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Ligand Field Parameters
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Book Synopsis Ligand-Field Parameters by : M. Gerloch
Download or read book Ligand-Field Parameters written by M. Gerloch and published by Cambridge University Press. This book was released on 1973-08-02 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.
Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Book Synopsis Ligand Field Theory and Its Applications by : Brian N. Figgis
Download or read book Ligand Field Theory and Its Applications written by Brian N. Figgis and published by Wiley-VCH. This book was released on 2000 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete, up-to-date treatment of ligand field theory and its applications Ligand Field Theory and Its Applications presents an up-to-date account of ligand field theory, the model currently used to describe the metal-ligand interactions in transition metal compounds, and the way it is used to interpret the physical properties of the complexes. It examines the traditional electrostatic crystal field model, still widely used by physicists, as well as covalent approaches such as the angular overlap model, which interprets the metal ligand interactions using parameters relating directly to chemical behavior. Written by internationally recognized experts in the field, this book provides a comparison between ligand field theory and more sophisticated treatments as well as an account of the methods used to calculate the energy levels in compounds of the transition metals. It also covers physical properties such as stereochemistry, light absorption, and magnetic behavior. An emphasis on the interpretation of experimental results broadens the book's field of interest beyond transition metal chemistry into the many other areas where these metal ions play an important role. As clear and accessible as Brian Figgis's 1966 classic Introduction to Ligand Fields, this new book provides inorganic and bioinorganic chemists as well as physical chemists, chemical physicists, and spectroscopists with a much-needed overview of the many significant changes that have taken place in ligand field theory over the past 30 years.
Book Synopsis Magnetism and Ligand-Field Analysis by : M. Gerloch
Download or read book Magnetism and Ligand-Field Analysis written by M. Gerloch and published by CUP Archive. This book was released on 1983 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, a synthesis of old and new notions straddling the disciplines of physics and chemistry is described.
Download or read book Ligand Field written by Ekkehard Konig and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: Twenty years ago Tanabe and Sugano published the first ligand field energy diagrarns which are applicable to dN electronic configurations. These diagrams are limited in scope in that they can be used only for octahedral symmetry and for a limited number of terms. The present volume is an attempt to fill the gap by providing a reasonable nurober of complete and accurate ligand field energy diagrarns for dN configurations in the most commonly encountered symmetries. Despite their limited nature, the diagrarns of Tanabe and Sugano were exten sively used in the past in order to rationalize optical and luminescence spectra and to discuss various electronic properties of transition metal ions, their coordination compounds and solids. Moreover, Tanabe-Sugano diagrams have an established place in the theory of transition metal compounds and are included in most textbooks of inorganic and coordination chemistry. It is expected that the present diagrarns will be found useful for a similar purpose.
Book Synopsis Spectroscopic Properties of Rare Earths in Optical Materials by : Guokui Liu
Download or read book Spectroscopic Properties of Rare Earths in Optical Materials written by Guokui Liu and published by Springer Science & Business Media. This book was released on 2006-01-29 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aimed at researchers and graduate students, this book provides up-to-date information about the electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties covers electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions of materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.
Book Synopsis Concise Encyclopedia of Magnetic and Superconducting Materials by : K.H.J. Buschow
Download or read book Concise Encyclopedia of Magnetic and Superconducting Materials written by K.H.J. Buschow and published by Elsevier. This book was released on 2005-12-28 with total page 1361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Magnetic and superconducting materials pervade every avenue of the technological world – from microelectronics and mass-data storage to medicine and heavy engineering. Both areas have experienced a recent revitalisation of interest due to the discovery of new materials, and the re-evaluation of a wide range of basic mechanisms and phenomena.This Concise Encyclopedia draws its material from the award-winning Encyclopedia of Materials and Engineering, and includes updates and revisions not available in the original set -- making it the ideal reference companion for materials scientists and engineers with an interest in magnetic and superconducting materials. - Contains in excess of 130 articles, taken from the award-winning Encyclopedia of Materials: Science and Technology, including ScienceDirect updates not available in the original set - Each article discusses one aspect of magnetic and superconducting materials and includes photographs, line drawings and tables to aid the understanding of the topic at hand - Cross-referencing guides readers to articles covering subjects of related interest
Book Synopsis Systematics and the Properties of the Lanthanides by : Shyama P. Sinha
Download or read book Systematics and the Properties of the Lanthanides written by Shyama P. Sinha and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science is not a mere collection of facts. It is the correlation of facts, the interpretative synthesis of the available knowledge and its application that excite the imagination of a scientist. Even in these days of modern technology, the need for quick and accurate dissemination of new information and current concepts still exists. Conferences and Symposia offer one direct method of communication. The Summer Schools are another approach. The success of a Summer School is mainly due to that human factor and under standing that goes with it and allows for extensive and often time-unrestricted discussions. During the course of the past 20 years, one of the most in tensively studied groups of elements in the Periodic Table is the Lanthanides. In this period, we have increased our knowledge on these once exotic elements, which were once considered to be a part of a lean and hungry industry, many-fold due to the involve ment of scientists from various disciplines. The purpose of our Summer School was to bring a group of ex perts and participants together for the exchange of ideas and in formation in an informal setting and to promote interdisciplinary interactions. Out of many conceivable topics, we selected the following five as the main basis to broaden our knowledge and understanding I) Systematics 2) Structure 3) Electronic and Magnetic Proper ties 4) Spectroscopic Properties and 5) Lanthanide Geochemistry.
Book Synopsis The Effective Crystal Field Potential by : J. Mulak
Download or read book The Effective Crystal Field Potential written by J. Mulak and published by Elsevier. This book was released on 2000-06-22 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: As it results from the very nature of things, the spherical symmetry of the surrounding of a site in a crystal lattice or an atom in a molecule can never occur. Therefore, the eigenfunctions and eigenvalues of any bound ion or atom have to differ from those of spherically symmetric respective free ions. In this way, the most simplified concept of the crystal field effect or ligand field effect in the case of individual molecules can be introduced. The conventional notion of the crystal field potential is narrowed to its non-spherical part only through ignoring the dominating spherical part which produces only a uniform energy shift of gravity centres of the free ion terms. It is well understood that the non-spherical part of the effective potential "seen" by open-shell electrons localized on a metal ion plays an essential role in most observed properties. Light adsorption, electron paramagnetic resonance, inelastic neutron scattering and basic characteristics derived from magnetic and thermal measurements, are only examples of a much wider class of experimental results dependent on it. The influence is discerned in all kinds of materials containing unpaired localized electrons: ionic crystals, semiconductors and metallic compounds including materials as intriguing as high-Tc superconductors, or heavy fermion systems. It is evident from the above that we deal with a widespread effect relative to all free ion terms except those which can stand the lowered symmetry, e.g. S-terms. Despite the universality of the phenomenon, the available handbooks on solid state physics pay only marginal attention to it, merely making mention of its occurrence. Present understanding of the origins of the crystal field potential differs essentially from the pioneering electrostatic picture postulated in the twenties. The considerable development of the theory that has been put forward since then can be traced in many regular articles scattered throughout the literature. The last two decades have left their impression as well but, to the authors' best knowledge, this period has not been closed with a more extended review. This has also motivated us to compile the main achievements in the field in the form of a book.
Book Synopsis Understanding Molecular Properties by : John S. Avery
Download or read book Understanding Molecular Properties written by John S. Avery and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The Theory of Atomic Spectra", surrrrnanzlllg all that was then known about the quantum theory of free atoms; and in 1961, J.S. Griffith published "The Theory of Transition Metal Ions", in which he combined the ideas in Condon and Shortley's book with those of Bethe, Schlapp, Penney and Van Vleck. All this work, however, was done by physicists, and the results were reported in a way which was more accessable to physicists than to chemists. In the meantime, Carl J. Ballhausen had been studying quantum theory with W. Moffitt at Harvard; and in 1962 (almost simultaneously with Griffith) he published his extremely important book, "Introduction to Ligand Field Theory". This influential book was written from the standpoint of a chemist, and it became the standard work from which chemists learned the quantum theory of transition metal complexes. While it treated in detail the group theoretical aspects of crystal field theory, Carl J. Ballhausen's book also emphasized the limitations of the theory. As he pointed out, it is often not sufficient to treat the central metal ion as free (apart from the influence of the charges on the surrounding ligands): - In many cases hybridization of metal and ligand orbitals is significant. Thus, in general. a molecular orbital treatment is needed to describe transition metal complexes. However, much of the group theory developed In connection with crystal field theory can also be used in the molecular orbital treatment.
Book Synopsis Optical Properties of Materials and Their Applications by : Jai Singh
Download or read book Optical Properties of Materials and Their Applications written by Jai Singh and published by John Wiley & Sons. This book was released on 2020-01-07 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a semi-quantitative approach to recent developments in the study of optical properties of condensed matter systems Featuring contributions by noted experts in the field of electronic and optoelectronic materials and photonics, this book looks at the optical properties of materials as well as their physical processes and various classes. Taking a semi-quantitative approach to the subject, it presents a summary of the basic concepts, reviews recent developments in the study of optical properties of materials and offers many examples and applications. Optical Properties of Materials and Their Applications, 2nd Edition starts by identifying the processes that should be described in detail and follows with the relevant classes of materials. In addition to featuring four new chapters on optoelectronic properties of organic semiconductors, recent advances in electroluminescence, perovskites, and ellipsometry, the book covers: optical properties of disordered condensed matter and glasses; concept of excitons; photoluminescence, photoinduced changes, and electroluminescence in noncrystalline semiconductors; and photoinduced bond breaking and volume change in chalcogenide glasses. Also included are chapters on: nonlinear optical properties of photonic glasses; kinetics of the persistent photoconductivity in crystalline III-V semiconductors; and transparent white OLEDs. In addition, readers will learn about excitonic processes in quantum wells; optoelectronic properties and applications of quantum dots; and more. Covers all of the fundamentals and applications of optical properties of materials Includes theory, experimental techniques, and current and developing applications Includes four new chapters on optoelectronic properties of organic semiconductors, recent advances in electroluminescence, perovskites, and ellipsometry Appropriate for materials scientists, chemists, physicists and electrical engineers involved in development of electronic materials Written by internationally respected professionals working in physics and electrical engineering departments and government laboratories Optical Properties of Materials and Their Applications, 2nd Edition is an ideal book for senior undergraduate and postgraduate students, and teaching and research professionals in the fields of physics, chemistry, chemical engineering, materials science, and materials engineering.
Book Synopsis Handbook on the Physics and Chemistry of Rare Earths by :
Download or read book Handbook on the Physics and Chemistry of Rare Earths written by and published by Elsevier. This book was released on 2011-09-22 with total page 559 pages. Available in PDF, EPUB and Kindle. Book excerpt: Optical spectroscopy has been instrumental in the discovery of many lanthanide elements. In return, these elements have always played a prominent role in lighting devices and light conversion technologies (Auer mantles, incandescent lamps, lasers, cathode-ray and plasma displays). They are also presently used in highly sensitive luminescent bio-analyses and cell imaging. This volume of the Handbook on the Physics and Chemistry of Rare Earths is entirely devoted to the photophysical properties of these elements. It is dedicated to the late Professor William T (Bill) Carnall who has pioneered the understanding of lanthanide spectra in the 1960's and starts with a Dedication to this scientist. The following five chapters describe various aspects of lanthanide spectroscopy and its applications. Chapters 231 presents state-of-the-art theoretical calculations of lanthanide energy levels and transition intensities. It is followed by a review (Chapter 232) on both theoretical and experimental aspects of f-d transitions, a less well known field of lanthanide spectroscopy, yet very important for the design of new optical materials. Chapter 233 describes how confinement effects act on the photophysical properties of lanthanides when they are inserted into nanomaterials, including nanoparticles, nanosheets, nanowires, nanotubes, insulating and semiconductor nanocrystals. The use of lanthanide chelates for biomedical analyses is presented in Chapter 234; long lifetimes of the excited states of lanthanide ions allow the use of time-resolved spectroscopy, which leads to highly sensitive analyses devoid of background effect from the autofluorescence of the samples. The last review (Chapter 235) provides a comprehensive survey of near-infrared (NIR) emitting molecular probes and devices, spanning an all range of compounds, from simple chelates to macrocyclic complexes, heterometallic functional edifices, coordination polymers and other extended structures. Applications ranging from telecommunications to light-emitting diodes and biomedical analyses are assessed.- Provides a comprehensive look at optical spectroscopy and its applications- A volume in the continuing authoritative series which deals with the chemistry, materials science, physics and technology of the rare earth elements
Book Synopsis Optical Spectra and Chemical Bonding in Inorganic Compounds by : Thomas Schönherr
Download or read book Optical Spectra and Chemical Bonding in Inorganic Compounds written by Thomas Schönherr and published by Springer Science & Business Media. This book was released on 2004-01-07 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: with contributions by numerous experts
Book Synopsis Handbook on the Physics and Chemistry of Rare Earths by : K.A. Gschneidner
Download or read book Handbook on the Physics and Chemistry of Rare Earths written by K.A. Gschneidner and published by Elsevier. This book was released on 2003-06-19 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of the Handbook illustrates the rich variety of topics covered by rare earth science. Three chapters are devoted to the description of solid state compounds: skutterudites (Chapter 211), rare earth -antimony systems (Chapter 212), and rare earth-manganese perovskites (Chapter 214). Two other reviews deal with solid state properties: one contribution includes information on existing thermodynamic data of lanthanide trihalides (Chapter 213) while the other one describes optical properties of rare earth compounds under pressure (Chapter 217). Finally, two chapters focus on solution chemistry. The state of the art in unraveling solution structure of lanthanide-containing coordination compounds by paramagnetic nuclear magnetic resonance is outlined in Chapter 215. The potential of time-resolved, laser-induced emission spectroscopy for the analysis of lanthanide and actinide solutions is presented and critically discussed in Chapter 216.
Book Synopsis Handbook of Applied Solid State Spectroscopy by : D.R. Vij
Download or read book Handbook of Applied Solid State Spectroscopy written by D.R. Vij and published by Springer Science & Business Media. This book was released on 2007-02-15 with total page 748 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid-State spectroscopy is a burgeoning field with applications in many branches of science, including physics, chemistry, biosciences, surface science, and materials science. This handbook brings together in one volume information about various spectroscopic techniques that is currently scattered in the literature of these disciplines. This concise yet comprehensive volume covers theory and applications of a broad range of spectroscopies. It provides an overview of sixteen spectroscopic technique and self-contained chapters present up-to-date scientific and technical information and references with minimal overlap and redundancy.
Book Synopsis Luminescent Materials by : Mikhail G. Brik
Download or read book Luminescent Materials written by Mikhail G. Brik and published by Walter de Gruyter GmbH & Co KG. This book was released on 2023-03-06 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives an overview on the fundamentals and recent developments in the field of luminescent materials. Starting from the definitions and properties of phosphors, novel application areas as well as spectroscopic methods for characterization will be described. The reader will benefit from the vast knowledge of the authors with backgrounds in industry as well as academia.
Book Synopsis Electronic Structure and Properties of Transition Metal Compounds by : Isaac B. Bersuker
Download or read book Electronic Structure and Properties of Transition Metal Compounds written by Isaac B. Bersuker and published by John Wiley & Sons. This book was released on 2010-12-01 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications. Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for advanced undergraduate and graduate students. Novel material is introduced in description of multi-orbital chemical bonding, spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems. This is an excellent reference for chemists, researchers and teachers, and advanced undergraduate and graduate students in inorganic, coordination, and organometallic chemistry.
