Elastomer Based Composite Materials

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Elastomer-Based Composite Materials

Author : Nikolay Dishovsky
Publisher : CRC Press
ISBN 13 : 1351659995
Total Pages : 486 pages
Book Rating : 4.3/5 (516 download)

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Book Synopsis Elastomer-Based Composite Materials by : Nikolay Dishovsky

Download or read book Elastomer-Based Composite Materials written by Nikolay Dishovsky and published by CRC Press. This book was released on 2018-05-15 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elastomer-Based Composite Materials: Mechanical, Dynamic, and Microwave Properties and Engineering Applications is focused on elastomer-based composite materials comprising different types of reinforcing fillers. The book provides an informative examination of the possibilities for broadening the engineering applications of elastomer composites through using various types of hybrid fillers, ferrites, and ceramics, and also examines their synthesis and characterization. It discusses new hybrid fillers that have been synthesized by different techniques, e.g. impregnation of different substrates (carbon black, conductive carbon black, activated carbons, etc.) with silica or magnetite. These new fillers have been thoroughly characterized by standard techniques and by up-to-date methods, such as energy dispersive X-ray spectroscopy in scanning transmission electron microscopy (STEM-EDX), atomic absorption spectroscopy (AAS), and inductively coupled plasma–optical emission spectroscopy (ICP-OES). The effect of those fillers upon the curing properties, mechanical and dynamic parameters, electrical conductivity, and dielectric and microwave characteristics of elastomer-based composites is discussed in detail in this volume. The book also covers the influence of various types of ceramics (SiC, B4C, and TiB2) and barium and strontium hexaferrites upon the aforementioned properties of rubber composites in conjunction with a view toward solutions for environmental problems caused by waste tires. The book shows that pyrolysis-cum-water vapor is a suitable and environmentally friendly method for the conversion of the waste green tires into useful carbon-silica hybrid fillers. The properties of elastomer-based composites comprising different types of nanostructures (fullerenes, carbon nanotubes, graphene nanoplatelets), modified activated carbons, and calcined kaolin are also discussed. Special attention is paid to composites with lower levels of zinc oxide. The volume provides an abundance of knowledge on the detailed characterization of these fillers and on the curing, mechanical, dynamic mechanical, and dielectric and microwave properties of the elastomeric composites. The book surveys the most recent research activities of the authors, which will make it a vital reference source for scientists in both the academic and industrial sectors, as well as for individuals who are interested in rubber materials. It will be very useful for students, especially PhD students, scientists, lecturers, and engineers working or doing research in the field of polymer materials science, elastomer-based composites and nanocomposites and their engineering applications in the production of microwave absorbers and electromagnetic waves shielding materials, materials for electronics devices and telecommunications.

Elastomer-Based Composite Materials

Author : Nikolay Dishovsky
Publisher :
ISBN 13 : 9781315159584
Total Pages : 450 pages
Book Rating : 4.1/5 (595 download)

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Book Synopsis Elastomer-Based Composite Materials by : Nikolay Dishovsky

Download or read book Elastomer-Based Composite Materials written by Nikolay Dishovsky and published by . This book was released on 2017 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elastomer-Based Composite Materials: Mechanical, Dynamic, and Microwave Properties and Engineering Applicationsis focused on elastomer-based composite materials comprising different types of reinforcing fillers. The book provides an informative examination of the possibilities for broadening the engineering applications of elastomer composites through using various types of hybrid fillers, ferrites, and ceramics, and also examines their synthesis and characterization. It discusses new hybrid fillers that have been synthesized by different techniques, e.g. impregnation of different substrates (carbon black, conductive carbon black, activated carbons, etc.) with silica or magnetite. These new fillers have been thoroughly characterized by standard techniques and by up-to-date methods, such as energy dispersive X-ray spectroscopy in scanning transmission electron microscopy (STEM-EDX), atomic absorption spectroscopy (AAS), and inductively coupled plasma-optical emission spectroscopy (ICP-OES). The effect of those fillers upon the curing properties, mechanical and dynamic mechanical parameters, electrical conductivity, and dielectric and microwave characteristics of elastomer-based composites is discussed in detail in this volume. The book also covers the influence of various types of ceramics (SiC, B4C, and TiB2) and barium and strontium hexaferrites upon the aforementioned properties of rubber composites in conjunction with a view toward solutions for environmental problems caused by waste tires. The book shows that pyrolysis-cum-water vapor is a suitable and environmentally friendly method for the conversion of the waste green tires into useful carbon-silica hybrid fillers. The properties of elastomer-based composites comprising different types of nanostructures (fullerenes, carbon nanotubes, graphene nanoplatelets), modified activated carbons, and calcined kaolin are also discussed. Special attention is paid to composites with lower levels of zinc oxide. The volume provides an abundance of knowledge on the detailed characterization of these fillers and on the curing, mechanical, dynamic mechanical, and dielectric and microwave properties of the elastomeric composites. The book surveys the most recent research activities of the authors, which will make it a vital reference source for scientists in both the academic and industrial sectors, as well as for individuals who are interested in rubber materials. It will be very useful for students, especially PhD students, scientists, lecturers, and engineers working or doing research in the field of polymer materials science, elastomer-based composites and nanocomposites and their engineering applications in the production of microwave absorbers and electromagnetic waves shielding materials, materials for electronics devices and telecommunications.

Elastomer-Based Composite Materials

Author : Nikolay Dishovsky
Publisher : CRC Press
ISBN 13 : 1351659987
Total Pages : 497 pages
Book Rating : 4.3/5 (516 download)

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Book Synopsis Elastomer-Based Composite Materials by : Nikolay Dishovsky

Download or read book Elastomer-Based Composite Materials written by Nikolay Dishovsky and published by CRC Press. This book was released on 2018-05-15 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elastomer-Based Composite Materials: Mechanical, Dynamic, and Microwave Properties and Engineering Applications is focused on elastomer-based composite materials comprising different types of reinforcing fillers. The book provides an informative examination of the possibilities for broadening the engineering applications of elastomer composites through using various types of hybrid fillers, ferrites, and ceramics, and also examines their synthesis and characterization. It discusses new hybrid fillers that have been synthesized by different techniques, e.g. impregnation of different substrates (carbon black, conductive carbon black, activated carbons, etc.) with silica or magnetite. These new fillers have been thoroughly characterized by standard techniques and by up-to-date methods, such as energy dispersive X-ray spectroscopy in scanning transmission electron microscopy (STEM-EDX), atomic absorption spectroscopy (AAS), and inductively coupled plasma–optical emission spectroscopy (ICP-OES). The effect of those fillers upon the curing properties, mechanical and dynamic parameters, electrical conductivity, and dielectric and microwave characteristics of elastomer-based composites is discussed in detail in this volume. The book also covers the influence of various types of ceramics (SiC, B4C, and TiB2) and barium and strontium hexaferrites upon the aforementioned properties of rubber composites in conjunction with a view toward solutions for environmental problems caused by waste tires. The book shows that pyrolysis-cum-water vapor is a suitable and environmentally friendly method for the conversion of the waste green tires into useful carbon-silica hybrid fillers. The properties of elastomer-based composites comprising different types of nanostructures (fullerenes, carbon nanotubes, graphene nanoplatelets), modified activated carbons, and calcined kaolin are also discussed. Special attention is paid to composites with lower levels of zinc oxide. The volume provides an abundance of knowledge on the detailed characterization of these fillers and on the curing, mechanical, dynamic mechanical, and dielectric and microwave properties of the elastomeric composites. The book surveys the most recent research activities of the authors, which will make it a vital reference source for scientists in both the academic and industrial sectors, as well as for individuals who are interested in rubber materials. It will be very useful for students, especially PhD students, scientists, lecturers, and engineers working or doing research in the field of polymer materials science, elastomer-based composites and nanocomposites and their engineering applications in the production of microwave absorbers and electromagnetic waves shielding materials, materials for electronics devices and telecommunications.

Elastomer Blends and Composites

Author : Sanjay Mavinkere Rangappa
Publisher : Elsevier
ISBN 13 : 0323858333
Total Pages : 440 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Elastomer Blends and Composites by : Sanjay Mavinkere Rangappa

Download or read book Elastomer Blends and Composites written by Sanjay Mavinkere Rangappa and published by Elsevier. This book was released on 2022-02-22 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elastomer Blends and Composites: Principles, Characterization, Advances, and Applications presents the latest developments in natural rubber and synthetic rubber-based blends and nanocomposites, with a focus on current trends, future directions and state-of-the-art applications. The book introduces the fundamentals of natural rubber and synthetic rubbers, outlining synthesis, structure, properties, challenges and potential applications. This is followed by detailed coverage of compounding and formulations, manufacturing methods, and preparation of elastomer-based blends, composites, and nanocomposites. The next section of the book focuses on properties and characterization, examining elasticity, spectroscopy, barrier properties, and rheological, morphological, mechanical, thermal, and viscoelastic behavior, and more. This is a highly valuable resource for researchers and advanced students in rubber (or elastomer) science, polymer blends, composites, polymer science, and materials science and engineering, as well as engineers, technologists, and scientists working with rubber-based materials for advanced applications. Guides the reader through the manufacturing, properties, characterization and latest innovations in elastomer blends and composites Addresses aging and degradation behavior, lifecycle analysis, and recycling of rubber-based materials Explores novel applications of rubber blends and composites in areas such as automotive, aerospace, medicine and engineering

Advances in Elastomers II

Author : P. M. Visakh
Publisher : Springer Science & Business Media
ISBN 13 : 3642209289
Total Pages : 434 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Advances in Elastomers II by : P. M. Visakh

Download or read book Advances in Elastomers II written by P. M. Visakh and published by Springer Science & Business Media. This book was released on 2013-04-09 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the second volume of a two-volume work which summarizes in an edited format and in a fairly comprehensive manner many of the recent technical research accomplishments in the area of Elastomers. “Advances in Elastomers” discusses the various attempts reported on solving these problems from the point of view of the chemistry and the structure of elastomers, highlighting the drawbacks and advantages of each method. It summarize the importance of elastomers and their multiphase systems in human life and industry, and covers all the topics related to recent advances in elastomers, their blends, IPNs, composites and nanocomposites. This second volume is deals with composites and nanocomposites of elastomers.

Flexible and Stretchable Electronic Composites

Author : Deepalekshmi Ponnamma
Publisher : Springer
ISBN 13 : 3319236636
Total Pages : 390 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Flexible and Stretchable Electronic Composites by : Deepalekshmi Ponnamma

Download or read book Flexible and Stretchable Electronic Composites written by Deepalekshmi Ponnamma and published by Springer. This book was released on 2015-10-16 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is the first comprehensive collection of electronic aspects of different kinds of elastomer composites, including combinations of synthetic, natural and thermoplastic elastomers with different conducting fillers like metal nanoparticles, carbon nanotubes, or graphenes, and many more. It covers elastomer composites, which are useful in electronic applications, including chemical and physical as well as material science aspects. The presented elastomer composites have great potential for solving emerging new material application requirements, for example as flexible and wearable electronics. The book is structured and organized by the rubber/elastomer type: each chapter describes a different elastomer matrix and its composites. While introducing to important fundamentals, it is application-oriented, discussing the current issues and challenges in the field of elastomer composites. This book will thus appeal to researchers and scientists, to engineers and technologists, but also to graduate students, working on elastomer composites, or on electronics engineering with the composites, providing the readers with a sound introduction to the field and solutions to both fundamental and applied problems.

Polymer Composites

Author : Srikanta Moharana
Publisher : Springer Nature
ISBN 13 : 9819720753
Total Pages : 563 pages
Book Rating : 4.8/5 (197 download)

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Book Synopsis Polymer Composites by : Srikanta Moharana

Download or read book Polymer Composites written by Srikanta Moharana and published by Springer Nature. This book was released on with total page 563 pages. Available in PDF, EPUB and Kindle. Book excerpt:

High Performance Elastomer Materials

Author : Dariusz M. Bielinski
Publisher : CRC Press
ISBN 13 : 1482255022
Total Pages : 292 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis High Performance Elastomer Materials by : Dariusz M. Bielinski

Download or read book High Performance Elastomer Materials written by Dariusz M. Bielinski and published by CRC Press. This book was released on 2014-10-23 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents selected papers on various aspects of rubber engineering, technology, and exploitation. The contributions range from new methods of the modification of filler surface and crosslinks structure of rubber vulcanizates, through modern functional elastomer composites, to aspects of their thermal stability, flammability, and ozone degradation. Each chapter contains a brief introduction to a particular topic, a description of the experimental techniques, and a discussion on the results obtained, followed by conclusions. The book will help to broaden the knowledge of researchers in the field of rubber compounding, crosslinking, and behavior under various exploitation conditions. The research and development presented in this book has potential for industrial applications as well as for new materials and technologies. The book also details theoretical background to a number of experimental techniques, which should make it interesting to research students and professionals.

Polymer-Based Advanced Functional Composites for Optoelectronic and Energy Applications

Author : Nithin Kundachira Subramani
Publisher : Elsevier
ISBN 13 : 0128185090
Total Pages : 376 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Polymer-Based Advanced Functional Composites for Optoelectronic and Energy Applications by : Nithin Kundachira Subramani

Download or read book Polymer-Based Advanced Functional Composites for Optoelectronic and Energy Applications written by Nithin Kundachira Subramani and published by Elsevier. This book was released on 2021-05-28 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer-Based Advanced Functional Composites for Optoelectronic and Energy Applications explains how polymer-based smart composites and nanocomposites can be prepared and utilized for novel optical, sensor and energy-related applications. The book begins with an introductory section on the fundamentals of smart polymer composites, including structure-property relationships and conjugated polymers. Other sections examine optical applications, including the use of polymer-based smart composites for luminescent solar concentrators, electro-chromic applications, light conversion applications, ultraviolet shielding applications, LED encapsulation applications, sensor applications, including gas-sensing, strain sensing, robotics and tactile sensors, with final sections covering energy-related applications, including energy harvesting, conversion, storage, vibrational energy harvesting, and more. This is an essential guide for researchers, scientists and advanced students in smart polymers and materials, polymer science, composites, nanocomposites, electronics and materials science. It is also a valuable book for scientists, R&D professionals and engineers working with products that could utilize smart polymer composites. Provides thorough coverage of the latest pioneering research in the field of polymer-based smart composites Offers an applications-oriented approach, enabling the reader to understand state-of-the-art optical, sensor and energy applications Includes an in-depth introductory section, covering important aspects such as structure-property relationships and the role of conjugated polymers

Engineering of Thermoplastic Elastomer with Graphene and Other Anisotropic Nanofillers

Author : Abhijit Bandyopadhyay
Publisher : Springer Nature
ISBN 13 : 9811590850
Total Pages : 227 pages
Book Rating : 4.8/5 (115 download)

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Book Synopsis Engineering of Thermoplastic Elastomer with Graphene and Other Anisotropic Nanofillers by : Abhijit Bandyopadhyay

Download or read book Engineering of Thermoplastic Elastomer with Graphene and Other Anisotropic Nanofillers written by Abhijit Bandyopadhyay and published by Springer Nature. This book was released on 2020-10-14 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an effort to tether all the exuberant observations on adding nanomaterial in the TPE matrix. With an enhanced processing property along with amplified recyclability and reprocessing feature, thermoplastic elastomers (TPE) proves to be one of the most significant polymeric materials till date. As the scientific world evolves, these advanced materials have attuned themselves with various anisotropic nanomaterials to induce an enhanced property effect on the final product. On an additional note, authors have done extensive research on graphene, the most multifaceted element in the filler family keeping TPE and its derivate as the matrix martial. Cogitating the idea of a multidimensional readership, authors have analyzed the synthesis, derivatization, and properties of graphene and its derivatives separately. Apart from reviewing the future prospects and the potential application of these nano-filled advanced materials, they have kept the structure–property relationship of graphene-based composites at the cynosure to provide firm understanding on the blossoming of these elastomeric composites. The authors believe this book is a potential content for both professionals and academicians.

Elastomer-based Composites and Nanocomposites

Author : Hamid Essabir
Publisher : Woodhead Publishing
ISBN 13 : 9780443188688
Total Pages : 0 pages
Book Rating : 4.1/5 (886 download)

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Book Synopsis Elastomer-based Composites and Nanocomposites by : Hamid Essabir

Download or read book Elastomer-based Composites and Nanocomposites written by Hamid Essabir and published by Woodhead Publishing. This book was released on 2024-02-01 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elastomer-Based Composite and Nanocomposites: Fundamentals, Recycling and Applications provides an updated review of the main innovations in this important research field.The chapters are written by well-known scholars and leading industrial experts from around the globe. Key aspects covered include properties and applications of reinforcement agents, filler morphology, synthesis, functionalization, processing and characterization of the resulting composites and their structural, mechanical, thermal, and rheological properties. The book will be an essential reference resource for academic and industrial researchers, materials scientists and engineers, and chemists working in the development of polymer materials and elastomer-based composites.

Self-Healing Polymer-Based Systems

Author : Sabu Thomas
Publisher : Elsevier
ISBN 13 : 0128184515
Total Pages : 546 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Self-Healing Polymer-Based Systems by : Sabu Thomas

Download or read book Self-Healing Polymer-Based Systems written by Sabu Thomas and published by Elsevier. This book was released on 2020-07-11 with total page 546 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-Healing Polymer-Based Systems presents all aspects of self-healing polymeric materials, offering detailed information on fundamentals, preparation methods, technology, and applications, and drawing on the latest state-of-the-art research. The book begins by introducing self-healing polymeric systems, with a thorough explanation of underlying concepts, challenges, mechanisms, kinetic and thermodynamics, and types of chemistry involved. The second part of the book studies the main categories of self-healing polymeric material, examining elastomer-based, thermoplastic-based, and thermoset-based materials in turn. This is followed by a series of chapters that examine the very latest advances, including nanoparticles, coatings, shape memory, self-healing biomaterials, ionomers, supramolecular polymers, photoinduced and thermally induced self-healing, healing efficiency, life cycle analysis, and characterization. Finally, novel applications are presented and explained. This book serves as an essential resource for academic researchers, scientists, and graduate students in the areas of polymer properties, self-healing materials, polymer science, polymer chemistry, and materials science. In industry, this book contains highly valuable information for R&D professionals, designers, and engineers, who are looking to incorporate self-healing properties in their materials, products, or components. Provides comprehensive coverage of self-healing polymeric materials, covering principles, techniques, and applications Includes the very latest developments in the field, such as the role of nanofillers in healing, life cycle analysis of materials, and shape memory assisted healing Enables the reader to unlock the potential of self-healing polymeric materials for a range of advanced applications

Liquid Crystal Elastomers

Author : Mark Warner
Publisher : Oxford University Press
ISBN 13 : 9780199214860
Total Pages : 423 pages
Book Rating : 4.2/5 (148 download)

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Book Synopsis Liquid Crystal Elastomers by : Mark Warner

Download or read book Liquid Crystal Elastomers written by Mark Warner and published by Oxford University Press. This book was released on 2007-04-05 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text is a primer for liquid crystals, polymers, rubber and elasticity. It is directed at physicists, chemists, material scientists, engineers and applied mathematicians at the graduate student level and beyond.

Polymer-Based Composites

Author : V. Arumugaprabu
Publisher : CRC Press
ISBN 13 : 1000433099
Total Pages : 167 pages
Book Rating : 4.0/5 (4 download)

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Book Synopsis Polymer-Based Composites by : V. Arumugaprabu

Download or read book Polymer-Based Composites written by V. Arumugaprabu and published by CRC Press. This book was released on 2021-08-23 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: The increasing use of composite materials over conventional materials has been a continual trend for over a decade. While the fundamental understanding of fiber reinforcement has not changed, many new material advancements have occurred, especially in manufacturing methods, and there is an ever-growing number of composite material applications across various industries. Polymer-Based Composites: Design, Manufacturing, and Applications presents the concepts and methods involved in the development of various fiber-reinforced composite materials. Features: Offers a comprehensive view of materials, mechanics, processing, design, and applications Bridges the gap between research, manufacturing science, and analysis and design Discusses composite materials composed of continuous synthetic fibers and matrices for use in engineering structures Presents codes and standards related to fiber-reinforced polymer composites Includes case studies and examples based on industrial, automotive, aerospace, and household applications This book is a valuable resource for advanced students, researchers, and industry personnel to understand recent advances in the field and achieve practical results in the development, manufacture, and application of advanced composite materials.

Handbook of Plastics, Elastomers, and Composites

Author : Charles A. Harper
Publisher : McGraw Hill Professional
ISBN 13 : 9780071384766
Total Pages : 904 pages
Book Rating : 4.3/5 (847 download)

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Book Synopsis Handbook of Plastics, Elastomers, and Composites by : Charles A. Harper

Download or read book Handbook of Plastics, Elastomers, and Composites written by Charles A. Harper and published by McGraw Hill Professional. This book was released on 2002 with total page 904 pages. Available in PDF, EPUB and Kindle. Book excerpt: Here is a thoroughly revised edition of the most comprehensive guide to plastics, elastomers and composites available today. A standard reference, it provides current data, costs & properties for all designers and manufacturers of plastic products.

Materials for Potential EMI Shielding Applications

Author : Joseph Kuruvilla
Publisher : Elsevier
ISBN 13 : 0128175915
Total Pages : 412 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Materials for Potential EMI Shielding Applications by : Joseph Kuruvilla

Download or read book Materials for Potential EMI Shielding Applications written by Joseph Kuruvilla and published by Elsevier. This book was released on 2019-11-01 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: Materials for Potential EMI Shielding Applications: Processing, Properties and Current Trends extensively and comprehensively reviews materials for EMI shielding applications, ranging from the principles to possible applications and various types of shielding materials. The book provides a thorough introduction to electromagnetic interference, its effect on both the environment and other electronic items, various materials that are used for electromagnetic interference shielding applications, and its properties. It explains the mechanism behind EMI shielding, the methods by which EMI SE of a given material is estimated, and the different fabrication methods currently employed for fabricating EMI shielding materials. Final sections focus on the theoretical background of EMI shielding and shielding mechanisms. This theoretical background is extended to the physics of EMI shielding, wherein the physics behind mechanism of shielding is explained. Focuses on the different types of available EMI shielding, their applications, processing, characterization, and the mechanism behind their shielding Discusses how to incorporate EMI shielding with low cost, low density and high strength Provides an understanding and clarifies both elementary and practical problems relating to EMI shielding materials

Developments in Thermoplastic Elastomers

Author : K. E. Kear
Publisher : iSmithers Rapra Publishing
ISBN 13 : 9781859574331
Total Pages : 158 pages
Book Rating : 4.5/5 (743 download)

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Book Synopsis Developments in Thermoplastic Elastomers by : K. E. Kear

Download or read book Developments in Thermoplastic Elastomers written by K. E. Kear and published by iSmithers Rapra Publishing. This book was released on 2003 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermoplastic elastomers (TPEs) have the elastic behaviour of rubber and the processability of thermoplastics. The Freedonia Group has forecast that demand will expand by 6.4% per year to around 2.15 million tons in 2006. There is potential for these new, exciting materials to expand into the much larger thermoset rubber markets. This review includes comparisons between the two material types. There are three major types of TPE: block copolymers, rubber/plastic blends and dynamically vulcanised rubber/plastic alloys known as thermoplastic vulcanisates. The chemistry of these materials and how.