Metal Vapour Synthesis In Organometallic Chemistry

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Metal Vapour Synthesis in Organometallic Chemistry

Author : J. R. Blackborow
Publisher : Springer Science & Business Media
ISBN 13 : 364267285X
Total Pages : 215 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Metal Vapour Synthesis in Organometallic Chemistry by : J. R. Blackborow

Download or read book Metal Vapour Synthesis in Organometallic Chemistry written by J. R. Blackborow and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Vapour Synthesis (MVS) can be defined as; "The use in synthesis of high temper ature gaseous species such as metal atoms by their reactions with themselves or other materials in a condensed phase. " This short book, covering the literature up to the middle of 1979, describes MVS in organic chemistry; i. e. the reactions of metal atoms with various, predominantly organic, substrates in the synthesis and reactivity studies of organic and organometallic compounds. In order to effectively describe all the underlying principles and to present a coesive picture of pertinent metal atom processes in condensed organic phases, some inorganic substrates such as rare gases, dinitrogen, dioxygen, dihalo gens, and inorganic halides have been included. For similar reasons, we have used, where relevent, information provided by the closely related technique of Matrix Isolation Spec troscopy (MIS). After an introductory chapter which gives the basis principles and includes a brief critique of the technique, the book is divided into three further chapters dealing respec tively with (a) experimental techniques, (b) behaviour of metal atoms in matrices, and (c) results of prep~rative experiments. While not being encyclopaedic the book describes or refers to all noteworthy areas if not in the deliberately short text in the many tables and figures.

Intramolecular Diels-Alder and Alder Ene Reactions

Author : Douglass F. Taber
Publisher : Springer Science & Business Media
ISBN 13 : 3642692338
Total Pages : 106 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Intramolecular Diels-Alder and Alder Ene Reactions by : Douglass F. Taber

Download or read book Intramolecular Diels-Alder and Alder Ene Reactions written by Douglass F. Taber and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Diels-Alder reaction has long been a powerful tool in organic synthesis. In recent years, the Alder ene reaction has also achieved some prominence. From the beginning, it was apparent that the intramolecular variants of these reactions would be feasible. Many such have been reported, but the results are widely scattered in the chemical literature. This volume is an attempt to synthesize results observed to date, and to suggest directions for future development. One of the limiting factors in the application of the intramolecular Diels Alder reaction has been the development of methods for the preparation of the requisite trienes. The fIrst chapter of this volume summarizes methods for the preparation of dienes and dienophiles. Examples representative of every general approach to 1,3-dienes and to dienophilic functional group combinations have been included. There are two questions one might ask in considering the prospective cyclization of a given triene: what are the factors that govern the rate of cyclization? and, for cyclizations that lead to the creation of one or more new chiral centers, what are the factors that govern diastereoselectivity? These questions are addressed in Chapter Two. The third chapter is devoted to the all-carbon intramolecular Alder ene reaction. The tables in that chapter summarize all examples that could be found in the literature through 1981, with several additional examples from 1982. Leading references to heterocyclic ene reactions are also included in this chapter.

Organometallic Chemistry

Author : M Green
Publisher : Royal Society of Chemistry
ISBN 13 : 1847554172
Total Pages : 566 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Organometallic Chemistry by : M Green

Download or read book Organometallic Chemistry written by M Green and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Chemistry Under Extreme and Non-Classical Conditions

Author : Rudi van Eldik
Publisher : John Wiley & Sons
ISBN 13 : 9780471165613
Total Pages : 586 pages
Book Rating : 4.1/5 (656 download)

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Book Synopsis Chemistry Under Extreme and Non-Classical Conditions by : Rudi van Eldik

Download or read book Chemistry Under Extreme and Non-Classical Conditions written by Rudi van Eldik and published by John Wiley & Sons. This book was released on 1996-12-06 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: The very best and latest advances compiled in a single volume-an ideal resource for graduate students and researchers . . . Here is the perfect introduction to chemistry under extreme or non-classical conditions, including use of high temperature species, high pressure, supercritical media, sonochemistry, and microwave chemistry. Written by leading experts in their respective fields, this unique text applies a unified approach to each method, including background, instrumentation, examples, information on industrial applications (where relevant), and sources for further reading. Featured topics: * Chemical Synthesis Using High Temperature Species * Effect of Pressure on Inorganic Reactions * Effect of Pressure on Organic Reactions * Organic Synthesis at High Pressure * Inorganic and Related Chemical Reactions in Supercritical Fluids * Organic Chemistry in Supercritical Fluids * Industrial and Environmental Applications of Supercritical Fluids * Ultrasound as a New Tool for Synthetic Chemists * Applications of High Intensity Ultrasound in Polymer Chemistry * Chemistry Under Extreme Conditions in Water Induced Electrohydraulic Cavitation and Pulsed-Plasma Discharges * Microwave Dielectric Heating Effects in Chemical Synthesis * Biomolecules Under Extreme Conditions

Organometallic Chemistry

Author : E W Abel
Publisher : Royal Society of Chemistry
ISBN 13 : 1847554032
Total Pages : 522 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Organometallic Chemistry by : E W Abel

Download or read book Organometallic Chemistry written by E W Abel and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Chemistry of Aluminium, Gallium, Indium and Thallium

Author : A.J. Downs
Publisher : Springer Science & Business Media
ISBN 13 : 9780751401035
Total Pages : 552 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Chemistry of Aluminium, Gallium, Indium and Thallium by : A.J. Downs

Download or read book Chemistry of Aluminium, Gallium, Indium and Thallium written by A.J. Downs and published by Springer Science & Business Media. This book was released on 1993-05-31 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron has all the best tunes. That may well be the first impression of the Group 13 elements. The chemical literature fosters the impression not only in the primary journals, but also in asteady outflowofbooks focussing more or less closely on boron and its compounds. The same preoccupation with boron is apparent in the coverage received by the Group 13 elements in the comprehensive and regularly updated volume of the Gmelin Handbook. Yet such an imbalance cannot be explained by any inherent lack ofvariety, interest or consequence in the 'heavier elements. Aluminium is the most abundant metal in the earth's crust; in the industrialised world the metal is second only to iron in its usage, and its compounds can justifiably be said to touch our lives daily - to the potential detriment of those and other lives, some would argue. From being chemical curios, gallium and indium have now gained considerably prominence as sources of compound semiconductors like gallium arsenide and indium antimonide. Nor is there any want ofincident in the chemistriesofthe heavier Group 13 elements. In their redox, coordination and structural properties, there is to be found music indeed, notable not always for its harmony but invariably for its richness and variety. Thisbook seeks to redress the balance with a definitive, wide-rangingand up-to-date review of the chemistry of the Group 13 metals aluminium, gallium, indium and thallium.

Organometallic Chemistry

Author : R. C. Mehrotra
Publisher : New Age International
ISBN 13 : 9788122412581
Total Pages : 636 pages
Book Rating : 4.4/5 (125 download)

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Book Synopsis Organometallic Chemistry by : R. C. Mehrotra

Download or read book Organometallic Chemistry written by R. C. Mehrotra and published by New Age International. This book was released on 2007 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Book Is A Revised Edition Of A Lucid And Stimulating Introductory Account Of Organometallic Chemistry, An Exciting And Rapidly Developing Interdisciplinary Branch Of Science.A Characteristic Feature Of This Book Is The Presentation Of An Integrated (Covering Different Facets Usually Dealt With Either In Organic Or/And Inorganic Texts) View Of The Rapidly Developing Field Of Organometallic Chemistry. Attempts Have Been Made To Choose The Latest Examples To Illustrate The Fundamental Properties As Well As The Synthetic Procedures Of Organometallic Chemistry. Other Features Include: (A) An Interesting Brief Historical Background Of The Subject Including Some Quotations From Relevant Nobel Lecture Accounts Of Epoch Making Advances By The Discoverers Themselves, (B) The Adoption As Far As Possible Of The Iupac Rules Of Nomenclature, (C) A Brief Account Of The Rapidly Emerging Organometallic Chemistry Of The F-Elements, And (D) Inclusion Of Study Questions At The End Of Each Chapter.During The Revision Of The Book, The Latest Examples Have Replaced The Older Ones Wherever Feasible. The Book Would Be Extremely Useful As A Basic Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.

Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis

Author : Michel Chanon
Publisher : Springer Science & Business Media
ISBN 13 : 9400908776
Total Pages : 568 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis by : Michel Chanon

Download or read book Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis written by Michel Chanon and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,"Advanced Organic Chemistry", J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, "Advanced Inorganic Chemistry", Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, "Principles and Applications of Organotransition Metal Chemistry", University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry.

Silver-Based Antimicrobials

Author : Raymond J. Turner
Publisher : MDPI
ISBN 13 : 3039438913
Total Pages : 252 pages
Book Rating : 4.0/5 (394 download)

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Book Synopsis Silver-Based Antimicrobials by : Raymond J. Turner

Download or read book Silver-Based Antimicrobials written by Raymond J. Turner and published by MDPI. This book was released on 2021-02-22 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is some talk about an antibiotic Armageddon due to quickly developing resistance towards commercially available antibiotics. For the most part, the classical antibiotic pipeline has dried up, and antibiotic resistance to any new drugs quickly develops. It is here that metal-based antimicrobials can step forward as possible solutions in this antimicrobial resistance era. The biological targets of metal atoms are more diverse, thus making it more difficult for bacteria to develop resistance compared with classical antibiotics. The metal silver has been used since antiquity for wound healing and water purification. At present, it is the most prevalent antimicrobial metal used in healthcare, industry, and consumer products. Silver is being used in the form of ionic salt, colloids, or in specific nanomaterials, and as described in this book, it can be applied as mixtures with other antimicrobials or coating composites. The different formulations are explored for their efficacy against a variety of problems related to agricultural and medical infections. Whilst by no means exhaustive, this book nicely highlights the present directions in silver-based antimicrobial research and antimicrobial formulation development. The chapters have been organized from a general introductory review to approaches of mixing other antimicrobials and materials to enhance silver performance. This is followed by synthetic approaches. First are biogenic (sometimes called green or eco-friendly) approaches, followed by advanced physical–chemical synthetic approaches. The book ends with an overview of applications through a review of patents over the past 10 years.

Chemistry for Electronic Materials

Author : K.F. Jensen
Publisher : Elsevier
ISBN 13 : 0444596909
Total Pages : 215 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Chemistry for Electronic Materials by : K.F. Jensen

Download or read book Chemistry for Electronic Materials written by K.F. Jensen and published by Elsevier. This book was released on 1993-03-09 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemical aspects of materials processing used for electronic applications, e.g. Si, III-V compounds, superconductors, metallization materials, are covered in this volume. Significant recent advances have occurred in the development of new volatile precursors for the fabrication of III-V semiconductor and metal [Cu, W] films by OMCVD. Some fundamentally new and wide-ranging applications have been introduced in recent times. Experimental and modeling studies regarding deposition kinetics, operating conditions and transport as well as properties of films produced by PVD, CVD and PECVD are discussed. The thirty papers in this volume report on many other significant topics also. Research workers involved in these aspects of materials technology may find here some new perspectives with which to augment their projects.

Electron Spin Resonance

Author : M C R Symons
Publisher : Royal Society of Chemistry
ISBN 13 : 184755346X
Total Pages : 312 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Electron Spin Resonance by : M C R Symons

Download or read book Electron Spin Resonance written by M C R Symons and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Modern High Temperature Science

Author : John L. Margrave
Publisher : Springer Science & Business Media
ISBN 13 : 146125180X
Total Pages : 463 pages
Book Rating : 4.4/5 (612 download)

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Book Synopsis Modern High Temperature Science by : John L. Margrave

Download or read book Modern High Temperature Science written by John L. Margrave and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 463 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is a great pleasure to have the opportunity to honor our distinguished colleague, Professor Leo Brewer, on the occasion of his sixty-fifth birth day, with this special volume of High Temperature Science. Leo and his wife, Rose, are personal friends of several generations of students and postdoctoral researchers at the University of California at Berkeley. Their concern and understanding has been important to many of us over the past forty years. Each paper in this volume has at least one author who was a gradu ate student or a postdoctoral researcher in Leo's laboratory at Berkeley. The variety of topics is indicative of the wide-ranging science done by Brewer-ites and by Leo Brewer himself. He has personally participated in the resolution of many of the classical problems of high-temperature science-from the heat of sublimation of graphite to the dissociation en ergy of nitrogen to the prediction of binary and ternary phase diagrams. He and his students have made major contributions to atomic and molec ular spectroscopy. He has made significant contributions to the develop ment of efficient systems for energy conversion and to ceramics. In addi tion to his research activities, Leo Brewer has been a long-time participant in the dynamic undergraduate teaching program of the Berkeley Chemistry Department. He has provided crucial insight for stu dents involved in those career-shaping experiences that one endures while acquiring the basics of inorganic, organic, and physical chemistry with that interwoven common bond of thermodynamics.

Inorganic Reactions and Methods, The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4)

Author : A. P. Hagen
Publisher : John Wiley & Sons
ISBN 13 : 0470145471
Total Pages : 664 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Inorganic Reactions and Methods, The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4) by : A. P. Hagen

Download or read book Inorganic Reactions and Methods, The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4) written by A. P. Hagen and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 664 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

New Frontiers in Catalysis, Parts A-C

Author : L. Guczi
Publisher : Elsevier
ISBN 13 : 0080887147
Total Pages : 2955 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis New Frontiers in Catalysis, Parts A-C by : L. Guczi

Download or read book New Frontiers in Catalysis, Parts A-C written by L. Guczi and published by Elsevier. This book was released on 1993-04-20 with total page 2955 pages. Available in PDF, EPUB and Kindle. Book excerpt: These volumes comprise the proceedings of the major international meeting on catalysis which is held at 4 year intervals. The programme focussed on New Frontiers in Catalysis including nontraditional catalytic materials and environmental catalysis. The contributions cover a wide range of fundamental, applied, industrial and engineering aspects of catalysis. The extensive range of highly efficient industrial techniques for observing and characterizing catalytically important surfaces is evident.The programme covered the following sessions: Mechanism, theory, in situ methods; Catalytic reaction on atomically clean surfaces; Catalytic reaction on zeolites and related substances; New methods and principles for catalyst preparation; Hydrotreatment reactions (HDS, HDN); Characterization of catalysts, application of novel techniques; Selective oxidation; New catalytic aspects of heteropoly acids and related compounds; Reaction of hydrocarbons; Nontraditional catalytic materials; Fuel upgrading; Alkane activation; Acid-base catalysis; New selective catalytic reactons, fine chemicals; Environmental catalysis; Industrial catalysis, deactivation, reactivation; Synthesis from syngas; Electrocatalysis; Photocatalysis.The invited lectures and 433 papers included in these volumes present an update on all areas of catalysis and applications.

Precursor Chemistry of Advanced Materials

Author : Roland A. Fischer
Publisher : Springer Science & Business Media
ISBN 13 : 9783540016052
Total Pages : 240 pages
Book Rating : 4.0/5 (16 download)

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Book Synopsis Precursor Chemistry of Advanced Materials by : Roland A. Fischer

Download or read book Precursor Chemistry of Advanced Materials written by Roland A. Fischer and published by Springer Science & Business Media. This book was released on 2005-09-29 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Material synthesis by the transformation of organometallic compounds (precursors) by vapor deposition techniques such as chemical vapor deposition (CVD) and atomic layer deposition (ALD) has been in the forefront of modern day research and development of new materials. There exists a need for new routes for designing and synthesizing new precursors as well as the application of established molecular precursors to derive tuneable materials for technological demands. With regard to the precursor chemistry, a most detailed understanding of the mechanistic complexity of materials formation from molecular precursors is very important for further development of new processes and advanced materials. To emphasize and stimulate research in these areas, this volume comprises a selection of case studies covering various key-aspects of the interplay of precursor chemistry with the process conditions of materials formation, particularly looking at the similarities and differences of CVD, ALD and nanoparticle synthesis, e.g. colloid chemistry, involving tailored molecular precursors.

Catalysis

Author : James J Spivey
Publisher : Royal Society of Chemistry
ISBN 13 : 1847558445
Total Pages : 401 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Catalysis by : James J Spivey

Download or read book Catalysis written by James J Spivey and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications.

Aspects of Homogeneous Catalysis

Author : R. Ugo
Publisher : Springer Science & Business Media
ISBN 13 : 9400963637
Total Pages : 350 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Aspects of Homogeneous Catalysis by : R. Ugo

Download or read book Aspects of Homogeneous Catalysis written by R. Ugo and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. INTRODUCTION Although quite spectacular results have been obtained in the last few decades in the field of homogeneous transition metal catalyzed transformations of olefins and alkynes [1], reactions which could lead to heterocycles have been partly neglected. An obvious reason for this is that substrates containing heteroatoms such as N, 0 or S could coordinate the metal and suppress the catalytic activity. Nevertheless, some interesting early examples of transition-metal-catalyzed syntheses of heterocyclic compounds have been reported and these have been reviewed by C. W. Bird [2] . More recently the incorporation of CO , which enables esters and lactones 2 to be synthesized from olefinic starting materials, has begun to attract attention (see, for example, ref. [3]). The dominant role of palladium as the catalyst for the formation of O-containing heterocycles has been suggested to be associated with the relatively low strength of the Pd-O bond. Among the first examples of a nitrogen-containing heterocycle to be formed by homogeneous catalysis is the triazine shown in Equation 1 which is the product of the trimerization of benzonitrile in the presence of iron penta carbonyl or Raney nickel [4] .