Insights Into Catalysts From Metal Adsorption And Adhesion Energies

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Insights Into Catalysts from Metal Adsorption and Adhesion Energies

Author : John Ransford Rumptz
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (138 download)

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Book Synopsis Insights Into Catalysts from Metal Adsorption and Adhesion Energies by : John Ransford Rumptz

Download or read book Insights Into Catalysts from Metal Adsorption and Adhesion Energies written by John Ransford Rumptz and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysts consisting of transition metal nanoparticles anchored to oxide and carbon support materials are ubiquitous in chemical production and pollution control. Despite their importance, the fundamental principles which control the performance and stability of these materials are still poorly understood. This dissertation provides insights into these fundamental principles through an investigation of the energetics of adsorption and adhesion of metals onto the surfaces of oxide and carbon supports, as well as studies on how the solvent environment can affect the final catalyst performance.Understanding the bonding energetics of transition metal atoms and nanoparticles to well-defined support surfaces helps to elucidate the effect of the support material on catalyst performance by providing important properties that correlate with performance, including the chemical potential of the metal versus particle size and metal monomer’s adsorption energy. The most suitable method for measuring these energies is metal vapor single-crystal adsorption calorimetry. Using these techniques, we studied a variety of metals and support surfaces. The first of these experiments investigated the structure, energetics, and charge transfer of Ni supported on CeO2-x(111) using a combination of experimental methods and theoretical calculations. This study showed that Ni preferentially binds to the oxygen atoms in the CeO2-x support and thus can be stabilized at edge-site defects on the surface. Furthermore, this binding to oxygen atoms is associated with oxidation of the deposited Ni atoms. The adsorption and adhesion of Ag to rutile TiO2 was studied using the same experimental techniques. This study began with an investigation of the TiO2 surface structure using low-energy electron diffraction which allowed us to determine that our TiO2 growth procedures resulted in TiO2(100) films on Mo(110). Measurements of the heats of adsorption and particle size showed that at 300 K, particles bind to defect sites on the surface while particles deposited at 100 K are not able to diffuse to these more energetically favorable sites. This study concluded with the determination of the Ag/TiO2(100) adhesion energy which qualitatively confirmed a trend of decreasing adhesion energies with the enthalpy of oxide reduction. The use of carbon materials as a support for metal nanoparticles has become increasingly common, especially for use in electrocatalysis. Despite their importance, metals on these carbon supports are much less studied than on oxide supports. The first calorimetrically measured heats of adsorption of metal atoms onto graphene are reported here. The chemical potential of silver atoms in Ag nanoparticles on graphene follows the same equation as developed for metal chemical potential versus size as on oxide supports, which depends on metal / support adhesion energy. A large adhesion energy and weak monomer bonding for silver onto graphene was found, suggesting that carbon-based supports can provide excellent catalyst thermal stability. The adsorption and adhesion of nickel atoms and nanoparticles on this same support material was also studied. It was found that these particles grow with a unique growth morphology. These studies will form the basis of future research on trends of the adsorption and adhesion of metals onto carbon-based materials. The adhesion energies of liquid solvents onto well-defined single crystal materials were also measured here. Catalysis in liquid solvents has become more important with the development of powerful electrocatalysts and fuel cells, however it is not well known how the solvent affects the binding of small molecules to the surface. It has been shown that these solvent adhesion energies can be used with a simple bond-additivity model to predict the adsorption energies of small molecules onto single crystalline surfaces in a solvent. These adhesion energies provide researchers with a way to determine how the choice of solvent affects the stability of small, adsorbed molecules and thus the reactivity of catalysts in different solvents.

Fundamental Insights Into Catalyst Design

Author : Stephanie Hemmingson
Publisher :
ISBN 13 :
Total Pages : 231 pages
Book Rating : 4.:/5 (981 download)

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Book Synopsis Fundamental Insights Into Catalyst Design by : Stephanie Hemmingson

Download or read book Fundamental Insights Into Catalyst Design written by Stephanie Hemmingson and published by . This book was released on 2016 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysts consisting of transition metal nanoparticles dispersed on high surface area oxide supports are ubiquitous in industrial-scale chemistry and alternative energy technology. Despite their importance, our fundamental understanding of the physical and chemical properties that make these systems catalytically effective is still incomplete. This dissertation details the use of surface-sensitive ultrahigh vacuum (UHV) techniques to study model catalysts consisting of late transition metals that are vapor-deposited onto single-crystal oxide films in order to understand how their fundamental physical and chemical properties affect their catalytic properties, such as activity, selectivity, and resistance to deactivation. Specifically, the binding energies of metal atoms and nanoparticles - and the adhesion energy of metal nanoparticles and films - are measured as a function of the size and type of nanoparticle, and the surface or site that they are adsorbed on. The key technique utilized in this study is single-crystal adsorption calorimetry (SCAC), which uses a highly sensitive detector to directly measure the heats of adsorption of metal vapor adsorbing onto oxide thin films. These calorimetric data are combined with surface-sensitive spectroscopic techniques to characterize the oxide surface, and to model the size of the nanoparticles a function of total metal coverage. This approach allows the heat data to be correlated with the surface structure, composition, particle size, or electronic character of the system. Several improvements to the instrument are discussed that allow for the study of metals with very low vapor pressures (high heats of vaporization), specifically Au, which is the focus of this work. This new instrument can also be operated at temperatures as low as 100 K, which is used to study metal atom adsorption under conditions where adatom diffusion is slower, which increases the particle density (reducing the size of particles formed) and increasing the likelihood that nucleation occurs at less favorable sites. Au adsorption is discussed here on three difference surfaces with increasing complexity: Pt(111), MgO(100), and CeO2-x(111). These results are compared to Cu adsorption on Pt(111) and CeO2-x(111) (also presented in this work), and to Cu adsorption on MgO(100) as well as Ag adsorption on MgO(100) and CeO2-x(111) (from previous work done by this research group). The first ever experimental measurements of gold adsorption onto an oxide surface as a function of particle size are presented, and the adsorption energy of both a single Au atom and a single Cu atom was measured on CeO1.95(111). This represents the first experimental measurements of any metal atom adsorption onto any oxide surface. The effect of defects on Au and Cu adsorption, such as step edges and electron-rich oxygen vacancies is discussed in detail. These defects are either introduced in film preparation (in the case of oxygen vacancies on CeO2-x(111)), or are inherently present in thin film preparations (morphological defects). The metals studied here, like most late transition metals, adsorb more strongly on morphological defects such as steps, while only Au and Ag bind more strongly to oxygen vacancies on CeO2-x(111) (Cu does not). Additionally, Au was found to nucleate significantly more strongly than Ag and Cu on morphological defects of MgO(100), and to form 2D islands on MgO(100) within the first 0.4 monolayers (ML) coverage. This work presents the first ever measurement of the heat of adsorption (and thus the chemical potential) of metal atoms in metal nanoparticles as a function of their 2D island diameter. A similar interpretation is used to present the chemical potential of Cu atoms in Cu nanoparticles as a function of their 3D particle dimeter on CeO2-x(111). The work contained in this dissertation has added critically important thermodynamic and structural data to the library of research in the catalysis and surface science communities, and has addressed some of the most relevant materials that could not be studied with previous generations of SCAC instruments. These model catalyst systems are of substantial fundamental and practice interest due to their immediate use in industrial catalysis, and combining these newest results with existing data (both from our group and from the literature) has allowed us to propose a new trend for metal-oxide adhesion. These investigations, and specifically this trend, will aid in the global effort to expedite the future design and testing process of new catalytic materials through improved understanding of their fundamental properties.

Adsorption and Adhesion Energies of Metal Films and Nanoparticles Studied by Adsorption Calorimetry

Author : Trevor E. James
Publisher :
ISBN 13 :
Total Pages : 138 pages
Book Rating : 4.:/5 (949 download)

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Book Synopsis Adsorption and Adhesion Energies of Metal Films and Nanoparticles Studied by Adsorption Calorimetry by : Trevor E. James

Download or read book Adsorption and Adhesion Energies of Metal Films and Nanoparticles Studied by Adsorption Calorimetry written by Trevor E. James and published by . This book was released on 2016 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal nanoparticles dispersed across solid surfaces form the basis of many important technologies such as heterogeneous catalysts, electrocatalysts, chemical sensors, microelectronics, and fuel cells. Understanding energetics of chemical bonding between the metal and oxide in these systems is important for the development of more efficient devices. First, in Chapter 2, this dissertations discusses a new, ultrahigh vacuum single crystal adsorption calorimeter which is used to directly measure metal adsorption and adhesion energies to model catalytic surfaces from 77-350 K. Some of the key instrumental improvements over previous designs include the capability of real-time metal atom flux monitoring and a decreased thermal radiation contribution to the heat signal. Next, in chapter 3, an improved data analysis method to determine average particle size and number density from low energy ion scattering spectroscopy (LEIS) measurements of nanoparticles that grow with the shape of hemispherical caps is discussed and validated. A correction is applied for the case when nanoparticles cause substrate shadowing due to source ion incident and detection angles being non-normal to the surface. The model was demonstrated for Cu growth on slightly reduced CeO2(111) where it improved the fit ~3-fold. In Chapters 4 and 5, the adsorption energy and growth morphology of vapor deposited copper atoms onto slightly reduced CeO2(111) was measured at 100 and 300 K. Copper was determined to grow as three-dimensional particles with preferential adsorption to stoichiometric ceria sites, opposite of what has been observed for other metals such as Ag, Au and Pt on ceria. An important result was the measurement of copper atom chemical potentials starting from single copper atoms up to large nanoparticles which provides unique insight into the increased reactivity of the small aggregates and their propensity to sinter. In Chapter 6, gold adsorption energies onto slightly reduced ceria was also measured. Like copper, gold grows as hemispherical caps on ceria, but with a smaller number density for a given temperature and extent of ceria reduction. Gold also adsorbs more strongly to reduced ceria sites than to stoichiometric sites. The adhesion energy between copper, silver, and gold nanoparticles and slightly reduced ceria was compared to previous adhesion energy trends discovered by our group. Adhesion energy of metals onto well-defined oxides adhere more strongly to ceria than MgO, and scales with the adsorbed metal’s heat of sublimation minus the heat of formation of the its most stable oxide, providing a method to predict adhesion energies of metals to oxides. Lastly, in Chapter 7, the adsorption and adhesion energy of 2D copper overlayers on Pt(111) was measured by calorimetry. The adsorption energy of copper atoms in each layer was used to explain the thermodynamic driving force of copper to form the quasi-pseudomorphic layer-by-layer structure. These studies provide new insights into interfacial chemical bonding and provide important benchmarks to test new density functional theory calculations. The results will aid in the rational design of more efficient catalysts. Future aims and conclusions of this work are presented in Chapter 8.

Energetics of Small Molecules and Molecular Fragments on Model Catalyst Surfaces

Author : Griffin Michael Ruehl
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (138 download)

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Book Synopsis Energetics of Small Molecules and Molecular Fragments on Model Catalyst Surfaces by : Griffin Michael Ruehl

Download or read book Energetics of Small Molecules and Molecular Fragments on Model Catalyst Surfaces written by Griffin Michael Ruehl and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis is essential for the development and support of modern society, with the vast majority of chemical production processes reliant on catalysts. New catalysts and catalytic reactions constitute promising pathways forward in combatting the effects of climate change and transitioning human society off of our reliance on fossil fuels. However, there is an absence of a complete fundamental understanding of observed differences and trends in catalytic behavior that impedes the rapid, strategic development of new catalytic processes. Computational modeling methods, such as Density Functional Theory (DFT), constitute powerful tools for the rapid screening of catalyst materials, but these methods have large errors in energy accuracy which severely limit their quantitative predictive abilities. These methods are dependent on experimentally determined benchmarks to guide modifications for improving their energy accuracy. The technique of single crystal adsorption calorimetry (SCAC) is uniquely able to study the energetics of irreversible adsorption processes on well-defined surface sites. SCAC can therefore provide these key benchmarks and fundamental understandings of the energetics of molecular and dissociative adsorption into molecular fragments and other key surface reaction intermediates commonly seen in industrial catalytic applications. This dissertation presents experimental SCAC results for the study of the energetics of adsorption of small molecules and molecular fragments on model catalyst surfaces, namely Pt(111) and Cu(111). This work builds upon previous efforts from the Campbell group to develop a systematic understanding of trends and observed differences in catalytic behavior on late-transition metal catalysts. Additionally, by employing models recently developed by this group, we are able to estimate the adhesion energies of liquid solvents to clean, single-crystal metal surfaces from the experimental calorimetry results. This allows for the estimation of the effects of each solvent on the energetics of adsorption and desorption for surface reactants and intermediates of interest. The study of the energetics of acetonitrile and n¬-decane adsorption on Pt(111), two solvents of particular interest, are reported here. Acetonitrile an important solvent due to its unique, desirable properties which make it of particular interest for electrochemical applications and the engineering of mixed solvent environments. n-Decane is similarly of interest in catalysis as linear alkanes of that and similar size are commonly used as solvents in catalytic reactions over Pt-group metals. From the experimentally determined heat of adsorption versus coverage we estimate adhesion energies of these liquid solvents to the Pt(111) surface to be Eadh = 0.198 J/m2 for acetonitrile and Eadh = 0.148 J/m2 for n-decane. Additionally, the adhesion energy of liquid formic acid to Cu(111) is estimated to be Eadh = 0.271 J/m2. These values can be used to quantify the solvent effects of these species on the local surface reaction environment. The calorimetrically measured heats of adsorption versus coverage are reported here for acetonitrile on Pt(111) at 100 K and 180 K, n-¬decane adsorption on Pt(111) at 150 K, azulene adsorption on Pt(111) at 150 K, and for both the molecular and dissociative adsorption of formic acid on clean and oxygen-precovered Cu(111). In combination with previously reported experimental results and DFT simulations of these systems, a number of important fundamental insights are drawn. The analysis of the n-decane heats of adsorption in comparison to a previous TPD study of shorter linear alkanes extends the observed trends to larger species such as n-decane that desorb irreversibly. Namely, we report that the adsorption energy increases nearly proportionally to carbon number, and the adhesion energy remains nearly constant (for a given surface). Naphthalene and azulene are of particular interest as representative molecules for the regular structure of graphene and the most common defect found in graphene sheets, respectively. Therefore the study of their adsorption energetics can inform experimental and computational systems involving graphene more broadly. Comparison of the heats of adsorption for azulene on Pt(111) first presented here with previous results for naphthalene and DFT simulations of both show that azulene binds significantly stronger to Pt(111) (by ~100 kJ/mol) than its isomer naphthalene. We show that DFT accurately predicts the adsorption energy of azulene but overestimates the binding energy of naphthalene, indicating that DFT is not accurately modeling the energy differences between these two systems. We report here the dissociative adsorption of formic acid on oxygen-precovered Cu(111), which results in the formation of adsorbed bidentate formate and gaseous water at 240 K. Formic acid and formate are common intermediates in a variety of reactions on late transition metals, ranging from well-established industrial reactions to emergent clean energy technologies. From the heats of this dissociative adsorption reaction, we extract a bond enthalpy of bidentate formate to Cu(111) of 335 kJ/mol, and an enthalpy of formation of bidentate formate on Cu(111) of -465 kJ/mol. We show that these enthalpies are slightly greater than those on Ni(111) (by ~15 kJ/mol) and significantly greater than those on Pt(111) (by ~85 kJ/mol). This is in opposition to the predicted order of bond strength from DFT, where Ni is predicted to bind formate more strongly than Cu, and indicates that DFT is not accurately modeling this trend in adsorption between these three surfaces. This study also constitutes the first experimental measurement of the energetics of any adsorbed molecular fragment on any Cu surface. In comparison to previous results on Pt(111) and Ni(111) this allows for the direct comparison of a single molecular fragment on all three surfaces for the first time. This forms a suite of key experimental benchmarks for improving the energy accuracy of computational models like DFT, as well as crucial fundamental insights into trends and observed differences in catalysis on late-transition metal surfaces. Lastly, we report a detailed kinetics study of the aqueous-phase hydrogenation of phenol and benzaldehyde on Pt, Pd, and Rh using small-scale thermal and electrocatalytic reactors. These molecules represent common intermediates in the process of breaking down biomass and converting its constituents into biofuels and other value-added chemicals. This work shows that the observed catalytic behavior is well fit by a Langmuir-Hinshelwood mechanism with competitive adsorption (organic versus hydrogen adsorption) on terrace, or (111)-like, sites. Additionally, we report that adsorbed benzaldehyde inhibits the formation of a bulk Pd-hydride whereas phenol does not, explaining the extreme differences in observed catalytic activity between these two systems. This work informs efforts to correlate molecular structure of biomass intermediates of interest with catalytic activity on late-transition metal catalysts.

Fundamental Studies on Model Catalyst Systems

Author : Zhongtian Mao
Publisher :
ISBN 13 :
Total Pages : 218 pages
Book Rating : 4.:/5 (119 download)

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Book Synopsis Fundamental Studies on Model Catalyst Systems by : Zhongtian Mao

Download or read book Fundamental Studies on Model Catalyst Systems written by Zhongtian Mao and published by . This book was released on 2020 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation includes the study of metal nanoparticles supported on oxide surfaces and the microkinetic analysis of complex reaction mechanisms using the degree of rate control (DRC). In Chapters 2-5, the energetics, structure and electron transfer of Ni nanoparticles supported on MgO(100) and CeO[subscript]2-x(111) are studied using Single Crystal Adsorption Calorimetry (SCAC), He+ low-energy ion scattering (LEIS), X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT). Both experiments and DFT calculation shows that the extent of reduction and the presence of step edge sites on CeO[subscript]2-x(111) can strongly affect its interaction with the supported Ni nanoparticles. At 300 K, Ni atoms nucleate preferentially on the step edges of CeO[subscript]2-x(111), and the initial heat of adsorption is higher than that measured at 100 K where Ni atoms nucleate mainly on terraces. The initial heat of adsorption of Ni on CeO1.8(111) is lower than that on CeO1.95(111), no matter for step edges or terraces. It suggests the bonding between the Ni atoms and the lattice O dominates the interaction between Ni and CeO[subscript]2-x(111). Upon adsorption, Ni can transfer electrons to stoichiometric ceria and form Ni cations at low coverages. DFT shows that adsorbed Ni monomers are in a +2 oxidation state on CeO2(111). As the Ni coverage and particle size increases, both XPS and DFT shows the charge transfer per Ni atom sharply decreases. The perturbation of the ceria support to the electronic property of Ni is crucial to understanding the nature of the active sites on the surface of Ni/CeO2 catalysts. On MgO(100), Ni has different growth modes at 300 and 100 K. At 300 K, Ni grows 3D nanoparticles. The Ni atoms form a metastable phase when the nanoparticles are smaller than 2.5 nm in diameter. At 100 K, the Ni atoms form single adatoms and then 2D islands with a thickness of 0.17 nm at low coverage. The 2D islands cover the entire surface rapidly before thickening. The initial heat of adsorption measured at 100 K is 148 kJ/mol, which corresponds to the binding energy of a single Ni atom on MgO(100). The XPS Ni 2p3/2 peak binding energy for 0.21 ML Ni on MgO(100) at 100 K is 2.2 eV higher than that for bulk Ni(solid), suggesting charge transfer from Ni to MgO(100) and formation of Ni2+ at very low coverage. The heat of adsorption and growth morphology of Ni on MgO(100) and CeO1.95(111) are then used to calculate the adhesion energy of Ni to MgO(100) and CeO1.95(111). Due to Ni’s high oxophilicity, the adhesion energy of Ni to MgO(100) and CeO195(111) is higher than any other metal that has been measured previously. The reported adhesion energy of Ni fits well in the trend, which states that the adhesion energy increases linearly from metal to metal with increasing heat of formation of the most stable oxide of the metal. In Chapters 6-8, the DRC analysis is applied to understand the kinetics of simple model reactions and real reaction mechanisms. In Chapter 6, we show the DRC for any catalyst-bound intermediate is proportional to its fractional population of catalyst sites, where the proportional constant is given as the DRC-weighted average of the site requirements for all the elementary steps. This relation offers opportunities to measure DRC experimentally since the fractional population of catalyst-bound intermediates can be measured. In Chapter 7, the DRC analysis is used for the interpretation of the kinetic isotope effect (KIE). The DRC analysis shows that the KIE of a multistep reaction results from the energy change of kinetically-relevant species upon isotope substitution. Considering the rate-determining step only is not enough to obtain a full understanding of KIE, and it can lead to conceptual mistakes. In Chapter 8, a general expression for the apparent activation energy is given via DRC. It shows that the apparent activation energy equals a weighted average of the standard-state enthalpies of all species in the reaction mechanism, each weighted by its DRC. This equation provides deep insights into the connection between the reaction energy diagram and the apparent activation energy.

Modeling Catalytic Properties of Metal Nanoparticles

Author : Lin Li
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (945 download)

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Book Synopsis Modeling Catalytic Properties of Metal Nanoparticles by : Lin Li

Download or read book Modeling Catalytic Properties of Metal Nanoparticles written by Lin Li and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are materials that can accelerate chemical reactions, and they are key to creating sustainable processes and a greener environment. Catalysts in the form of metal nanoparticles are ubiquitous in current industrial processes, and they are critical to creating a sustainable energy future. Theory has provided vital insights into the fundamental limitations of various types of processes, and density functional theory (DFT) calculations have inspired the discovery of new active materials. Advancements in supercomputing resources and scalable quantum chemistry codes have enabled us to explore the catalytic behavior of metal nanoparticles from the fundamental atomic level. We present calculated adsorption energies of oxygen on gold and platinum clusters with up to 923 atoms (3 nm diameter) using Density Functional Theory. We find that surface tension of the clusters induces a compression of which weakens the bonding of adsorbates compared to the bonding on extended surfaces. The effect is largest for close packed surfaces and almost non-existent on the more reactive steps and edges. The effect is largest at low coverage and decreases, even changing sign, at higher coverages where the strain changes from compressive to tensile. Quantum-size-effects also influence adsorption energies but only below a critical size of 1.5 nm for platinum and 2.5 nm for gold. We develop a model to describe the strain-induced size effects on adsorption energies, which is able to describe the influence of surface structure, adsorbate, metal, and coverage. Stability of metal nanoparticle is also a great concern in the field of heterogeneous, and a dominant process that degrades the activity of these catalysts is the agglomeration of individual nanoparticles. In order to better understand the sintering mechanism, we propose a kinetic Monte-Carlo (kMC) model for simulating the movement of platinum particles on supports, based on atom-by-atom diffusion on the surface the particle. The proposed model was able to reproduce equilibrium cluster shapes predicted using Wulff-construction. The diffusivity of platinum particles was simulated both purely based on random motion and assisted using a drift velocity. The overall particle diffusivity increases with temperature, however the extracted activation barrier appears to be temperature independent. In addition, this barrier was found to increase with particle size, as well as, with the adhesion between the particle and the support.

Ammonia

Author : Anders Nielsen
Publisher : Springer Science & Business Media
ISBN 13 : 3642791972
Total Pages : 352 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Ammonia by : Anders Nielsen

Download or read book Ammonia written by Anders Nielsen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ammonia is one of the 10 largest commodity chemicals produced. The editor, Anders Nielsen, is research director with one of the largest industrial catalyst producers. He has compiled a complete reference on all aspects of catalytical ammonia production in industry, from thermodynamics and kinetics to reactor and plant design. One chapter deals with safety aspects of ammonia handling and storage.

Journal

Author : American Chemical Society
Publisher :
ISBN 13 :
Total Pages : 1042 pages
Book Rating : 4.:/5 (334 download)

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Book Synopsis Journal by : American Chemical Society

Download or read book Journal written by American Chemical Society and published by . This book was released on 2004 with total page 1042 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal Nanoparticles for Catalysis

Author : Franklin Tao
Publisher : Royal Society of Chemistry
ISBN 13 : 1782621032
Total Pages : 285 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Metal Nanoparticles for Catalysis by : Franklin Tao

Download or read book Metal Nanoparticles for Catalysis written by Franklin Tao and published by Royal Society of Chemistry. This book was released on 2014-06-12 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis is a central topic in chemical transformation and energy conversion. Thanks to the spectacular achievements of colloidal chemistry and the synthesis of nanomaterials over the last two decades, there have also been significant advances in nanoparticle catalysis. Catalysis on different metal nanostructures with well-defined structures and composition has been extensively studied. Metal nanocrystals synthesized with colloidal chemistry exhibit different catalytic performances in contrast to metal nanoparticles prepared with impregnation or deposition precipitation. Additionally, theoretical approaches in predicting catalysis performance and understanding catalytic mechanism on these metal nanocatalysts have made significant progress. Metal Nanoparticles for Catalysis is a comprehensive text on catalysis on Nanoparticles, looking at both their synthesis and applications. Chapter topics include nanoreactor catalysis; Pd nanoparticles in C-C coupling reactions; metal salt-based gold nanocatalysts; theoretical insights into metal nanocatalysts; and nanoparticle mediated clock reaction. This book bridges the gap between nanomaterials synthesis and characterization, and catalysis. As such, this text will be a valuable resource for postgraduate students and researchers in these exciting fields.

Exploring the Chemistry of Metal/metal Oxide Catalysts

Author : Carly Byron
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.3/5 (776 download)

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Book Synopsis Exploring the Chemistry of Metal/metal Oxide Catalysts by : Carly Byron

Download or read book Exploring the Chemistry of Metal/metal Oxide Catalysts written by Carly Byron and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work outlined in this dissertation is dedicated to the surface chemistry of promoted metal nanoparticle catalysts for dry reforming of methane (DRM). The main part of this work focuses on the effect of promoters on platinum and nickel active catalysts and understanding how the change in surface chemistry affects the mechanism of the DRM reaction. We have identified several promoters that improve the DRM activity by tuning the surface chemistry; boron promoter with platinum catalyst and transition metal promoters with nickel catalyst. The addition of promoter sites led to the migration of coke deposits away from active sites, improved surface activation of CO2, and morphological control over the coke deposits. This work is necessary because growing concern over the effects of climate change has necessitated research into potential fossil fuel replacements. The current energy infrastructure already supports hydrocarbon fuel sources. However, researchers' current challenge is the ability to produce fuel in a carbon-neutral process using inexpensive catalytic materials. Heterogeneous catalysis is paramount to solving the energy problem, and the chemistry of catalytic surfaces must be optimized to achieve carbon-based fuel production that can replace fossil fuels long term. Noble metals and transition metals are highly active to hydrocarbon conversion. The dry reforming of methane (DRM) is a promising reaction because it converts methane and carbon dioxide into a "synthesis gas", or syngas, which can be processed to produce fuels and other value-added chemicals. When in the form of a nanoparticle supported on metal oxide, the active surface area of the metal is maximized, and less metal is required for catalysis. However, nanoparticle catalysts are readily deactivated by coking (carbon deposits) and sintering (nanoparticle agglomeration). Noble metals are highly active to DRM due to their high selectivity and resistance to deactivation, but they are typically too costly for practical use. Nickel is a promising DRM catalyst because of its low cost and high activity but is more susceptible to deactivation, therefore nickel is often paired with a second "promoter" metal to optimize the material and prevent deactivation. The development of active, stable bimetallic catalysts requires a detailed understanding of the chemistry at the surface during the reaction. In this work, we have identified the role of promoter sites using surface characterization techniques which provide better understanding of the catalytic mechanism.

Springer Handbook of Advanced Catalyst Characterization

Author : Israel E. Wachs
Publisher : Springer Nature
ISBN 13 : 3031071255
Total Pages : 1109 pages
Book Rating : 4.0/5 (31 download)

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Book Synopsis Springer Handbook of Advanced Catalyst Characterization by : Israel E. Wachs

Download or read book Springer Handbook of Advanced Catalyst Characterization written by Israel E. Wachs and published by Springer Nature. This book was released on 2023-06-12 with total page 1109 pages. Available in PDF, EPUB and Kindle. Book excerpt: Co-edited by world-renowned scientists in the field of catalysis, this book contains the cutting-edge in situ and operando spectroscopy characterization techniques operating under reaction conditions to determine a materials’ bulk, surface, and solution complex and their applications in the field of catalysis with emphasis on solid catalysts in powder form since such catalyst are relevant for industrial applications. The handbook covers from widely-used to cutting-edge techniques. The handbook is written for a broad audience of students and professionals who want to pursue the full capabilities available by the current state-of-the-art in characterization to fully understand how their catalysts really operate and guide the rational design of advanced catalysts. Individuals involved in catalysis research will be interested in this handbook because it contains a catalogue of cutting-edge methods employed in characterization of catalysts. These techniques find wide use in applications such as petroleum refining, chemical manufacture, natural gas conversion, pollution control, transportation, power generation, pharmaceuticals and food processing. fdsfds

Strength from Weakness: Structural Consequences of Weak Interactions in Molecules, Supermolecules, and Crystals

Author : Aldo Domenicano
Publisher : Springer Science & Business Media
ISBN 13 : 940100546X
Total Pages : 419 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Strength from Weakness: Structural Consequences of Weak Interactions in Molecules, Supermolecules, and Crystals by : Aldo Domenicano

Download or read book Strength from Weakness: Structural Consequences of Weak Interactions in Molecules, Supermolecules, and Crystals written by Aldo Domenicano and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: The accurate determination of the structure of molecular systems provides information about the consequences of weak interactions both within and between molecules. These consequences impact the properties of the materials and the behaviour in interactions with other substances. The book presents modern experimental and computational techniques for the determination of molecular structure. It also highlights applications ranging from the simplest molecules to DNA and industrially significant materials. Readership: Graduate students and researchers in structural chemistry, computational chemistry, molecular spectroscopy, crystallography, supramolecular chemistry, solid state chemistry and physics, and materials science.

Computational Catalysis

Author : Aravind Asthagiri
Publisher : Royal Society of Chemistry
ISBN 13 : 1849734518
Total Pages : 277 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Computational Catalysis by : Aravind Asthagiri

Download or read book Computational Catalysis written by Aravind Asthagiri and published by Royal Society of Chemistry. This book was released on 2014 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive review of the methods and approaches being adopted to push forward the boundaries of computational catalysis.

En Route Towards Advanced Catalyst Materials for the Electrocatalytic Water Splitting Reaction

Author : Marc Ledendecker
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (956 download)

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Book Synopsis En Route Towards Advanced Catalyst Materials for the Electrocatalytic Water Splitting Reaction by : Marc Ledendecker

Download or read book En Route Towards Advanced Catalyst Materials for the Electrocatalytic Water Splitting Reaction written by Marc Ledendecker and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The thesis on hand deals with the development of new types of catalysts based on pristine metals and ceramic materials and their application as catalysts for the electrocatalytic water splitting reaction. In order to breathe life into this technology, cost-efficient, stable and efficient catalysts are imploringly desired. In this manner, the preparation of Mn-, N-, S-, P-, and C-containing nickel materials has been investigated together with the theoretical and electrochemical elucidation of their activity towards the hydrogen (and oxygen) evolution reaction. The Sabatier principle has been used as the principal guideline towards successful tuning of catalytic sites. Furthermore, two pathways have been chosen to ameliorate the electrocatalytic performance, namely, the direct improvement of intrinsic properties through appropriate material selection and secondly the increase of surface area of the catalytic material with an increased amount of active sites. In this manner, bringing materials with optimized hydrogen adsorption free energy onto high surface area support, catalytic performances approaching the golden standards of noble metals were feasible. Despite varying applied synthesis strategies (wet chemistry in organic solvents, ionothermal reaction, gas phase reaction), one goal has been systematically pursued: to understand the driving mechanism of the growth. Moreover, deeper understanding of inherent properties and kinetic parameters of the catalytic materials has been gained.

Supported Metal Single Atom Catalysis

Author : Philippe Serp
Publisher : Wiley-VCH
ISBN 13 : 9783527348442
Total Pages : 688 pages
Book Rating : 4.3/5 (484 download)

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Book Synopsis Supported Metal Single Atom Catalysis by : Philippe Serp

Download or read book Supported Metal Single Atom Catalysis written by Philippe Serp and published by Wiley-VCH. This book was released on 2022-02-22 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: b”Supported Metal Single Atom CatalysisCovers all key aspects of supported metal single atom catalysts, an invaluable resource for academic researchers and industry professionals alike Single atom catalysis is one of the most innovative and dynamic research areas in catalysis science. Supported metal catalysts are used extensively across the chemical industry, ranging from fine and bulk chemical production to petrochemicals. Single atom catalysts (SACs) combine the advantages of both homogeneous and heterogeneous catalysts such as catalyst stability, activity, and high dispersion of the active phase. Supported Metal Single Atom Catalysis provides an authoritative and up-to-date overview of the emerging field, covering the synthesis, preparation, characterization, modeling, and applications of SACs. This comprehensive volume introduces the basic principles of single atom catalysis, describes metal oxide and carbon support materials for SAC preparation, presents characterization techniques and theoretical calculations, and discusses SACs in areas including selective hydrogenation, oxidation reactions, activation of small molecules, C-C bond formation, and biomedical applications. Highlights the activity, selectivity, and stability advantages of supported metal SACs compared to other heterogeneous catalysts Covers applications of SACs in thermal catalysis, electrocatalysis, and photocatalysis Includes chapters on single atom alloys and supported double and triple metal atom catalysts Discusses the prospects, challenges, and potential industrial applications of SACs Supported Metal Single Atom Catalysis is an indispensable reference for all those working in the fields of catalysis, solid-state chemistry, materials science, and spectroscopy, including catalytic chemists, organic chemists, electrochemists, theoretical chemists, and industrial chemists.

Adsorption through Advanced Nanoscale Materials

Author : Chandrabhan Verma
Publisher : Elsevier
ISBN 13 : 0443184577
Total Pages : 729 pages
Book Rating : 4.4/5 (431 download)

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Book Synopsis Adsorption through Advanced Nanoscale Materials by : Chandrabhan Verma

Download or read book Adsorption through Advanced Nanoscale Materials written by Chandrabhan Verma and published by Elsevier. This book was released on 2023-08-14 with total page 729 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption through Advanced Nanoscale Materials: Applications in Environmental Remediation brings together the latest developments in the utilization of advanced nanoadsorbents in wastewater treatment, pollution control, removal and remediation, gas separation and other environmental applications. The book begins by providing an overview of absorption, adsorbents and nanoadsorbents, introducing properties, classification, synthesis, characterization, enhancement of adsorption capabilities, principles and advantages and disadvantages of nanoadsorbents. Other sections cover the preparation of advanced nanoadsorbents based on specific materials for wastewater treatment, including adsorbents incorporating carbon nanotubes, graphene and graphene oxide, carbon dots and fullerene, polymer nanocomposites, metal oxides, nanoclay, nanofillers, and filtration membranes. Final sections examine the role of nanoadsorbents in broader environmental applications, including areas such as pollution control and removal and gas separation. Finally, other important considerations are studied, including toxicity and health impact, ecotoxicological effects, commercialization and economic issues, challenges and research gaps, trends, and future opportunities. Provides in-depth coverage of nanoadsorbents for a range of targeted environmental applications Covers, in detail, fundamentals such as synthesis methods, characterization and inhibition mechanisms Addresses key areas such as toxicity, health impact, research gaps, trends and commercialization

Chemical Modelling

Author : Alan Hinchliffe
Publisher : Royal Society of Chemistry
ISBN 13 : 1847555268
Total Pages : 543 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Chemical Modelling by : Alan Hinchliffe

Download or read book Chemical Modelling written by Alan Hinchliffe and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 543 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Modelling: Applications and Theory comprises critical literature reviews of molecular modelling, both theoretical and applied. Molecular modelling in this context refers to modelling the structure, properties and reactions of atoms, molecules & materials. Each chapter is compiled by experts in their fields and provides a selective review of recent literature. With chemical modelling covering such a wide range of subjects, this Specialist Periodical Report serves as the first port of call to any chemist, biochemist, materials scientist or molecular physicist needing to acquaint themselves of major developments in the area. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis. Current subject areas covered are Amino Acids, Peptides and Proteins, Carbohydrate Chemistry, Catalysis, Chemical Modelling. Applications and Theory, Electron Paramagnetic Resonance, Nuclear Magnetic Resonance, Organometallic Chemistry. Organophosphorus Chemistry, Photochemistry and Spectroscopic Properties of Inorganic and Organometallic Compounds. From time to time, the series has altered according to the fluctuating degrees of activity in the various fields, but these volumes remain a superb reference point for researchers.