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Author : Pek Ling Lye
Publisher :
ISBN 13 :
Total Pages : 282 pages
Book Rating : 4.:/5 (968 download)
Download or read book Indium-mediated Allylation Reactions written by Pek Ling Lye and published by . This book was released on 2001 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jodi L. Connell
Publisher :
ISBN 13 :
Total Pages : 102 pages
Book Rating : 4.:/5 (553 download)
Download or read book Mechanism and Kinetics of the Reaction of Allyl Bromides at Indium Surfaces written by Jodi L. Connell and published by . This book was released on 2006 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Terra Danielle Haddad
Publisher :
ISBN 13 :
Total Pages : 484 pages
Book Rating : 4.:/5 (26 download)
Download or read book Novel Asymmetric Indium-mediated Barbier-type Addition Reactions written by Terra Danielle Haddad and published by . This book was released on 2011 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Isabel Olson
Publisher :
ISBN 13 :
Total Pages : 170 pages
Book Rating : 4.:/5 (64 download)
Download or read book Heterogeneous Reactions written by Isabel Olson and published by . This book was released on 2009 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Dr. Pervinder Kaur
Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783845473925
Total Pages : 164 pages
Book Rating : 4.4/5 (739 download)
Download or read book Stereoelectronic Features in Indium Mediated Allylation written by Dr. Pervinder Kaur and published by LAP Lambert Academic Publishing. This book was released on 2011-09 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homoallylic alcohols and amines are fundamental building blocks for many biologically active compounds. The allylation of carbonyl compounds with allyl organometallic reagents constitutes a simple and straight forward approach for their synthesis. Allyl indium reagents have emerged as a reagent of choice for allylation of carbonyl compounds under both aqueous and non-aqueous conditions. However, in application of this approach for the synthesis of homoallylic alcohols/ amines from ketones/ imines, the lower electrophilicity of ketone/imine carbon makes the transfer of allyl group to ketone/imine carbon much more challenging. The ease of hydrolysis of imine to carbonyl compound and amine further add to the difficulties. The present work is aimed to unravel the regio- and diastereochemical aspects in indium mediated allylation of ketones bearing proton donor groups (OH, COOH) alpha to carbonyl moiety and imines derived from heterocycles like pyridine-2-imines, quinoline-2-imines and indole-3-imines. In selected cases the homoallylic alcohols have been subjected to iodine mediated cyclization to provide 2,3-diaryltetrahydrofuran and 3-hydroxy-3,4-dihydrofuran-2(5H)-one derivatives.
Author : Haythem K. Dema
Publisher :
ISBN 13 :
Total Pages : 9 pages
Book Rating : 4.:/5 (961 download)
Download or read book Indium-Mediated Allylation of N-Tert-Butylsulfinylaldimines with Dimethyl 2-(2-(Chloromethyl) Allyl) Malonate \\ Jordan Journal of Chemistry .- 2011, Vol. 6, No. 3 written by Haythem K. Dema and published by . This book was released on 2011 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : U. Marcus Lindstrom
Publisher : John Wiley & Sons
ISBN 13 : 047099424X
Total Pages : 424 pages
Book Rating : 4.4/5 (79 download)
Download or read book Organic Reactions in Water written by U. Marcus Lindstrom and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volatile organic solvents are the normal media used in both research scale and industrial scale synthesis of organic chemicals. Their environmental impact is significant, however, and so the development of alternative reaction media has become of great interest. Developments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.
Author : Chao-Jun Li
Publisher : John Wiley & Sons
ISBN 13 : 0470131438
Total Pages : 435 pages
Book Rating : 4.4/5 (71 download)
Download or read book Comprehensive Organic Reactions in Aqueous Media written by Chao-Jun Li and published by John Wiley & Sons. This book was released on 2007-06-04 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.
Author : Rui-Bin Wang
Publisher :
ISBN 13 :
Total Pages : 386 pages
Book Rating : 4.:/5 (969 download)
Download or read book Metal-mediated Allylation Reactions written by Rui-Bin Wang and published by . This book was released on 1999 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Indium-mediated Allylations in Aqueous Media, an Expansion of the Scope and a Demonstration of the Synthetic Utility of the Reaction written by and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Chao-Jun Li
Publisher : John Wiley & Sons
ISBN 13 : 047176129X
Total Pages : 452 pages
Book Rating : 4.4/5 (717 download)
Download or read book Comprehensive Organic Reactions in Aqueous Media written by Chao-Jun Li and published by John Wiley & Sons. This book was released on 2007-06-15 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.
Author : Craig Ritchie
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)
Download or read book Indium- and Tin-mediated Allylation of Carbonyl Compounds in Ionic Liquids written by Craig Ritchie and published by . This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Christopher Albler
Publisher : Sudwestdeutscher Verlag Fur Hochschulschriften AG
ISBN 13 : 9783838150895
Total Pages : 196 pages
Book Rating : 4.1/5 (58 download)
Download or read book Metals in Carbohydrate Synthesis written by Christopher Albler and published by Sudwestdeutscher Verlag Fur Hochschulschriften AG. This book was released on 2015-04-14 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes two different projects associated with the chemical (de novo) synthesis of rare and unnatural carbohydrates from readily available starting materials. After a comprehensive introduction to indium chemistry and stereoselective aldol reactions, two new methodologies are presented which complement the synthetic arsenal available to the carbohydrate chemist. The indium mediated allylation of unprotected carbohydrates was applied in the synthesis of acetamido-heptoses and octoses which are constituents of the aminoglycoside antibiotics Apramycin and Destomycin. Furthermore, a new approach for the incorporation of fluorine into carbohydrates is described. Amino acid building blocks were chain-elongated via a titanium mediated aldol addition, finally furnishing amino-, fluoro-functionalised pentoses and hexoses. These compounds are of high interest not only concerning their potential antimicrobial activity but also their usefulness in elucidating fundamental biological processes such as antigen-antibody aggregation.
Author : V. Tamara Perchyonok
Publisher : Royal Society of Chemistry
ISBN 13 : 1849730008
Total Pages : 142 pages
Book Rating : 4.8/5 (497 download)
Download or read book Radical Reactions in Aqueous Media written by V. Tamara Perchyonok and published by Royal Society of Chemistry. This book was released on 2010 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
Author : David Crich
Publisher : John Wiley & Sons
ISBN 13 : 1118634896
Total Pages : 1874 pages
Book Rating : 4.1/5 (186 download)
Download or read book Reagents for Radical and Radical Ion Chemistry written by David Crich and published by John Wiley & Sons. This book was released on 2013-05-30 with total page 1874 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.
Author : A. C. Knipe
Publisher : John Wiley & Sons
ISBN 13 : 047086673X
Total Pages : 618 pages
Book Rating : 4.4/5 (78 download)
Download or read book Organic Reaction Mechanisms 2001 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2005-07-15 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: This annual series on organic reaction mechanisms research provides concise, comprehensive coverage of the year's literature as well as discussions of important results, each volume is extensively referenced to previous volumes and primary journals. This the 37th book in the series will survey research on organic reaction mechanisms described in the literature between December 1999 to November 2000. As in previous volumes new mechanisms for the synthesis of all types of organic compounds will be included as well as such mechanisms as addition and elimination reactions, nucleophilic and electrophilic aromatic substitutions and molecular arrangements.
Author : P.A. Grieco
Publisher : Springer Science & Business Media
ISBN 13 : 940114950X
Total Pages : 321 pages
Book Rating : 4.4/5 (11 download)
Download or read book Organic Synthesis in Water written by P.A. Grieco and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.
