Kinetics and Mechanisms of Reactions of Cyanocobalt and -chromium Complexes in Acidic Solution

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Total Pages : 302 pages
Book Rating : 4.:/5 (311 download)

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Book Synopsis Kinetics and Mechanisms of Reactions of Cyanocobalt and -chromium Complexes in Acidic Solution by : Birk James P.

Download or read book Kinetics and Mechanisms of Reactions of Cyanocobalt and -chromium Complexes in Acidic Solution written by Birk James P. and published by . This book was released on 1967 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Kinetics and Mechanisms of Some Reactions Involving Chromium (III) Malonate Complexes

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ISBN 13 :
Total Pages : 122 pages
Book Rating : 4.:/5 (861 download)

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Book Synopsis The Kinetics and Mechanisms of Some Reactions Involving Chromium (III) Malonate Complexes by : Michael J. Frank

Download or read book The Kinetics and Mechanisms of Some Reactions Involving Chromium (III) Malonate Complexes written by Michael J. Frank and published by . This book was released on 1971 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Scientific and Technical Aerospace Reports

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ISBN 13 :
Total Pages : 1498 pages
Book Rating : 4.U/5 (183 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1968 with total page 1498 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear Science Abstracts

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ISBN 13 :
Total Pages : 874 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Nuclear Science Abstracts by :

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1967-11 with total page 874 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Current Chemical Papers

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ISBN 13 :
Total Pages : 1764 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Current Chemical Papers by : Chemical Society (Great Britain)

Download or read book Current Chemical Papers written by Chemical Society (Great Britain) and published by . This book was released on 1968 with total page 1764 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Kinetics and Mechanisms of Decomposition Reactions of Binuclear, Double-bridged Chromium (III) Complexes

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ISBN 13 :
Total Pages : 178 pages
Book Rating : 4.:/5 (472 download)

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Book Synopsis The Kinetics and Mechanisms of Decomposition Reactions of Binuclear, Double-bridged Chromium (III) Complexes by : Damien Wolcott

Download or read book The Kinetics and Mechanisms of Decomposition Reactions of Binuclear, Double-bridged Chromium (III) Complexes written by Damien Wolcott and published by . This book was released on 1965 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Kinetics and Mechanisms of Reactions of Some Polymeric Cobalt (III) Ammines

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ISBN 13 :
Total Pages : 226 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Kinetics and Mechanisms of Reactions of Some Polymeric Cobalt (III) Ammines by : Alan Bruce Hoffman

Download or read book Kinetics and Mechanisms of Reactions of Some Polymeric Cobalt (III) Ammines written by Alan Bruce Hoffman and published by . This book was released on 1967 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Dissertation Abstracts

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ISBN 13 :
Total Pages : 1018 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Dissertation Abstracts by :

Download or read book Dissertation Abstracts written by and published by . This book was released on 1967 with total page 1018 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Dissertation Abstracts International

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ISBN 13 :
Total Pages : 1396 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Dissertation Abstracts International by :

Download or read book Dissertation Abstracts International written by and published by . This book was released on 1970 with total page 1396 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hydrolysis Reactions of Some Fluorotetramine Chromium (III) Complexes

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ISBN 13 :
Total Pages : 136 pages
Book Rating : 4.:/5 (117 download)

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Book Synopsis Hydrolysis Reactions of Some Fluorotetramine Chromium (III) Complexes by : Mahmoud Delavar

Download or read book Hydrolysis Reactions of Some Fluorotetramine Chromium (III) Complexes written by Mahmoud Delavar and published by . This book was released on 1976 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of the study was to investigate the kinetics and mechanisms of the replacement of fluoro-ligand from a series of complexes in aqueous acidic solutions. The compounds studied were all octahedral complexes of chromium (III) or cobalt (III). The kinetic runs were studied by a spectrophotometric method and by direct estimation of free fluoride ion concentrations. All reactions were first order in complex ion concentration. The rate constants were all acidity function dependent. In no case was a maximum rate constant observed, even at very high acid concentrations. For some of the complexes rapid reversible changes of the visible and ultraviolet spectra are observed when the solutions are alternately carefully acidified and diluted. These spectral changes may be attributed to a rapid reversible protonation of the fluoro-ligand. The apparent ionisation ratios of the protonated species have been evaluated. The initial product of the hydrolysis reactions is the corresponding aquo (or aquofluoro) complex. For some of the compounds studied the aquofluoro species have been isolated for the first time. At later times some of the aquo-fluoro-species are anated by e.g. nitric or sulphuric acid. The kinetic results have been analysed according to the postulates of Zucker and Hammett and of Bunnett and of Bunnett and Olsen. The chromium complexes all appear to react via a mechanism in which water is involved as a proton transfer agent. In the case of a cobalt complex the water molecule is involved as a nucleophile. The reactions do not exhibit general acid catalysis but fluoro species (e.g. HF 2-, HF or F-) do catalyse the replacement of the fluoro-ligand. This catalysis is attributed to the unusual properties of hydrogen fluoride.

Iowa State Journal of Science

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ISBN 13 :
Total Pages : 912 pages
Book Rating : 4.:/5 (3 download)

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Book Synopsis Iowa State Journal of Science by :

Download or read book Iowa State Journal of Science written by and published by . This book was released on 1967 with total page 912 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Kinetics and Mechanisms of Substitutions in Octahedral Cobalt and Chromium Complexes

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Publisher : Open Dissertation Press
ISBN 13 : 9781361416631
Total Pages : pages
Book Rating : 4.4/5 (166 download)

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Book Synopsis The Kinetics and Mechanisms of Substitutions in Octahedral Cobalt and Chromium Complexes by : 許均如

Download or read book The Kinetics and Mechanisms of Substitutions in Octahedral Cobalt and Chromium Complexes written by 許均如 and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "The Kinetics and Mechanisms of Substitutions in Octahedral Cobalt and Chromium Complexes" by 許均如, Kwan-yu, Hui, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3122865 Subjects: Organochromium compounds Organocobalt compounds Substitution reactions

Kinetics and Mechanisms of Reactions of Cobaltic Complexes in Aqueous Solution

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)

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Book Synopsis Kinetics and Mechanisms of Reactions of Cobaltic Complexes in Aqueous Solution by : M. N. Malik

Download or read book Kinetics and Mechanisms of Reactions of Cobaltic Complexes in Aqueous Solution written by M. N. Malik and published by . This book was released on 1969 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Equilibrium and Kinetic Studies on Reactions of Chromium (III)-chloride Complex Ions in Acidic Water-methanol Solutions

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ISBN 13 :
Total Pages : 306 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis Equilibrium and Kinetic Studies on Reactions of Chromium (III)-chloride Complex Ions in Acidic Water-methanol Solutions by : Richard J. Baltisberger

Download or read book Equilibrium and Kinetic Studies on Reactions of Chromium (III)-chloride Complex Ions in Acidic Water-methanol Solutions written by Richard J. Baltisberger and published by . This book was released on 1963 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Iowa State College Journal of Science

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ISBN 13 :
Total Pages : 740 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Iowa State College Journal of Science by :

Download or read book Iowa State College Journal of Science written by and published by . This book was released on 1967 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Kinetics and Mechanism of the Reaction Between Chromium-carbene Complexes and Group IV Element Hydrides Inthe Presence of Pyridine

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Total Pages : pages
Book Rating : 4.:/5 (643 download)

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Book Synopsis Kinetics and Mechanism of the Reaction Between Chromium-carbene Complexes and Group IV Element Hydrides Inthe Presence of Pyridine by : Robert Miles Turner

Download or read book Kinetics and Mechanism of the Reaction Between Chromium-carbene Complexes and Group IV Element Hydrides Inthe Presence of Pyridine written by Robert Miles Turner and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Kinetics and Mechanisms of the Reactions of Several Cobalt Oxime Complexes and Nitrous Acid

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Total Pages : pages
Book Rating : 4.:/5 (988 download)

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Book Synopsis The Kinetics and Mechanisms of the Reactions of Several Cobalt Oxime Complexes and Nitrous Acid by : Steven C. Marolf

Download or read book The Kinetics and Mechanisms of the Reactions of Several Cobalt Oxime Complexes and Nitrous Acid written by Steven C. Marolf and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: