Multicomponent Free Radical Polymerization Model Refinements And Extensions With Depropagation

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Multicomponent Free Radical Polymerization Model Refinements and Extensions with Depropagation

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Author : David Dorschner
Publisher :
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.:/5 (827 download)

Book Synopsis Multicomponent Free Radical Polymerization Model Refinements and Extensions with Depropagation by : David Dorschner

Download or read book Multicomponent Free Radical Polymerization Model Refinements and Extensions with Depropagation written by David Dorschner and published by . This book was released on 2010 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is directed towards expanding and refining a free radical multi-component polymerization model. The model considers up to six monomers (unique in the literature), both in bulk and solution polymerization, for either batch or semi-batch reactor modes. As the simulator database contains 13 monomers, 5 initiators, 4 solvents, 3 chain transfer agents and 2 inhibitors, all tested over a wide range of polymerization conditions, from data in both academic and industrial laboratories, several hundred combinations of ingredients can be modeled. The many outputs generated by the model include conversion, molecular weight, polymer composition, branching indicators, sequence length, as well as many others polymerization characteristics related to both production rate and polymer quality. Although the only literature data found to-date contains a maximum of four monomers, model predictions for homo-, co-, ter- and tetra-polymerizations show reasonable agreement against the data at both regular and elevated temperatures. Recently, with the basic polymerization kinetics modeled sufficiently, several expansions to the simulation software have been added. Specifically, depropagation, multiple initiators, back-biting, and composition control have been incorporated and/or improved, each adding to the advancement of the polymerization simulation tool. Depropagation is a vital mechanism that should be accounted for at elevated temperatures. Currently the software has the functionality to implement depropagation but requires further literature resources for improving the kinetic predictions for conversion and polymer composition. Consequently, depropagation research is ongoing. Back-biting and beta-scission of butyl acrylate (BA) is a recent development in free radical polymerization. The completed extension can model BA under the same diverse conditions as the base model, in homo-, co- and ter-polymerizations with depropagation, if applicable. The ability to generate a polymer with a constant (or controlled) composition throughout the reaction has several practical uses. Originally, three composition control scenarios were considered. At present, several methods as well as combinations of methods have been integrated into the model. With these new expansions and the ability to simulate several initiators at the same time, this model is directed towards becoming a complete free radical polymerization tool for training and educational uses both in industry and academia.

Handbook of Polymer Synthesis, Characterization, and Processing

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Author : Enrique Saldivar-Guerra
Publisher : John Wiley & Sons
ISBN 13 : 0470630329
Total Pages : 660 pages
Book Rating : 4.4/5 (76 download)

Book Synopsis Handbook of Polymer Synthesis, Characterization, and Processing by : Enrique Saldivar-Guerra

Download or read book Handbook of Polymer Synthesis, Characterization, and Processing written by Enrique Saldivar-Guerra and published by John Wiley & Sons. This book was released on 2013-03-04 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering a broad range of polymer science topics, Handbook of Polymer Synthesis, Characterization, and Processing provides polymer industry professionals and researchers in polymer science and technology with a single, comprehensive handbook summarizing all aspects involved in the polymer production chain. The handbook focuses on industrially important polymers, analytical techniques, and formulation methods, with chapters covering step-growth, radical, and co-polymerization, crosslinking and grafting, reaction engineering, advanced technology applications, including conjugated, dendritic, and nanomaterial polymers and emulsions, and characterization methods, including spectroscopy, light scattering, and microscopy.

Modeling and Control of Continuous Free-radical Polymerization

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Author : Siddarth Raman
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (144 download)

Book Synopsis Modeling and Control of Continuous Free-radical Polymerization by : Siddarth Raman

Download or read book Modeling and Control of Continuous Free-radical Polymerization written by Siddarth Raman and published by . This book was released on 2008 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The kinetics of free radical polymerization

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Author : Alastair M. North
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (112 download)

Book Synopsis The kinetics of free radical polymerization by : Alastair M. North

Download or read book The kinetics of free radical polymerization written by Alastair M. North and published by . This book was released on 1966 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Chemistry of Free Radical Polymerization

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Author : Graeme Moad
Publisher : Pergamon
ISBN 13 : 9780080420783
Total Pages : 0 pages
Book Rating : 4.4/5 (27 download)

Book Synopsis The Chemistry of Free Radical Polymerization by : Graeme Moad

Download or read book The Chemistry of Free Radical Polymerization written by Graeme Moad and published by Pergamon. This book was released on 1995 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall aim of this work is to provide a framework for greater understanding of free radical polymerization. Each chapter describes some of the techniques that have been employed to characterize polymers and polymerizations.

Polymer Chemistry

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Author : Timothy P. Lodge
Publisher : CRC Press
ISBN 13 : 1466581654
Total Pages : 676 pages
Book Rating : 4.4/5 (665 download)

Book Synopsis Polymer Chemistry by : Timothy P. Lodge

Download or read book Polymer Chemistry written by Timothy P. Lodge and published by CRC Press. This book was released on 2020-07-14 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: A well-rounded and articulate examination of polymer properties at the molecular level, Polymer Chemistry focuses on fundamental principles based on underlying chemical structures, polymer synthesis, characterization, and properties. It emphasizes the logical progression of concepts and provide mathematical tools as needed as well as fully derived problems for advanced calculations. The much-anticipated Third Edition expands and reorganizes material to better develop polymer chemistry concepts and update the remaining chapters. New examples and problems are also featured throughout. This revised edition: Integrates concepts from physics, biology, materials science, chemical engineering, and statistics as needed Contains mathematical tools and step-by-step derivations for example problems Incorporates new theories and experiments using the latest tools and instrumentation and topics that appear prominently in current polymer science journals The number of homework problems has been greatly increased, to over 350 in all The worked examples and figures have been augmented More examples of relevant synthetic chemistry have been introduced into Chapter 2 ("Step-Growth Polymers") More details about atom-transfer radical polymerization and reversible addition/fragmentation chain-transfer polymerization have been added to Chapter 4 ("Controlled Polymerization") Chapter 7 (renamed "Thermodynamics of Polymer Mixtures") now features a separate section on thermodynamics of polymer blends Chapter 8 (still called "Light Scattering by Polymer Solutions") has been supplemented with an extensive introduction to small-angle neutron scattering Polymer Chemistry, Third Edition offers a logical presentation of topics that can be scaled to meet the needs of introductory as well as more advanced courses in chemistry, materials science, polymer science, and chemical engineering.

Dictionary of Oil, Gas, and Petrochemical Processing

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Author : Alireza Bahadori
Publisher : CRC Press
ISBN 13 : 1466588268
Total Pages : 480 pages
Book Rating : 4.4/5 (665 download)

Book Synopsis Dictionary of Oil, Gas, and Petrochemical Processing by : Alireza Bahadori

Download or read book Dictionary of Oil, Gas, and Petrochemical Processing written by Alireza Bahadori and published by CRC Press. This book was released on 2013-12-04 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: In industry, miscommunication can cause frustration, create downtime, and even trigger equipment failure. By providing a common ground for more effective discourse, the Dictionary of Oil, Gas, and Petrochemical Processing can help eliminate costly miscommunication.An essential resource for oil, gas, and petrochemical industry professionals, enginee

Forensic Examination of Glass and Paint

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Author : Brian Caddy
Publisher : CRC Press
ISBN 13 : 0203483588
Total Pages : 305 pages
Book Rating : 4.2/5 (34 download)

Book Synopsis Forensic Examination of Glass and Paint by : Brian Caddy

Download or read book Forensic Examination of Glass and Paint written by Brian Caddy and published by CRC Press. This book was released on 2001-08-23 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume represents an approach to the analysis of glass and paint as they occur as trace evidence in forensic cases. Each chapter is written by an expert in their particular area. The book is divided into two sections: one referring to paint and one referring to glass. Each section covers an introduction to the composition of these materials an

Publications of the National Bureau of Standards, 1966-1967

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Author : United States. National Bureau of Standards
Publisher :
ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.3/5 (91 download)

Book Synopsis Publications of the National Bureau of Standards, 1966-1967 by : United States. National Bureau of Standards

Download or read book Publications of the National Bureau of Standards, 1966-1967 written by United States. National Bureau of Standards and published by . This book was released on 1969 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Principles of Polymerization

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Author : George Odian
Publisher : John Wiley & Sons
ISBN 13 : 0471274003
Total Pages : 850 pages
Book Rating : 4.4/5 (712 download)

Book Synopsis Principles of Polymerization by : George Odian

Download or read book Principles of Polymerization written by George Odian and published by John Wiley & Sons. This book was released on 2004-02-09 with total page 850 pages. Available in PDF, EPUB and Kindle. Book excerpt: The new edition of a classic text and reference The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: * Metallocene and post-metallocene polymerization catalysts * Living polymerizations (radical, cationic, anionic) * Dendrimer, hyperbranched, brush, and other polymer architectures and assemblies * Graft and block copolymers * High-temperature polymers * Inorganic and organometallic polymers * Conducting polymers * Ring-opening polymer ization * In vivo and in vitro polymerization Appropriate for both novice and advanced students as well as professionals, this comprehensive yet accessible resource enables the reader to achieve an advanced, up-to-date understanding of polymer synthesis. Different methods of polymerization, reaction parameters for synthesis, molecular weight, branching and crosslinking, and the chemical and physical structure of polymers all receive ample coverage. A thorough discussion at the elementary level prefaces each topic, with a more advanced treatment following. Yet the language throughout remains straightforward and geared towards the student. Extensively updated, Principles of Polymerization, Fourth Edition provides an excellent textbook for today's students of polymer chemistry, chemical engineering, and materials science, as well as a current reference for the researcher or other practitioner working in these areas.

Polymer Reaction Engineering

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Author : Jose Asua
Publisher : John Wiley & Sons
ISBN 13 : 0470691425
Total Pages : 392 pages
Book Rating : 4.4/5 (76 download)

Book Synopsis Polymer Reaction Engineering by : Jose Asua

Download or read book Polymer Reaction Engineering written by Jose Asua and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers are an example of “products-by-process”, where the final product properties are mostly determined during manufacture, in the reactor. An understanding of processes occurring in the polymerization reactor is therefore crucial to achieving efficient, consistent, safe and environmentally friendly production of polymeric materials. Polymer Reaction Engineering provides the link between the fundamentals of polymerization kinetics and polymer microstructure achieved in the reactor. Organized according to the type of polymerization, each chapter starts with a description of the main polymers produced by the particular method, their key microstructural features and their applications Polymerization kinetics and its effect on reactor configuration, mass and energy balances and scale-up are covered in detail. The text is illustrated with examples emphasizing general concepts, principles and methodology. Written as an authoritative guide for chemists and chemical engineers in industry and academe, Polymer Reaction Engineering will also be a key reference source for advanced courses in polymer chemistry and technology.

Handbook of Thermoset Plastics

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Author : A. Gandini
Publisher : Elsevier Inc. Chapters
ISBN 13 : 0128090642
Total Pages : 50 pages
Book Rating : 4.1/5 (28 download)

Book Synopsis Handbook of Thermoset Plastics by : A. Gandini

Download or read book Handbook of Thermoset Plastics written by A. Gandini and published by Elsevier Inc. Chapters. This book was released on 2013-11-28 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer networks derived from furan monomers are discussed, with particular emphasis on recent contributions. Resins based on furfural and furfuryl alcohol represent the most important family within this context, but other materials are becoming relevant, such as polyurethane foams, various photo-curable macromolecules bearing furan rings within the chain (or pendant to it), conjugated cross-linked poly(2-vinylfuran) as proton traps, and thermo-reversible networks prepared by Diels-Alder polycondensations involving furan and maleimide moieties.

Polymer Process Engineering

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Author : Eric A. Grulke
Publisher : Prentice Hall
ISBN 13 :
Total Pages : 694 pages
Book Rating : 4.3/5 (91 download)

Book Synopsis Polymer Process Engineering by : Eric A. Grulke

Download or read book Polymer Process Engineering written by Eric A. Grulke and published by Prentice Hall. This book was released on 1994 with total page 694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an overview of both the basic science composition, morphology, physical states, and properties of polymers as well as quantitative engineering tools required to design polymer systems.

Dielectric Polymer Materials for High-Density Energy Storage

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Author : Zhi-Min Dang
Publisher : William Andrew
ISBN 13 : 0128132167
Total Pages : 502 pages
Book Rating : 4.1/5 (281 download)

Book Synopsis Dielectric Polymer Materials for High-Density Energy Storage by : Zhi-Min Dang

Download or read book Dielectric Polymer Materials for High-Density Energy Storage written by Zhi-Min Dang and published by William Andrew. This book was released on 2018-06-13 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dielectric Polymer Materials for High-Density Energy Storage begins by introducing the fundamentals and basic theories on the dielectric behavior of material. It then discusses key issues on the design and preparation of dielectric polymer materials with strong energy storage properties, including their characterization, properties and manipulation. The latest methods, techniques and applications are explained in detail regarding this rapidly developing area. The book will support the work of academic researchers and graduate students, as well as engineers and materials scientists working in industrial research and development. In addition, it will be highly valuable to those directly involved in the fabrication of capacitors in industry, and to researchers across the areas of materials science, polymer science, materials chemistry, and nanomaterials. Focuses on how to design and prepare dielectric polymer materials with strong energy storage properties Includes new techniques for adjusting the properties of dielectric polymer materials Presents a thorough review of the state-of-the-art in the field of dielectric polymer materials, providing valuable insights into potential avenues of development

Polymerization Process Modeling

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Author : N. A. Dotson
Publisher : John Wiley & Sons
ISBN 13 : 9780471186151
Total Pages : 392 pages
Book Rating : 4.1/5 (861 download)

Book Synopsis Polymerization Process Modeling by : N. A. Dotson

Download or read book Polymerization Process Modeling written by N. A. Dotson and published by John Wiley & Sons. This book was released on 1996-12-17 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Large numbers of chemical engineers work with polymerization reactions and the problems and the challenges particular to the production of polymers. These problems have no counterparts in small-molecule reactions, and thus usually are neglected in standard reactor courses. This book provides a clearly written, comprehensive textbook on polymerization reactor engineering, appropriate for senior-level undergraduate and 1st- and 2nd-year graduate students. It focuses on polymer structure and structure-property relationships conditions that can play a role in dictating stucture.

Introduction to Macromolecular Science

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Author : Petr Munk
Publisher : Wiley-Interscience
ISBN 13 : 9780471417163
Total Pages : 0 pages
Book Rating : 4.4/5 (171 download)

Book Synopsis Introduction to Macromolecular Science by : Petr Munk

Download or read book Introduction to Macromolecular Science written by Petr Munk and published by Wiley-Interscience. This book was released on 2002-03-05 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to Macromolecular Science provides a broad introduction to polymer science, including polymer structure, techniques for synthesis, properties in solution, and the technology of polymeric materials. This revised Second Edition presents up-to-date information on the newest aspects of polymer science, as well as expanded, comprehensive treatments of foundational techniques and theories. Additionally, each chapter concludes with a list of references for further research, a set of review questions, and a list of theoretical derivations and numerical problems. Other new features of this edition include: Coverage of recent synthetic procedures for polymers, such as living radical and cationic polymerizations, group transfer polymerization, polymerizations using metallocene and metathesis catalysts, and syntheses leading to dendrimers Expanded material on separation techniques and the technological facets of polymer processing An introduction to the techniques used for studying the structure of nucleic acids Techniques for studying polymer surfaces and polymeric membranes Topics such as polymer nomenclature, liquid crystalline polymers, and block copolymer micelles Introduction to Macromolecular Science, Second Edition is an essential volume for students and scholars of chemistry and chemical engineering, as well as polymer researchers, chemists, and chemical engineers in government and industry.

Scientific and Technical Aerospace Reports

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Author :
Publisher :
ISBN 13 :
Total Pages : 296 pages
Book Rating : 4.:/5 (3 download)

Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1991 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: