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Book Synopsis Hydrogen Isotope Separation Utilizing Bulk Getters by :
Download or read book Hydrogen Isotope Separation Utilizing Bulk Getters written by and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.
Book Synopsis Cascades for Hydrogen Isotope Separation Using Metal Hydrides by :
Download or read book Cascades for Hydrogen Isotope Separation Using Metal Hydrides written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.
Book Synopsis A Gas Flow-Through System for Hydrogen Isotopic Separation with Metal-Organic Frameworks by : Katharine Harp Rigdon
Download or read book A Gas Flow-Through System for Hydrogen Isotopic Separation with Metal-Organic Frameworks written by Katharine Harp Rigdon and published by . This book was released on 2019 with total page 47 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, we designed and built a gas flow-through system to study dynamic adsorption separation of hydrogen isotopes in metal-organic frameworks (MOFs). MOFs are porous, crystalline materials composed of metal complexes connected by organic linkers. They have been proposed as a cheaper, more energy efficient approach to hydrogen isotope separation than current industrial methods. We have previously found evidence of a zero-point energy-based separation mechanism for hydrogen isotopes in two MOFs: Co-MOF-74 and Cu(I)-MFU-4l. This mechanism, chemical affinity quantum sieving (CAQS), has been extensively studied under static equilibrium conditions. The system in this work was developed so that CAQS could be studied under dynamic conditions that more closely resemble those in industrial separation. Breakthrough analysis is an established technique for studying dynamic separation in porous materials. Generally, a breakthrough experiment involves flowing a gas mixture through a fixed bed of adsorbent material and measuring the composition of the effluent flow. In this work, a 1:1 mixture of common hydrogen and its isotope deuterium was flowed through 71 mg of Co-MOF-74 or 22 mg of Cu(I)-MFU-4l. A quadrupole mass spectrometer was used to monitor the composition of the effluent flow. We saw preferential adsorption of deuterium over common hydrogen in Co-MOF-74 at 77K and Cu(I)-MFU-4l at 170K, 140K, and 110K. This behavior was absent in Cu(I)-MFU-4l at 77K, a phenomenon that we would like to investigate further. Minimal adsorption occurred in both MOFs at room temperature, as expected. A selectivity of deuterium over common hydrogen was calculated for each temperature. These selectivities were approximately 30% lower than comparable literature values. Our goal is to make improvements to our system and methods to measure the selectivity more accurately and reproducibly. Notably, all measured selectivities were higher than the selectivity of the Girdler Sulfide method and cryogenic distillation, two industrial hydrogen isotope separation processes we are trying to improve on. This new system gives us the capability to study dynamic adsorption and kinetic separation of hydrogen isotopes in metal-organic frameworks going forward. We hope that our work will inform the development of efficient, environmentally sustainable separation processes.
Book Synopsis Studies of Hydrogen Isotope Separation Using Vanadium Hydride in a Temperature Cycling Process by :
Download or read book Studies of Hydrogen Isotope Separation Using Vanadium Hydride in a Temperature Cycling Process written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Separations of gaseous HT-H2 mixtures on vanadium monohydride were carried out using a two-column temperature cycling process similar to parametric pumping. An equilibrium theory of process operation is presented which was in qualitative agreement with experimental results. Failure to achieve complete removal of HT from the cold column effluent as predicted was ascribed to the finite rates of the exchange reaction and to the presence and operation of an isotope effect in the rate of hydrogen absorption.
Book Synopsis Cascades for Hydrogen Isotope Separation Using Metal Hydrides by :
Download or read book Cascades for Hydrogen Isotope Separation Using Metal Hydrides written by and published by . This book was released on 1982 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Official Gazette of the United States Patent and Trademark Office by :
Download or read book Official Gazette of the United States Patent and Trademark Office written by and published by . This book was released on 1991 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrogen in Intermetallic Compounds II by : Louis Schlapbach
Download or read book Hydrogen in Intermetallic Compounds II written by Louis Schlapbach and published by Springer Science & Business Media. This book was released on 2006-01-21 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The topic of hydrogen in an on metals and alloys is important in a number ofdisciplines including solid-state physics, materials science, physical chemistry, and energy technology. This volume treats the dynamics of hydrogen in intermetallic compounds, surface properties, kinetics, and applications of metal hydrides in energy technology. In addition, selected experimental methods are described. The introductory chapter will enable non-specialists to gain an overall picture of the field and to appreciate the relevant scientific issue. The companion volume, Hydrogene in Intermetallic Compounds I, was published as Vol. 63 of Topics in Applied Physics.
Download or read book Fusion Energy Update written by and published by . This book was released on 1986 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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Book Synopsis Index of Patents Issued from the United States Patent and Trademark Office by :
Download or read book Index of Patents Issued from the United States Patent and Trademark Office written by and published by . This book was released on 1990 with total page 1754 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Proceedings of the Second Topical Meeting on the Technology of Controlled Nuclear Fusion by :
Download or read book Proceedings of the Second Topical Meeting on the Technology of Controlled Nuclear Fusion written by and published by . This book was released on 1976 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Tritium Control Technology by : P. H. Lamberger
Download or read book Tritium Control Technology written by P. H. Lamberger and published by . This book was released on 1973 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :United States. Energy Research and Development Administration. Technical Information Center Publisher : ISBN 13 : Total Pages :1682 pages Book Rating :4.3/5 (129 download)
Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration. Technical Information Center
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration. Technical Information Center and published by . This book was released on 1977 with total page 1682 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1977 with total page 646 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book WASH written by and published by . This book was released on 1973 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fusion Technology written by and published by . This book was released on 1997 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy written by and published by . This book was released on 1980 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: