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Electron Transfer Reactions Of Complex Ions In Solution
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Book Synopsis Electron Transfer Reactions of Complex Ions in Solution by : Henry Taube
Download or read book Electron Transfer Reactions of Complex Ions in Solution written by Henry Taube and published by Elsevier. This book was released on 2012-12-02 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron Transfer Reactions of Complex Ions in Solution covers the significant development of some important area of electron transfer reactions of complex ions. This four-chapter book emerged from a series of lectures at the Polytechnic Institute of Brooklyn in November and December 1967. Chapter I presents research studies in cation hydration. This chapter describes principal methods for composition determination of the first coordination spheres of the aquo ions. Chapter II examines the distinction between reactions in which electron transfer takes place from one primary bond system to another. Chapter III discusses some aspects of ligand effects in electron-transfer reactions. This chapter demonstrates that differences in the behavior of systems can be expected at least in the extremes of mechanisms. Chapter IV deals with the history, principles and applications of the induced electron-transfer effect. This book is of great value to electrochemists, students, and researchers.
Book Synopsis Electron Transfer Reactions of Complex Ions in Solution by : Henry Taube
Download or read book Electron Transfer Reactions of Complex Ions in Solution written by Henry Taube and published by . This book was released on 1970 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reaction Mechanisms of Metal Complexes by : R W Hay
Download or read book Reaction Mechanisms of Metal Complexes written by R W Hay and published by Elsevier. This book was released on 2000-03-01 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. - Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry - Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands
Book Synopsis Electron Transfer Reactions by : Stephan S. Isied
Download or read book Electron Transfer Reactions written by Stephan S. Isied and published by . This book was released on 1997 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Begins with a historical overview by Henry Taube. Overviews the advances pioneered by Taube, including mechanisms of electron transfer reactions, charge transfer complexes, and *p back bonding effects in metal-ligand interactions. Discusses applications of principles of electron transfer to diverse areas of chemistry and biology such as the selective and controlled oxidation of organic functional groups, polymerization catalysis, metal biological interactions with DNA, biological electron transfer reactions, and new imaging agents in diagnostic medicine.
Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Book Synopsis Metal Ions and Complexes in Solution by : Ingmar Persson
Download or read book Metal Ions and Complexes in Solution written by Ingmar Persson and published by Royal Society of Chemistry. This book was released on 2023-12-04 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electron Transfer Reactions in Organic Chemistry by : Lennart Eberson
Download or read book Electron Transfer Reactions in Organic Chemistry written by Lennart Eberson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.
Book Synopsis Inorganic Chemistry by : Ram Charitra Maurya
Download or read book Inorganic Chemistry written by Ram Charitra Maurya and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-04-06 with total page 821 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers different aspects of Inorganic Chemistry in terms of 10 Chapters with in-depth and up-to-date coverage. Starting with the VSEPR theory in the first chapter, the book symmetrically presents delocalized p-bonding in polyatomic molecules; structure, bonding and topology of borane and related compounds; synthesis and reactivity of metal clusters and their bonding; some aspects of stability constants of metal complexes; magnetochemistry; mechanism of inorganic reactions; molecular orbital (MO) approach of bonding in transition metals; bonding in organometallic sandwich compounds based on MO approach. Safe and economical inorganic experiments at UG and PG Levels are also presented in the last chapter. At the end, five relevant topics are included as appendices for updating students and faculty members.
Author :John O'M. Bockris Publisher :Springer Science & Business Media ISBN 13 :9780306443398 Total Pages :1054 pages Book Rating :4.4/5 (433 download)
Book Synopsis Surface Electrochemistry by : John O'M. Bockris
Download or read book Surface Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 1993-05-31 with total page 1054 pages. Available in PDF, EPUB and Kindle. Book excerpt: Not an updated edition of the introductory textbook, Modern Electrochemistry (authored by J.O'M. Bockris and A.K.N. Reddy and published by Plenum in 1970), but an advanced text that takes the reader from 1970 to the 1990s. The sophisticated, and sometimes nonconsensual or speculative treatment covers experimental techniques, the interphasial structure, phenomenological electrode kinetics, quantum-oriented electrochemistry, photoelectrochemistry, organoelectrochemistry, bioelectrochemistry, electrochemical aspects of the stability of materials, electrochemical conversion and storage of energy, and the electrochemistry of cleaner environments. Annotation copyright by Book News, Inc., Portland, OR
Book Synopsis On Being Well-coordinated by : Fred Basolo
Download or read book On Being Well-coordinated written by Fred Basolo and published by World Scientific. This book was released on 2003 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Book Synopsis Coordination Chemistry by : Tomoaki Tanase
Download or read book Coordination Chemistry written by Tomoaki Tanase and published by Royal Society of Chemistry. This book was released on 2024-10-16 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: New to coordination chemistry and looking for some straightforward resources? In this long-established field of science, developments have continued between disciplines. Thus, modern coordination chemistry is recognized as an interdisciplinary molecular science that has developed at the intersection of inorganic and organic chemistry. Translated from the original Japanese, this accessible book is for undergraduate and graduate students and young researchers new to coordination chemistry. It explores transition metal complexes involving d and f orbitals and is structured as a step-by-step guide. It starts with the basics, as the foundation of the topic, progressing in complexity to explain some of the recent interdisciplinary developments. Important analytical methods related to the contents are introduced for completeness. You need look no further for concise and easy-to-understand explanations of coordination chemistry.
Book Synopsis Solutions Manual to Accompany Elements of Physical Chemistry by : David Smith
Download or read book Solutions Manual to Accompany Elements of Physical Chemistry written by David Smith and published by Oxford University Press, USA. This book was released on 2013-05-30 with total page 562 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Solutions Manual to accompany Elements of Physical Chemistry 6th edition contains full worked solutions to all end-of-chapter discusssion questions and exercises featured in the book. The manual provides helpful comments and friendly advice to aid understanding. It is also a valuable resource for any lecturer who wishes to use the extensive selection of exercises featured in the text to support either formative or summative assessment, and wants labour-saving, ready access to the full solutions to these questions.
Book Synopsis Research and Development in Progress by :
Download or read book Research and Development in Progress written by and published by . This book was released on 1973 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Current Topics in Bioenergetics by : D. Rao Sanadi
Download or read book Current Topics in Bioenergetics written by D. Rao Sanadi and published by Elsevier. This book was released on 2014-11-25 with total page 478 pages. Available in PDF, EPUB and Kindle. Book excerpt: Current Topics in Bioenergetics, Volume 3 provides information pertinent to the phenomena associated with biological energy transduction at different levels of sophistication. This book discusses the energy-linked processes in mitochondria. Organized into seven chapters, this volume begins with an overview of the core of the mechanism of oxidative phosphorylation. This text then explains the basic features of artificial membranes model system and its usefulness in probing membrane phenomena. Other chapters consider the thermodynamic and kinetic aspects of active transport of ions and attempt to relate photoreception with the subsequent electrophysiological events. This book discusses as well the regulation of respiration by muscular activity and on energy transduction in phototropism and phototaxis. The final chapter deals with the mechanism of phototaxis in microorganisms and explains the phenomenon as a translational response of a freely moving organism to a light stimulus. This book is a valuable resource for biochemists, cell biologists, and physiologists.
Download or read book Chemistry written by Arthur Greenberg and published by Infobase Publishing. This book was released on 2014-05-14 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents a history of chemistry, providing definitions and explanations of related topics, plus brief biographies of scientists of the 20th century.
Book Synopsis Theoretical Chemistry Accounts by : Christopher Cramer
Download or read book Theoretical Chemistry Accounts written by Christopher Cramer and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the New Century Issue of the journal "Theroretical Chemistry Accounts" the advisory editors identified papers from the first century of theoretical chemistry and discussed their importance for the twentieth century with an eye towards the twenty-first century. Sixty-six such perspectives are published in the New Century Issue. To make this unique collection available to younger scientists for entertaining reading and re-reading of the original publications, the publisher decided to reprint a special edition of the issue.
Book Synopsis Electron Transfer Reactions by : Roderick David Cannon
Download or read book Electron Transfer Reactions written by Roderick David Cannon and published by Butterworth-Heinemann. This book was released on 1980 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:
