanding role of nanosized particles in the field of catalysis, art conservation, and biomedicine The book’s contributors address the growing global interest in the application of inorganic nanoparticles in various technological sectors. Discussing advances in materials, device fabrication, and large-scale production—all of which are urgently required to reduce global energy demands—they cover innovations in areas such as solid-state lighting, detailing how it still offers higher efficiency but higher costs, compared to conventional lighting. They also address the impact of nanotechnology in the biomedical field, focusing on topics such as quantum dots for bioimaging, nanoparticle-based cancer therapy, drug delivery, antibacterial agents, and more. Fills the informational gap on the wide range of applications for inorganic nanoparticles in areas including biomedicine, electronics, storage media, conservation of cultural heritage, optics, textiles, and cosmetics Assembling work from an array of experts at the top of their respective fields, this book delivers a useful analysis of the vast scope of existing and potential applications for inorganic nanoparticles. Versatile as either a professional research resource or textbook, this effective tool elucidates fundamentals and current advances associated with design, characterization, and application development of this promising and ever-evolving device.

Reactive Oxygen Species (ROS), Nanoparticles, and Endoplasmic Reticulum (ER) Stress-Induced Cell Death Mechanisms

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Author :
Publisher : Academic Press
ISBN 13 : 0128224967
Total Pages : 782 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Reactive Oxygen Species (ROS), Nanoparticles, and Endoplasmic Reticulum (ER) Stress-Induced Cell Death Mechanisms by : Loutfy H. Madkour

Download or read book Reactive Oxygen Species (ROS), Nanoparticles, and Endoplasmic Reticulum (ER) Stress-Induced Cell Death Mechanisms written by Loutfy H. Madkour and published by Academic Press. This book was released on 2020-06-27 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Oxygen Species (ROS), Nanoparticles, and Endoplasmic Reticulum (ER) Stress-Induced Cell Death Mechanisms presents the role of ROS?mediated pathways cellular signaling stress, endoplasmic reticulum (ER) stress, oxidative stress, oxidative damage, nanomaterials, and the mechanisms by which metalloids and nanoparticles induce their toxic effects. The book covers the ecotoxicology of environmental heavy metal ions and free radicals on macromolecules cells organisms, heavy metals?induced cell responses, oxidative stress, the source of oxidants, and the roles of ROS, oxidative stress and oxidative damage mechanisms. It also examines the nanotoxicity, cytotoxicity and genotoxicity mechanisms of nanomaterials and the effects of nanoparticle interactions. Antioxidant defense therapy and strategies for treatment round out the book, making it an ideal resource for researchers and professional scientists in toxicology, environmental chemistry, environmental science, nanomaterials and the pharmaceutical sciences. - Covers the ecotoxicology of environmental heavy metal ions and the interactions between specific heavy metals?induced cell responses and oxidative stress - Provides a better understanding of the mechanism of nanomaterial-induced toxicity as a first defense for hazard prevention - Covers recent advances in new nanomedication technologies for the effects of NPs on oxidative stress, ROS and ER stress - Discusses the effects of interactions between antioxidant defense therapy, ROS and strategies for treatment

Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 1788018052
Total Pages : 370 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry by : Rafael Luque

Download or read book Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry written by Rafael Luque and published by Royal Society of Chemistry. This book was released on 2019-05-10 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles exhibit a range of different properties when compared to bulk materials. Their high surface-area to volume ratio makes them particularly attractive for use as catalysts and recent years have seen an explosion of research in this area. The ability to fine-tune the size and structure of nanoparticles means that it is possible to design catalytic materials for improved activity or specificity. As catalysis is one of the key technologies for more sustainable production of both chemicals and energy, the past few years have seen increasing numbers of nanomaterials reported for these applications. Depending on the application, a number of different catalyst synthesis and optimization protocols can be used. This book provides comprehensive links between the design and fabrication method for nanoparticles and their catalytic performance (activity, selectivity and stability) in various applications. Presenting an introduction to the concept of catalyst design and recent developments in the preparation and characterisation of nanomaterials, followed by several chapters on the design of catalysts for specific applications, this book is a valuable resource for researchers working on catalytic reactions, industrial processes and nanomaterial applications.

Understanding the Reactivity of Molecular Precursors to Colloidal Nanocrystals

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (931 download)

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Book Synopsis Understanding the Reactivity of Molecular Precursors to Colloidal Nanocrystals by :

Download or read book Understanding the Reactivity of Molecular Precursors to Colloidal Nanocrystals written by and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Colloidal semiconductor nanocrystals are materials with intriguing properties that make them useful for a diverse array of applications such as photocatalysts, light-absorbing materials in solar cells, light emitting diodes and luminescent biological tags, to name only a few. Performance of nanomaterials in these applications is directly related to the size, shape and stoichiometry of the nanocrystals. Strategies exist to control these characteristics during colloidal synthesis, but they tend to rely on certain surfactants, additives, or multi-step procedures to achieve desirable properties. This thesis describes new directions in the synthesis of colloidal nanomaterials that use computational chemistry as a guide. Using new and efficient methods in density functional theory (DFT) to reliably calculate bond dissociation energies (BDEs) of organodichalcogenide (sulfide or selenide) precursors enables the rational synthesis of dot, rod and tetrapod morphology cadmium chalcogenide nanocrystals. Precursors with weaker C-E (E = S, Se) bonds and stronger E-E bonds yielded dot-shaped nanocrystals, while precursors with stronger C-E and weaker E-E bonds afforded rod or tetrapod shapes. This methodology readily extends to the BDE calculation of tertiary phosphine chalcogenides with substituted phenyl, alkyl, perfluoroalkyl moieties or Verkade-type cage structures. In these systems the BDE of a series of P--S or P--Se bonds increases with slightly increasing bond distance, although the BDE of P--Se bonds is significantly lower than P--S bonds. Another promising method in colloidal nanocrystal synthesis is photochemical decomposition of precursors to access unusual phases or shapes. This thesis also describes the photochemical synthesis of cobalt(III) oxyhydroxide, Co(O)OH, nanocrystals from chloropentaamminecobalt(III) salts in aqueous solution. Compared to the thermal decomposition of the starting material in the absence of light, the photochemically-synthesized material exh

Reducing Agents in Colloidal Nanoparticle Synthesis

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Publisher : Royal Society of Chemistry
ISBN 13 : 1839163631
Total Pages : 483 pages
Book Rating : 4.8/5 (391 download)

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Book Synopsis Reducing Agents in Colloidal Nanoparticle Synthesis by : Stefanos Mourdikoudis

Download or read book Reducing Agents in Colloidal Nanoparticle Synthesis written by Stefanos Mourdikoudis and published by Royal Society of Chemistry. This book was released on 2021-05-14 with total page 483 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles can be synthesised via a number of methods, including chemical vapor deposition, ball milling, laser ablation, thermal decomposition and chemical reduction. Chemical reduction is usually preferred, due to its ease and cost-effectiveness. There are several types of compound used as reducing agents in nanoparticle synthesis, and one recent development is the use of biological entities as environmentally friendly reductants. This book will highlight the role of reducing agents in the chemical synthesis of nanoparticle systems, presenting the main categories of reducing agents, which vary on reactivity, selectivity, availability and toxicity. It will provide a comprehensive presentation of both modern and more conventional types of reagents. Emphasis will be given on the presentation not only of the functionality, but also of all the different advantages and limitations of each kind of reducing agent. With contributions from global experts, this title will be appropriate for graduate students and researchers in nanochemistry, colloidal synthesis, inorganic chemistry, organometallic chemistry, chemical engineering, physical chemistry, materials science, biology and physics.

Nanoparticles in Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527346074
Total Pages : 384 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Nanoparticles in Catalysis by : Karine Philippot

Download or read book Nanoparticles in Catalysis written by Karine Philippot and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.

Nanomaterials

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Publisher : Morgan & Claypool Publishers
ISBN 13 : 1643276441
Total Pages : 94 pages
Book Rating : 4.6/5 (432 download)

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Book Synopsis Nanomaterials by : Maria Benelmekki

Download or read book Nanomaterials written by Maria Benelmekki and published by Morgan & Claypool Publishers. This book was released on 2019-05-02 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials and nanostructures are the original product of nanotechnology, and the key building blocks for enabling technologies. In this context, this book presents a concise overview of the synthesis and characterization methods of nanomaterials and nanostructures, while integrating facets of physics, chemistry, and engineering. The book summarizes the fundamentals and technical approaches in synthesis, and processing of nanostructures and nanomaterials, so as the reader can have a systematic and quick picture of the field. This book focuses on functional aspects of nanomaterials that have a high relevance to immediate applications, such as catalysis, energy harvesting, biosensing, and surface functionalization. There are chapters addressing nanostructured materials and composites and covering basic properties and requirements of this new class of engineered materials.

Nanoscale Materials in Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 0470523662
Total Pages : 650 pages
Book Rating : 4.4/5 (75 download)

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Book Synopsis Nanoscale Materials in Chemistry by : Kenneth J. Klabunde

Download or read book Nanoscale Materials in Chemistry written by Kenneth J. Klabunde and published by John Wiley & Sons. This book was released on 2009-10-15 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference on nanoscale materials chemistry—now revised and updated. This extensive text provides twenty-two revised chapters on the preparations, applications, and characterization as well as the environmental and toxicological aspects of nanoscale materials, with an emphasis on the chemistry component. This Second Edition contains core topics including: New synthetic methods for nanomaterials Nanostructured solids Organized two- and three-dimensional nanocrystals Nanotubes, ribbons, and sheets Nanocatalysts, sorbents, and energy applications Unique physical properties of nanomaterials Photochemistry of nanomaterials Biological and environmental aspects of nanomaterials With input from top experts in the field, such as Bruce Dunn, Vicki Grassian, Warren Ford, and Chris Sorensen, among others, Nanoscale Materials in Chemistry presents a balanced survey of different topics in basic nanoparticle science, and includes helpful end-of-chapter questions and answers. Significantly expanded, the Second Edition remains a key text for understanding the fundamentals of nanoscale materials chemistry and a reliable resource for scientists and researchers.

Sustainable Preparation of Metal Nanoparticles

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849734283
Total Pages : 243 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Sustainable Preparation of Metal Nanoparticles by : Rafael Luque

Download or read book Sustainable Preparation of Metal Nanoparticles written by Rafael Luque and published by Royal Society of Chemistry. This book was released on 2013 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: This timely publication bridges and presents the latest trends and updates in three hot topics of current and future society: nanomaterials, energy and environment. It provides the state-of-the-art as well as current challenges and advances in the sustainable preparation of metal nanoparticles and their applications. The book fills a critical gap in a multidisciplinary area of high economic, social and environmental importance. Currently, there are no books published that deal with these ever increasing important topics, as most books in this area focus on a particular topic (eg. nanomaterials or catalysis or energy or environment). This is the first multidisciplinary edited book covering the very basics to the more advanced, trendy developments, containing a unique blend of nano, green, renewable and bio.

Nanoparticles

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Publisher : Springer Science & Business Media
ISBN 13 : 1441990429
Total Pages : 291 pages
Book Rating : 4.4/5 (419 download)

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Book Synopsis Nanoparticles by : Vincent Rotello

Download or read book Nanoparticles written by Vincent Rotello and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: The integration of top-down lithographic techniques with synthetic organic and inorganic technologies is a key challenge for the development of effective nanosca1e devices. In terms of assembly, nanoparticles provide an excellent tool for bridging the gap between the resolution of electron beam lithography (-60 nm) and the molecular level. Nanoparticles possess an array of unique properties associated with their core materials, including distinctive magnetic, photonic and electronic behavior. This behavior can be controlled and applied through monolayer functionalization and assembly strategies, making nanoparticles both scaffolds and building blocks for nanotechnology. The diverse structures and properties of nanoparticles makes them useful tools for both fundamental studies and pragmatic applications in a range of disciplines. This volume is intended to provide an integrated overview of the synthesis and assembly of nanoparticles, and their applications in chemistry, biology, and materials science. The first three chapters focus on the creation and intrinsic properties of nanoparticles, covering some of the myriad core materials and shapes that have been created. The remaining chapters of the book discuss the assembly of nanoparticles, and applications of both discrete particles and particle assemblies in a wide range of fields, including device and sensor fabrication, catalysis, biology, and nanosca1e electronic and magnetic systems.

Nanoparticles

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Publisher :
ISBN 13 :
Total Pages : 474 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Nanoparticles by : American Chemical Society. Meeting

Download or read book Nanoparticles written by American Chemical Society. Meeting and published by . This book was released on 2008 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes recent advances in methods to synthesize, stabilize, passivate and functionalize diverse nanoparticles from metals, metal oxides, semiconductors, polymers, organics and biomolecules. A wide range of potential appplications with nanoparticles as building blocks are described.

Recent Advances in Nanoparticle Catalysis

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Publisher : Springer Nature
ISBN 13 : 3030458237
Total Pages : 460 pages
Book Rating : 4.0/5 (34 download)

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Book Synopsis Recent Advances in Nanoparticle Catalysis by : Piet W.N.M. van Leeuwen

Download or read book Recent Advances in Nanoparticle Catalysis written by Piet W.N.M. van Leeuwen and published by Springer Nature. This book was released on 2020-07-01 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of the latest developments in the field of nanoparticle catalysis. It not only discusses established topics in detail, but also explores several emerging topics. Catalysis with nanoparticles is expanding exponentially and is attracting significant interest due to the many exciting findings being reported. Mastering the synthesis, characterization, stabilization and use of these catalysts offers numerous possibilities that far exceed those of classic heterogeneous and homogeneous catalysis.

Nanotechnology in Catalysis 3

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Publisher : Springer Science & Business Media
ISBN 13 : 0387346880
Total Pages : 342 pages
Book Rating : 4.3/5 (873 download)

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Book Synopsis Nanotechnology in Catalysis 3 by : Bing Zhou

Download or read book Nanotechnology in Catalysis 3 written by Bing Zhou and published by Springer Science & Business Media. This book was released on 2007-09-05 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume continues the tradition formed in Nanotechnology in Catalysis 1 and 2. As with those books, this one is based upon an ACS symposium. Some of the most illustrious names in heterogeneous catalysis are among the contributors. The book covers: Design, synthesis, and control of catalysts at nanoscale; understanding of catalytic reaction at nanometer scale; characterization of nanomaterials as catalysts; nanoparticle metal or metal oxides catalysts; nanomaterials as catalyst supports; new catalytic applications of nanomaterials.

Biomineralization

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Publisher :
ISBN 13 : 9780198508823
Total Pages : 220 pages
Book Rating : 4.5/5 (88 download)

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Book Synopsis Biomineralization by : Stephen Mann

Download or read book Biomineralization written by Stephen Mann and published by . This book was released on 2001 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: