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I Oxygen Atom Transfer Reactions Of Molybdenum Complexes Ii Sulfur Oxygen Complexes Of Macrocyclic Iron Ii Iii Iii Hexanuclear Iron Sulfur Basket Clusters
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Book Synopsis I. Oxygen Atom Transfer Reactions of Molybdenum Complexes ; II. Sulfur-oxygen Complexes of Macrocyclic Iron (II, III) ; III. Hexanuclear Iron-sulfur Basket Clusters by : Martha Susan Reynolds
Download or read book I. Oxygen Atom Transfer Reactions of Molybdenum Complexes ; II. Sulfur-oxygen Complexes of Macrocyclic Iron (II, III) ; III. Hexanuclear Iron-sulfur Basket Clusters written by Martha Susan Reynolds and published by . This book was released on 1988 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Oxygen Complexes and Oxygen Activation by Transition Metals by : Arthur Martell
Download or read book Oxygen Complexes and Oxygen Activation by Transition Metals written by Arthur Martell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph consists of manuscripts, summary statements, and poster abstracts submitted by invited speakers and poster contributors who participated in the symposium "Oxygen Complexes and Oxygen Activation by Transition Metals," held March 23-26, 1987, at Texas A&M University. This meeting was the fifth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The co chairmen of the conference were Professors Arthur E. Martell and Donald T. Sawyer of the Texas A&M University Chemistry Department. The program was developed by an academic-industrial steering committee consisting of the co-chairmen and members appointed by the sponsoring chemical companies Dr. James F. Bradzil, The Standard Oil Company, Ohio; Dr. Jerry R. Ebner, Monsanto Company; Dr. Craig Murchison, Dow Chemical Company; Dr. Donald C. Olsen, Shell Development Company; Dr. Tim R. Ryan, Celanese Chemical Company; and Dr. Ron Sanderson, Texaco Chemical Company. The subject of this conference reflects the intense interest that has developed in academic institutions and industry on several aspects of dioxygen chemistry. These include the formation of dioxygen complexes and their applications in facilitated transport and oxygen separation; homo geneous and heterogeneous catalysis of oxidation; and oxygenation of organic substrates by molecular oxygen. The conference differs in two respects from several other symposia on dioxygen chemistry held during the past few years. First, there is extensive industrial participation, especially with respect to oxygen activation.
Book Synopsis Studies on Oxygen Atom and Nitrene Group Transfer by : Diana Elisabeth Over
Download or read book Studies on Oxygen Atom and Nitrene Group Transfer written by Diana Elisabeth Over and published by . This book was released on 1992 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molybdenum-mediated Oxygen Atom and Imido Group Transfer Reactions by : Edgar Wall Harlan
Download or read book Molybdenum-mediated Oxygen Atom and Imido Group Transfer Reactions written by Edgar Wall Harlan and published by . This book was released on 1989 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Atom and Group Transfer Reactions Involving High-valent Iron Complexes by : Yong Li
Download or read book Atom and Group Transfer Reactions Involving High-valent Iron Complexes written by Yong Li and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Iron enzymes play critical roles in biological oxidation reactions by utilizing highly reactive high-valent iron intermediates, such as FeIV=O, FeV(O)(OH), and FeIV=NR species, for catalytic reactions. These intermediates exhibit remarkable catalytic behavior with high reactivities and high regio- and stereospecificity in various biochemical reactions. Understanding these metal intermediates is crucial not only for replicating their activity but also for discovering new synthetic possibilities in chemical synthesis. To address the challenge of comprehending high-valent iron intermediates in biology, chemists have developed a number of bio-inspired functional models that exhibit a diverse range of catalytic properties. The main objective of this thesis is to examine the functional mimicry of mononuclear non-heme active sites in iron enzymes, specifically targeting FeIV=O, FeV(O)(OH) and FeIV=NR intermediates. Chapter 1 provides an introduction to active sites of iron enzymes in biological systems and related bio-inspired models utilizing iron complexes. Chapter 2 relates to Papers I and IV. Paper I describes the syntheses and characterizations of four new FeIV=O complexes based on new ligands with minor steric restriction. The reactivity of these complexes in C-H activation and O-atom transfer reactions has been investigated in detail. As the ligands include negligible steric restrictions, the reactivity differences between these FeIV=O complexes are attributed to the electronic properties of the ligands. On the other hand, Paper IV provides an example of a ligand framework where the steric restrictions of the specific ligand dictate the substrate accessibility. Chapter 3 relates to Paper II and gives a comparative study on the structure and reactivity patterns of a new FeIV=NR complex versus its FeIV=O congener. Chapter 4 relates to Paper III and studies the epoxidation of alkenes by two mononuclear non-heme FeIV=O complexes based on ligands with different electron-donating properties. The catalysis and kinetics studies shed light on the influence of electron-donating properties on the reactivity and mechanism of alkene epoxidation. This research provides insights into the influence exerted by ligand environments on the reactivities of FeIV=O, FeV(O)(OH) and FeIV=NR complexes. The study may contribute to the development of new, highly active catalysts for important oxidation reactions.
Book Synopsis Polyoxometalate-Based Assemblies and Functional Materials by : Yu-Fei Song
Download or read book Polyoxometalate-Based Assemblies and Functional Materials written by Yu-Fei Song and published by Springer. This book was released on 2018-03-24 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors of this volume concentrate on the recent progress of novel polyoxometalate (POM) syntheses, as well as advances made in catalytic, electrochemical, and sensing systems. The state-of-the-art techniques such as flow system and gel-electrophoresis for the discovery of POMs are covered with a detailed discussion. Of particular importance, the application of POM-based materials in photo-sensing, heterogeneous catalysis, energy conservation and storage, and gas separation is reviewed. Over the past few years, POM chemistry has witnessed a remarkable progress with more than 1500 papers published each year. Due to their intrinsic structural features, POMs are considered as versatile building blocks for the construction of sophisticated complex assemblies and advanced multi-functional materials. Various strategies, methods, and techniques have been adopted to develop POM-based materials with intriguing properties and excellent performance. All the contributors to this volume are young, vibrant chemists in this research field and all the works are carefully collected from the authors’ years of experience. This volume serves as an essential reference for every POM chemist and is of great interest to new researchers who wish to learn more about this area.
Book Synopsis Transition Metal Sulphides by : Th. Weber
Download or read book Transition Metal Sulphides written by Th. Weber and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrotreating catalysis with transition metal sulphides is one of the most important areas of industrial heterogeneous catalysis. The present book deals with the chemical and catalytic aspects of transition metal sulphides, focusing on their use in hydrotreating catalysis. The book¿s 12 chapters present reviews of solid-state, coordination and organometallic chemistry, surface science and spectroscopic studies, quantum chemical calculations, catalytic studies with model and real catalysts, as well as refinery processes. A presentation of state-of-the-art background to pertinent work in the field. Can be used as an introduction to the chemical and catalytic properties of transition metal sulphides as well as an advanced level reference.
Book Synopsis Field Emission and Field Ionization by : Robert Gomer
Download or read book Field Emission and Field Ionization written by Robert Gomer and published by . This book was released on 1961 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Market: Students and researchers in vacuum and surface science, microscopy, and semiconductor physics. This definitive work was based on four lectures presented at Harvard University in 1958. When it was written, field emission was one of the few techniques available for surface studies and the attainment of ultra-high vacuum was a little-known art. Though more sophisticated treatments have since been developed, Gomer's pioneering work remains valid to this day.
Book Synopsis Photochemistry of Coordination Compounds by : Vincenzo Balzani
Download or read book Photochemistry of Coordination Compounds written by Vincenzo Balzani and published by . This book was released on 1970 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nanotechnology in Catalysis 3 by : Bing Zhou
Download or read book Nanotechnology in Catalysis 3 written by Bing Zhou and published by Springer Science & Business Media. This book was released on 2007-09-05 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume continues the tradition formed in Nanotechnology in Catalysis 1 and 2. As with those books, this one is based upon an ACS symposium. Some of the most illustrious names in heterogeneous catalysis are among the contributors. The book covers: Design, synthesis, and control of catalysts at nanoscale; understanding of catalytic reaction at nanometer scale; characterization of nanomaterials as catalysts; nanoparticle metal or metal oxides catalysts; nanomaterials as catalyst supports; new catalytic applications of nanomaterials.
Book Synopsis Elements of Inorganic Photochemistry by : G. J. Ferraudi
Download or read book Elements of Inorganic Photochemistry written by G. J. Ferraudi and published by Wiley-Interscience. This book was released on 1988-02-22 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph/reference focuses on those subjects that are considered essential to an understanding of inorganic photochemistry. Graduate students with a background in physical chemistry will find that the quantum mechanical treatments related to the principles of spectroscopy and chemical dynamics are readily accessible. And professionals will find that the tabulated data, equations, and general information makes this book an essential complement to the journal literature required in the daily planning of photochemical work. Chapters cover the nature of light and the uncertainty principle, detection of intermediates, elements of inorganic spectroscopy, kinetics of photoluminescence, photoredox reactions, ligand field photochemistry, and elements of organometallic photochemistry. Extensive appendixes cover physical constants and conversion factors for photochemical work, character tables for symmetry groups, vibrational motions, description of the chemical bonding in coordination complexes, charge transfer transitions, and Born cycles related to charge transfer processes.
Book Synopsis Inorganic Biochemistry by : J. A. Cowan
Download or read book Inorganic Biochemistry written by J. A. Cowan and published by John Wiley & Sons. This book was released on 1997-03-21 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: Das erfolgreiche Werk des jungen, kreativen Autors jetzt in aktualisierter und korrigierter Auflage! Der Text wurde um Fragenkomplexe und Übungsbeispiele, teils mit Lösungen, erweitert; dies empfiehlt ihn besonders zur Ergänzung einer Vorlesung.
Book Synopsis Concepts of Inorganic Photochemistry by : Arthur W. Adamson
Download or read book Concepts of Inorganic Photochemistry written by Arthur W. Adamson and published by John Wiley & Sons. This book was released on 1975 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: PHOTOPHYSICAL PROCESSES - ENERGY LEVELS AND SPECTRA; KINETICS OF PHOTOPHYSICAL PROCESSES; CHARGE - TRANSFER PHOTOCHEMISTRY; SUBSTITUTIONAL PHOTOCHEMISTRY OF FIRST - ROW TRANSITION ELEMENTS; PHOCHEMISTRY OF THE HEAVIER ELEMENTS; PHOTOCHEMISTRY OF CARBONYL COMPLEXES; PHOTOCHEMISTRY OF 1,3 - DIKETONATE CHELATES; THE PHOTOLYSIS OF SIMPLE INORGANIC IONS IN SOLUTION; PHOTOCHEMISTRY IN THE SOLID STATE; PHOTOCHROMISM AND CHEMILUMINESCENCE.
Book Synopsis Introduction to Molecular Magnetism by : Cristiano Benelli
Download or read book Introduction to Molecular Magnetism written by Cristiano Benelli and published by John Wiley & Sons. This book was released on 2015-06-22 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first introduction to the rapidly growing field of molecular magnetism is written with Masters and PhD students in mind, while postdocs and other newcomers will also find it an extremely useful guide. Adopting a clear didactic approach, the authors cover the fundamental concepts, providing many examples and give an overview of the most important techniques and key applications. Although the focus is one lanthanide ions, thus reflecting the current research in the field, the principles and the methods equally apply to other systems. The result is an excellent textbook from both a scientific and pedagogic point of view.
Book Synopsis Charge Transfer Photochemistry of Coordination Compounds by : Ottó Horváth
Download or read book Charge Transfer Photochemistry of Coordination Compounds written by Ottó Horváth and published by Wiley-VCH. This book was released on 1992-12-07 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes the results of studies on charge transfer photochemistry of metal complexes of the past few years. The material covered is organized in such a manner that each chapter discusses the photoredox properties of complexes of a series of metals which belong to the same column of the periodic table, including both transition metals and main group metals (for those that show photoactivity). Foremostly, the book covers photoinduced processes in which the primary step is a charge transfer reaction of the excited metal complex. It is concerned primarily with in-depth descriptions and discussions of the photochemistry of complexes themselves, with less emphasis on theoretical discussions. This book is aimed at professional photochemical researchers as well as students and chemists who are interested in organometallic and inorganic metal complexes and plan to become familiar with their charge transfer photochemistry.
Book Synopsis The Unknown Errors of Our Lives by : Chitra Banerjee Divakaruni
Download or read book The Unknown Errors of Our Lives written by Chitra Banerjee Divakaruni and published by Anchor. This book was released on 2002-08-13 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: In nine poignant stories spiked with humor and intelligence, Chitra Banerjee Divakaruni captures lives at crossroad moments–caught between past and present, home and abroad, tradition and fresh experience. A widow in California, recently arrived from India, struggles to adapt to a world in which neighbors are strangers and her domestic skills are deemed superfluous in the award-winning “Mrs. Dutta Writes a Letter.” In “The Intelligence of Wild Things,” a woman from Sacramento visits her brother in Vermont to inform him that back in Calcutta their mother is dying. And in the title story, a painter looks to ancient myth and the example of her grandmother for help in navigating her first real crisis of faith. Knowing, compassionate and expertly rendered, the stories in The Unknown Errors of Our Lives depict the eternal struggle to find a balance between the pull of home and the allure of change.
Book Synopsis The F Elements by : Nikolas Kaltsoyannis
Download or read book The F Elements written by Nikolas Kaltsoyannis and published by . This book was released on 1999 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: The lanthanides and actinides (the f elements) are rarely studied in detail by chemistry undergraduates. More often they appear as an afterthought in bonding, spectroscopy, magnetism, coordination chemistry, and organometallics courses. This is largely because of a lack of an accessible text treating the chemistry of these elements in one cover. Moreover, the placement of lanthanides and actinides in the closing pages of standard inorganic chemistry text books serves to marginalise these elements further. The f elements has therefore been written to fill a gap in the undergraduate chemistry textbook market. It covers much of the fundamental chemistry of the lanthanide and actinide elements, including coordination chemistry, solid state compounds, organometallic chemistry, electronic spectroscopy, and magnetism. Many comparisons are made between the chemistry of the lanthanides and actinides and that of the transition elements, which is generally much more familiar to undergraduate chemistry students. The book uses the chemistry of the f elements as a vehicle for the communication of several important chemical concepts that are not usually discussed in detail in undergraduate courses, for example the chemical consequences of relativity and the lanthanide and actinide contractions. Many important modern applications of f element chemistry, e.g. the use of actinides in nuclear power generation and of the lanthanides in magnetic resonance imaging and catalytic converters in motor vehicle exhausts, are also discussed in depth.
