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Author : Monica Garcia-Gonzalez
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (599 download)
Download or read book Electron Transfer Across Self-assembled Monolayers written by Monica Garcia-Gonzalez and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Emel Adaligil
Publisher :
ISBN 13 : 9781109669480
Total Pages : 272 pages
Book Rating : 4.6/5 (694 download)
Download or read book Electron Transfer Through Self-assembled Monolayers of Alkaneselenols and Alkanethiols on Mercury Electrode written by Emel Adaligil and published by . This book was released on 2010 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: The kinetics of long-range electron transfer through self-assembled monolayers of n-alkanethiols and n-alkaneselenols (SAMs) was studied via voltammetry of hexaammineruthenium (III) on a hanging mercury drop electrode (HMDE). Electron tunneling rates across the both monolayer films decay exponentially with thickness with a tunneling coefficient [beta] = 1.1 per CH2. Gradual additions of aliphatic alcohols to the solution result in a decrease of the long-range electron transfer rate, by a maximum of 7-fold, dependent upon the alcohol concentration, but independent of the thickness of the n-alkanethiol monolayer (SAM) and the alcohol's chain length. The mechanism involving competitive adsorption of the alcohol on the SAM surface is proposed to interpret the kinetic data. Electron tunneling rates across n-alkanethiol monolayers are approximately 4-fold larger than the rates measured on n-alkaneselenol monolayers containing the same number of carbon atoms signifying the importance of head-group contact in electron transfer through SAMs.
Download or read book Stability of and Electron Transfer Through Self-assembled Monolayers of Conformationally Constrained Peptides written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Volker Kriegisch
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (118 download)
Download or read book Electron transfer processes between organic redox centres and electrodes via active bridges in self-assembled monolayers written by Volker Kriegisch and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Sergey Kharabash
Publisher :
ISBN 13 :
Total Pages : 80 pages
Book Rating : 4.:/5 (225 download)
Download or read book Electron Transfer Kinetics Through Self Assembled Monolayers on Gold written by Sergey Kharabash and published by . This book was released on 2005 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 32 pages
Book Rating : 4.:/5 (227 download)
Download or read book Kinetics of Mediated Electron Transfer Between Viologen Groups in a Self-Assembled Monolayer and Metal Complexes in Solution written by and published by . This book was released on 1993 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-assembled monolayers are used in an experimental configuration which allows the extraction of the cross reaction electron exchange rate constant for the electron transfer between a viologen group embedded within the SAM and a metal complex in solution. This cross reaction rate constant is compared with predictions from the Marcus theory using the cross reaction relation and the known self-exchange rate constants for the two reagents. The results reveal that the intrinsic barrier to the electron transfer is relatively unchanged in the SAM, while the rate constant is somewhat depressed due to the long distance over which the electron must transfer, Electrochemistry, Marcus theory, Cross reaction.
Author : Roychelle S. Ingram
Publisher :
ISBN 13 :
Total Pages : 326 pages
Book Rating : 4.:/5 (388 download)
Download or read book Investigations of Electron Transfer and Mass Transport of Two- and Three-dimensional Self-assembled Monolayers written by Roychelle S. Ingram and published by . This book was released on 1997 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Robert Samuel Clegg
Publisher :
ISBN 13 :
Total Pages : 700 pages
Book Rating : 4.:/5 (451 download)
Download or read book Structure, Stability and Electron Transfer Characteristics of Self-assembled Monolayers Containing Internal Peptide Groups written by Robert Samuel Clegg and published by . This book was released on 1999 with total page 700 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Kent Stuart Alleman
Publisher :
ISBN 13 :
Total Pages : 156 pages
Book Rating : 4.:/5 (363 download)
Download or read book Electron-transfer Mediation by Ferrocene-containing Self-assembled Monolayers written by Kent Stuart Alleman and published by . This book was released on 1995 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Federico Polo
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (955 download)
Download or read book Electron Transfer to and Through Peptides and Characterization of Related Self-assembled Monolayers written by Federico Polo and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jian Liang
Publisher :
ISBN 13 : 9780549284871
Total Pages : 308 pages
Book Rating : 4.2/5 (848 download)
Download or read book Electron Transfer Mediating Properties of Self-assembled Monolayers written by Jian Liang and published by . This book was released on 2008 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular electronics have been attracting tremendous interest in recent years. One of the basic questions remaining unanswered, however, in this field is how to determine the "conductivity" of molecules. Conventional methods for measuring electron transport properties through metal-molecule-metal junctions lack the precise descriptions of the contact properties in the junction. Consequently, the "conductivities" of molecules reported in the literature are not consistent. In this dissertation we report a new experimental method for measuring relatively small differences in electron tunneling through two distinct monolayers. We place them side by side using scanning probe nanolithography and compare the tunneling currents by conductive probe atomic force microscopy under identical force, voltage, and tip contamination conditions. We demonstrate the validity of our approach by applying it to two isomeric molecules with similar length and functional groups, with only the position of two functional groups, one aromatic and the other aliphatic, being inverted with respect to each other. The relative values of the two tunneling currents, calculated using density functional theory in the Tersoff-Hamann approach, compare very well with the experimental data, providing us with an example of theory vs experiment agreement that is rather uncommon in this field.
Author : Ari Aviram
Publisher :
ISBN 13 :
Total Pages : 392 pages
Book Rating : 4.F/5 ( download)
Download or read book Molecular Electronics written by Ari Aviram and published by . This book was released on 1998 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume explores the resurgence of interest in the field of molecular electronics in view of recent advances in such areas as molecular wires, molecular components, fabrication, and assemblies of molecular scale devices and their wiring on surfaces. It shows how molecular electronics offer scientists an opportunity to study and understand a new class of materials, on the molecular level and in isolation, while offering to engineers a new microelectronics technology.
Author : Everardus Hendrik Huisman
Publisher :
ISBN 13 : 9789036741873
Total Pages : 139 pages
Book Rating : 4.7/5 (418 download)
Download or read book Electron Transport Through Single Organic Molecules and Self-assembled Monolayers written by Everardus Hendrik Huisman and published by . This book was released on 2010 with total page 139 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Mahmood Aliofkhazraei
Publisher : Springer
ISBN 13 : 9783319152653
Total Pages : 0 pages
Book Rating : 4.1/5 (526 download)
Download or read book Handbook of Nanoelectrochemistry written by Mahmood Aliofkhazraei and published by Springer. This book was released on 2015-11-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited book is devoted to different electrochemical aspects of nano materials. This comprehensive reference text is basically divided in 3 parts: electrochemical synthesis routes for nanosized materials, electrochemical properties of nano materials and electrochemical characterization methods for nanostructures. The Handbook is a reference work to chemists and materials scientists interested in the nano aspects of electrochemistry. The chapters are written by a number of international experts in the field and the content will assist members of both electrochemical and materials communities to keep abreast of developments in the field.
Author : Lisa Ann Hockett
Publisher :
ISBN 13 :
Total Pages : 402 pages
Book Rating : 4.:/5 (372 download)
Download or read book Electron-transfer Kinetics in Ferrocene-containing Self-assembled Monolayers on Gold Macro- and Microelectrodes Studied by Fast-scan Cyclic Voltammetry written by Lisa Ann Hockett and published by . This book was released on 1995 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jin Zhang
Publisher : Springer Science & Business Media
ISBN 13 : 0306479419
Total Pages : 327 pages
Book Rating : 4.3/5 (64 download)
Download or read book Self-Assembled Nanostructures written by Jin Zhang and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructures refer to materials that have relevant dimensions on the nanometer length scales and reside in the mesoscopic regime between isolated atoms and molecules in bulk matter. These materials have unique physical properties that are distinctly different from bulk materials. Self-Assembled Nanostructures provides systematic coverage of basic nanomaterials science including materials assembly and synthesis, characterization, and application. Suitable for both beginners and experts, it balances the chemistry aspects of nanomaterials with physical principles. It also highlights nanomaterial-based architectures including assembled or self-assembled systems. Filled with in-depth discussion of important applications of nano-architectures as well as potential applications ranging from physical to chemical and biological systems, Self-Assembled Nanostructures is the essential reference or text for scientists involved with nanostructures.
Author : Darrin Lee Smith
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (139 download)
Download or read book Energy-transfer, Electron-transfer, and Atom/group-transfer Resulting from Low-energy Ion-surface Collisions Characterize Hydrocarbon, Fluorocarbon, and Mixed Self-assembled Monolayers (PHD). written by Darrin Lee Smith and published by . This book was released on 2002 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
