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Ion Radical Organic Chemistry
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Book Synopsis Ion-Radical Organic Chemistry by : Zory Vlad Todres
Download or read book Ion-Radical Organic Chemistry written by Zory Vlad Todres and published by CRC Press. This book was released on 2008-10-20 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry: Principles and Applications, Second Edition presents the recent changes that have occurred in the field since the publication of the first edition in 2003. This volume examines the formation, transformation, and application of ion-radicals in typical conditions of organic synthesis. Avoiding complex mathematics, the author explains the principles of ion-radical organic chemistry and presents an overview of organic ion-radical reactions. He reviews methods of determining ion-radical mechanisms and controlling ion-radical reactions. Wherever applicable, the text addresses issues relating to ecology and biomedical concerns as well as inorganic participants of the ion-radical organic reactions. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. Additional topics include electronic and opto-electronic devices, organic magnets and conductors, lubricants, other materials, and reactions of industrial or biomedical importance. The book concludes by providing an outlook on possible future development in this field. Researchers and practitioners engaged in active work on synthetic or mechanistic organic chemistry and its practical applications will find this text to be invaluable in both its scope and its depth.
Book Synopsis Ion-Radical Organic Chemistry by : Zory Vlad Todres
Download or read book Ion-Radical Organic Chemistry written by Zory Vlad Todres and published by CRC Press. This book was released on 2002-09-10 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relati
Book Synopsis Ion-Radical Organic Chemistry by : Zory Vlad Todres
Download or read book Ion-Radical Organic Chemistry written by Zory Vlad Todres and published by CRC Press. This book was released on 2002-09-10 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relating to ecology and biology, and inorganic participants in ion radical organic reactions. Applications discussed include the roles of ion radicals in biological systems and their uses in optoelectronics, organic metals, and the manufacture of paper.
Book Synopsis Organic Ion Radicals by : Zory V. Todres
Download or read book Organic Ion Radicals written by Zory V. Todres and published by . This book was released on 2003 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relating to ecology and biology, and inorganic participants in ion radical organic reactions. Applications discussed include the roles of ion radicals in biological systems and their uses in optoelectronics, organic metals, and the manufacture of paper.
Book Synopsis Free-Radical Chemistry by : D. C. Nonhebel
Download or read book Free-Radical Chemistry written by D. C. Nonhebel and published by CUP Archive. This book was released on 1974-01-31 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Radical Reactions in Organic Synthesis by : Samir Z. Zard
Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford Chemistry Masters. This book was released on 2003 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samir Zard provides a description of radical reactions and their applications in organic synthesis. This book shows that an with an elementary knowledge of kinetic and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems.
Book Synopsis Reagents for Radical and Radical Ion Chemistry by : David Crich
Download or read book Reagents for Radical and Radical Ion Chemistry written by David Crich and published by John Wiley & Sons. This book was released on 2013-05-30 with total page 1874 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.
Book Synopsis Radicals, Ion Radicals, and Triplets by : Nathan L. Bauld
Download or read book Radicals, Ion Radicals, and Triplets written by Nathan L. Bauld and published by Wiley-VCH. This book was released on 1997-09-26 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by an internationally acknowledged expert in the field, this book provides an overview of all major types of spin-bearing radicals, important intermediates in organic reactions. Many new synthetic methods involving radicals have been developed and discussed in the past five years; this is the only source book that focuses on the physical-organic aspects of radical chemistry.
Book Synopsis Radical Ions by : Emil Thomas Kaiser
Download or read book Radical Ions written by Emil Thomas Kaiser and published by . This book was released on 1968 with total page 814 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron spin densities / James R. Bolton -- Metal ketyls and related radical ions - electron structures and ion pair equilibria / Noboru Hirota -- Semidione radical anions / Glen A. Russell -- Radical cations / Gershon Vincow -- Orbital degeneracy in benzene and substituent effects / Kerry W. Bowers -- Recent advances in the chemistry of aromatic anion radicals / M. Thomas Jones -- Some organometallic radicals and ion radicals of the group IV elements / Grant Urry -- Radical anions of sulfur-containing aromatic compounds / M.M. Urberg and E.T. Kaiser -- Ionic processes in [gamma]-irradiated organic solids at -196 [degrees] / William H. Hamill -- The structure of inorganic radicals / Hilary J. Bower, M.C.R. Symons and D.J.A. Tinling -- Fragments in irradiated ionic solids / Joseph Cunningham -- Trapped radicals in inorganic glasses / A. Treinin -- Electron spin resonance of first row transition metal complex ions / H.A. Kuska and Max t. Rogers.
Book Synopsis Free Radicals in Organic Synthesis by : D. I. Davies
Download or read book Free Radicals in Organic Synthesis written by D. I. Davies and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Radical Ionic Systems by : Anders Lund
Download or read book Radical Ionic Systems written by Anders Lund and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.
Book Synopsis Organic reactive intermediates by : Samuel McManus
Download or read book Organic reactive intermediates written by Samuel McManus and published by Elsevier. This book was released on 2012-12-02 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry: A Series of Monographs, Volume 26: Organic Reactive Intermediates focuses on the study of reactive intermediates. This book discusses the methods of formation and investigation, factors affecting the stability, and reactions of the intermediate. Other topics include the formation and reaction of free radicals; kinetic aspects of free-radical chain reactions; electronic states and structures of carbenes; and formation of transient carbenes and carbenoids in solution. The intermediacy of nitrenes in reactions; electronic structure and spectra; methods of investigating carbonium ions; and reactions of carbonium ions are also elaborated. This publication likewise covers the preparation of carbanions; factors affecting the stability of carbanions; reactions involving radical ions; and methods of investigating arynes. This volume serves as a textbook for the first graduate-level course, as well as a reference for industrial chemists interested in organic reaction mechanisms.
Book Synopsis Radical and Ion-pairing Strategies in Asymmetric Organocatalysis by : Maxime R Vitale
Download or read book Radical and Ion-pairing Strategies in Asymmetric Organocatalysis written by Maxime R Vitale and published by Elsevier. This book was released on 2017-07-21 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Considering the challenge of sustainability facing our society in the coming decades, catalysis is without any doubt a research area of major importance. In this regard, asymmetric organocatalysis, now considered a pillar of green chemistry, deserves particular attention. The first chapter of this volume examines the topic of asymmetric organocatalysis in light of radical chemistry. Recent important progress in this field has been attained by promoting the formation and harnessing the high reactivity of open-shell intermediates. Merging organocatalysis with radical chemistry has been the key to solving some longstanding bottlenecks, and has also significantly contributed to reinforcing the key role of organocatalysis in asymmetric catalysis. This chapter presents the most significant developments in this area, with a particular focus on asymmetric SOMO- and photoredox-organocatalyzed transformations. Chapter 2 focuses on quaternary ammonium salts (R4N+X-), especially chiral derivatives, and their behavior as unique catalysts in organocatalysis. Forming chiral ion-pairs capable of promoting asymmetric reactions, they also operate as unique “transporters involved in phase transfer catalytic processes between liquid–liquid or liquid–solid systems. Furthermore, they offer unique opportunities when forming cooperative ion-paired entities R4N+X-, allowing a synergistic implication of the counter-ion X- either as Brønsted bases or Lewis bases. Specific design of such chiral catalysts in modern chemistry and better insight into their mode of activation facilitates efficient and unprecedented chemical transformations. This chapter provides an overview of the use of chiral quaternary ammonium salts in organocatalysis, emphasizing both general mechanistic aspects and the scope of this approach. Presents the most significant developments with a particular focus on asymmetric SOMO- and photoredox-organocatalyzed transformations Givies a larger overview of chiral ammonium salts in organocatalysis rather than a specific review dedicated to specialists in this area Affords a historical evolution of this field of research
Download or read book Radical Reactions written by Nathan Price and published by American Chemical Society. This book was released on 2023-03-31 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions provides the reader a brief overview of radical reactions, an overview overlooked in most undergraduate chemistry curriculums. Most of the exciting developments in the field of radical and radical ion chemistry came about because someone understood the fundamentals and was able to design new chemistry based upon that understanding. The target audience is individuals who have had at least one semester of organic chemistry.
Book Synopsis Free Radical Chain Reactions in Organic Synthesis by : William B. Motherwell
Download or read book Free Radical Chain Reactions in Organic Synthesis written by William B. Motherwell and published by Elsevier. This book was released on 2013-10-22 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field
Book Synopsis Advances in Physical Organic Chemistry by : Thomas Tidwell
Download or read book Advances in Physical Organic Chemistry written by Thomas Tidwell and published by Gulf Professional Publishing. This book was released on 2000-08-15 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a fast developing one, with results and methodologies finding application from biology to solid state physics. The previous volumes in this serial constitute a lasting record of this field and will continue to do so as they are widely used and cited. The serial has maintained high levels of quality and utility over the years. Volume 35, devoted to the study of carbocations and free radicals, includes contributions on excess acidities, the relationship between structure and organic reactivity, electron transfer, bond-breaking and formation, donor/acceptor organizations, and the electron-transfer paradigm for organic reactivity. Readers will also benefit from the comprehensive subject and citation index.
Book Synopsis Free Radicals in Organic Chemistry by : Jacques Fossey
Download or read book Free Radicals in Organic Chemistry written by Jacques Fossey and published by . This book was released on 1995-11-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.
