Kinetics and Modeling of the Radical Polymerization of Acrylic Acid and of Methacrylic Acid in Aqueous Solution

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (931 download)

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Book Synopsis Kinetics and Modeling of the Radical Polymerization of Acrylic Acid and of Methacrylic Acid in Aqueous Solution by : Nils Friedrich Gunter Wittenberg

Download or read book Kinetics and Modeling of the Radical Polymerization of Acrylic Acid and of Methacrylic Acid in Aqueous Solution written by Nils Friedrich Gunter Wittenberg and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The radical polymerization of methacrylic acid, acrylic acid and acrylamide in aqueous solution has been investigated. Detailed kinetic models for both acrylic acid, AA, and methacrylic acid, MAA, have been developed applying the program PREDICI. Good representation of experimental conversion vs. time profiles and molar mass distributions as well as, in case of AA, the branching level could be achieved. The polymerization of MAA has been studied at 35 and 50 °C with focus on the influence of 2-mercaptoethanol, ME, as chain transfer agent, CTA, on reaction kinetics. The rate coefficient of t ...

Radical Polymerization Kinetics in Aqueos Solution and in Systems with Secondary and Tertiary Radicals Studied by Novel Pulsed-laser Techniques

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Publisher : Cuvillier Verlag
ISBN 13 : 386727682X
Total Pages : 325 pages
Book Rating : 4.8/5 (672 download)

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Book Synopsis Radical Polymerization Kinetics in Aqueos Solution and in Systems with Secondary and Tertiary Radicals Studied by Novel Pulsed-laser Techniques by : Pascal Hesse

Download or read book Radical Polymerization Kinetics in Aqueos Solution and in Systems with Secondary and Tertiary Radicals Studied by Novel Pulsed-laser Techniques written by Pascal Hesse and published by Cuvillier Verlag. This book was released on 2008 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Radical Polymerization

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Publisher : John Wiley & Sons
ISBN 13 : 3527610871
Total Pages : 270 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Radical Polymerization by : Michael Buback

Download or read book Radical Polymerization written by Michael Buback and published by John Wiley & Sons. This book was released on 2007-06-27 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume from the successful Macromolecular Symposia series presents the contributions from the IUPAC-sponsored International Symposium on "Radical Polymerization: Kinetics and Mechanism", held in Il Ciocco, Italy, in September, 2006. This was the fourth within the series of so-called SML conferences, which are the major scientific forum for addressing kinetic and mechanistic aspects of free-radical polymerization and controlled radical polymerization. SML IV again marked an important step forward toward the better understanding of the kinetics and mechanism of radical polymerization, which is extremely relevant for both conventional and controlled radical polymerization and for people in academia as well as in industry. Here, top international authors, such as K. Matyjaszewski, T. P. Davis and T. Fukuda, present their latest research. The five major themes covered were: Fundamentals of free-radical polymerization, heterogeneous polymerization, controlled radical polymerization, polymer reaction engineering, and polymer characterization.

Kinetics and Modeling of Free Radical Aqueous Phase Polymerization of Acrylamide with Acrylic Acid at Varying Degrees of Ionization

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Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Kinetics and Modeling of Free Radical Aqueous Phase Polymerization of Acrylamide with Acrylic Acid at Varying Degrees of Ionization by : CALISTA. Preusser

Download or read book Kinetics and Modeling of Free Radical Aqueous Phase Polymerization of Acrylamide with Acrylic Acid at Varying Degrees of Ionization written by CALISTA. Preusser and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Kinetics of polymerization in aqueous Solution, mechanism of methacrylic acid polymerization

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ISBN 13 :
Total Pages : pages
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Book Synopsis Kinetics of polymerization in aqueous Solution, mechanism of methacrylic acid polymerization by : Gideon Blauer

Download or read book Kinetics of polymerization in aqueous Solution, mechanism of methacrylic acid polymerization written by Gideon Blauer and published by . This book was released on 1951 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ullmann's Polymers and Plastics

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Publisher : John Wiley & Sons
ISBN 13 : 3527685952
Total Pages : 1934 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Ullmann's Polymers and Plastics by : Wiley-VCH

Download or read book Ullmann's Polymers and Plastics written by Wiley-VCH and published by John Wiley & Sons. This book was released on 2016-03-18 with total page 1934 pages. Available in PDF, EPUB and Kindle. Book excerpt: Your personal Ullmann's: Chemical and physical characteristics, production processes and production figures, main applications, toxicology and safety information are all to be found here in one single resource - bringing the vast knowledge of the Ullmann's Encyclopedia to the desks of industrial chemists and chemical engineers. The ULLMANN’S perspective on polymers and plastics brings reliable information on more than 1500 compounds and products straight to your desktop Carefully selected “best of” compilation of 61 topical articles from the Encyclopedia of Industrial Chemistry on economically important polymers provide a wealth of chemical, physical and economic data on more than 1000 different polymers and hundreds of modifications Contains a wealth of information on the production and use of all industrially relevant polymers and plastics, including organic and inorganic polymers, fibers, foams and resins Extensively updated: more than 30% of the content has been added or updated since the launch of the 7th edition of the Ullmann’s encyclopedia in 2011 and is now available in print for the first time 4 Volumes

Process-Spray

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Publisher : Springer
ISBN 13 : 3319323709
Total Pages : 1030 pages
Book Rating : 4.3/5 (193 download)

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Book Synopsis Process-Spray by : Udo Fritsching

Download or read book Process-Spray written by Udo Fritsching and published by Springer. This book was released on 2016-08-01 with total page 1030 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the latest research on producing functional particles using spray processes. The authors detail micro level elementary processes and phase boundaries, process analysis scaling and modeling, and macro level process functions and particle properties. They include numerical simulations and particulars of experiments for deriving process conditions for particle production.

A Kinetic Study of Acrylamide/ Acrylic Acid Copolymerization

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ISBN 13 :
Total Pages : 97 pages
Book Rating : 4.:/5 (827 download)

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Book Synopsis A Kinetic Study of Acrylamide/ Acrylic Acid Copolymerization by : Muhammad Haque

Download or read book A Kinetic Study of Acrylamide/ Acrylic Acid Copolymerization written by Muhammad Haque and published by . This book was released on 2010 with total page 97 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homo- and co-polymers of acrylamide (AAm) and acrylic acid (or acrylate salt) (AA) or methacrylic acid (MAA)) are important classes of water-soluble polymers due to their numerous applications in fields such as super absorbents, additives in cosmetics, membrane technology, waste-water treatment and oil field operations. These polymers are generally made by free radical polymerization. For copolymerization reactions it is extremely important to know the details of reaction kinetics in order to ascertain the kinetic effects of different reaction parameters, which ultimately dictate final copolymer composition, microstructure and properties. The reactivity ratios for copolymerization of AAm and AA have been shown to be dependent on pH and they also change with reaction solvent. The present experimental investigation has been performed to study the kinetics of copolymerization of these monomers in aqueous and alcoholic media by considering factors such as type of initiator and solvent, and pH, in order to determine how they affect the reactivity ratios of these monomers. Reactivity ratios were determined by non-linear least squares (NLLS) and the error-in-variables-model (EVM) techniques and full conversion range kinetic investigations were carried out to confirm these values.

Monitoring Polymerization Reactions

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Publisher : John Wiley & Sons
ISBN 13 : 0470917385
Total Pages : 493 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Monitoring Polymerization Reactions by : Wayne F. Reed

Download or read book Monitoring Polymerization Reactions written by Wayne F. Reed and published by John Wiley & Sons. This book was released on 2014-01-21 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.

A Calorimetric Evaluation of the PH- and Conversion-dependent Kinetics of (meth)acrylic Acid Solution Polymerization

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ISBN 13 :
Total Pages : 4 pages
Book Rating : 4.:/5 (368 download)

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Book Synopsis A Calorimetric Evaluation of the PH- and Conversion-dependent Kinetics of (meth)acrylic Acid Solution Polymerization by : Robert A. Scott

Download or read book A Calorimetric Evaluation of the PH- and Conversion-dependent Kinetics of (meth)acrylic Acid Solution Polymerization written by Robert A. Scott and published by . This book was released on 1996 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Polymer Reaction Engineering

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Publisher : Academic Press
ISBN 13 : 0128215224
Total Pages : 350 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Advances in Polymer Reaction Engineering by :

Download or read book Advances in Polymer Reaction Engineering written by and published by Academic Press. This book was released on 2020-10-31 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Polymer Reaction Engineering, Volume 56 in the Advances in Chemical Engineering series is aimed at reporting the latest advances in the field of polymer synthesis. Chapters in this new release include Polymer reaction engineering and composition control in free radical copolymers, Reactor control and on-line process monitoring in free radical emulsion polymerization, Exploiting pulsed laser polymerization to retrieve intrinsic kinetic parameters in radical polymerization, 3D printing in chemical engineering, Renewable source monomers in waterborne polymer dispersions, Importance of models and digitalization in Polymer Reaction Engineering, Recent Advances in Modelling of Radical Polymerization, and more. Covers recent advances in the control and monitoring of polymerization processes and in reactor configurations Provides modelling of polymerization reactions and up-to-date approaches to estimate reaction rate constants Includes authoritative opinions from experts in academia and industry

Radical Polymerization: Kinetics and Mechanism

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Publisher : Cuvillier Verlag
ISBN 13 : 3736919913
Total Pages : 176 pages
Book Rating : 4.7/5 (369 download)

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Book Synopsis Radical Polymerization: Kinetics and Mechanism by :

Download or read book Radical Polymerization: Kinetics and Mechanism written by and published by Cuvillier Verlag. This book was released on 2006-08-22 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Cu- and Fe-mediated Atom-Transfer Radical Polymerization in Aqueous Solution

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (958 download)

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Book Synopsis Cu- and Fe-mediated Atom-Transfer Radical Polymerization in Aqueous Solution by : Sebastian Smolne

Download or read book Cu- and Fe-mediated Atom-Transfer Radical Polymerization in Aqueous Solution written by Sebastian Smolne and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The mechanism and the kinetics of metal-catalyzed radical polymerization were investigated by spectroscopic methods and by PREDICI® simulation. A particular focus was on Cu- and Fe-mediated atom-transfer radical polymerization (ATRP) in aqueous solution of poly(ethylene glycol)ether methacrylate (PEGMA) and on monomer-free model systems. The propagation kinetics of PEGMA in aqueous solution were determined between 20 and 77 °C via PLP-SEC. The significant dependence of kp on monomer content is due to the difference in the degree by which internal rotations of the transition state for propag...

Photoinitiated Polymerization

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ISBN 13 :
Total Pages : 592 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Photoinitiated Polymerization by : Kevin D. Belfield

Download or read book Photoinitiated Polymerization written by Kevin D. Belfield and published by . This book was released on 2003 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photoinitiated Polymerization discusses the latest developments in photoinitiated polymerization. This book includes the current state of free radical, cationic, and based catalyzed photopolymerization and their applications.

Poly(2-vinylpyridine) as a Template for the Radical Polymerization of Methacrylic Acid

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ISBN 13 :
Total Pages : 126 pages
Book Rating : 4.:/5 (521 download)

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Book Synopsis Poly(2-vinylpyridine) as a Template for the Radical Polymerization of Methacrylic Acid by : Jaap Smid

Download or read book Poly(2-vinylpyridine) as a Template for the Radical Polymerization of Methacrylic Acid written by Jaap Smid and published by . This book was released on 1985 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear Science Abstracts

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ISBN 13 :
Total Pages : 680 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Nuclear Science Abstracts by :

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Poly(2-vinylpyridine) [Poly(two-vinylpyridine)] as a template for the radical polymerization of methacrylic acid

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ISBN 13 :
Total Pages : 126 pages
Book Rating : 4.:/5 (256 download)

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Book Synopsis Poly(2-vinylpyridine) [Poly(two-vinylpyridine)] as a template for the radical polymerization of methacrylic acid by : Jacob Smid

Download or read book Poly(2-vinylpyridine) [Poly(two-vinylpyridine)] as a template for the radical polymerization of methacrylic acid written by Jacob Smid and published by . This book was released on 1985 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt: