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Improvement Of Catalyst Life Time In The Direct Oxidation Of Benzene To Phenol With N2o Using Modified Zsm 5 Type Zeolites
Download Improvement Of Catalyst Life Time In The Direct Oxidation Of Benzene To Phenol With N2o Using Modified Zsm 5 Type Zeolites full books in PDF, epub, and Kindle. Read online Improvement Of Catalyst Life Time In The Direct Oxidation Of Benzene To Phenol With N2o Using Modified Zsm 5 Type Zeolites ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis Improvement of Catalyst Life Time in the Direct Oxidation of Benzene to Phenol with N_1tn2O Using Modified ZSM-5 Type Zeolites by : Saiprasath Gopalakrishnan
Download or read book Improvement of Catalyst Life Time in the Direct Oxidation of Benzene to Phenol with N_1tn2O Using Modified ZSM-5 Type Zeolites written by Saiprasath Gopalakrishnan and published by . This book was released on 2012 with total page 173 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Improvement of Catalyst Life Time in the Direct Oxidation of Benzene to Phenol with N2O Using Modified ZSM-5 Type by : Saiprasath Gopalakrishnan
Download or read book Improvement of Catalyst Life Time in the Direct Oxidation of Benzene to Phenol with N2O Using Modified ZSM-5 Type written by Saiprasath Gopalakrishnan and published by . This book was released on 2012 with total page 173 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Zeolites and Zeolite-like Materials by : Bert Sels
Download or read book Zeolites and Zeolite-like Materials written by Bert Sels and published by Elsevier. This book was released on 2016-07-29 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) Contains chapters prepared by known specialists who are members of the International Zeolite Association
Book Synopsis Catalyst Characterization by : Boris Imelik
Download or read book Catalyst Characterization written by Boris Imelik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt: to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitive ly expensive. There are few chemical-or oil-based material items in modern society that do not depend in some way on a catalytic stage in their manufacture. Apart from manufacturing processes, catalysis is finding other important and over-increasing uses; for example, successful applications of catalysis in the control ofpollution and its use in environmental control are certain to in crease in the future. The commercial import an ce of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists including chemists, physicists, chemical engineers, and material scientists. Increasing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recentlyas sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 19 50s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth.
Book Synopsis Mesoporous Zeolites by : Javier García-Martínez
Download or read book Mesoporous Zeolites written by Javier García-Martínez and published by John Wiley & Sons. This book was released on 2015-05-26 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.
Book Synopsis Handbook of Climate Change Mitigation by : Wei-Yin Chen
Download or read book Handbook of Climate Change Mitigation written by Wei-Yin Chen and published by Springer. This book was released on 2012-02-13 with total page 2130 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a mounting consensus that human behavior is changing the global climate and its consequence could be catastrophic. Reducing the 24 billion metric tons of carbon dioxide emissions from stationary and mobile sources is a gigantic task involving both technological challenges and monumental financial and societal costs. The pursuit of sustainable energy resources, environment, and economy has become a complex issue of global scale that affects the daily life of every citizen of the world. The present mitigation activities range from energy conservation, carbon-neutral energy conversions, carbon advanced combustion process that produce no greenhouse gases and that enable carbon capture and sequestion, to other advanced technologies. From its causes and impacts to its solutions, the issues surrounding climate change involve multidisciplinary science and technology. This handbook will provide a single source of this information. The book will be divided into the following sections: Scientific Evidence of Climate Change and Societal Issues, Impacts of Climate Change, Energy Conservation, Alternative Energies, Advanced Combustion, Advanced Technologies, and Education and Outreach.
Book Synopsis Catalytic Processes for The Valorisation of Biomass Derived Molecules by : Francesco Mauriello
Download or read book Catalytic Processes for The Valorisation of Biomass Derived Molecules written by Francesco Mauriello and published by MDPI. This book was released on 2019-11-22 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decades, inedible lignocellulosic biomasses have attracted significant attention for being abundant resources that are not in competition with agricultural land or food production and, therefore, can be used as starting renewable material for the production of a wide variety of platform chemicals. The three main components of lignocellulosic biomasses are cellulose, hemicellulose and lignin, complex biopolymers that can be converted into a pool of platform molecules including sugars, polyols, alchols, ketons, ethers, acids and aromatics. Various technologies have been explored for their one-pot conversion into chemicals, fuels and materials. However, in order to develop new catalytic processes for the selective production of desired products, a complete understanding of the molecular aspects of the basic chemistry and reactivity of biomass derived molecules is still crucial. This Special Issue reports on recent progress and advances in the catalytic valorization of cellulose, hemicellulose and lignin model molecules promoted by novel heterogeneous systems for the production of energy, fuels and chemicals.
Book Synopsis Zeolites in Catalysis by : Jiří Čejka
Download or read book Zeolites in Catalysis written by Jiří Čejka and published by Royal Society of Chemistry. This book was released on 2017-06-07 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accessible references for researchers and industrialists in this exciting field, covering both developments and applications of catalysis.
Book Synopsis Biomass Combustion Science, Technology and Engineering by : Lasse Rosendahl
Download or read book Biomass Combustion Science, Technology and Engineering written by Lasse Rosendahl and published by Elsevier. This book was released on 2013-04-04 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: The utilisation of biomass is increasingly important for low- or zero-carbon power generation. Developments in conventional power plant fuel flexibility allow for both direct biomass combustion and co-firing with fossil fuels, while the integration of advanced technologies facilitates conversion of a wide range of biomass feedstocks into more readily combustible fuel. Biomass combustion science, technology and engineering reviews the science and technology of biomass combustion, conversion and utilisation. Part one provides an introduction to biomass supply chains and feedstocks, and outlines the principles of biomass combustion for power generation. Chapters also describe the categorisation and preparation of biomass feedstocks for combustion and gasification. Part two goes on to explore biomass combustion and co-firing, including direct combustion of biomass, biomass co-firing and gasification, fast pyrolysis of biomass for the production of liquids and intermediate pyrolysis technologies. Largescale biomass combustion and biorefineries are then the focus of part three. Following an overview of large-scale biomass combustion plants, key engineering issues and plant operation are discussed, before the book concludes with a chapter looking at the role of biorefineries in increasing the value of the end-products of biomass conversion. With its distinguished editor and international team of expert contributors, Biomass combustion science, technology and engineering provides a clear overview of this important area for all power plant operators, industrial engineers, biomass researchers, process chemists and academics working in this field. Reviews the science and technology of biomass combustion, conversion and utilisation Provides an introduction to biomass supply chains and feedstocks and outlines the principles of biomass combustion for power generation Describes the categorisation and preparation of biomass feedstocks for combustion and gasification
Book Synopsis Advanced Oxidation Processes for Water and Wastewater Treatment by : Simon Parsons
Download or read book Advanced Oxidation Processes for Water and Wastewater Treatment written by Simon Parsons and published by IWA Publishing. This book was released on 2004-03-01 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: The suitability of Advanced Oxidation Processes (AOPs) for pollutant degradation was recognised in the early 1970s and much research and development work has been undertaken to commercialise some of these processes. AOPs have shown great potential in treating pollutants at both low and high concentrations and have found applications as diverse as ground water treatment, municipal wastewater sludge destruction and VOCs control. Advanced Oxidation Processes for Water and Wastewater Treatment is an overview of the advanced oxidation processes currently used or proposed for the remediation of water, wastewater, odours and sludge. The book contains two opening chapters which present introductions to advanced oxidation processes and a background to UV photolysis, seven chapters focusing on individual advanced oxidation processes and, finally, three chapters concentrating on selected applications of advanced oxidation processes. Advanced Oxidation Processes for Water and Wastewater Treatment will be invaluable to readers interested in water and wastewater treatment processes, including professionals and suppliers, as well as students and academics studying in this area. Dr Simon Parsons is a Senior Lecturer in Water Sciences at Cranfield University with ten years' experience of industrial and academic research and development.
Book Synopsis Nano Catalysts for Diesel Engine Emission Remediation by :
Download or read book Nano Catalysts for Diesel Engine Emission Remediation written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this project was to develop durable zeolite nanocatalysts with broader operating temperature windows to treat diesel engine emissions to enable diesel engine based equipment and vehicles to meet future regulatory requirements. A second objective was to improve hydrothermal durability of zeolite catalysts to at least 675 C. The results presented in this report show that we have successfully achieved both objectives. Since it is accepted that the first step in NOx conversion under SCR (selective catalytic reduction) conditions involves NO oxidation to NO2, we reasoned that catalyst modification that can enhance NO oxidation at low-temperatures should facilitate NOx reduction at low temperatures. Considering that Cu-ZSM-5 is a more efficient catalyst than Fe-ZSM-5 at low-temperature, we chose to modify Cu-ZSM-5. It is important to point out that the poor low-temperature efficiency of Fe-ZSM-5 has been shown to be due to selective absorption of NH3 at low-temperatures rather than poor NO oxidation activity. In view of this, we also reasoned that an increased electron density on copper in Cu-ZSM-5 would inhibit any bonding with NH3 at low-temperatures. In addition to modified Cu-ZSM-5, we synthesized a series of new heterobimetallic zeolites, by incorporating a secondary metal cation M (Sc{sup 3+}, Fe{sup 3+}, In{sup 3+}, and La{sup 3+}) in Cu exchanged ZSM-5, zeolite-beta, and SSZ-13 zeolites under carefully controlled experimental conditions. Characterization by diffuse-reflectance ultra-violet-visible spectroscopy (UV-Vis), X-ray powder diffraction (XRD), extended X-ray absorption fine structure spectroscopy (EXAFS) and electron paramagnetic resonance spectroscopy (EPR) does not permit conclusive structural determination but supports the proposal that M{sup 3+} has been incorporated in the vicinity of Cu(II). The protocols for degreening catalysts, testing under various operating conditions, and accelerated aging conditions were provided by our collaborators at John Deere Power Systems. Among various zeolites reported here, CuFe-SSZ-13 offers the best NOx conversion activity in 150-650 C range and is hydrothermally stable when tested under accelerated aging conditions. It is important to note that Cu-SSZ-13 is now a commercial catalyst for NOx treatment on diesel passenger vehicles. Thus, our catalyst performs better than the commercial catalyst under fast SCR conditions. We initially focused on fast SCR tests to enable us to screen catalysts rapidly. Only the catalysts that exhibit high NOx conversion at low temperatures are selected for screening under varying NO2:NOx ratio. The detailed tests of CuFe-SSZ-13 show that CuFe-SSZ-13 is more effective than commercial Cu-SSZ-13 even at NO2:NOx ratio of 0.1. The mechanistic studies, employing stop-flow diffuse reflectance FTIR spectroscopy (DRIFTS), suggest that high concentration of NO, generated by heterobimetallic zeolites, is probably responsible for their superior low temperature NOx activity. The results described in this report clearly show that we have successfully completed the first step in a new emission treatment catalyst which is synthesis and laboratory testing employing simulated exhaust. The next step in the catalyst development is engine testing. Efforts are in progress to obtain follow-on funding to carry out scale-up and engine testing to facilitate commercialization of this technology.
Book Synopsis Deactivation of PtH-ZSM-5 Bifunctional Catalysts by Coke Formation During Benzene Alkylation with Ethane by : Li M. Chua
Download or read book Deactivation of PtH-ZSM-5 Bifunctional Catalysts by Coke Formation During Benzene Alkylation with Ethane written by Li M. Chua and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The alkylation of benzene with ethane was studied at 370 oC over two Pt-containing ZSM-5 catalysts with SiO2/Al2O3 ratios of 30 and 80. While the benzene and ethane conversion decreased with time-on-stream for the PtH-ZSM-5(30) catalyst, the PtH-ZSM-5(80) catalyst demonstrated a stable performance. The deactivation of the PtH-ZSM-5(30) catalyst was found to be more significant, when compared to the PtH-ZSM-5(80) catalyst as a result of differences in the formation of coke. Results from gas sorption and x-ray diffraction experiments showed that coke is preferentially formed within the channel segments of the PtH-ZSM-5(30) catalyst as opposed to coke deposition on the outside surface of the PtH-ZSM-5(80) crystallites, subsequently blocking entrance to the zeolite channels. The location of the coke deposition was found to affect the product selectivity of the two PtH-ZSM-5 catalysts. The accessibility functions, derived from nitrogen and argon sorption data, suggested that, with prolonged time-on-stream, the coke molecules build up from the middle of the zeolite crystallites outwards towards the surface, as the reaction was carried out over the PtH-ZSM-5(30) catalyst. Partial blockage of the internal pore structure of the PtH-ZSM-5(30) catalyst decreased the diffusion length within the crystallites. In contrast to the typical effect of coking, where the selectivity of para- isomers would be enhanced with coke deposition, the effect of the reduction in the diffusion length of the PtH-ZSM-5(30) crystallites is consistent with the decreasing para-selectivity of the diethylbenzene (DEB) isomers with time-on-stream. n investigation of the causes of coke locations was conducted, and the results suggested that, the spatial distribution of Pt metal was responsible for the different locations of coke observed. Surface reactions initiated coking in the intercrystalline region of the PtH-ZSM-5(80) catalyst, as the Pt particles on the surface of the PtH-ZSM-5(80) crystallites increased the difficulty of access for reactants to the interior of the crystallites. Within the PtH-ZSM-5(30) catalyst, ethane dehydrogenation and benzene alkylation took place in the micropore network as a result of preferential intracrystalline deposition of Pt metal. Further conversions on the active sites within the PtH-ZSM-5(30) crystallites thus lead intracrystalline coking.
Book Synopsis Nanotechnology in Catalysis 3 by : Bing Zhou
Download or read book Nanotechnology in Catalysis 3 written by Bing Zhou and published by Springer Science & Business Media. This book was released on 2007-09-05 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume continues the tradition formed in Nanotechnology in Catalysis 1 and 2. As with those books, this one is based upon an ACS symposium. Some of the most illustrious names in heterogeneous catalysis are among the contributors. The book covers: Design, synthesis, and control of catalysts at nanoscale; understanding of catalytic reaction at nanometer scale; characterization of nanomaterials as catalysts; nanoparticle metal or metal oxides catalysts; nanomaterials as catalyst supports; new catalytic applications of nanomaterials.
Book Synopsis New Materials for Advanced Solid State Lasers: Volume 329 by : T. H. Allik
Download or read book New Materials for Advanced Solid State Lasers: Volume 329 written by T. H. Allik and published by Materials Research Society. This book was released on 1994-03-15 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
Book Synopsis Catalytic Conversion of Energy Resources into High Value-Added Products by : José Luis Pinilla
Download or read book Catalytic Conversion of Energy Resources into High Value-Added Products written by José Luis Pinilla and published by MDPI. This book was released on 2021-09-02 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt: Developing active, selective and energy-efficient heterogeneous catalysts is of paramount importance for the production of high value-added products from energy resources in a more sustainable manner. In this Special Issue of Energies, we provide a showcase of the latest progress in the development of cleaner, more efficient processes for the conversion of these feedstocks into valuable fuels, chemicals and energy. Most of the works collected are focused on the conversion of biomass which clearly reflects the paramount importance that the biorefinery concept will play in the years to come.
Book Synopsis Classical And Quantum Dynamics In Condensed Phase Simulations: Proceedings Of The International School Of Physics by : Bruce J Berne
Download or read book Classical And Quantum Dynamics In Condensed Phase Simulations: Proceedings Of The International School Of Physics written by Bruce J Berne and published by World Scientific. This book was released on 1998-06-17 with total page 881 pages. Available in PDF, EPUB and Kindle. Book excerpt: The school held at Villa Marigola, Lerici, Italy, in July 1997 was very much an educational experiment aimed not just at teaching a new generation of students the latest developments in computer simulation methods and theory, but also at bringing together researchers from the condensed matter computer simulation community, the biophysical chemistry community and the quantum dynamics community to confront the shared problem: the development of methods to treat the dynamics of quantum condensed phase systems.This volume collects the lectures delivered there. Due to the focus of the school, the contributions divide along natural lines into two broad groups: (1) the most sophisticated forms of the art of computer simulation, including biased phase space sampling schemes, methods which address the multiplicity of time scales in condensed phase problems, and static equilibrium methods for treating quantum systems; (2) the contributions on quantum dynamics, including methods for mixing quantum and classical dynamics in condensed phase simulations and methods capable of treating all degrees of freedom quantum-mechanically.
Book Synopsis Green Chemistry and Catalysis by : R. A. Sheldon
Download or read book Green Chemistry and Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2007-06-27 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: · Numerous catalytic reductions and oxidations methods · Solid-acid and solid-base catalysis · C-C bond formation reactions · Biocatalysis · Asymmetric catalysis · Novel reaction media like e.g. ionic liquids, supercritical CO2 · Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.
