Local Structure and Molecular Dynamics of Supramolecules and Semicrystalline Polymers as Investigated by Solid State NMR

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ISBN 13 :
Total Pages : 151 pages
Book Rating : 4.:/5 (112 download)

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Book Synopsis Local Structure and Molecular Dynamics of Supramolecules and Semicrystalline Polymers as Investigated by Solid State NMR by : Wei Chen

Download or read book Local Structure and Molecular Dynamics of Supramolecules and Semicrystalline Polymers as Investigated by Solid State NMR written by Wei Chen and published by . This book was released on 2016 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this dissertation, we have focused on the study of the interplay of structure and molecular dynamics of soft materials including supramolecules and semicrystalline polymers at the molecular scale through various state-of-the-art solid state NMR techniques. The dissertation is consisting of three parts. In Chapter IV, we focus on the atomic scale dynamics for a Janus bisamide supramolecule. Relationship between unique structure and dynamics will be demonstrated. On the basis of the determined conformations and packing structures of the alkyl chains in ordered and disordered crystalline phases, along with the geometry and kinetic parameters of the structural elements' dynamics, the self-assembly, the phase-transition mechanisms, and the relationship between the structure and dynamics of the asymmetric Janus bisamide supramolecules were addressed.In Chapter V, we investigate molecular dynamics of semicrystalline polymers including poly-lactic acid-PLA, polyethylene oxide PEO, and polyoxymethylene POM in well controlled morphologies. Based on dynamic frequency and geometry of molecular motions, we've discussed possible structural factors that influence chain dynamics in the crystalline regions. In Chapter VI, we investigate the chain-trajectory of PLA stereocomplex by 13C Double-Quantum -DQ NMR in combination with spin-dynamics simulation. Poly-L-lactide PLLA and poly-D-lactide -PDLA alternatively pack with each other and form stereocomplex crystals (SCs). The habits of SCs formed in the dilute solution depend highly on the molecular weight Mw. It was demonstrated that the ensemble average of the successive adjacent re-entry number n for the l-PLLA chains drastically changes depending on Mws of the counter PDLA chains in the SCs. It was concluded that the limited space for two kinds of PLA chains at the fold surface significantly influence the chain-folding patterns inside the SCs and as a result led to the unique Mw dependence of the crystal morphology.

Molecular Characterization of Polymers

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Publisher : Elsevier
ISBN 13 : 012822598X
Total Pages : 670 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Molecular Characterization of Polymers by : Muhammad Imran Malik

Download or read book Molecular Characterization of Polymers written by Muhammad Imran Malik and published by Elsevier. This book was released on 2021-03-09 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular Characterization of Polymers presents a range of advanced and cutting-edge methods for the characterization of polymers at the molecular level, guiding the reader through theory, fundamentals, instrumentation, and applications, and supporting the end goal of efficient material selection and improved material performance. Each chapter focuses on a specific technique or family of techniques, including the different areas of chromatography, field flow fractionation, long chain branching, static and dynamic light scattering, mass spectrometry, NMR, X-Ray and neutron scattering, polymer dilute solution viscometry, microscopy, and vibrational spectroscopy. In each case, in-depth coverage explains how to successfully implement and utilize the technique. This practical resource is highly valuable to researchers and advanced students in polymer science, materials science, and engineering, and to those from other disciplines and industries who are unfamiliar with polymer characterization techniques. - Introduces a range of advanced characterization methods, covering aspects such as molecular weight, polydispersity, branching, composition, and tacticity - Enables the reader to understand and to compare the available technique, and implement the selected technique(s), with a view to improving properties of the polymeric material - Establishes a strong link between basic principles, characterization techniques, and real-life applications

Solid State NMR of Polymers

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Publisher : Elsevier
ISBN 13 : 0080541461
Total Pages : 1017 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Solid State NMR of Polymers by : T. Asakura

Download or read book Solid State NMR of Polymers written by T. Asakura and published by Elsevier. This book was released on 1998-08-03 with total page 1017 pages. Available in PDF, EPUB and Kindle. Book excerpt: In polymer science and technology, the advanced development of various new polymer materials with excellent properties and functions is desirable. For this purpose it is necesary to determine the exact relationship between physical properties and molecular structure-dynamics with powerful techniques. One such technique is solid state NMR. Recently, high resolution NMR studies of solids have been realized by using advanced pulse and mechanical techniques, which has resulted in a variety of structural and dynamical information on polymer systems. Solid state NMR has provided characteristic information which cannot be obtained by other spectroscopic methods. This book is divided into two parts. The first part covers the principles of NMR, important NMR parameters such as chemical shifts, relaxation times, dipolar interactions, quadrupolar interactions, pulse techniques and new NMR methods. In the second part, applications of NMR to a variety of polymer systems in the solid state are described. Features of this book: • Contains an up-to-date and comprehensive account of solid state NMR of polymers by leading researchers in the field • Provides a compilation of solid state NMR of polymers, which makes it an ideal reference book for both NMR researchers and general polymer scientists. This book will be of interest to the NMR community, and will be invaluable for both the beginner and the expert.

Structure and Dynamics of Supramolecular Assemblies Studied by Advanced Solid-state NMR Spectroscopy

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (697 download)

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Book Synopsis Structure and Dynamics of Supramolecular Assemblies Studied by Advanced Solid-state NMR Spectroscopy by :

Download or read book Structure and Dynamics of Supramolecular Assemblies Studied by Advanced Solid-state NMR Spectroscopy written by and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of the present thesis is the investigation of the structure and dynamics of rather large and complex supramolecular systems with solid-state nuclear magnetic resonance (NMR) spectroscopy. The results contribute to the understanding of structural and dynamical properties induced by pi-pi interactions in different supramolecular systems and, in this way, promote the understanding as well as the chemical design of complex self-organizing materials. Dipolar 1H-1H and 1H-13C recoupling NMR methods under fast magic angle spinning (MAS), which do not rely on isotopic labeling, enable the analysis of 1H NMR chemical shift effects as well as dipolar 1H-1H and 1H-13C couplings. In this way, site-specific information about the local structure and the segmental dynamics of different moieties in a supramolecular system is provided. In combination with nucleus independent chemical shift (NICS) maps (computed in the framework of ab-initio methods), protons can be positioned relative to pi-electron systems to suggest local arrangements of the molecules which form the supramolecular assembly. Moreover, local order parameters are selectively and precisely determined for different molecular building blocks from homo- and heteronuclear dipolar spinning sideband patterns. In this way, valuable information about structural and dynamical properties is gained, which helps to identify structure-directing elements, to quantify local interactions and to understand principal order phenomena, which altogether determine the self-assembly process of supramolecular systems.

Elucidation of Chain-folding Structure and Crystallization Mechanism of Semicrystalline Polymer by Solid-state NMR

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ISBN 13 :
Total Pages : 190 pages
Book Rating : 4.:/5 (914 download)

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Book Synopsis Elucidation of Chain-folding Structure and Crystallization Mechanism of Semicrystalline Polymer by Solid-state NMR by : Youlee Hong

Download or read book Elucidation of Chain-folding Structure and Crystallization Mechanism of Semicrystalline Polymer by Solid-state NMR written by Youlee Hong and published by . This book was released on 2015 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since Keller found single crystal of polyethylene (PE) in 1957, he first proposed the long polymer chains are more or less regularly folded in thin lamellae and the chain stems between successive folds oriented preferentially normal to the plane of the lamellae. The discovery has triggered the study of how long polymer molecules are embedded in the thin lamellae of semicrystalline polymers. Subsequently, several different crystallization mechanisms had been proposed such as Lauritzen-Hoffman kinetic theory, multistage model, aggregation model, and bundle model, etc. In order to prove these crystallization models, chain trajectory of semicrystalline polymers have been investigated prominently by neutron scattering (NS) and infrared (IR) spectroscopy combined with 1H/2H polymers because the chain-level structure would reflect the process during the crystallization. Later on, other techniques such as atomic force microscopy (AFM) and decoration method on the surface of PE crystals have been developed. Irrespective of the tremendous efforts over the last half century, the detailed chain trajectory of semicrystalline polymers still remains missing due to insufficient resolution of available techniques and intrinsic polymer structures that consist of repeating monomer units. Therefore, various crystallization theories could not be verified until now and hence a new approach is required to clarify the molecular level structure. In this dissertation, we have developed a novel strategy to investigate chain trajectory of semicrystalline polymers as a function of concentration and crystallization temperature. We have used solid-state nuclear magnetic resonance (SS-NMR) spectroscopy combined with selectively 13C isotopic labeling approach. Since the SS-NMR approach based on 13C-13C magnetically dipolar interactions has atomic level resolutions, the approach was able to investigate the chain trajectory of isotactic poly(1-butene) (iPB1). 13C-13C double quantum (DQ) NMR and spin-dynamics simulations determined adjacent re-entry parameters of the re-entrance site, chain-folding fraction (F), average successive chain-folding number n, and molecular dimension of folded chains of iPB1 with a relatively low Mw of 37 K g/mol in melt- and solution-grown crystals in a wide range of crystallization temperature (T[subscript c]). The determined chain trajectory of form I iPB1, which is one of the type of iPB1 crystal form, turned out that the re-entrance site of iPB1 is independence of the concentration and crystallization temperatures while the lower concentration induces long-range order and higher fraction of adjacent re-entry chain-folding. The n and F values were nearly invariant of T[subscript c] in each the solution- and melt-grown systems. In addition, we studied the effects of T[subscript c] on the lamellar thickness (l[subscript c]), crystallinity ([Chi][subscript c]), and morphology of iPB1 crystallized in both states. The combined data obtained at different length scales demonstrated that kinetics plays different roles for the structural formations from molecular to morphological levels. Lastly, another iPB1 form III displayed three dimensional clusters of folded chains instead of the two dimensional one expected by classical surface nucleation model of crystallization. Through the molecular level structures, [Chi][subscript c], l[subscript c], morphology of single crystal, and the dimension of folded chains as well as the molecular dynamics information reported in the literature, we discussed the crystallization mechanisms of semicrystalline polymer from a molecular level of view.

Hierarchical Macromolecular Structures: 60 Years after the Staudinger Nobel Prize I

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Publisher : Springer
ISBN 13 : 3319011375
Total Pages : 434 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Hierarchical Macromolecular Structures: 60 Years after the Staudinger Nobel Prize I by : Virgil Percec

Download or read book Hierarchical Macromolecular Structures: 60 Years after the Staudinger Nobel Prize I written by Virgil Percec and published by Springer. This book was released on 2014-07-08 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.

Polymer Science: A Comprehensive Reference

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Publisher : Newnes
ISBN 13 : 0080878628
Total Pages : 7752 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Polymer Science: A Comprehensive Reference by :

Download or read book Polymer Science: A Comprehensive Reference written by and published by Newnes. This book was released on 2012-12-05 with total page 7752 pages. Available in PDF, EPUB and Kindle. Book excerpt: The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)

Spectroscopic and Computational Studies of Supramolecular Systems

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Publisher : Springer Science & Business Media
ISBN 13 : 940157989X
Total Pages : 310 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Spectroscopic and Computational Studies of Supramolecular Systems by : J.E. Davies

Download or read book Spectroscopic and Computational Studies of Supramolecular Systems written by J.E. Davies and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical techniques such as X-ray crystallography, IR spectroscopy and solution-phase NMR spectroscopy have played key roles in the development of supramolecular chemistry. In recent years other spectroscopic techniques have been applied, expanding the range of information obtainable. The most widely used technique is solid-state NMR spectroscopy but techniques such as neutron scattering and NQR spectroscopy can yield significant information. Computational approaches are now becoming powerful complementary methods to experimental techniques and this book reviews the application of these methods to supramolecular systems. The ten chapters provide up-to-date information on the applications of spectroscopic and computational techniques to a wide range of supramolecular systems: Solid State NMR Studies of Host-Guest Materials Infrared Studies of Zeolite Complexes NQR Studies of Inclusion Compounds Neutron Scattering Studies of Zeolite Complexes Solid State NMR Studies of Catalytic Reactions on Molecular Sieves Recent Advances in Computational Studies of Zeolites Theoretical Studies of Cyclodextrins and their Inclusion Complexes Computer Modelling of the Structures of Host-Guest Complexes Computational Studies of Clathrate Hydrates Ab initio Electronic Structure Calculations on Endohedral Complexes of the C60 Cluster. This timely book will prove to be of great value to supramolecular researchers who are familiar with the spectroscopic techniques but who wish to extend their knowledge of the computational methods (and vice versa), to supramolecular researchers working in allied areas whose work would benefit from applying spectroscopic and computational methods, and finally to workers just entering the fascinating area of supramolecular chemistry.

Structure and Dynamics of Supramolecular Assemblies Studied by Advanced Solid State NMR Spectroscopy

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (614 download)

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Book Synopsis Structure and Dynamics of Supramolecular Assemblies Studied by Advanced Solid State NMR Spectroscopy by : Almut Rapp

Download or read book Structure and Dynamics of Supramolecular Assemblies Studied by Advanced Solid State NMR Spectroscopy written by Almut Rapp and published by . This book was released on 2003 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Influence of Spatial Constraints in Non-crystalline Regions on the Polymer Dynamics in Semi-crystalline Polyethylene

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Publisher :
ISBN 13 :
Total Pages : 195 pages
Book Rating : 4.:/5 (246 download)

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Book Synopsis Influence of Spatial Constraints in Non-crystalline Regions on the Polymer Dynamics in Semi-crystalline Polyethylene by : Yefeng Yao

Download or read book Influence of Spatial Constraints in Non-crystalline Regions on the Polymer Dynamics in Semi-crystalline Polyethylene written by Yefeng Yao and published by . This book was released on 2007 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Supramolecular Order and Dynamics of Functional Materials Studied by Solid State NMR.

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (697 download)

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Book Synopsis Supramolecular Order and Dynamics of Functional Materials Studied by Solid State NMR. by :

Download or read book Supramolecular Order and Dynamics of Functional Materials Studied by Solid State NMR. written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The goal of this thesis was the investigation of the structure, conformation, supramolecular order and molecular dynamics of different classes of functional materials (phthalocyanine, perylene and hexa-peri-hexabenzocoronene derivatives and mixtures of those), all having planar aromatic cores modified with various types of alkyl chains. The planar aromatic systems are known to stack in the solid and the liquid-crystalline state due to p-p interactions forming columnar superstructures with high one-dimensional charge carrier mobility and potential application in photovoltaic devices. The different functionalities attached to the aromatic cores significantly influence the behavior of these systems allowing the experimentalists to modify the structures to fine-tune the desired thermotropic properties or charge carrier mobility. The aim of the presented studies was to understand the interplay between the driving forces causing self-assembly by relating the structural and dynamic information about the investigated systems. The supramolecular organization is investigated by applying 1H solid state NMR recoupling techniques. The results are related with DSC and X-ray scattering data. Detailed information about the site-specific molecular dynamics is gained by recording spinning sideband patterns using 1H-1H and 13C-1H solid state NMR recoupling techniques. The determined dipole-dipole coupling constants are then related with the coupling constants of the respective rigid pairs, thus providing local dynamic order parameters for the respective moieties. The investigations presented reveal that in the crystalline state the preferred arrangement in the columnar stack of discotic molecules modified with alkyl chains is tilted. This leads to characteristic differences in the 1H chemical shifts of otherwise chemically equivalent protons. Introducing branches and increasing the length of the alkyl chains results in lower mesophase transitions and disordered columnar stacks. In the.

Structure and Dynamics of Bulk Polymers by NMR-Methods

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Publisher : Springer
ISBN 13 :
Total Pages : 200 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Structure and Dynamics of Bulk Polymers by NMR-Methods by : Vladimir D. Fedotov

Download or read book Structure and Dynamics of Bulk Polymers by NMR-Methods written by Vladimir D. Fedotov and published by Springer. This book was released on 1989-05-11 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years the development of the NMR method has been closely linked to the creation of the theory of the NMR in solids and with the elaboration on their basic principles and methods of high resolution in solids. The aim of this volume is to explain simply and clearly the principles for the understanding of the NMR in solid polymers, to show what kind of information can be gained using NMR investigations of bulk polymers, and to demonstrate the ways of obtaining this information, their correctness and their place in comparison with other methods. The discussion is restricted to the most important and typical nuclei 1H, 13C, and (briefly) 2D, and, in connection with that, to the dipolar and quadrupolar interaction and to the chemical shift.

Supramolecular Order and Dynamics of Discotic Materials Studied by Solid-state NMR Recoupling Methods

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ISBN 13 :
Total Pages : pages
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Book Synopsis Supramolecular Order and Dynamics of Discotic Materials Studied by Solid-state NMR Recoupling Methods by :

Download or read book Supramolecular Order and Dynamics of Discotic Materials Studied by Solid-state NMR Recoupling Methods written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The topic of this thesis is the investigation of structure, order and dynamics in discotic mesogens by advancedsolid-state NMR spectroscopy. Most of the discotic mesogensunder investigation are hexa-peri-hexabenzocoronene (HBC)derivatives which are of particular interest for potentialdevice applications due to their high one-dimensional chargecarrier mobilities. The supramolecular stacking arrangement of the discoticcores was investigated by 2D 1H-1H double-quantum (DQ)methods, which were modified by incorporating the WATERGATEsuppression technique into the experiments in order toovercome severe phase problems arising from the strongsignal of the long alkyl sidechains. Molecular dynamics and sample orientation was probed throughthe generation of sideband patterns by reconversion rotorencoding in 2D recoupling experiments. These experimentswere extended by new recoupling schemes to enable thedistinction of motion and orientation effects. The solid-state NMR studies presented in this work aim tothe understanding of structure-property relationships in theinvestigated discotic materials, while the experimentsapplied to these materials include new recoupling schemeswhich make the desired information on molecular orientationand dynamics accessible without isotope labelling.

Structure, Organization and Dynamics of Functional Supramolecular Materials Studied by Solid-state NMR

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (463 download)

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Book Synopsis Structure, Organization and Dynamics of Functional Supramolecular Materials Studied by Solid-state NMR by : Ümit Akbey

Download or read book Structure, Organization and Dynamics of Functional Supramolecular Materials Studied by Solid-state NMR written by Ümit Akbey and published by . This book was released on 2008 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Supramolecular Chemistry II

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Publisher : Elsevier
ISBN 13 : 0128031999
Total Pages : 4627 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Comprehensive Supramolecular Chemistry II by : George W. Gokel

Download or read book Comprehensive Supramolecular Chemistry II written by George W. Gokel and published by Elsevier. This book was released on 2017-06-22 with total page 4627 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Supramolecular Chemistry II, Second Edition, Nine Volume Set is a ‘one-stop shop’ that covers supramolecular chemistry, a field that originated from the work of researchers in organic, inorganic and physical chemistry, with some biological influence. The original edition was structured to reflect, in part, the origin of the field. However, in the past two decades, the field has changed a great deal as reflected in this new work that covers the general principles of supramolecular chemistry and molecular recognition, experimental and computational methods in supramolecular chemistry, supramolecular receptors, dynamic supramolecular chemistry, supramolecular engineering, crystallographic (engineered) assemblies, sensors, imaging agents, devices and the latest in nanotechnology. Each section begins with an introduction by an expert in the field, who offers an initial perspective on the development of the field. Each article begins with outlining basic concepts before moving on to more advanced material. Contains content that begins with the basics before moving on to more complex concepts, making it suitable for advanced undergraduates as well as academic researchers Focuses on application of the theory in practice, with particular focus on areas that have gained increasing importance in the 21st century, including nanomedicine, nanotechnology and medicinal chemistry Fully rewritten to make a completely up-to-date reference work that covers all the major advances that have taken place since the First Edition published in 1996

Dynamics and Structure of Semicrystalline Polymers as Characterized by NMR, and Their Relationship to Macroscopic Properties

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Publisher :
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.:/5 (431 download)

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Book Synopsis Dynamics and Structure of Semicrystalline Polymers as Characterized by NMR, and Their Relationship to Macroscopic Properties by : Weiguo Hu

Download or read book Dynamics and Structure of Semicrystalline Polymers as Characterized by NMR, and Their Relationship to Macroscopic Properties written by Weiguo Hu and published by . This book was released on 1999 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:

A Practical Guide to Understanding the NMR of Polymers

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Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 440 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis A Practical Guide to Understanding the NMR of Polymers by : Peter A. Mirau

Download or read book A Practical Guide to Understanding the NMR of Polymers written by Peter A. Mirau and published by Wiley-Interscience. This book was released on 2005 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Practical Guide to Understanding the NMR of Polymers presents an introduction to the theory and practice of NMR, and includes sections on the fundamental principles of NMR and the applications to polymers. This book will help readers understand how these methods can be used to determine the chemical structure of polymers that influences the macroscopic properties. Solid state NMR methods are introduced to enable the readers to measure the structure of polymers on longer length scales. It is also shown how NMR is used to measure the molecular dynamics that can be related to the mechanical properties of polymers.