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Electrodeposition De Films De Polypyrrole Sur Zinc Amelioration De Leurs Proprietes Dadherence Et De Protection Contre La Corrosion
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Book Synopsis ELECTRODEPOSITION DE FILMS DE POLYPYRROLE SUR ZINC. AMELIORATION DE LEURS PROPRIETES D'ADHERENCE ET DE PROTECTION CONTRE LA CORROSION by : ERIC.. HERMELIN
Download or read book ELECTRODEPOSITION DE FILMS DE POLYPYRROLE SUR ZINC. AMELIORATION DE LEURS PROPRIETES D'ADHERENCE ET DE PROTECTION CONTRE LA CORROSION written by ERIC.. HERMELIN and published by . This book was released on 2000 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: L'OBJECTIF DE CETTE RECHERCHE EST D'AMELIORER LES PROPRIETES D'ADHERENCE A L'ETAT REDUIT ET DE PROTECTION CONTRE LA CORROSION DE FILMS DE POLYPYRROLE ELECTRODEPOSES SUR ZINC A PARTIR D'UNE SOLUTION AQUEUSE DE SALICYLATE DE SODIUM ET DE PYRROLE. UNE GRANDE PARTIE DE CE TRAVAIL A PORTE SUR L'ETUDE DE L'INFLUENCE DE LA MODIFICATION DE LA COMPOSITION DE LA SOLUTION DE SYNTHESE. L'INTRODUCTION D'UN CO-MONOMERE (LE 1,2-BIS-(2-PYRROLYLETHOXY) ETHANE, NOTE DEDP) OU / ET D'UN CO-ELECTROLYTE (L'ACIDE 3,5 DIISOPROPYL SALICYLIQUE, NOTE DISACH) AMELIORE CONSIDERABLEMENT LES PROPRIETES DES FILMS DE PPY. LE DEDP PERMET AINSI D'ATTEINDRE UNE ADHERENCE DE 100% DES FILMS APRES REDUCTION ET LE DISACH INDUIT UNE FORTE VARIATION DE L'ENERGIE DE SURFACE DES REVETEMENTS ET AMELIORE LEURS PROPRIETES DE PROTECTION CONTRE LA CORROSION. LA PRESENCE SIMULTANEE DE CES COMPOSES CONDUIT A UNE SYNERGIE DE LEURS EFFETS, MAIS MALHEUREUSEMENT, LA POROSITE DES FILMS DEMEURE TROP IMPORTANTE POUR ATTEINDRE DES EFFICACITES DE PROTECTION COMPATIBLES AVEC LES CONTRAINTES DE L'INDUSTRIE. LA SECONDE PARTIE DE CE TRAVAIL A ETE PRECISEMENT CONSACREE A L'AMELIORATION DES PROPRIETES PHYSICO-CHIMIQUES DES FILMS DE POLYPYRROLE PAR UN POST-TRAITEMENT THERMIQUE. LA COMPACITE DES FILMS A AINSI ETE CONSIDERABLEMENT AUGMENTEE GRACE A UNE RETICULATION OXYDANTE PAR L'OXYGENE DE L'AIR A 180\C. EN EFFET, LE TRAITEMENT THERMIQUE DES REVETEMENTS PERMET D'ATTEINDRE DES EFFICACITES DE PROTECTION CONTRE LA CORROSION AU MOIS EQUIVALENTES A CELLE DU ZINC. APRES OPTIMISATION DU PROCEDE, LES FILMS SYNTHETISES EN PRESENCE DE DISACH APPARAISSENT LE PLUS INTERESSANTS POUR TENDRE VERS UN TEMPS DE TRAITEMENT TRES COURT ET COMPATIBLE AVEC LES IMPERATIFS INDUSTRIELS (6 MN POUR UNE TEMPERATURE DE CUISSON DE 225\C).
Book Synopsis Electrodéposition, caractérisation et propriétés anti-corrosion de films à base d'oxyde de cérium sur des alliages de zinc by : Sylvain Poupard
Download or read book Electrodéposition, caractérisation et propriétés anti-corrosion de films à base d'oxyde de cérium sur des alliages de zinc written by Sylvain Poupard and published by . This book was released on 2009 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ces dernières années, de fortes recommandations ont été émises concernant les rejets des métaux lourds et l’impact éventuel d’éléments tels que le zinc sur l’environnement. L’utilisation abondante de cet élément notamment dans le domaine de la durabilité des structures métalliques a menée à des taux de rejets de zinc liés à l’activité humaine dans les eaux fluviales et les zones portuaires qui atteignent des doses critiques pour l’environnement. Indépendamment de la nature du revêtement sacrificiel à base de zinc, il est aussi nécessaire de réaliser des traitements de surface pour assurer l’aspect esthétique des produits revêtus, une amélioration supplémentaire de la résistance à la corrosion à vocation esthétique et/ou protectrice comme le chrome. Cependant, les nouvelles directives européennes et nationales de plus en plus exigeantes restreignent l’utilisation de Cr(VI), qui doit être abandonnée et remplacée par des méthodes plus écologiques. Ainsi, la nouvelle génération des méthodes alternatives consiste à déposer des composés de terres rares et plus particulièrement des oxydes de cérium (CeO2) qui pourraient conférer une très bonne protection grâce à leur action comme film passif. L’objet de cette étude est axé sur l’élaboration par électrodéposition, la caractérisation et les propriétés physico-chimiques des couches minces d’oxyde de cérium sur des revêtements à base de zinc. Pour cela, l’étude a été menée sur des substrats modèles de zinc pur ainsi que sur des revêtements électrodéposés de zinc allié. Les caractérisations effectuées ont montré l’influence de certains paramètres de l’électrodéposition (densité de courant, temps, concentration, additif et courants pulsés) sur les mécanismes mis en jeu et donc sur la morphologie et la composition des films. Le comportement des revêtements électrodéposés vis-à-vis de la corrosion en milieu aqueux a également été étudié en combinant des essais d’immersion et des tests accélérés de corrosion (brouillard salin). Si les différents essais ont montré que ces films agissent comme une barrière physique bloquant la diffusion de l’oxygène, leur efficacité semble fortement dépendantes des conditions d’élaboration des revêtements.
Book Synopsis ELECTROSYNTHESE DE COUCHES DE POLYPYRROLE SUR ELECTRODES DE FER ET DE ZINC. APPLICATION A LA PROTECTION DES METAUX by : CARLOS ARTHUR.. FERREIRA
Download or read book ELECTROSYNTHESE DE COUCHES DE POLYPYRROLE SUR ELECTRODES DE FER ET DE ZINC. APPLICATION A LA PROTECTION DES METAUX written by CARLOS ARTHUR.. FERREIRA and published by . This book was released on 1991 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: DANS CETTE THESE, J'AI MONTRE POUR LA PREMIERE FOIS QU'IL ETAIT POSSIBLE DE DEPOSER PAR ELECTROPOLYMERISATION ANODIQUE DU PPY DES FILMS DE POLYPYRROLE (PPY) EPAIS ET EXTREMEMENT ADHERENT SUR DES METAUX OXYDABLES. CET OBJECTIF N'A PU ETRE ATTEINT QU'APRES AVOIR MIS AU POINT DES TRAITEMENTS DE SURFACE SPECIFIQUES A CHAQUE METAL ET QU'APRES OPTIMISATION DU MILIEU. DANS CE TRAVAIL J'AI ETUDIE EN DETAIL LE PROCESSUS D'ELECTROPOLYMERISATION DU PYRROLE SUR DES ELECTRODES DE FER OU D'ACIER DOUX DANS DIFFERENTS MILIEUX ORGANIQUES ET MONTRE QUE LE COMPORTEMENT ELECTROCHIMIQUE DU METAL ETAIT LIE A LA BASICITE DU MILIEU. LE TRAITEMENT PREALABLE DE LA SURFACE DES ELECTRODES PAR HNO#3 DILUE M'A PERMIS DE DEPOSER EN MILIEU AQUEUX ET PAR OXYDATION ELECTROCHIMIQUE DU PYRROLE DES FILMS DE PPY EXTREMEMENT ADHERENTS A LA SURFACE DU METAL. DANS LE CAS DES ACIERS ZINGUES, NOUS AVONS EGALEMENT REUSSI A RALENTIR SUFFISAMMENT LA CORROSION DU ZINC, GRACE A UN TRAITEMENT OPTIMAL DE LA SURFACE ET A DEPOSER DES FILMS DE POLYPYRROLE EN MILIEU ORGANIQUE ET AQUEUX. EN INTRODUISANT PAR AILLEURS DANS LE MILIEU D'ELECTROLYTE UNE FAIBLE PROPORTION DE PYRROLES FONCTIONNALISES EN POSITION 2 PAR DES GROUPES COOH ET NH#2, J'AI MONTRE UNE AMELIORATION CONSIDERABLE DES PROPRIETES DE PROTECTION DE CES FILMS DE PPY CONTRE LA CORROSION. LE COMPORTEMENT DE L'ACIER RECOUVERT DE PPY, PUIS D'UNE COUCHE DE CATAPHORESE ORGANIQUE EST ALORS COMPARABLE A CELUI DU METAL PHOSPHATE, REVETU DE LA MEME COUCHE DE CATAPHORESE. EN REALISANT L'ETUDE (IR, XPS) DES FILMS PPY ET DES SURFACES METALLIQUES J'AI PROPOSE UNE INTERPRETATION COHERENTE DE CES PHENOMENES DE DEPOSITION ET D'ADHERENCE DES FILMS DE PPY SUR LES METAUX OXYDABLES
Book Synopsis SYNTHESE ELECTROCHIMIQUE DU POLYPYRROLE SUR L'ACIER AISI 1010 EN PRESENCE DE TI O2 ET DU PIGMENT PHOSPHATE DE ZINC COMMERCIAL. APPLICATION A LA PROTECTION CONTRE LA CORROSION by : DENISE MARIA.. LENZ
Download or read book SYNTHESE ELECTROCHIMIQUE DU POLYPYRROLE SUR L'ACIER AISI 1010 EN PRESENCE DE TI O2 ET DU PIGMENT PHOSPHATE DE ZINC COMMERCIAL. APPLICATION A LA PROTECTION CONTRE LA CORROSION written by DENISE MARIA.. LENZ and published by . This book was released on 1999 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: DANS CE TRAVAIL, L'INCORPORATION DES PIGMENTS DIOXIDE DE TITANE ET PHOSPHATE DE ZINC COMMERCIAL ZMP DANS POLYPYRROLE (PPY) AU COURS DE LA SYNTHESE ELECTROCHIMIQUE DU POLYMERE SUR ELECTRODES D'ACIER AISI 1010 A ETE ETUDIEE. L'INFLUENCE DE PARAMETRES COMME L'AGITATION, LA NATURE, LA CONCENTRATION ET LE PH DE L'ELECTROLYTE ET DU TEMPS ET DE LA DENSITE DE COURANT DU PROCEDE ELECTROCHIMIQUE A ETE ETUDIEE. DANS LE BUT D'EVALUER L'AMELIORATION DES PROPRIETES ANTICORROSIVES DU FILM DE PPY DUE A LA PRESENCE DES PIGMENTS, LES FILMS ONT ETE SOUMIS AU TEST DE CORROSION ACCELERE SOUS BROUILLARD SALIN ET A DES ANALYSES ELECTROCHIMIQUES COMME LA PERTE DE MASSE, LES COURBES POTENTIEL-TEMPS ET LA SPECTROSCOPIE D'IMPEDANCE ELECTROCHIMIQUE. LA MORPHOLOGIE DES FILMS A ETE ETUDIEE PAR MICROSCOPIE ELECTRONIQUE A BALAYAGE ET LA DISTRIBUTION DES PIGMENTS DANS LA MATRICE POLYMERE PAR SPECTROSCOPIE DE PHOTOELECTRONS X. LES FILMS ONT ETE EGALEMENT CARACTERISES PAR SPECTROSCOPIE INFRAROUGE.
Book Synopsis Amélioration des propriétés physico-chimiques et anticorrosives du revêtement de polypyrrole électrodéposé sur l'acier inoxydable 304 by : Olfa Grari
Download or read book Amélioration des propriétés physico-chimiques et anticorrosives du revêtement de polypyrrole électrodéposé sur l'acier inoxydable 304 written by Olfa Grari and published by . This book was released on 2015 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt: L'objectif de ce travail est d'élaborer par voie électrochimique un film de polypyrrole sur l'acier inoxydable 304 à partir d'un électrolyte support d'acide phosphorique et d'améliorer sa résistance à la corrosion par l'utilisation d'ondes ultrasonores haute fréquence (US) et l'incorporation d'un inhibiteur inorganique (KNO3) et de particules de silice (SiO2). L'inhibiteur inorganique a réduit le potentiel d'oxydation du monomère et a été incorporé dans la chaîne polymérique. Les ultrasons ont favorisé la réaction d'électropolymérisation en augmentant le transport des espèces électroactives vers l'électrode. Ils ont engendré des films plus compacts, présentant une topographie plus fine et plus homogène. Les films composites PPy-SiO2 ont été élaborés par différentes méthodes. Une bonne répartition des particules dans la chaîne polymérique a été obtenue avec la méthode multicouche. Tous les films élaborés : PPy-NO3-, PPy-US et PPy-SiO2 offrent une meilleure protection de l'acier inoxydable contre la corrosion en milieu chloruré que le revêtement PPy.
Download or read book Sol-Gel Silica written by Larry L. Hench and published by William Andrew. This book was released on 1998-12-31 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique perspective of twentieth century research and development in materials science. It summarizes the fifteen years of sol-gel silica processing research leading to the commercial development of bioactive gel-glasses for medical applications. It demonstrates the combined use of quantum mechanical molecular modeling and spectroscopy to solve environmental stability problems. A final chapter addresses the topic of Technology Transfer - how to transfer technology from the laboratory to a profitable commercial enterprise using examples from various chapters in the book.
Book Synopsis Plasma Electrolytic Oxidation (PEO) Coatings by : Marta Mohedano
Download or read book Plasma Electrolytic Oxidation (PEO) Coatings written by Marta Mohedano and published by MDPI. This book was released on 2021-06-02 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plasma electrolytic oxidation (PEO), also known as micro-arc oxidation (MAO), functionalizes surfaces, improving the mechanical, thermal, and corrosion performance of metallic substrates, along with other tailored properties (e.g., biocompatibility, catalysis, antibacterial response, self-lubrication, etc.). The extensive field of applications of this technique ranges from structural components, in particular, in the transport sector, to more advanced fields, such as bioengineering. The present Special Issue covers the latest advances in PEO‐coated light alloys for structural (Al, Mg) and biomedical applications (Ti, Mg), with 10 research papers and 1 review from leading research groups around the world.
Book Synopsis Flexoelectricity in Liquid Crystals by : Agnes Buka
Download or read book Flexoelectricity in Liquid Crystals written by Agnes Buka and published by World Scientific. This book was released on 2013 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book intends to give a state-of-the-art overview of flexoelectricity, a linear physical coupling between mechanical (orientational) deformations and electric polarization, which is specific to systems with orientational order, such as liquid crystals. Chapters written by experts in the field shed light on theoretical as well as experimental aspects of research carried out since the discovery of flexoelectricity. Besides a common macroscopic (continuum) description the microscopic theory of flexoelectricity is also addressed. Electro-optic effects due to or modified by flexoelectricity as well as various (direct and indirect) measurement methods are discussed. Special emphasis is given to the role of flexoelectricity in pattern-forming instabilities. While the main focus of the book lies in flexoelectricity in nematic liquid crystals, peculiarities of other mesophases (bent-core systems, cholesterics, and smectics) are also reviewed. Flexoelectricity has relevance to biological (living) systems and can also offer possibilities for technical applications. The basics of these two interdisciplinary fields are also summarized.
Book Synopsis Clay-containing Polymeric Nanocomposites by : L. A. Utracki
Download or read book Clay-containing Polymeric Nanocomposites written by L. A. Utracki and published by iSmithers Rapra Publishing. This book was released on 2004 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is Part 1 of a two-part set. Part 2 ISBN is 1859574823
Book Synopsis Guidelines for the Control and Management of Ships' Biofouling to Minimize the Transfer of Invasive Aquatic Species by : International Maritime Organization
Download or read book Guidelines for the Control and Management of Ships' Biofouling to Minimize the Transfer of Invasive Aquatic Species written by International Maritime Organization and published by . This book was released on 2012 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: These Guidelines for the control and management of ships' biofouling to minimize the transfer of invasive aquatic species (hereafter 'the Guidelines') are intended to provide a globally consistent approach to the management of biofouling. As scientific and technological advances are made, the Guidelines will be refined to enable the risk to be more adequately addressed. Port States, flag States, coastal States and other parties that can assist in mitigating the problems associated with biofouling should exercise due diligence to implement the Guidelines to the maximum extent possible.
Book Synopsis Alternative Fuels by : Michael F. Hordeski
Download or read book Alternative Fuels written by Michael F. Hordeski and published by The Fairmont Press, Inc.. This book was released on 2008 with total page 297 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Newly revised, the second edition of this pioneering work addresses emerging factors affecting energy production and use, including the availability and desirability of various fuels. The text provides extensive discussion on hydrogen sources, both solar and nuclear, and fuel cell technology, as well as other alternative fuels such as biomass, and wind power. It delves into cost analysis, regulatory issues, barriers to implementation, conversion and storage systems, thermodynamic efficiency, fuel chain efficiency, air emission issues, and safety. The book also covers natural gas hydrogen gas, methanol, ethanol, and steam reforming."--pub. desc.
Book Synopsis Nonlinear Optical Materials by : Jerome V. Moloney
Download or read book Nonlinear Optical Materials written by Jerome V. Moloney and published by Springer Science & Business Media. This book was released on 1998-08-13 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mathematical methods play a significant role in the rapidly growing field of nonlinear optical materials. This volume discusses a number of successful or promising contributions. The overall theme of this volume is twofold: (1) the challenges faced in computing and optimizing nonlinear optical material properties; and (2) the exploitation of these properties in important areas of application. These include the design of optical amplifiers and lasers, as well as novel optical switches. Research topics in this volume include how to exploit the magnetooptic effect, how to work with the nonlinear optical response of materials, how to predict laser-induced breakdown in efficient optical devices, and how to handle electron cloud distortion in femtosecond processes.
Book Synopsis Marketing in Zambia by : Reginald Biddle
Download or read book Marketing in Zambia written by Reginald Biddle and published by . This book was released on 1985 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis 2016 IEEE WIC ACM International Conference on Web Intelligence Workshops (WIW) by : IEEE Staff
Download or read book 2016 IEEE WIC ACM International Conference on Web Intelligence Workshops (WIW) written by IEEE Staff and published by . This book was released on 2016-10-13 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: As an important part of the conference, the workshop special session program will focus on new research challenges and initiatives The workshops may have special invited sessions organized by prominent researchers Each paper will be allocated 4 pages in the proceedings and all papers accepted for workshops will be included in the Workshop Proceedings published by the IEEE Computer Society Press that is indexed by EI, and will be available at the workshops
Book Synopsis Unsteady Transonic Flow by : Mårten T. Landahl
Download or read book Unsteady Transonic Flow written by Mårten T. Landahl and published by Courier Dover Publications. This book was released on 2019-04-17 with total page 147 pages. Available in PDF, EPUB and Kindle. Book excerpt: This classic monograph on unsteady transonic flow — the flow of air encountered at speeds at or near the speed of sound — is of continuing interest to students and professionals in aerodynamics, fluid dynamics, and other areas of applied mathematics. After a brief Introduction, Swedish physicist Mårten T. Landahl presents a chapter in which the two-dimensional solution is derived, succeeded by a discussion of its relation to the subsonic and supersonic solutions. Three chapters on low aspect ratio configurations follow, covering triangular wings and similar planforms with curved leading edges, rectangular wings, and cropped delta wings, and low aspect ratio wing-body combinations. The treatment concludes with a consideration of the experimental determination of air forces on oscillating wings at transonic speeds.
Book Synopsis Nanostructured Oxide Thin Films Synthesized by Spray Pyrolysis. by : Najoua Kamoun-Turki
Download or read book Nanostructured Oxide Thin Films Synthesized by Spray Pyrolysis. written by Najoua Kamoun-Turki and published by . This book was released on 2018-03 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the spray pyrolysis technique that is used to produce thin films of metallic oxides on glass substrates. Also discussed are the process variables of the spray pyrolysis process used to manufacture specific structures such as nanostructured thin films.
Book Synopsis Masters Theses in the Pure and Applied Sciences by : Wade H. Shafer
Download or read book Masters Theses in the Pure and Applied Sciences written by Wade H. Shafer and published by Springer. This book was released on 1976 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Masters Theses in the Pure and Applied Sciences was first conceived, published, and dis· seminated by the Center for Information and Numerical Data Analysis and Synthesis (CINDAS) *at Purdue University in 1957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemination phases of the ac· tivity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we had concluded that it was in the interest of all concerned if the printing and distribution of the volume were handled by an international publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and Applied Sciences has been disseminated on a worldwide basis by Plenum Publishing Corporation of New York, and in the same year the coverage was broadened to include Canadian universities. All back issues can also be ordered from Plenum. We have reported in Volume 20 (thesis year 1975) a total of 10,374 theses titles from 28 Canadian and 239 United States universities. We are sure that this broader base for theses titles reported will greatly enhance the value of this important annual reference work. The organization of Volume 20 is identical to that of past years. It consists of theses titles arranged by discipline and by university within each discipline.