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Author : M. M. Taqui Khan
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (72 download)
Download or read book Activation of alkenes and alkynes written by M. M. Taqui Khan and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : M.M. Taqui Khan
Publisher : Elsevier
ISBN 13 : 0323160166
Total Pages : 208 pages
Book Rating : 4.3/5 (231 download)
Download or read book Activation Of Alkenes And Alkynes written by M.M. Taqui Khan and published by Elsevier. This book was released on 2012-12-02 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation of alkenes and alkynes, as well as the multiple insertion reactions of alkenes and alkynes.
Author : M. M. Taqui Khan
Publisher :
ISBN 13 : 9780124061019
Total Pages : pages
Book Rating : 4.0/5 (61 download)
Download or read book Homogeneous Catalysis by Metal Complexes: Activation of alkenes and alkynes written by M. M. Taqui Khan and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : P.A. Chaloner
Publisher : Springer Science & Business Media
ISBN 13 : 9401717915
Total Pages : 293 pages
Book Rating : 4.4/5 (17 download)
Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.
Author : M.M. Taqui Khan
Publisher : Academic Press
ISBN 13 :
Total Pages : 216 pages
Book Rating : 4.3/5 (97 download)
Download or read book Activation Of Alkenes And Alkynes written by M.M. Taqui Khan and published by Academic Press. This book was released on 1974-01-28 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Band 2.
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)
Download or read book Homogenous Catalysis by Metal Complexes written by and published by . This book was released on 1974 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : M.M. Taqui Khan
Publisher : Elsevier
ISBN 13 : 0323150381
Total Pages : 437 pages
Book Rating : 4.3/5 (231 download)
Download or read book Activation Of Small Inorganic Molecules written by M.M. Taqui Khan and published by Elsevier. This book was released on 2012-12-02 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous Catalysis by Metal Complexes, Volume I: Activation of Small Inorganic Molecules reviews and systematizes the chemistry of the metal ion activation of the small diatomic molecules. The book discusses the activation of molecular hydrogen, molecular oxygen, molecular nitrogen, carbon monoxide, and nitric oxide.
Author : Gheorghe Duca
Publisher : Springer Science & Business Media
ISBN 13 : 364224629X
Total Pages : 484 pages
Book Rating : 4.6/5 (422 download)
Download or read book Homogeneous Catalysis with Metal Complexes written by Gheorghe Duca and published by Springer Science & Business Media. This book was released on 2012-06-15 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.
Author : Jiro Tsuji
Publisher : John Wiley & Sons
ISBN 13 : 9780471560272
Total Pages : 500 pages
Book Rating : 4.5/5 (62 download)
Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Author : Boy Cornils
Publisher : John Wiley & Sons
ISBN 13 : 3527328971
Total Pages : 1778 pages
Book Rating : 4.5/5 (273 download)
Download or read book Applied Homogeneous Catalysis with Organometallic Compounds written by Boy Cornils and published by John Wiley & Sons. This book was released on 2017-12-26 with total page 1778 pages. Available in PDF, EPUB and Kindle. Book excerpt: The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.
Author : P.A. Chaloner
Publisher : Springer
ISBN 13 : 9789401717922
Total Pages : 290 pages
Book Rating : 4.7/5 (179 download)
Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer. This book was released on 2014-03-14 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.
Author : Denis Forster
Publisher :
ISBN 13 :
Total Pages : 354 pages
Book Rating : 4.F/5 ( download)
Download or read book Homogeneous Catalysis--II. written by Denis Forster and published by . This book was released on 1974 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 0851865313
Total Pages : 516 pages
Book Rating : 4.8/5 (518 download)
Download or read book Organometallic Chemistry Volume 4 written by and published by Royal Society of Chemistry. This book was released on 1975 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation. Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author : Jim Atwood (D.)
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (316 download)
Download or read book Catalytic Hydration of Alkenes and Alkynes written by Jim Atwood (D.) and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The fifteen years of DOE support have encompassed two different projects, electron-transfer reactions of metal carbonyl anions and water-soluble organometallic complexes. Each of these is related to homogeneous catalysis and will be described in separate sections. Electron Transfer--Twenty-one manuscripts resulted from our studies of electron-transfer reactions of metal carbonyl anions and acknowledge DOE support. Construction of an infrared stopped-flow system allowed us to measure rates of reactions for the extremely air-sensitive metal carbonyl anions. As for carbanions, both one-electron and two-electron processes occur for metal carbonyl anions. The most unexpected feature was examples of a very rapid two-electron process, followed by a much slower one-electron back transfer. The two-electron processes were accompanied by transfer of a ligand between two metals, M-X + M{prime}{sup -} {yields} M{sup -} + M{prime}-X with X groups of CO{sup 2}, H{sup +}, CH{sub 3}{sup +} and Br{sup +}. These transfers, which can be considered nucleophilic displacements, occurred when M{prime}{sup -} was more nucleophilic than M{sup -}. The 21 published manuscripts explore one- and two-electron processes for many such organometallic complexes. Water-Soluble Organometallic Complexes--The potential of water-soluble organometallic complexes in ''green chemistry'' intrigued us. Sixteen manuscripts acknowledging DOE support have appeared thus far in this field. Our research centered on sulfonated phosphine ligands, PPh{sub 2}(m-C{sub 6}H{sub 4}SO{sub 3}Na) and P(m-C{sub 6}H{sub 4}SO{sub 3}Na){sub 3}, to solubilize organometallic complexes in water. These analogues of PPH{sub 3} allowed us to synthesize complexes of Ir, Rh, Ru, Ni, Pd, Pt and Ag that are water-soluble and contain such common organometallic ligands as CO, H and CH{sub 3} in addition to halides and the phosphine ligands. These metal complexes show the ability to activate H{sub 2}, CO, C{sub 2}H{sub 4}, H{sub 2}O, SO{sub 2} etc. in aqueous solution. The primary conclusion is that water-soluble organometallic complexes can be prepared and show very similar reactivity in water to analogous compounds in organic solvents. Thus, organometallic complexes in aqueous solution do provide a ''green'' route to products currently prepared in organic solvents.
Author : John C. Chadwick
Publisher : John Wiley & Sons
ISBN 13 : 3527636005
Total Pages : 592 pages
Book Rating : 4.5/5 (276 download)
Download or read book Homogeneous Catalysts written by John C. Chadwick and published by John Wiley & Sons. This book was released on 2011-06-09 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.
Author : Catherine S.J. Cazin
Publisher : Springer Science & Business Media
ISBN 13 : 9048128668
Total Pages : 348 pages
Book Rating : 4.0/5 (481 download)
Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis written by Catherine S.J. Cazin and published by Springer Science & Business Media. This book was released on 2010-10-04 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, ... Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.
Author : W.J. Mijs
Publisher : Springer Science & Business Media
ISBN 13 : 1461321093
Total Pages : 924 pages
Book Rating : 4.4/5 (613 download)
Download or read book Organic Syntheses by Oxidation with Metal Compounds written by W.J. Mijs and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is concerned with the synthetic aspects of oxidation reactions involving metal compounds. which are readily available or easy to prepare. The sequence followed in the chapters is as follows: a general introduction. a limited treatment of reaction mechanisms to serve as a basis for synthesis. and scope and limitations of the oxidant system. mostly in terms of substrate and product classes. Finally, at the end of each chapter. representative synthetic procedures are given together with relevant experimental considerations. A general table is included as an appendix. This contains substrate classes and resulting product classes, referring to the oxidative procedures in the chapters. The table provides the synthetic organic chemist with a quick overview of oxidation possibilities with metal-contain ing oxidants, enabling him to select the right method for his purpose. The editors hope that not only organic research chemists in industry and at universities, but also advanced undergraduate and graduate students in organic chemistry, will find this book a useful guide in the design, understanding, and practical performance of oxidative organic syntheses. The editors are grateful to the authors not only for their contributions. containing interesting new developments in oxidation chemistry, but also for the way they fitted the text into the general framework given for the book. Their suggestions and comments are gratefully acknowledged. Thanks are also due to Mrs. A. I. Rohnstrom-Ouwejan, secretary to the editors, for her administrative support.
