High-Performance Corrosion-Resistant Materials

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ISBN 13 :
Total Pages : 198 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis High-Performance Corrosion-Resistant Materials by :

Download or read book High-Performance Corrosion-Resistant Materials written by and published by . This book was released on 2007 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: The multi-institutional High Performance Corrosion Resistant Materials (HPCRM) Team is cosponsored by the Defense Advanced Projects Agency (DARPA) Defense Science Office (DSO) and the Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM), and has developed new corrosion-resistant, iron-based amorphous metals that can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The Fe-based corrosion-resistant, amorphous-metal coatings under development may prove of importance for applications on ships. Such coatings could be used as an 'integral drip shield' on spent fuel containers, as well as protective coatings that could be applied over welds, thereby preventing exposure to environments that might cause stress corrosion cracking. In the future, such new high-performance iron-based materials could be substituted for more-expensive nickel-based alloys, thereby enabling a reduction in the $58-billion life cycle cost for the long-term storage of the Nation's spent nuclear fuel by tens of percent.

Corrosion Characterization of Iron-Based High-Performance Amorphous-Metal Thermal-Spray Coatings

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Total Pages : 18 pages
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Book Synopsis Corrosion Characterization of Iron-Based High-Performance Amorphous-Metal Thermal-Spray Coatings by : C. A. Blue

Download or read book Corrosion Characterization of Iron-Based High-Performance Amorphous-Metal Thermal-Spray Coatings written by C. A. Blue and published by . This book was released on 2005 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. One of these compositions, SAM1651, is discussed in detail to illustrate the promise of this general class of materials.

Iron-Based Amorphous Metals

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ISBN 13 :
Total Pages : 34 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Iron-Based Amorphous Metals by :

Download or read book Iron-Based Amorphous Metals written by and published by . This book was released on 2007 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt: An overview of the High-Performance Corrosion-Resistant Materials (HPCRM) Program, which was co-sponsored by the Defense Advanced Research Projects Agency (DARPA) Defense Sciences Office (DSO) and the United States Department of Energy (DOE) Office of Civilian and Radioactive Waste Management (OCRWM), is discussed. Programmatic investigations have included a broad range of topics: alloy design and composition; materials synthesis; thermal stability; corrosion resistance; environmental cracking; mechanical properties; damage tolerance; radiation effects; and important potential applications. Amorphous alloys identified as SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe4Mo14Cr15Y2C15B6) have been produced as melt-spun ribbons, drop-cast ingots and thermal-spray coatings. Chromium (Cr), molybdenum (Mo) and tungsten (W) additions provided corrosion resistance, while boron (B) enabled glass formation. Earlier electrochemical studies of melt-spun ribbons and ingots of these amorphous alloys demonstrated outstanding passive film stability. More recently thermal-spray coatings of these amorphous alloys have been made and subjected to long-term salt-fog and immersion tests. Good corrosion resistance has been observed during salt-fog testing. Corrosion rates were measured in situ with linear polarization, while simultaneously monitoring the open-circuit corrosion potentials. Reasonably good performance was observed. The sensitivity of these measurements to electrolyte composition and temperature was determined. The high boron content of this particular amorphous metal makes this amorphous alloy an effective neutron absorber, and suitable for criticality control applications. In general, the corrosion resistance of such iron-based amorphous metals is maintained at operating temperatures up to the glass transition temperature. These materials are much harder than conventional stainless steel and nickel-based materials, and are proving to have excellent wear properties, sufficient to warrant their use in earth excavation, drilling and tunnel boring applications. Large areas have been successfully coated with these materials, with thicknesses of approximately one centimeter. The observed corrosion resistance may enable applications of importance in industries such as: oil and gas production, refining, nuclear power generation, shipping, and others.

Iron-Based Amorphous-Metals

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ISBN 13 :
Total Pages : 32 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Iron-Based Amorphous-Metals by :

Download or read book Iron-Based Amorphous-Metals written by and published by . This book was released on 2009 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: An overview of the High-Performance Corrosion-Resistant Materials (HPCRM) Program, which was co-sponsored by the Defense Advanced Research Projects Agency (DARPA) Defense Sciences Office (DSO) and the United States Department of Energy (DOE) Office of Civilian and Radioactive Waste Management (OCRWM), is discussed. Programmatic investigations have included a broad range of topics: alloy design and composition; materials synthesis; thermal stability; corrosion resistance; environmental cracking; mechanical properties; damage tolerance; radiation effects; and important potential applications. Amorphous alloys identified as SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe4Mo14Cr15Y2C15B6) have been produced as melt-spun ribbons, drop-cast ingots and thermal-spray coatings. Chromium (Cr), molybdenum (Mo) and tungsten (W) additions provided corrosion resistance, while boron (B) enabled glass formation. Earlier electrochemical studies of melt-spun ribbons and ingots of these amorphous alloys demonstrated outstanding passive film stability. More recently thermal-spray coatings of these amorphous alloys have been made and subjected to long-term salt-fog and immersion tests. Good corrosion resistance has been observed during salt-fog testing. Corrosion rates were measured in situ with linear polarization, while simultaneously monitoring the open-circuit corrosion potentials. Reasonably good performance was observed. The sensitivity of these measurements to electrolyte composition and temperature was determined. The high boron content of this particular amorphous metal make this amorphous alloy an effective neutron absorber, and suitable for criticality control applications. In general, the corrosion resistance of these iron-based amorphous metals is maintained at operating temperatures up to the glass transition temperature. These materials are much harder than conventional stainless steel and nickel-based materials, and are proving to have excellent wear properties, sufficient to warrant their use in earth excavation, drilling and tunnel boring applications. The observed corrosion resistance may enable applications of importance in industries such as: oil and gas production, refining, nuclear power generation, shipping, and others. Large areas have been successfully coated with these materials, with thicknesses of approximately one centimeter.

Iron-Based Amorphous-Metals

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ISBN 13 :
Total Pages : 33 pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Iron-Based Amorphous-Metals by :

Download or read book Iron-Based Amorphous-Metals written by and published by . This book was released on 2008 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt: An overview of the High-Performance Corrosion-Resistant Materials (HPCRM) Program, which was co-sponsored by the Defense Advanced Research Projects Agency (DARPA) Defense Sciences Office (DSO) and the United States Department of Energy (DOE) Office of Civilian and Radioactive Waste Management (OCRWM), is discussed. Programmatic investigations have included a broad range of topics: alloy design and composition; materials synthesis; thermal stability; corrosion resistance; environmental cracking; mechanical properties; damage tolerance; radiation effects; and important potential applications. Amorphous alloys identified as SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe4Mo14Cr15Y2C15B6) have been produced as melt-spun ribbons, drop-cast ingots and thermal-spray coatings. Chromium (Cr), molybdenum (Mo) and tungsten (W) additions provided corrosion resistance, while boron (B) enabled glass formation. Earlier electrochemical studies of melt-spun ribbons and ingots of these amorphous alloys demonstrated outstanding passive film stability. More recently thermal-spray coatings of these amorphous alloys have been made and subjected to long-term salt-fog and immersion tests. Good corrosion resistance has been observed during salt-fog testing. Corrosion rates were measured in situ with linear polarization, while simultaneously monitoring the open-circuit corrosion potentials. Reasonably good performance was observed. The sensitivity of these measurements to electrolyte composition and temperature was determined. The high boron content of this particular amorphous metal makes this amorphous alloy an effective neutron absorber, and suitable for criticality control applications. In general, the corrosion resistance of such iron-based amorphous metals is maintained at operating temperatures up to the glass transition temperature. These materials are much harder than conventional stainless steel and nickel-based materials, and are proving to have excellent wear properties, sufficient to warrant their use in earth excavation, drilling and tunnel boring applications. Large areas have been successfully coated with these materials, with thicknesses of approximately one centimeter. The observed corrosion resistance may enable applications of importance in industries such as: oil and gas production, refining, nuclear power generation, shipping, and others.

High-Performance Corrosion-Resistant Iron-Based Amorphous Metals - The Effects of Composition, Structure and Environment

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ISBN 13 :
Total Pages : 49 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis High-Performance Corrosion-Resistant Iron-Based Amorphous Metals - The Effects of Composition, Structure and Environment by : J. Farmer

Download or read book High-Performance Corrosion-Resistant Iron-Based Amorphous Metals - The Effects of Composition, Structure and Environment written by J. Farmer and published by . This book was released on 2006 with total page 49 pages. Available in PDF, EPUB and Kindle. Book excerpt: Several Fe-based amorphous metal formulations have been identified that appear to have corrosion resistance comparable to (or better than) that of Ni-based Alloy C-22 (UNS No. N06022), based on measurements of breakdown potential and corrosion rate in seawater. Both chromium (Cr) and molybdenum (Mo) provide corrosion resistance, boron (B) enables glass formation, and rare earths such as yttrium (Y) lower critical cooling rate (CCR). SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) has no yttrium, and is characterized by relatively high critical cooling rates of approximately 600 Kelvin per second. Data for the SAM2X5 formulation is reported here. In contrast to yttrium-containing iron-based amorphous metals, SAM2X5 can be readily gas atomized to produce spherical powders which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer or inhibitor. SAM2X5 also experiences crevice corrosion under sufficiently harsh conditions. Both Alloy C-22 and Type 316L stainless lose their resistance to corrosion during thermal spraying, due to the formation of deleterious intermetallic phases which depletes the matrix of key alloy elements, whereas SAM2X5 can be applied as coatings with the same corrosion resistance as a fully-dense completely amorphous melt-spun ribbon, provided that its amorphous nature is preserved during thermal spraying. The hardness of Type 316L Stainless Steel is approximately 150 VHN, that of Alloy C-22 is approximately 250 VHN, and that of HVOF SAM2X5 ranges from 1100-1300 VHN [MRS12-13]. Such hardness makes these materials particularly attractive for applications where corrosion-erosion and wear are also issues. Since SAM2X5 has high boron content, it can absorb neutrons efficiently, and may therefore find useful applications as a criticality control material within the nuclear industry.

FY05 HPCRM Annual Report

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ISBN 13 :
Total Pages : 140 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis FY05 HPCRM Annual Report by :

Download or read book FY05 HPCRM Annual Report written by and published by . This book was released on 2007 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Two Fe-based amorphous metal formulations have been found that appear to have corrosion resistance comparable to, or better than that of Ni-based Alloy C-22, based on breakdown potential and corrosion rate. Both Cr and Mo provide corrosion resistance, B enables glass formation, and Y lowers critical cooling rate (CCR). SAM1651 has yttrium added, and has a nominal critical cooling rate of only 80 Kelvin per second, while SAM2X7 (similar to SAM2X5) has no yttrium, and a relatively high critical cooling rate of 610 Kelvin per second. Both amorphous metal formulations have strengths and weaknesses. SAM1651 (yttrium added) has a low critical cooling rate (CCR), which enables it to be rendered as a completely amorphous thermal spray coating. Unfortunately, it is relatively difficult to atomize, with powders being irregular in shape. This causes the powder to be difficult to pneumatically convey during thermal spray deposition. Gas atomized SAM1651 powder has required cryogenic milling to eliminate irregularities that make flow difficult. SAM2X5 (no yttrium) has a high critical cooling rate, which has caused problems associated with devitrification. SAM2X5 can be gas atomized to produce spherical powders of SAM2X5, which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer or inhibitor. Comparable metallic alloys such as SAM2X5 and SAM1651 may also experience crevice corrosion under sufficiently harsh conditions. Accelerated crevice corrosion tests are now being conducted to intentionally induce crevice corrosion, and to determine those environmental conditions where such localized attack occurs. Such materials are extremely hard, and provide enhanced resistance to abrasion and gouges (stress risers) from backfill operations, and possibly even tunnel boring. The hardness of Type 316L Stainless Steel is approximately 150 VHN, that of Alloy C-22 is approximately 250 VHN, and that of HVOF SAM2X5 ranges from 1100-1300 VHN. These new materials provide a viable coating option for repository engineers. SAM2X5 and SAM1651 coatings can be applied with thermal spray processes without any significant loss of corrosion resistance. Both Alloy C-22 and Type 316L stainless lose their resistance to corrosion during thermal spraying. Containers for the transportation, storage and disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) with corrosion resistant coatings are envisioned. For example, an enhanced multi-purpose container (MPC) could be made with such coatings, leveraging existing experience in the fabrication of such containers. These coating materials could be used to protect the final closure weld on SNF/HLW disposal containers, eliminate need for stress mitigation. Integral drip shield could be produced by directly spraying it onto the disposal container, thereby eliminating the need for an expensive titanium drip shield. In specific areas where crevice corrosion is anticipated, such as the contact point between the disposal container and pallet, HVOF coatings could be used to buildup thickness, thereby selectively adding corrosion life where it is needed. Both SAM2X5 & SAM1651 have high boron content which enable them to absorb neutrons and therefore be used for criticality control in baskets. Alloy C-22 and 316L have no neutron absorber, and cannot be used for such functions. Borated stainless steel and G.

FY05 HPCRM Annual Report

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ISBN 13 :
Total Pages : 69 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis FY05 HPCRM Annual Report by :

Download or read book FY05 HPCRM Annual Report written by and published by . This book was released on 2007 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt: New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Two Fe-based amorphous metal formulations have been found that appear to have corrosion resistance comparable to, or better than that of Ni-based Alloy C-22, based on breakdown potential and corrosion rate. Both Cr and Mo provide corrosion resistance, B enables glass formation, and Y lowers critical cooling rate (CCR). SAM1651 has yttrium added, and has a nominal critical cooling rate of only 80 Kelvin per second, while SAM2X7 (similar to SAM2X5) has no yttrium, and a relatively high critical cooling rate of 610 Kelvin per second. Both amorphous metal formulations have strengths and weaknesses. SAM1651 (yttrium added) has a low critical cooling rate (CCR), which enables it to be rendered as a completely amorphous thermal spray coating. Unfortunately, it is relatively difficult to atomize, with powders being irregular in shape. This causes the powder to be difficult to pneumatically convey during thermal spray deposition. Gas atomized SAM1651 powder has required cryogenic milling to eliminate irregularities that make flow difficult. SAM2X5 (no yttrium) has a high critical cooling rate, which has caused problems associated with devitrification. SAM2X5 can be gas atomized to produce spherical powders of SAM2X5, which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer or inhibitor. Comparable metallic alloys such as SAM2X5 and SAM1651 may also experience crevice corrosion under sufficiently harsh conditions. Accelerated crevice corrosion tests are now being conducted to intentionally induce crevice corrosion, and to determine those environmental conditions where such localized attack occurs. Such materials are extremely hard, and provide enhanced resistance to abrasion and gouges (stress risers) from backfill operations, and possibly even tunnel boring. The hardness of Type 316L Stainless Steel is approximately 150 VHN, that of Alloy C-22 is approximately 250 VHN, and that of HVOF SAM2X5 ranges from 1100-1300 VHN. These new materials provide a viable coating option for repository engineers. SAM2X5 and SAM1651 coatings can be applied with thermal spray processes without any significant loss of corrosion resistance. Both Alloy C-22 and Type 316L stainless lose their resistance to corrosion during thermal spraying. Containers for the transportation, storage and disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) with corrosion resistant coatings are envisioned. For example, an enhanced multi-purpose container (MPC) could be made with such coatings, leveraging existing experience in the fabrication of such containers. These coating materials could be used to protect the final closure weld on SNF/HLW disposal containers, eliminate need for stress mitigation. Integral drip shield could be produced by directly spraying it onto the disposal container, thereby eliminating the need for an expensive titanium drip shield. In specific areas where crevice corrosion is anticipated, such as the contact point between the disposal container and pallet, HVOF coatings could be used to buildup thickness, thereby selectively adding corrosion life where it is needed. Both SAM2X5 & SAM1651 have high boron content which enable them to absorb neutrons and therefore be used for criticality control in baskets. Alloy C-22 and 316L have no neutron absorber, and cannot be used for such functions. Borated stainless steel and G.

Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings

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ISBN 13 :
Total Pages : 16 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings by :

Download or read book Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings written by and published by . This book was released on 2007 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt: Amorphous metal and ceramic thermal spray coatings have been developed that can be used to enhance the corrosion resistance of containers for the transportation, aging and disposal of spent nuclear fuel and high-level radioactive wastes. Iron-based amorphous metal formulations with chromium, molybdenum and tungsten have shown the corrosion resistance believed to be necessary for such applications. Rare earth additions enable very low critical cooling rates to be achieved. The boron content of these materials, and their stability at high neutron doses, enable them to serve as high efficiency neutron absorbers for criticality control. Ceramic coatings may provide even greater corrosion resistance for container applications, though the boron-containing amorphous metals are still favored for criticality control applications. These amorphous metal and ceramic materials have been produced as gas atomized powders and applied as near full density, non-porous coatings with the high-velocity oxy-fuel process. This paper summarizes the performance of these coatings as corrosion-resistant barriers, and as neutron absorbers. Relevant corrosion models are also discussed, as well as a cost model to quantify the economic benefits possible with these new materials.

CORROSION RESISTANCE OF STRUCTURAL AMORPHOUS METAL.

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ISBN 13 :
Total Pages : 7 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis CORROSION RESISTANCE OF STRUCTURAL AMORPHOUS METAL. by : J. C. Farmer

Download or read book CORROSION RESISTANCE OF STRUCTURAL AMORPHOUS METAL. written by J. C. Farmer and published by . This book was released on 2006 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The potential advantages of amorphous metals have been recognized for some time [Latanison 1985]. Iron-based corrosion-resistant, amorphous-metal coatings under development may prove important for maritime applications [Farmer et al. 2005]. Such materials could also be used to coat the entire outer surface of containers for the transportation and long-term storage of spent nuclear fuel, or to protect welds and heat affected zones, thereby preventing exposure to environments that might cause stress corrosion cracking [Farmer et al. 1991, 2000a, 2000b]. In the future, it may be possible to substitute such high-performance iron-based materials for more-expensive nickel-based alloys, thereby enabling cost savings in a wide variety of industrial applications. It should be noted that thermal-spray ceramic coatings have also been investigated for such applications [Haslam et al. 2005]. This report focuses on the corrosion resistance of a yttrium-containing amorphous metal, SAM1651. SAM1651 has a glass transition temperature of {approx}584 C, a recrystallization temperature of {approx}653 C, and a melting point of {approx}1121 C. The measured critical cooling rate for SAM1651 is {le} 80 K per second, respectively. The yttrium addition to SAM1651 enhances glass formation, as reported by Guo and Poon [2003]. The corrosion behavior of SAM1651 was compared with nickel-based Alloy 22 in electrochemical polarization measurements performed in several highly concentrated chloride solutions.

CORROSION STUDY OF AMORPHOUS METAL RIBBONS.

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ISBN 13 :
Total Pages : 9 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis CORROSION STUDY OF AMORPHOUS METAL RIBBONS. by : J. C. Farmer

Download or read book CORROSION STUDY OF AMORPHOUS METAL RIBBONS. written by J. C. Farmer and published by . This book was released on 2006 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The potential advantages of amorphous metals have been recognized for some time [Latanison 1985]. Iron-based corrosion-resistant, amorphous-metal coatings under development may prove important for maritime applications [Farmer et al. 2005]. Such materials could also be used to coat the entire outer surface of containers for the transportation and long-term storage of spent nuclear fuel, or to protect welds and heat affected zones, thereby preventing exposure to environments that might cause stress corrosion cracking [Farmer et al. 1991, 2000a, 2000b]. In the future, it may be possible to substitute such high-performance iron-based materials for more-expensive nickel-based alloys, thereby enabling cost savings in a wide variety of industrial applications. It should be noted that thermal-spray ceramic coatings have also been investigated for such applications [Haslam et al. 2005]. This report focuses on the corrosion resistance of iron-based melt-spun amorphous metal ribbons. Melt-Spun ribbon is made by rapid solidification--a stream of molten metal is dropped onto a spinning copper wheel, a process that enables the manufacture of amorphous metals which are unable to be manufactured by conventional cold or hot rolling techniques. The study of melt-spun ribbon allows quick evaluation of amorphous metals corrosion resistance. The melt-spun ribbons included in this study are DAR40, SAM7, and SAM8, SAM1X series, and SAM2X series. The SAM1X series ribbons have Ni additions in increments of 1, 3, 5, and 7 atom percent, to DAR40. For example, 1X7 means a composition of 7-atom% Ni added to 93-atom% of DAR40. Similarly, The SAM1X series ribbons have Mo additions in increments of 1, 3, 5, and 7 atom percent, to DAR40. For example, 2X3 means a composition of 3-atom% Mo added to 97-atom% of DAR40. SAM7 ribbon is a Fe-Cr-Mo-Y-C-B metal glass, commonly called Alloy1651. SAM8 is SAM7 with an additional 3-atom% W. The nominal compositions of DAR40 and SAM7 are listed in Table 1. SAM7 ribbon is extremely brittle and hard to manufactured by melt-spinning, only limited number of SAM7 ribbons were tested.

Thermal Spray Coatings

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Publisher : CRC Press
ISBN 13 : 1000479307
Total Pages : 365 pages
Book Rating : 4.0/5 (4 download)

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Book Synopsis Thermal Spray Coatings by : Lalit Thakur

Download or read book Thermal Spray Coatings written by Lalit Thakur and published by CRC Press. This book was released on 2021-11-22 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the latest information about the research being conducted and established solutions available in the field of thermal spray coatings for various engineering applications. The readers of this book will be mainly the graduates, engineers and researchers who are pursuing their carrier in the field of thermal spraying. This book will cover the studies and research works of reputed scientists and engineers who have developed thermal spray coatings for thermal protection, bio-implants, renewal energy, wear and corrosion in hydraulic turbines and jet engines, hydrophobic surfaces etc. Hence, the book serves as a valuable resource of latest advancement in thermal spray technology and consolidated references for aspirants and professionals of surface engineering community. The book covers following topics for different industrial applications: Introduction: Historical developments, Science and Engineering aspects of thermal spray coating technology and different thermal spray coatings techniques and its comparison with other fabrication processes. Recent advancements and applications of thermal spray coatings Cold spray technology for additive manufacturing. High-temperature corrosion and erosion resistant coatings and thermal barrier coatings for power plants, automotive sector, and jet engines. Erosion and corrosion-resistant coatings for hydro-power plants, offshore, chemical and oil industries. Bio-coatings for human body implants. Thermal spray coating for super-hydrophobic surface. 3. Case study of boiler tubes failure and prevention by thermal spray coatings.

Coatings for High-Temperature Environments

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Publisher : Springer Nature
ISBN 13 : 3031455347
Total Pages : 433 pages
Book Rating : 4.0/5 (314 download)

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Book Synopsis Coatings for High-Temperature Environments by : Amirhossein Pakseresht

Download or read book Coatings for High-Temperature Environments written by Amirhossein Pakseresht and published by Springer Nature. This book was released on 2023-12-05 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses the recent trends in high-temperature coatings that are used to provide oxidation and wear resistance to metallic/ceramic components in extreme environments. Ceramics, intermetallics, organosilicon polymers, cermets, and other materials with great thermal stability have long been recognized for these applications. This book introduces the state of the art in coating materials and processes for high-temperature environments and identifies areas for improvement in materials selection, performance upgrades, design considerations, and manufacturing methods. The book covers a variety of high-temperature coatings prepared through various synthesis processes such as thermal spraying, physical vapor deposition, electrodeposition, and sol–gel methods. It covers corrosion/oxidation, phase stability, and thermal and mechanical behavior of high-temperature coating materials having greater thermal stability. With contributions from international researchers active in the field, this edited book features the most recent and up-to-date literature references for a broad readership consisting of academic and industrial professionals. It is suitable for graduate students as well as scientists and engineers working in the area of anti-corrosion and anti-wear resistant high-temperature coatings for industrial applications.

Thermal Spray Coatings: Materials, Techniques & Applications

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Publisher : Bentham Science Publishers
ISBN 13 : 9815223569
Total Pages : 296 pages
Book Rating : 4.8/5 (152 download)

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Book Synopsis Thermal Spray Coatings: Materials, Techniques & Applications by : Santosh Kumar

Download or read book Thermal Spray Coatings: Materials, Techniques & Applications written by Santosh Kumar and published by Bentham Science Publishers. This book was released on 2024-07-30 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book explores the techniques, materials, and real-world applications of thermal spray coatings across various industries, including power generation, aerospace, medical, and automotive sectors. Readers will learn about the basic science and engineering aspects of thermal spray technology, its historical developments, and the diverse range of materials used, from metallic to ceramic materials, and nano-crystallization materials. Distinct thermal spray techniques are explained (flame spray, detonation-gun spray, high-velocity oxy-fuel spray, electric arc spray, plasma spray and cold spray). Chapters on advanced topics also give an understanding of crucial material properties such as high temperature corrosion, oxidation, erosion or wear resistance, and biocompatibility. Key features - Contributions from materials science experts with references for each topic - Gives a comprehensive overview of materials and distinct spray techniques used in thermal coatings - Dedicated chapters for applications of thermal coatings in different industries - Covers recent trends and new advances such as surface modification techniques to improve functionality and performance This book is intended as a resource for an in-depth understanding of the fundamentals and applications of thermal spray coatings for students, professionals and researchers in materials science and chemical engineering disciplines.

Thermal Spray Fundamentals

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Publisher : Springer Nature
ISBN 13 : 3030706729
Total Pages : 1147 pages
Book Rating : 4.0/5 (37 download)

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Book Synopsis Thermal Spray Fundamentals by : Maher I. Boulos

Download or read book Thermal Spray Fundamentals written by Maher I. Boulos and published by Springer Nature. This book was released on 2021-10-19 with total page 1147 pages. Available in PDF, EPUB and Kindle. Book excerpt: This fully revised, industry-standard resource offers practical details on every aspect of the fundamentals necessary for understanding thermal spray technology, from powder all the way to the final part. The second edition is presented in a reader-friendly format that is split into four parts. Part I presents a review of thermal spray coating and its position in the broad field of surface modification technologies. Highlights of combustion and thermal plasmas are given with an expanded treatment of in-flight plasma-particle interactions. The second and third parts deal respectively with an updated presentation of thermal spray technologies and coating formation, including solution and suspension plasma spraying. The last part of the book includes a comparative analysis of different thermal spray processes, which is essential for the optimal selection of the appropriate thermal spray process in a given application. Coverage of system integration has been expanded with the addition of a detailed discussion of online instrumentation and process diagnostics and numerous examples of industrial scale spray booth designs. Attention is also given to coating finishing and health and safety issues. An extensive review is presented of thermal spray applications grouped in terms of process objectives and present use in different industrial sectors. This book will serve as an invaluable resource as a textbook for graduate courses in the field and as an exhaustive reference for professionals involved in the thermal spray field.

Thermal Spray Fundamentals

Download Thermal Spray Fundamentals PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 0387689915
Total Pages : 1587 pages
Book Rating : 4.3/5 (876 download)

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Book Synopsis Thermal Spray Fundamentals by : Pierre L. Fauchais

Download or read book Thermal Spray Fundamentals written by Pierre L. Fauchais and published by Springer Science & Business Media. This book was released on 2014-01-24 with total page 1587 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides readers with the fundamentals necessary for understanding thermal spray technology. Coverage includes in-depth discussions of various thermal spray processes, feedstock materials, particle-jet interactions, and associated yet very critical topics: diagnostics, current and emerging applications, surface science, and pre and post-treatment. This book will serve as an invaluable resource as a textbook for graduate courses in the field and as an exhaustive reference for professionals involved in thermal spray technology.

Corrosion of Stainless Steels

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 0471007927
Total Pages : 467 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Corrosion of Stainless Steels by : A. John Sedriks

Download or read book Corrosion of Stainless Steels written by A. John Sedriks and published by John Wiley & Sons. This book was released on 1996-04-19 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Complete, Up-to-Date Introduction to Corrosion of StainlessSteels and Metallurgical Factors This fully updated Second Editionof Corrosion of Stainless Steels covers the tremendous advancesmade with stainless steels in recent decades, includingapplications in many new areas--from marine technologies andoff-shore oil production to power plants and the kitchen sink. Thisbook offers unique insights into the corrosion mechanisms affectingstainless steels, details problem-avoidance strategies, and helpsidentify corrosion-resistant capabilities for these remarkablealloys Sponsored by the Electrochemical Society, Corrosion osStainless Steels * Provides a comprehensive introduction to the selection,development, and production of all types of stainless steels * Emphasizes how metallurgical factors affect corrosionresistance * Examines the limitations of stainless steels within the contextof a discussion on higher alloys * Takes an interdisciplinary approach that demonstrates thecombined effects of metallurgy, chemistry, and electrochemistry oncorrosion resistance * Provides baseline knowledge and testing standards for stainlesssteels, and facilitates failure analysis for industrial purposes orlitigation related to equipment failure This is a much-needed text for materials scientists, chemicalengineers, corrosion specialists, graduate students, and anyone whoneeds to be brought up to date on this subject.