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Magnetic Relaxation In Organic Based Magnets
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Book Synopsis Magnetic Relaxation in Organic-based Magnets by : Stephen J. Etzkorn
Download or read book Magnetic Relaxation in Organic-based Magnets written by Stephen J. Etzkorn and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: Spin glasses are magnetic systems with random, frustrated magnetic interactions. The result of this frustration is that these materials possess no true long-range order, but rather have a "freezing transition" to a state which appears ordered on observable time scales. This frustration induces many complicated magnetic phenomena, including frequency dependence of the ac susceptibility and dc magnetic relaxation on an experimentally observable time scale. This dissertation addresses the nature of magnetic relaxation observed in the organic-based magnet [MnTPP] + [TCNE] - · y (solvent). This material forms linear chains of alternating electron donor ([MnTPP]) and acceptor ([TCNE]) pairs with large interchain spacing. The low dimension of the structure enables this system to serve as an experimental platform for testing spin glass theory. Relaxation and spin glass behavior was investigated in [MnTPP] + [TCNE] - · 2(1,3-C 6 H 4 Cl 2) by incorporating both ac and dc magnetic measurements. A scaling analysis of the ac susceptibility reveals a spin glass transition at 4.1 K. The thermoremanent magnetization exhibits long time relaxation above this temperature. The effects of relaxation on magnetic reversal were examined via time dependent magnetic measurements. The results of these measurements were analyzed using a fractal cluster model for spin glasses. This model provided a method for obtaining a physical interpretation of the results of the relaxation data. Through an extension of this model, the fractal dimension of the spin clusters was obtained. The value for the spin cluster dimension ranged from 0.8 to over 1.5 as the glass transition temperature is approached. These results suggest a picture of anisotropic spin clusters as the mechanism for magnetic ordering in [MnTPP] + [TCNE] - · y (solvent).
Book Synopsis Molecular Magnetism by : Olivier Kahn
Download or read book Molecular Magnetism written by Olivier Kahn and published by Courier Dover Publications. This book was released on 2021-11-17 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highly regarded and historic book covers basic concepts of magnetization and magnetic susceptibility, establishes the fundamental equations of molecular magnetism, and examines molecules containing a unique magnetic center. 2019 edition.
Book Synopsis Lanthanide Single Molecule Magnets by : Jinkui Tang
Download or read book Lanthanide Single Molecule Magnets written by Jinkui Tang and published by Springer. This book was released on 2015-04-24 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book begins by providing basic information on single-molecule magnets (SMMs), covering the magnetism of lanthanide, the characterization and relaxation dynamics of SMMs and advanced means of studying lanthanide SMMs. It then systematically introduces lanthanide SMMs ranging from mononuclear and dinuclear to polynuclear complexes, classifying them and highlighting those SMMs with high barrier and blocking temperatures – an approach that provides some very valuable indicators for the structural features needed to optimize the contribution of an Ising type spin to a molecular magnet. The final chapter presents some of the newest developments in the lanthanide SMM field, such as the design of multifunctional and stimuli-responsive magnetic materials as well as the anchoring and organization of the SMMs on surfaces. In addition, the crystal structure and magnetic data are clearly presented with a wealth of illustrations in each chapter, helping newcomers and experts alike to better grasp ongoing trends and explore new directions. Jinkui Tang is a professor at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Peng Zhang is currently pursuing his PhD at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, with a specific focus on the molecular magnetism of lanthanide compounds under the supervision of Prof. Jinkui Tang.
Book Synopsis Organometallic Magnets by : Vadapalli Chandrasekhar
Download or read book Organometallic Magnets written by Vadapalli Chandrasekhar and published by Springer Nature. This book was released on 2019-11-22 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.
Book Synopsis Molecular Nanomagnets by : Dante Gatteschi
Download or read book Molecular Nanomagnets written by Dante Gatteschi and published by OUP Oxford. This book was released on 2011-04-14 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomagnetism is a rapidly expanding area of research which appears to be able to provide novel applications. Magnetic molecules are at the very bottom of the possible size of nanomagnets and they provide a unique opportunity to observe the coexistence of classical and quantum properties. The discovery in the early 90's that a cluster comprising twelve manganese ions shows hysteresis of molecular origin, and later proved evidence of quantum effects, opened a new research area which is still flourishing through the collaboration of chemists and physicists. This book is the first attempt to cover in detail the new area of molecular nanomagnetism, for which no other book is available. In fact research and review articles, and book chapters are the only tools available for newcomers and the experts in the field. It is written by the chemists originators and by a theorist who has been one of the protagonists of the development of the field, and is explicitly addressed to an audience of chemists and physicists, aiming to use a language suitable for the two communities.
Book Synopsis Single-Molecule Magnets by : Malgorzata Holynska
Download or read book Single-Molecule Magnets written by Malgorzata Holynska and published by John Wiley & Sons. This book was released on 2019-02-11 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concise overview of synthesis and characterization of single molecule magnets Molecular magnetism is explored as an alternative to conventional solid-state magnetism as the basis for ultrahigh-density memory materials with extremely fast processing speeds. In particular single-molecule magnets (SMM) are in the focus of current research, both because of their intrinsic magnetization properties, as well as because of their potential use in molecular spintronic devices. SMMs are fascinating objects on the example of which one can explain many concepts. Single-Molecule Magnets: Molecular Architectures and Building Blocks for Spintronics starts with a general introduction to single-molecule magnets (SMM), which helps readers to understand the evolution of the field and its future. The following chapters deal with the current synthetic methods leading to SMMs, their magnetic properties and their characterization by methods such as high-field electron paramagnetic resonance, paramagnetic nuclear magnetic resonance, and magnetic circular dichroism. The book closes with an overview of radical-bridged SMMs, which have shown application potential as building blocks for high-density memories. Covers a hot topic – single-molecule magnetism is one of the fastest growing research fields in inorganic chemistry and materials science Provides researchers and newcomers to the field with a solid foundation for their further work Single-Molecule Magnets: Molecular Architectures and Building Blocks for Spintronics will appeal to inorganic chemists, materials scientists, molecular physicists, and electronics engineers interested in the rapidly growing field of study.
Book Synopsis Molecular Cluster Magnets by : Richard Winpenny
Download or read book Molecular Cluster Magnets written by Richard Winpenny and published by World Scientific. This book was released on 2012 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work covers new developments in the field of molecular nanomagnetism, complementing previous books in this area (for example the volume by Gatteschi, Sessoli and Villain on Single Molecule Magnets). The book is written by experts in the field and is intended as a compilation of critical reviews of new areas rather than a comprehensive text.
Book Synopsis Metal-Organic and Organic Molecular Magnets by : Peter Day
Download or read book Metal-Organic and Organic Molecular Magnets written by Peter Day and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: Traditionally, magnetic materials have been metals or, if inorganic compounds such as oxides, of continuous lattice type. However, in recent years chemists have synthesized increasing numbers of crystalline solids based on molecular building blocks in the form of coordination and organometallic complexes or purely organic molecules, which exhibit spontaneous magnetization. In striking contrast to conventional magnets, these materials are made from solutions close to room temperature rather than by metallurgical or ceramic methods. This book, which originates from contributions to a Discussion Meeting of The Royal Society of London, brings together many of the leading international practitioners in the field, who survey their own recent work and place it in the context of the wider fields of magnetism and supramolecular chemistry. All aspects of molecular-based magnets are addressed, including synthesis, structure-property relations and physical properties. Contents include details of the characterization of the first purely organic ferromagnet, the synthesis of high coercivity materials and a unique description of new materials with Curie temperatures well above ambient. A coherent survey of this rapidly developing field for the more general reader, Metal-Organic and Organic Molecular Magnets will also be welcomed by researchers and lecturers in materials science and inorganic or solid state chemistry.
Book Synopsis A Study of Magnetic Materials Based Upon the Organic Acceptor 7,7,8,8-tetracyanoquinodimethane by : Adam Berlie
Download or read book A Study of Magnetic Materials Based Upon the Organic Acceptor 7,7,8,8-tetracyanoquinodimethane written by Adam Berlie and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of organic based materials is a flourishing area of interest as the physical/chemical properties of the compound can be tuned through functionalisation or simple chemical changes to the organic component. This thesis will focus on the magnetic behaviour of metal-organic magnetic materials where a variety of techniques will be used to study the magnetism such as bulk magnetometry and muon spin relaxation. As well as the magnetic properties, some comments will be made on the chemical properties such as molecular structure. The thesis begins with an overview of the theory of magnetism and details regarding experimental techniques. Ni(TCNQ)$-2$ is a recently discovered non-solvated metal organic magnet that was reported to show ferromagnetic behaviour below 20 K where there was evidence of a glassy magnetic component. This thesis reports the synthesis of both a protio and deutero form of the material where upon deuteration of the TCNQ molecule, a shift in critical temperature ($T-{\rm C}$) was observed to a higher temperature by approximately 15%. Diffraction experiments were conducted to attempt to provide information on the atomic structure however this proved unsuccessful. Magnetometry experiments showed a ferromagnetic transition at approximately 20 K in the deuterated and 17 K in the protonated materials where at low temperatures the sample appeared to be a three-dimensional magnetically order material. Muon spin relaxation studies were conducted on the deuterated sample which showed two peaks within the dynamical relaxation in zero-field; one associated with the transition and a low temperature (5 K) spin freezing effect where it is believed there are interactions between magnetic clusters that enter a quasi-static regime. It may be possible that the glassy component and the ferromagnetic behaviour of the material are not due to the same exchange mechanism or magnetic interactions. KTCNQ is a compound that undergoes a spin-Peierls transition, $T-{\rm SP}$, at approximately 400 K where below this temperature there is a dimerisation of the TCNQ radical spins that couple antiferromagnetically and the system goes from a conductive to insulating state. In an attempt to tune the TCNQ-TCNQ interactions different materials were synthesised where the protons on the TCNQ ring were substituted for fluorine and bromine atoms. On substitution of the protons with other elements a dramatic shift in Tsp was observed where for the fluorine based compounds $T-{\rm SP}$ = 150 K and the KTCNQ-Br$-2$ compound showed no evidence of a transition. Both KTCNQ-H$-4$ and KTCNQ-F$-4$ were studied further using muon spin relaxation where the transition is clearly modelled using a stretched exponential where an increase in electronic fluctuation rate is shown by a gradual move from an exponential to Gaussian relaxation. At low temperatures the relaxation again changes and within the KTCNQ-F$-4$ sample 2 F-$\mu +$-F states are observed. Another controversial organic based magnet is Ni$-2$TCNQ which was first synthesised in 2007. Here a study of a similar material is reported where the TCNQ has been swapped for TCNQF$-4$ and the magnetic properties are shown to be a result of nickel nanoparticles trapped within a metal-organic or purely organic based matrix. The room temperature ferromagnetism is not strictly due to only the bulk Ni particles as this would result in a blocking temperature below 20 K and so the matrix is shown to play an important role. The size of the Ni nanoparticles was shown to be tuneable when using different solvents within the reaction, generally use of chlori- nated solvents lead to rapid decomposition of the starting material, Ni(COD)$-2$ and lead to larger nanoparticles, however use of a nitrile based solvent led to Ni clusters that were approximately 1 nm in size and dispersed within the matrix. A novel scaling of the magnetisation curves as a function of field showed that once the ferromagnetic component had been subtracted the matrix or Ni based clusters show an antiferromagnetic ground state at low temperature. The final chapter describes an investigation of the starting material, Ni(COD)$-2$ which was studied using a SQUID magnetometer where it was shown that there was a high level of magnetic impurities, which was attributed to small Ni clusters that showed a similar scaling relationship of the magnetisation as for the Ni2TCNQF$-4$ based material. This demonstrates the inappropriate nature of Ni(COD)$-2$ as a starting material for metal-organic based magnetic compounds.
Book Synopsis Theoretical And Computational Aspects Of Magnetic Organic Molecules by : Sambhu N Datta
Download or read book Theoretical And Computational Aspects Of Magnetic Organic Molecules written by Sambhu N Datta and published by World Scientific. This book was released on 2013-12-23 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic materials with extraordinary magnetic properties promise a wide range of light, flexible, and inexpensive alternatives to familiar metal-based magnets. Individual organic molecules with high magnetic moments will be the foundation for design and fabrication of these materials.This book provides a systematic understanding of the structure and properties of organic magnetic molecules. After a summary of the phenomenon of magnetism at the molecular level, it presents a survey of the challenges to theoretical description and evaluation of the magnetic character of open-shell molecules, and an overview of recently developed methods and their successes and shortfalls. Several fields of application, including very strong organic molecular magnets and photo-magnetic switches, are surveyed. Finally, discussions on metal-based materials and simultaneously semiconducting and ferromagnetic extended systems and solids point the way toward future advances.The reader will find a comprehensive discourse on current understanding of magnetic molecules, a thorough survey of computational methods of characterizing known and imagined molecules, simple rules for design of larger magnetic systems, and a guide to opportunities for progress toward organic magnets.
Book Synopsis Handbook of Magnetic Materials by : Ekkes H. Brück
Download or read book Handbook of Magnetic Materials written by Ekkes H. Brück and published by Elsevier. This book was released on 2017-11-13 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Magnetic Materials, Volume 26, covers the expansion of magnetism over the last few decades and its applications in research, notably the magnetism of several classes of novel materials that share the presence of magnetic moments with truly ferromagnetic materials. The book is an ideal reference for scientists active in magnetism research, providing readers with novel trends and achievements in magnetism. Each article contains an extensive description given in graphical, as well as, tabular form, with much emphasis placed on the discussion of the experimental material within the framework of physics, chemistry and material science. Comprises topical review articles written by leading authorities Includes a variety of self-contained introductions to a given area in the field of magnetism without requiring recourse to the published literature Introduces given topics in the field of magnetism Describes novel trends and achievements in magnetism
Book Synopsis Introduction to Frustrated Magnetism by : Claudine Lacroix
Download or read book Introduction to Frustrated Magnetism written by Claudine Lacroix and published by Springer Science & Business Media. This book was released on 2011-01-12 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of highly frustrated magnetism has developed considerably and expanded over the last 15 years. Issuing from canonical geometric frustration of interactions, it now extends over other aspects with many degrees of freedom such as magneto-elastic couplings, orbital degrees of freedom, dilution effects, and electron doping. Its is thus shown here that the concept of frustration impacts on many other fields in physics than magnetism. This book represents a state-of-the-art review aimed at a broad audience with tutorial chapters and more topical ones, encompassing solid-state chemistry, experimental and theoretical physics.
Book Synopsis Functional Phthalocyanine Molecular Materials by : Jianzhuang Jiang
Download or read book Functional Phthalocyanine Molecular Materials written by Jianzhuang Jiang and published by Springer. This book was released on 2010-02-02 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phthalocyanines exhibit intriguing physic-chemical properties that render them important as a class of molecular functional materials. In addition to their traditional applications as dyes and pigments, more recently their use as the organic semiconductors, photodynamic therapy medicines, non-linear optical materials, catalysts for the photo oxidation, optical recording materials, and gas sensors attracts great research interests in these tetrapyrrole species.
Download or read book Magnetism written by Joel S. Miller and published by . This book was released on 2001 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis World Scientific Reference On Spin In Organics (In 4 Volumes) by : Zeev Valy Vardeny
Download or read book World Scientific Reference On Spin In Organics (In 4 Volumes) written by Zeev Valy Vardeny and published by World Scientific. This book was released on 2017-12-27 with total page 1364 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference work on Spin in Organics contains four volumes dedicated to spin injection, spin transport, spin pumping, organic magnetic field effect, and molecular spintronics. The field of Organic Spintronics has accelerated and matured in the last dozen years with the realization of an organic spin-valve (in 2004) and magneto-resistance and magneto-electroluminescence in organic optoelectronic devices (2006).The book series is comprehensive in that it summarizes all aspects of Organic Spintronics to date. The first two volumes deal with spin injection, spin transport, spin manipulation and spin pumping into organic semiconductors. The main device that is thoroughly discussed here is the organic spin-valve, where spinterface states at the interface between the organic semiconductor and the ferromagnetic (FM) electrode has been the focus of many chapters. An interesting emerging subject is the role of chirality in the organic layer of the device. A relatively new method of achieving spin aligned carriers in organic semiconductors is spin pumping, where magnons in the FM substrate generate spin aligned carriers in the organic layer at the FM/organic interface.The third volume deals mainly with magnetic field effect in organic devices. Several spin-mixture processes that lead to magnetic field effect in devices and films are thoroughly discussed, such as hyperfine interaction, direct spin-orbit coupling, indirect spin-orbit coupling via Δg, triplet-triplet annihilation, and thermal spin alignment. The similarity between the magnetic field effect obtained in optoelectronic devices based on organic semiconductors and the novel hybrid organic-inorganic semiconductors is also a subject of intense interest. The fourth volume deals with spin in molecular films and devices. It includes thorough discussion of spin exchange interaction that leads to organic ferromagnets, as well as manifestation of various spin interactions in thin molecular films and devices.
Book Synopsis Handbook of Spintronics by : Yongbing Xu
Download or read book Handbook of Spintronics written by Yongbing Xu and published by Springer. This book was released on 2015-10-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over two volumes and 1500 pages, the Handbook of Spintronics will cover all aspects of spintronics science and technology, including fundamental physics, materials properties and processing, established and emerging device technology and applications. Comprising 60 chapters from a large international team of leading researchers across academia and industry, the Handbook provides readers with an up-to-date and comprehensive review of this dynamic field of research. The opening chapters focus on the fundamental physical principles of spintronics in metals and semiconductors, including an introduction to spin quantum computing. Materials systems are then considered, with sections on metallic thin films and multilayers, magnetic tunnelling structures, hybrids, magnetic semiconductors and molecular spintronic materials. A separate section reviews the various characterisation methods appropriate to spintronics materials, including STM, spin-polarised photoemission, x-ray diffraction techniques and spin-polarised SEM. The third part of the Handbook contains chapters on the state of the art in device technology and applications, including spin valves, GMR and MTJ devices, MRAM technology, spin transistors and spin logic devices, spin torque devices, spin pumping and spin dynamics and other topics such as spin caloritronics. Each chapter considers the challenges faced by researchers in that area and contains some indications of the direction that future work in the field is likely to take. This reference work will be an essential and long-standing resource for the spintronics community.
Book Synopsis Spin Crossover in Transition Metal Compounds I by : Philipp Gütlich
Download or read book Spin Crossover in Transition Metal Compounds I written by Philipp Gütlich and published by Springer Science & Business Media. This book was released on 2004-05-12 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts
