Deactivation Of Pth Zsm 5 Bifunctional Catalysts By Coke Formation During Benzene Alkylation With Ethane

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Deactivation and Regeneration of Zeolite Catalysts

Author : M. Guisnet
Publisher : World Scientific
ISBN 13 : 1848166370
Total Pages : 359 pages
Book Rating : 4.8/5 (481 download)

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Book Synopsis Deactivation and Regeneration of Zeolite Catalysts by : M. Guisnet

Download or read book Deactivation and Regeneration of Zeolite Catalysts written by M. Guisnet and published by World Scientific. This book was released on 2011 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation and encompasses the state-of-the-art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration, by collecting a series of contributions by experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, an anthology of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice.

Catalyst Characterization

Author : Boris Imelik
Publisher : Springer Science & Business Media
ISBN 13 : 1475795890
Total Pages : 720 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Catalyst Characterization by : Boris Imelik

Download or read book Catalyst Characterization written by Boris Imelik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt: to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitive ly expensive. There are few chemical-or oil-based material items in modern society that do not depend in some way on a catalytic stage in their manufacture. Apart from manufacturing processes, catalysis is finding other important and over-increasing uses; for example, successful applications of catalysis in the control ofpollution and its use in environmental control are certain to in crease in the future. The commercial import an ce of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists including chemists, physicists, chemical engineers, and material scientists. Increasing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recentlyas sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 19 50s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth.

Mesoporous Zeolites

Author : Javier García-Martínez
Publisher : John Wiley & Sons
ISBN 13 : 3527335749
Total Pages : 608 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Mesoporous Zeolites by : Javier García-Martínez

Download or read book Mesoporous Zeolites written by Javier García-Martínez and published by John Wiley & Sons. This book was released on 2015-05-26 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.

Luminescence Thermometry

Author : Miroslav Dramićanin
Publisher : Woodhead Publishing
ISBN 13 : 0081020309
Total Pages : 304 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Luminescence Thermometry by : Miroslav Dramićanin

Download or read book Luminescence Thermometry written by Miroslav Dramićanin and published by Woodhead Publishing. This book was released on 2018-04-21 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Luminescence Thermometry: Methods, Materials, and Applications presents the state-of-the art applications of luminescence thermometry, giving a detailed explanation of luminescence spectroscopic schemes for the read-out of temperature, while also describing the diverse materials that are capable of sensing temperature via luminescence. Chapters cover the fundamentals of temperature, traditional thermometers and their figures of merit, a concise description of optical thermometry methods, luminescence and instrumentation, and an explanation of the ways in which increases in temperature quench luminescence. Additional sections focus on materials utilized for luminescence thermometry and the broad range of applications for luminescence thermometry, including temperature measurement at the nanoscale and the application of multifunctional luminescent materials. - Provides an overview of luminescence thermometry applications, including high-temperature, biomedical, nanoscale and multifunctional - Delves into luminescence thermometry by materials group, including Rare-earth and transition Metal Ion Doped, Semiconductors, Quantum Dots and Organic materials - Gives a concise introduction of the latest methods of temperature measurement, including luminescence spectroscopic schemes and methods of analysis

Fast Pyrolysis of Biomass

Author : Robert C Brown
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626182
Total Pages : 291 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Fast Pyrolysis of Biomass by : Robert C Brown

Download or read book Fast Pyrolysis of Biomass written by Robert C Brown and published by Royal Society of Chemistry. This book was released on 2017-07-07 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.

Catalytic Processes for The Valorisation of Biomass Derived Molecules

Author : Francesco Mauriello
Publisher : MDPI
ISBN 13 : 3039219146
Total Pages : 114 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Catalytic Processes for The Valorisation of Biomass Derived Molecules by : Francesco Mauriello

Download or read book Catalytic Processes for The Valorisation of Biomass Derived Molecules written by Francesco Mauriello and published by MDPI. This book was released on 2019-11-22 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decades, inedible lignocellulosic biomasses have attracted significant attention for being abundant resources that are not in competition with agricultural land or food production and, therefore, can be used as starting renewable material for the production of a wide variety of platform chemicals. The three main components of lignocellulosic biomasses are cellulose, hemicellulose and lignin, complex biopolymers that can be converted into a pool of platform molecules including sugars, polyols, alchols, ketons, ethers, acids and aromatics. Various technologies have been explored for their one-pot conversion into chemicals, fuels and materials. However, in order to develop new catalytic processes for the selective production of desired products, a complete understanding of the molecular aspects of the basic chemistry and reactivity of biomass derived molecules is still crucial. This Special Issue reports on recent progress and advances in the catalytic valorization of cellulose, hemicellulose and lignin model molecules promoted by novel heterogeneous systems for the production of energy, fuels and chemicals.

Science and Technology in Catalysis

Author : Masakazu Anpo
Publisher : Gulf Professional Publishing
ISBN 13 : 9780444513496
Total Pages : 612 pages
Book Rating : 4.5/5 (134 download)

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Book Synopsis Science and Technology in Catalysis by : Masakazu Anpo

Download or read book Science and Technology in Catalysis written by Masakazu Anpo and published by Gulf Professional Publishing. This book was released on 2003-07-09 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Selected) -- Plenary Lecures: New Catalysts for Controlled/Living Atom Transfer Radical Polymerization (ATRP; Catalysis and Applications of Gold Nanoparticles -- Oral Presentations: Ionic Liquids as New Solvents and Catalysis for Petrochemical and Refining Processes; High Throughput Experiment on the Investigation of Oxidation Catalysts with Gas Sensor System -- Poster Presentations: Development of a Low-Temperature Dioxin Decomposition Catalyst; Studies on Unique Properties of Polyolefins Prepared with Metallocene Catalyst Systems -- Index.

The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals

Author : Kostas Triantafyllidis
Publisher : Newnes
ISBN 13 : 0444563326
Total Pages : 607 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals by : Kostas Triantafyllidis

Download or read book The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals written by Kostas Triantafyllidis and published by Newnes. This book was released on 2013-03-19 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: - Catalytic pyrolysis of lignocellulosic biomass - Hybrid biogasoline by co-processing in FCC units - Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) - Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. - Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes - Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process - Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature

Catalysis and Zeolites

Author : Jens Weitkamp
Publisher : Springer Science & Business Media
ISBN 13 : 3662037645
Total Pages : 582 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Catalysis and Zeolites by : Jens Weitkamp

Download or read book Catalysis and Zeolites written by Jens Weitkamp and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites occur in nature and have been known for almost 250 years as alumino silicate minerals. Examples are clinoptilolite, mordenite, offretite, ferrierite, erionite and chabazite. Today, most of these and many other zeolites are of great interest in heterogeneous catalysis, yet their naturally occurring forms are of limited value as catalysts because nature has not optimized their properties for catalytic applications and the naturally occurring zeolites almost always contain undesired impurity phases. It was only with the advent of synthetic zeolites in the period from about 1948 to 1959 (thanks to the pioneering work of R. M. Barrer and R. M. Milton) that this class of porous materials began to playa role in catalysis. A landmark event was the introduction of synthetic faujasites (zeolite X at first, zeolite Y slightly later) as catalysts in fluid catalytic cracking (FCC) of heavy petroleum distillates in 1962, one of the most important chemical processes with a worldwide capacity of the order of 500 million t/a. Compared to the previously used amorphous silica-alumina catalysts, the zeolites were not only orders of magnitude more active, which enabled drastic process engineering improvements to be made, but they also brought about a significant increase in the yield of the target product, viz. motor gasoline. With the huge FCC capacity worldwide, the added value of this yield enhancement is of the order of 10 billion US $ per year.

Pillared Clays and Related Catalysts

Author : Antonio Gil
Publisher : Springer Science & Business Media
ISBN 13 : 1441966706
Total Pages : 531 pages
Book Rating : 4.4/5 (419 download)

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Book Synopsis Pillared Clays and Related Catalysts by : Antonio Gil

Download or read book Pillared Clays and Related Catalysts written by Antonio Gil and published by Springer Science & Business Media. This book was released on 2010-08-28 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the first works introducing the aluminum intercalated clay family in the early 1970s, interest in the synthesis of pillared interlayered clays has increased tremendously, especially research into the properties and applications of new synthesis methods. The need for solids that could be used as cracking catalysts with larger pores than zeolitic materials has spurred the synthesis of new porous materials from clays. Pillared Clays and Related Catalysts reviews the properties and applications of pillared clays and other layered materials used as catalysts, focusing on: the acidity of pillared clays and the effect it has on catalytic performance the use of pillared clays as supports for catalytically active phases, and the use of the resulting solids in environmentally friendly reactions the applications of the selective reduction of NOx the comparison between the reactions of pillared clays and anionic clays.

Thermal and Catalytic Processes in Petroleum Refining

Author : Serge Raseev
Publisher : CRC Press
ISBN 13 : 1135545596
Total Pages : 1185 pages
Book Rating : 4.1/5 (355 download)

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Book Synopsis Thermal and Catalytic Processes in Petroleum Refining by : Serge Raseev

Download or read book Thermal and Catalytic Processes in Petroleum Refining written by Serge Raseev and published by CRC Press. This book was released on 2003-02-26 with total page 1185 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text examines the thermal and catalytic processes involved in the refining of petroleum including visbreaking, coking, pyrolysis, catalytic cracking, oligomerization, alkylation, hydrofining, hydroisomerization, hydrocracking, and catalytic reforming. It analyzes the thermodynamics, reaction mechanisms, and kinetics of each process, as well as

Zeolite Characterization and Catalysis

Author : Arthur W. Chester
Publisher : Springer Science & Business Media
ISBN 13 : 140209678X
Total Pages : 372 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Zeolite Characterization and Catalysis by : Arthur W. Chester

Download or read book Zeolite Characterization and Catalysis written by Arthur W. Chester and published by Springer Science & Business Media. This book was released on 2009-10-03 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The idea for putting together a tutorial on zeolites came originally from my co-editor, Eric Derouane, about 5 years ago. I ?rst met Eric in the mid-1980s when he spent 2 years working for Mobil R&D at our then Corporate lab at Princeton, NJ. He was on the senior technical staff with projects in the synthesis and characterization of new materials. At that time, I managed a group at our Paulsboro lab that was responsible for catalyst characterization in support of our catalyst and process development efforts, and also had a substantial group working on new material synthesis. Hence, our interests overlapped considerably and we met regularly. After Eric moved back to Namur (initially), we maintained contact, and in the 1990s, we met a number of times in Europe on projects of joint interest. It was after I retired from ExxonMobil in 2002 that we began to discuss the tutorial concept seriously. Eric had (semi-)retired and lived on the Algarve, the southern coast of Portugal. In January 2003, my wife and I spent 3 weeks outside of Lagos, and I worked parts of most days with Eric on the proposed content of the book. We decided on a comprehensive approach that ultimately amounted to some 20+ chapters covering all of zeolite chemistry and catalysis and gave it the title Zeolite Chemistry and Catalysis: An integrated Approach and Tutorial.

Zeolite Microporous Solids: Synthesis, Structure, and Reactivity

Author : E.G. Derouane
Publisher : Springer Science & Business Media
ISBN 13 : 9401126046
Total Pages : 635 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Zeolite Microporous Solids: Synthesis, Structure, and Reactivity by : E.G. Derouane

Download or read book Zeolite Microporous Solids: Synthesis, Structure, and Reactivity written by E.G. Derouane and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 635 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intensive research on zeolites, during the past thirty years, has resulted in a deep understanding of their chemistry and in a true zeolite science, including synthesis, structure, chemical and physical properties, and catalysis. These studies are the basis for the development and growth of several industrial processes applying zeolites for selective sorption, separation, and catalysis. In 1983, a NATO Advanced Study Institute was organized in Alcabideche (portugal) to establish the State-of-the-Art in Zeolite Science and Technology and to contribute to a better understanding of the structural properties of zeolites, the configurational constraints they may exert, and their effects in adsorption, diffusion, and catalysis. Since then, zeolite science has witnessed an almost exponential growth in published papers and patents, dealing with both fundamentals issues and original applications. The proposal of new procedures for zeolite synthesis, the development of novel and sophisticated physical techniques for zeolite characterization, the discovery of new zeolitic and related microporous materials, progresses in quantum chemistry and molecular modeling of zeolites, and the application of zeolites as catalysts for organic reactions have prompted increasing interest among the scientific community. An important and harmonious interaction between various domains of Physics, Chemistry, and Engineering resulted therefrom.

Recent Advances in Pyrolysis

Author : Hassan Al- Haj Ibrahim
Publisher : BoD – Books on Demand
ISBN 13 : 1789840635
Total Pages : 124 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Recent Advances in Pyrolysis by : Hassan Al- Haj Ibrahim

Download or read book Recent Advances in Pyrolysis written by Hassan Al- Haj Ibrahim and published by BoD – Books on Demand. This book was released on 2020-01-22 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pyrolysis is an irreversible thermochemical treatment process of materials at elevated temperatures in an inert atmosphere. It is basically a carbonisation process where an organic material is decomposed to produce a solid residue with high (or higher) carbon content and some volatile products. The decomposition reactions are accompanied in general with polymerisation and isomerisation reactions. The end products of pyrolysis can be controlled by optimizing pyrolysis parameters such as temperature and residence time. Pyrolysis is used heavily in the chemical industry to produce many forms of carbon and other chemicals from petroleum, coal, wood, oil shale, biomass or organic waste materials, and it is the basis of several methods for producing fuel from biomass. Pyrolysis also is the process of conversion of buried organic matter into fossil fuels.

Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities

Author : E.G. Derouane
Publisher : Springer Science & Business Media
ISBN 13 : 9781402033094
Total Pages : 464 pages
Book Rating : 4.0/5 (33 download)

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Book Synopsis Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities by : E.G. Derouane

Download or read book Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities written by E.G. Derouane and published by Springer Science & Business Media. This book was released on 2005-06-01 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy and feedstock materials for the chemical industry are in increasing demand and, with constraints related to the availability and use of oil, the energy and chemical industry is undergoing considerable changes. In recent years, major restructuring has occurred in the oil, petrochemical, and chemical industry, with increasing attention devoted to the use of natural gas, methane in particular, as a chemical feedstock rather than just as a fuel. The conversion of remote natural gas into liquid fuels or other transportable chemicals is a challenge to industrial catalysis. Few processes exist so far with the major ones involving the conversion of natural gas to synthesis gas by steam reforming, CO2 reforming, or partial oxidation, followed by the syntheses of methanol, hydrocarbons (Fischer-Tropsch synthesis), or ammonia. In this book, a comprehensive overview of the field of processing natural gas is given, through a series of chapters written by leading scientists and engineers in the field. New developments are discussed and current work relevant to the area is shown by a series of recent works by researchers working in this and related fields.

Surface Chemistry and Catalysis

Author : Albert F. Carley
Publisher : Springer Science & Business Media
ISBN 13 : 9780306473937
Total Pages : 404 pages
Book Rating : 4.4/5 (739 download)

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Book Synopsis Surface Chemistry and Catalysis by : Albert F. Carley

Download or read book Surface Chemistry and Catalysis written by Albert F. Carley and published by Springer Science & Business Media. This book was released on 2002-09-30 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exciting results are still emerging from the many research groups working in this fertile area and the book is an excellent stimulus to researchers at the start of the 21st century."--BOOK JACKET.

Deterministic Global Optimization

Author : Christodoulos A. Floudas
Publisher : Springer Science & Business Media
ISBN 13 : 9780792360148
Total Pages : 774 pages
Book Rating : 4.3/5 (61 download)

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Book Synopsis Deterministic Global Optimization by : Christodoulos A. Floudas

Download or read book Deterministic Global Optimization written by Christodoulos A. Floudas and published by Springer Science & Business Media. This book was released on 2000 with total page 774 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a unified and insightful treatment of deterministic global optimization. It introduces theoretical and algorithmic advances that address the computation and characterization of global optima, determine valid lower and upper bounds on the global minima and maxima, and enclose all solutions of nonlinear constrained systems of equations. Among its special features, the book: Introduces the fundamentals of deterministic global optimization; Provides a thorough treatment of decomposition-based global optimization approaches for biconvex and bilinear problems; Covers global optimization methods for generalized geometric programming problems Presents in-depth global optimization algorithms for general twice continuously differentiable nonlinear problems; Provides a detailed treatment of global optimization methods for mixed-integer nonlinear problems; Develops global optimization approaches for the enclosure of all solutions of nonlinear constrained systems of equations; Includes many important applications from process design, synthesis, control, and operations, phase equilibrium, design under uncertainty, parameter estimation, azeotrope prediction, structure prediction in clusters and molecules, protein folding, and peptide docking. Audience: This book can be used as a textbook in graduate-level courses and as a desk reference for researchers in all branches of engineering and applied science, applied mathematics, industrial engineering, operations research, computer science, economics, computational chemistry and molecular biology.