Read Books Online and Download eBooks, EPub, PDF, Mobi, Kindle, Text Full Free.
Download Dynamics And Kinetics Of Interface Reactions full books in PDF, epub, and Kindle. Read online Dynamics And Kinetics Of Interface Reactions ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Author : D. Dwyer
Publisher :
ISBN 13 :
Total Pages : 199 pages
Book Rating : 4.:/5 (256 download)
Download or read book Dynamics and Kinetics of Interface Reactions written by D. Dwyer and published by . This book was released on 1990 with total page 199 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael Grunze
Publisher : Springer Science & Business Media
ISBN 13 : 3642726755
Total Pages : 309 pages
Book Rating : 4.6/5 (427 download)
Download or read book Kinetics of Interface Reactions written by Michael Grunze and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 309 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains the proceedings of the first Workshop on Interface Phenomena, organized jointly by the surface science groups at Dalhousie University and the University of Maine. It was our intention to concentrate on just three topics related to the kinetics of interface reactions which, in our opinion, were frequently obscured unnecessarily in the literature and whose fundamental nature warranted an extensive discussion to help clarify the issues, very much in the spirit of the Discussions of the Faraday Society. Each session (day) saw two principal speakers expounding the different views; the session chairmen were asked to summarize the ensuing discussions. To understand the complexity of interface reactions, paradigms must be formulated to provide a framework for the interpretation of experimen tal data and for the construction of theoretical models. Phenomenological approaches have been based on a small number of rate equations for the concentrations or mole numbers of the various species involved in a par ticular system with the relevant rate constants either fitted (in the form of the Arrheniusparametrization) to experimental data or calculated on the basis of microscopic models. The former procedure can at best serve as a guide to the latter, and is, in most cases, confined to ruling out certain reaction pathways rather than to ascertaining a unique answer.
Author : Niels E. Henriksen
Publisher : Oxford University Press, USA
ISBN 13 : 0199203865
Total Pages : 391 pages
Book Rating : 4.1/5 (992 download)
Download or read book Theories of Molecular Reaction Dynamics written by Niels E. Henriksen and published by Oxford University Press, USA. This book was released on 2008 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with a central topic at the interface of chemistry and physics - the understanding of how the transformation of matter takes place at the atomic level. Building on the laws of physics, the book focuses on the theoretical framework for predicting the outcome of chemical reactions. The style is highly systematic with attention to basic concepts and clarity of presentation. Molecular reaction dynamics is about the detailed atomic-level description of chemical reactions. Based on quantum mechanics and statistical mechanics or, as an approximation, classical mechanics, the dynamics of uni- and bi-molecular elementary reactions are described. The book features a detailed presentation of transition-state theory which plays an important role in practice, and a comprehensive discussion of basic theories of reaction dynamics in condensed phases. Examples and end-of-chapter problems are included in order to illustrate the theory and its connection to chemical problems.
Author : Niels E. Henriksen
Publisher : Oxford Graduate Texts
ISBN 13 : 0198805012
Total Pages : 458 pages
Book Rating : 4.1/5 (988 download)
Download or read book Theories of Molecular Reaction Dynamics written by Niels E. Henriksen and published by Oxford Graduate Texts. This book was released on 2018 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with a central topic at the interface of chemistry and physics--the understanding of how the transformation of matter takes place at the atomic level. Building on the laws of physics, the book focuses on the theoretical framework for predicting the outcome of chemical reactions. The style is highly systematic with attention to basic concepts and clarity of presentation. The emphasis is on concepts and insights obtained via analytical theories rather than computational and numerical aspects. Molecular reaction dynamics is about the detailed atomic-level description of chemical reactions. Based on quantum mechanics and statistical mechanics, the dynamics of uni- and bi-molecular elementary reactions are described. The book features a comprehensive presentation of transition-state theory which plays an important role in practice, and a detailed discussion of basic theories of reaction dynamics in condensed phases. Examples and end-of-chapter problems are included in order to illustrate the theory and its connection to chemical problems. The second edition includes updated descriptions of adiabatic and non-adiabatic electron-nuclear dynamics, an expanded discussion of classical two-body models of chemical reactions, including the Langevin model, additional material on quantum tunnelling and its implementation in Transition-State Theory, and a more thorough description of the Born and Onsager models for solvation.
Author : M. Grunze
Publisher :
ISBN 13 :
Total Pages : 311 pages
Book Rating : 4.:/5 (227 download)
Download or read book Kinetics of Interface Reactions. Proceedings of a Workshop on Interface Phenomena, Held in Campobello Island, Canada on 24-27 September 1986. Springer Series in Surface Sciences written by M. Grunze and published by . This book was released on 1987 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first Workshop of Interface Phenomena concentrated on just three topics related to the kinetics of interface reactions: (1) adsorption-desorption kinetics, (2) precursors, (3) kinetics and phase transitions. The adsorption and desorption processes themselves are to be understood as surface bond making and breaking mechanisms, respectively. If the energy transfer is fast enough, then these processes can be understood in terms of thermodynamic arguments such as formulated in transition state theory. However, in most situations such as simple treatment is not sufficient and the details of the microscopic dynamics must be invoked. Unfortunately, this point is very frequently overlooked in the analysis of kinetic data of gas-surface reactions, leading to rather murky discussions in the literature. The phenomenological analysis of surface reactions in terms of kinetic rate equations quite often has to invoke precursor states as reaction intermediates to fit experimental data. However, because such an analysis rarely leads to a unique answer, independent evidence must be brought forward if precursors in a given reaction are to be accepted as more than just mythical mis-fits. The equilibrium properties of surface phase transitions have been studied for many decades, and they exhibit a wealth of fascinating detail. The exploration of their kinetics, on the other hand, had to await the advent of time resolved surface analysis techniques. In particular, video-LEED has made it possible to study kinetics of surface reconstruction.
Author : Raphael D. Levine
Publisher : Cambridge University Press
ISBN 13 : 9781139442879
Total Pages : 574 pages
Book Rating : 4.4/5 (428 download)
Download or read book Molecular Reaction Dynamics written by Raphael D. Levine and published by Cambridge University Press. This book was released on 2009-06-04 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular reaction dynamics is the study of chemical and physical transformations of matter at the molecular level. The understanding of how chemical reactions occur and how to control them is fundamental to chemists and interdisciplinary areas such as materials and nanoscience, rational drug design, environmental and astrochemistry. This book provides a thorough foundation to this area. The first half is introductory, detailing experimental techniques for initiating and probing reaction dynamics and the essential insights that have been gained. The second part explores key areas including photoselective chemistry, stereochemistry, chemical reactions in real time and chemical reaction dynamics in solutions and interfaces. Typical of the new challenges are molecular machines, enzyme action and molecular control. With problem sets included, this book is suitable for advanced undergraduate and graduate students, as well as being supplementary to chemical kinetics, physical chemistry, biophysics and materials science courses, and as a primer for practising scientists.
Author :
Publisher : World Scientific
ISBN 13 : 981453417X
Total Pages : 374 pages
Book Rating : 4.8/5 (145 download)
Download or read book Far-from-equilibrium Dynamics of Chemical Systems written by and published by World Scientific. This book was released on 1994 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Santosh K. Upadhyay
Publisher : Springer Science & Business Media
ISBN 13 : 1402045476
Total Pages : 256 pages
Book Rating : 4.4/5 (2 download)
Download or read book Chemical Kinetics and Reaction Dynamics written by Santosh K. Upadhyay and published by Springer Science & Business Media. This book was released on 2007-04-29 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.
Author : Peter M. Rentzepis
Publisher : Springer Science & Business Media
ISBN 13 : 9400947348
Total Pages : 608 pages
Book Rating : 4.4/5 (9 download)
Download or read book Advances in Chemical Reaction Dynamics written by Peter M. Rentzepis and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains the formal lectures and contributed papers presented at the NATO Advanced Study Institute on. the Advances in Chemical Reaction Dynamics. The meeting convened at the city of Iraklion, Crete, Greece on 25 August 1985 and continued to 7 September 1985. The material presented describes the fundamental and recent advances in experimental and theoretical aspects of, reaction dynamics. A large section is devoted to electronically excited states, ionic species, and free radicals, relevant to chemical sys tems. In addition recent advances in gas phase polymerization, formation of clusters, and energy release processes in energetic materials were presented. Selected papers deal with topics such as the dynamics of electric field effects in low polar solutions, high electric field perturbations and relaxation of dipole equilibria, correlation in picosecond/laser pulse scattering, and applications to fast reaction dynamics. Picosecond transient Raman spectroscopy which has been used for the elucidation of reaction dynamics and structural changes occurring during the course of ultrafast chemical reactions; propagation of turbulent flames and detonations in gaseous· energetic systems are also discussed in some detail. In addition a large portion of the program was devoted to current experimental and theoretical studies of the structure of the transition state as inferred from product state distributions; translational energy release in the photodissociation of aromatic molecules; intramolecu lar and intraionic dynamic processes.
Author :
Publisher :
ISBN 13 :
Total Pages : 414 pages
Book Rating : 4.F/5 ( download)
Download or read book Dynamics at the Gas/solid Interface written by and published by . This book was released on 1994 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : G.F. Froment
Publisher : Elsevier
ISBN 13 : 0080530621
Total Pages : 611 pages
Book Rating : 4.0/5 (85 download)
Download or read book Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis written by G.F. Froment and published by Elsevier. This book was released on 1997-09-03 with total page 611 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many processes of the chemical industry are based upon heterogeneous catalysis. Two important items of these processes are the development of the catalyst itself and the design and optimization of the reactor. Both aspects would benefit from rigorous and accurate kinetic modeling, based upon information on the working catalyst gained from classical steady state experimentation, but also from studies using surface science techniques, from quantum chemical calculations providing more insight into possible reaction pathways and from transient experimentation dealing with reactions and reactors. This information is seldom combined into a kinetic model and into a quantitative description of the process. Generally the catalytic aspects are dealt with by chemists and by physicists, while the chemical engineers are called upon for mechanical aspects of the reactor design and its control. The symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis" aims at illustrating a more global and concerted approach through a number of prestigious keynote lectures and severely screened oral and poster presentations.
Author : Tomas Baer
Publisher : Oxford University Press
ISBN 13 : 0195360591
Total Pages : 447 pages
Book Rating : 4.1/5 (953 download)
Download or read book Unimolecular Reaction Dynamics written by Tomas Baer and published by Oxford University Press. This book was released on 1996-06-27 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a penetrating and comprehensive description of energy selected reactions from a theoretical as well as experimental view. Three major aspects of unimolecular reactions involving the preparation of the reactants in selected energy states, the rate of dissociation of the activated molecule, and the partitioning of the excess energy among the final products, are fully discussed with the aid of 175 illustrations and over 1,000 references, most from the recent literature. Examples of both neutral and ionic reactions are presented. Many of the difficult topics are discussed at several levels of sophistication to allow access by novices as well as experts. Among the topics covered for the first time in monograph form is a discussion of highly excited vibrational/rotational states and intramolecular vibrational energy redistribution. Problems associated with the application of RRKM theory are discussed with the aid of experimental examples. Detailed comparisons are also made between different statistical models of unimolecular decomposition. Both quantum and classical models not based on statistical assumptions are described. Finally, a chapter devoted to the theory of product energy distribution includes the application of phase space theory to the dissociation of small and large clusters. The work will be welcomed as a valuable resource by practicing researchers and graduate students in physical chemistry, and those involved in the study of chemical reaction dynamics.
Author :
Publisher :
ISBN 13 :
Total Pages : 12 pages
Book Rating : 4.:/5 (227 download)
Download or read book Kinetics and Dynamics of Reacting Systems written by and published by . This book was released on 1993 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: This project was devoted to a study of the kinetics of diffusion- controlled and surface catalytic reactions. For catalytic reactions, the kinetics of the saturation process was elucidated. The role of interactions between adsorbates on the surface reaction was examined. For diffusion- controlled reaction, a comprehensive theoretical framework to describe the spatial organization of reactants was developed. Particular attention was devoted to understanding the reaction dynamics at an interface which separates two reactive species. Geometrical features of this interface and the time dependence of the reaction rate were determined ... Chemical kinetics; Catalysis; Diffusion-controlled reactions.
Author : Michael Moreau
Publisher : Springer Science & Business Media
ISBN 13 : 1461310237
Total Pages : 617 pages
Book Rating : 4.4/5 (613 download)
Download or read book Chemical Reactivity in Liquids written by Michael Moreau and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 617 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding chemical reactivity has been the permanent concern of chemists from time immemorial. If we were able to understand it and express it quantitatively there would practically remain no unsolved mystery, and reactions would be fully predictable, with their products and rates and even side reactions. The beautiful developments of thermodynamics through the 19th century supplied us with the knowledge of the way a reactions progresses, and the statistical view initiated by Gibbs has progressively led to an unders tanding closer to the microscopic phenomena. But is was always evident to all that these advances still left our understanding of chemical reactivity far behind our empirical knowledge of the chemical reaction in its practically infinite variety. The advances of recent years in quantum chemistry and statistical mechanics, enhanced by the present availability of powerful and fast compu ters, are very fast changing this picture, and bringing us really close to a microscopic understanding of chemical equilibria, reaction rates, etc.... This is the reason why our Society encouraged a few years ago the initiative of Professor Savo Bratos who, with a group of French colleagues, prepared an impressive study on "Reactivite chimique en phase liquide", a prospective report which was jointly published by the Societe Fran
Author : Nikola Kallay
Publisher : CRC Press
ISBN 13 : 1482289792
Total Pages : 760 pages
Book Rating : 4.4/5 (822 download)
Download or read book Interfacial Dynamics written by Nikola Kallay and published by CRC Press. This book was released on 2000-01-03 with total page 760 pages. Available in PDF, EPUB and Kindle. Book excerpt: An examination of the theoretical foundations of the kinetics and thermodynamics of solid-liquid interfaces, as well as state-of-the-art industrial applications, this book presents information on surface and colloidal chemical processes and evaluates vital analytical tools such as atomic force microscopy, surface force apparatus measurements, and p
Author : Robert Wyatt
Publisher : CRC Press
ISBN 13 : 9780824795382
Total Pages : 692 pages
Book Rating : 4.7/5 (953 download)
Download or read book Dynamics of Molecules and Chemical Reactions written by Robert Wyatt and published by CRC Press. This book was released on 1996-06-27 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers both molecular and reaction dynamics. The work presents important theroetical and computational approaches to the study of energy transfer within and between molecules, discussing the application of these approaches to problems of experimental interest. It also describes time-dependent and time-independent methods, variational and perturbative techniques, iterative and direct approaches, and methods based upon the use of physical grids of finite sets of basic function.
Author : S. Bernasek
Publisher : John Wiley & Sons
ISBN 13 : 9780471185475
Total Pages : 186 pages
Book Rating : 4.1/5 (854 download)
Download or read book Heterogeneous Reaction Dynamics written by S. Bernasek and published by John Wiley & Sons. This book was released on 1995-10-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is an in-depth monograph covering the topic of energy transfer and reactions on solid surfaces. This topic is of great interest now because of its applications to catalysis and solid-state electronics, including the manufacture of semiconductors, integrated circuits and other solid state devices. Initially it describes what is meant by heterogenous reaction dynamics. Basically, this is the study, on a molecular level, of the elementary dynamics of energy transfer and reactions at surface. The emphasis of the book will be on well characterized solid surfaces. Energy transfer and reactions are broadly defined to include phase transitions in adsorbed layers, diffusion, the absorption process itself, and energy transfer between adsorbate and subtrate, as well as gas-surface energy transfer, catalytic and oxidative type surface reactions.
