d-d Excitations in Transition-Metal Oxides

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Publisher : Springer
ISBN 13 : 9783662146842
Total Pages : 147 pages
Book Rating : 4.1/5 (468 download)

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Book Synopsis d-d Excitations in Transition-Metal Oxides by : Bärbel Fromme

Download or read book d-d Excitations in Transition-Metal Oxides written by Bärbel Fromme and published by Springer. This book was released on 2014-03-12 with total page 147 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this monograph, investigations of the electronic structures of the transition-metal oxides MnO, CoO, and NiO with spin-polarized electron energy-loss spectroscopy are presented and compared with other experimental and theoretical results. After a review of the present knowledge of the electronic structure of the monoxides, the spectroscopic method applied and its special advantages are described. The knowledge and use of the different spin, angle, and primary-energy dependences of the various relevant inelastic electron-scattering mechanisms provide new insights into the excitation processes of the optically forbidden transitions between the crystal-field-split 3d states of the bulk and of the surface.

d-d Excitations in Transition-Metal Oxides

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Publisher : Springer
ISBN 13 : 3540453423
Total Pages : 156 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis d-d Excitations in Transition-Metal Oxides by : Bärbel Fromme

Download or read book d-d Excitations in Transition-Metal Oxides written by Bärbel Fromme and published by Springer. This book was released on 2007-08-03 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this monograph, investigations of the electronic structures of the transition-metal oxides MnO, CoO, and NiO with spin-polarized electron energy-loss spectroscopy are presented and compared with other experimental and theoretical results. After a review of the present knowledge of the electronic structure of the monoxides, the spectroscopic method applied and its special advantages are described. The knowledge and use of the different spin, angle, and primary-energy dependences of the various relevant inelastic electron-scattering mechanisms provide new insights into the excitation processes of the optically forbidden transitions between the crystal-field-split 3d states of the bulk and of the surface.

Low-energy Excitations in Some Complex Oxides by Resonant Inelastic X-ray Scattering

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis Low-energy Excitations in Some Complex Oxides by Resonant Inelastic X-ray Scattering by : Jiatai Feng

Download or read book Low-energy Excitations in Some Complex Oxides by Resonant Inelastic X-ray Scattering written by Jiatai Feng and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The intriguing physical properties presented in some complex oxides of transition metals draw attention not only in fundamental research but also in applications, for instance, superconductivity, colossal magnetoresistance, multiferroicity. The strong electronic correlation is at the origin of these behaviours. The thesis is a contribution to both the experimental effort to determine the electronic structure of strongly correlated systems and the critical assesment of the theoretical models describing them. Experimentally, the work of is devoted to the investigations of the low-energy excitations (d-d excitations, charge transfer, ...) of the ground state by resonant inelastic x-ray scattering. The experiments have been performed on the SEXTANTS beamline of SOLEIL synchrotron (France) using the high resolving power AERHA spectrometer. The analysis of the data has been focused on the determination of the the crystal field of the transition metal involved using the crystal field multiplets theory.Two systems have been investigated: the multiferroics RMnO3 (R = Tb, Dy) and the ferromagnetic Mott insulator Lu2V2O7.

Frontiers of 4D- and 5D-transition Metal Oxides

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Publisher : World Scientific
ISBN 13 : 9814374865
Total Pages : 328 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis Frontiers of 4D- and 5D-transition Metal Oxides by : Gang Cao

Download or read book Frontiers of 4D- and 5D-transition Metal Oxides written by Gang Cao and published by World Scientific. This book was released on 2013 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is aimed at advanced undergraduates, graduate students and other researchers who possess an introductory background in materials physics and/or chemistry, and an interest in the physical and chemical properties of novel materials, especially transition metal oxides.New materials often exhibit novel phenomena of great fundamental and technological importance. Contributing authors review the structural, physical and chemical properties of notable 4d- and 5d-transition metal oxides discovered over the last 10 years. These materials exhibit extraordinary physical properties that differ significantly from those of the heavily studied 3d-transition metal oxides, mainly due to the relatively strong influence of the spin-orbit interaction and orbital order in 4d- and 5d materials. The immense growth in publications addressing the physical properties of these novel materials underlines the need to document recent advances and the current state of this field. This book includes overviews of the current experimental situation concerning these materials.

Resonant X-Ray Scattering in Correlated Systems

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Publisher : Springer
ISBN 13 : 3662532271
Total Pages : 246 pages
Book Rating : 4.6/5 (625 download)

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Book Synopsis Resonant X-Ray Scattering in Correlated Systems by : Youichi Murakami

Download or read book Resonant X-Ray Scattering in Correlated Systems written by Youichi Murakami and published by Springer. This book was released on 2016-12-27 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt: The research and its outcomes presented here is devoted to the use of x-ray scattering to study correlated electron systems and magnetism. Different x-ray based methods are provided to analyze three dimensional electron systems and the structure of transition-metal oxides. Finally the observation of multipole orderings with x-ray diffraction is shown.

Magnetism and Synchrotron Radiation

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Publisher : Springer Science & Business Media
ISBN 13 : 3642044980
Total Pages : 435 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Magnetism and Synchrotron Radiation by : Eric Beaurepaire

Download or read book Magnetism and Synchrotron Radiation written by Eric Beaurepaire and published by Springer Science & Business Media. This book was released on 2010-03-12 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in the synthesis of new materials with often complex, nano-scaled structures require increasingly sophisticated experimental techniques that can probe the electronic states, the atomic magnetic moments and the magnetic microstructures responsible for the properties of these materials. At the same time, progress in synchrotron radiation techniques has ensured that these light sources remain a key tool of investigation, e.g. synchrotron radiation sources of the third generation are able to support magnetic imaging on a sub-micrometer scale. With the Fifth Mittelwihr School on Magnetism and Synchrotron Radiation the tradition of teaching the state-of-the-art on modern research developments continues and is expressed through the present set of extensive lectures provided in this volume. While primarily aimed at postgraduate students and newcomers to the field, this volume will also benefit researchers and lecturers actively working in the field.

Transition Metal Oxides

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Publisher : Oxford University Press
ISBN 13 : 0191030139
Total Pages : 295 pages
Book Rating : 4.1/5 (91 download)

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Book Synopsis Transition Metal Oxides by : P. A. Cox

Download or read book Transition Metal Oxides written by P. A. Cox and published by Oxford University Press. This book was released on 2010-08-19 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal oxides form a series of compounds with a uniquely wide range of electronic properties. They have important applications as dielectrics,semiconductors, and metals, and as materials for magnetic and optical uses. The recent discovery of `high temperature' superconductors has brought the attention of a wide scientific community to this area and has highlighted the problems involved in trying to understand transition metal oxides. The present book is not primarily about Tc superconductors, although their main properties are discussed in the final sections. The main aim is to describe the varied electronic behaviour shown by transition metal oxides, and to discuss the different types of theoretical model that have been proposed to interpret it. It is intended to provide an introduction to this fascinating and difficult field, at a level suitable for graduate students and other research workers with a background in solid- state chemistry or physics.

Physics of Spin-Orbit-Coupled Oxides

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Publisher : Oxford University Press
ISBN 13 : 0199602026
Total Pages : 202 pages
Book Rating : 4.1/5 (996 download)

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Book Synopsis Physics of Spin-Orbit-Coupled Oxides by : Gang Cao

Download or read book Physics of Spin-Orbit-Coupled Oxides written by Gang Cao and published by Oxford University Press. This book was released on 2021 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is aimed at graduate students, post docs and senior researchers with preliminary expertise in materials physics or chemistry, and with an interest in the physical and chemical properties of 4d- and 5d transition metal oxides, especially ruthenates and iridates. The 4d- and 5d-transition metal oxides are among the most current and interesting quantum materials. This book reviews recent experimental and theoretical evidence that the physical and structural properties of these materials are decisively influenced by strong spin-orbit interactions that compete with comparable Coulomb, magnetic exchange and crystalline electric field interactions. This competition often leads to unusual ground states and magnetic frustration that are unique to this class of materials. Novel coupling between the orbital/lattice and spin degrees of freedom, which seriously challenge current theoretical models and are not addressed by traditional textbooks, are of particular interest, This book also reviews a few techniques for single-crystal growth that are most suitable for the 4d- and 5d-transition metal oxides. The discussion is intended to help fill an existing void in the literature describing relevant synthesis techniques for 4d- and 5d-materials, which is a daunting experimental challenge.

Metal Organic Frameworks as Heterogeneous Catalysts

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849735727
Total Pages : 446 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Metal Organic Frameworks as Heterogeneous Catalysts by : Francesc X. Llabrés i Xamena

Download or read book Metal Organic Frameworks as Heterogeneous Catalysts written by Francesc X. Llabrés i Xamena and published by Royal Society of Chemistry. This book was released on 2013-07-01 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.

Low-energy D-d Excitations in MnO Studied by Resonant X-ray Fluorescence Spectroscopy

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Publisher :
ISBN 13 :
Total Pages : 2 pages
Book Rating : 4.:/5 (925 download)

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Book Synopsis Low-energy D-d Excitations in MnO Studied by Resonant X-ray Fluorescence Spectroscopy by :

Download or read book Low-energy D-d Excitations in MnO Studied by Resonant X-ray Fluorescence Spectroscopy written by and published by . This book was released on 1997 with total page 2 pages. Available in PDF, EPUB and Kindle. Book excerpt: Resonant soft X-ray emission spectroscopy has been demonstrated to possess interesting abilities for studies of electronic structure in various systems, such as symmetry probing, alignment and polarization dependence, sensitivity to channel interference, etc. In the present abstract the authors focus on the feasibility of resonant soft X-ray emission to probe low energy excitations by means of resonant electronic X-ray Raman scattering. Resonant X-ray emission can be regarded as an inelastic scattering process where a system in the ground state is transferred to a low excited state via a virtual core excitation. The energy closeness to a core excitation of the exciting radiation enhances the (generally) low probability for inelastic scattering at these wavelengths. Therefore soft X-ray emission spectroscopy (in resonant electronic Raman mode) can be used to study low energy d-d excitations in transition metal systems. The involvement of the intermediate core state allows one to use the selection rules of X-ray emission, and the appearance of the elastically scattered line in the spectra provides the reference to the ground state.

New Trends in Quantum Systems in Chemistry and Physics

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Publisher : Springer Science & Business Media
ISBN 13 : 0306469502
Total Pages : 310 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis New Trends in Quantum Systems in Chemistry and Physics by : J. Maruani

Download or read book New Trends in Quantum Systems in Chemistry and Physics written by J. Maruani and published by Springer Science & Business Media. This book was released on 2006-04-10 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: These two volumes collect thirty-eight selected papers from the scientific contributions presented at the Fourth European Workshop on Quantum Systems in Chemistry and Physics (QSCP-IV), held in Marly-le-Roi (France) in April 22-27, 1999. A total of one hundred and fifteen scientists attended the workshop, 99 from Europe and 16 from the rest of the world. They discussed the state of the art, new trends, and future evolution of the methods and applications. The workshop was held in the old town of Marly-le-Roi, which lies to the West of Paris between the historic centres of Saint-Germain-en-Laye and Versailles. Participants were housed at the National Youth Institute, where over sixty lectures were given by l- ding members of the scientific community; in addition, over sixty posters were presented in two very animated sessions. We are grateful to the oral speakers and to the poster p- senters for making the workshop such an stimulating experience. The social programme was also memorable – and not just for the closing banquet, which was held at the French Senate House. We are sure that participants will long remember their visit to the 'Musée des Antiquités Nationales': created by Napoleon III at the birthplace of Louis XIV, this museum boasts one of the world finest collections of archeological artifacts. The Marly-le-Roi workshop followed the format established at the three previous meetings, organized by Prof.

Principles and Applications of Density Functional Theory in Inorganic Chemistry II

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540218616
Total Pages : 264 pages
Book Rating : 4.2/5 (186 download)

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Book Synopsis Principles and Applications of Density Functional Theory in Inorganic Chemistry II by : Nikolas Kaltsoyannis

Download or read book Principles and Applications of Density Functional Theory in Inorganic Chemistry II written by Nikolas Kaltsoyannis and published by Springer Science & Business Media. This book was released on 2004 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: E. Clot, O. Eisenstein: Agostic Interactions from a Computational Perspective: One Name, many Interpretations.- Robert J. Deet: Recent Developments in Computational Bioinorganic Chemistry.- E. Ruiz: Theoretical Study of the Exchange Coupling in Large Polynuclear Transition Metal Complexes Using DFT Methods.- D. Sánches-Portal, P. Ordejón, E. Canadell: Computing the Properties of Materials from First Principles with SIESTA.- F. Corà, M. Alfredsson, G. Mallia, D.S. Middlemiss, W.C. Mackrodt, R. Dovesi, R. Orlando: The Performance of Hybrid Density Functionals in Solid State Chemistry

Nanostructure Control of Materials

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Publisher : Woodhead Publishing
ISBN 13 : 1845691180
Total Pages : 373 pages
Book Rating : 4.8/5 (456 download)

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Book Synopsis Nanostructure Control of Materials by : R H J Hannink

Download or read book Nanostructure Control of Materials written by R H J Hannink and published by Woodhead Publishing. This book was released on 2006-02-28 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ability to measure and manipulate matter on the nanometer level is making possible a new generation of materials with enhanced mechanical, optical, transport and magnetic properties. This important book summarises key developments in nanotechnology and their impact on the processing of metals, polymers, composites and ceramics.After a brief introduction, a number of chapters discuss the practical issues involved in the commercial production and use of nanomaterials. Other chapters review ways of nanoengineering steel, aluminium and titanium alloys. Elsewhere the book discusses the use of nanoengineered metal hydrides to store hydrogen as an energy source, and the development of nanopolymers for batteries and other energy storage devices. Other chapters discuss the use of nanotechnology to enhance the toughness of ceramics, the production of synthetic versions of natural materials such as bone, and the development of nanocomposites.Nanostructure control of materials is an ideal introduction to the ways nanotechnology is being used to create new materials for industry. It will be welcomed by R&D managers in such sectors as automotive engineering as well as academics working in this exciting area. Reviews key developments in nanotechnology and their impact on various materials Edited by leading experts in the field

Capillary Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 3540418156
Total Pages : 388 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Capillary Surfaces by : Dieter W. Langbein

Download or read book Capillary Surfaces written by Dieter W. Langbein and published by Springer Science & Business Media. This book was released on 2002-01-29 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Featuring a foreword by the astronaut Ulf Merbold, this book is devoted to interfaces between two fluids, that is, between a liquid and a gas or between two liquids. It is the first review on the subject, providing an up-to-date overview.

Physics of Transition Metal Oxides

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540212935
Total Pages : 356 pages
Book Rating : 4.2/5 (129 download)

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Book Synopsis Physics of Transition Metal Oxides by : Sadamichi Maekawa

Download or read book Physics of Transition Metal Oxides written by Sadamichi Maekawa and published by Springer Science & Business Media. This book was released on 2004-06-22 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fact that magnetite (Fe304) was already known in the Greek era as a peculiar mineral is indicative of the long history of transition metal oxides as useful materials. The discovery of high-temperature superconductivity in 1986 has renewed interest in transition metal oxides. High-temperature su perconductors are all cuprates. Why is it? To answer to this question, we must understand the electronic states in the cuprates. Transition metal oxides are also familiar as magnets. They might be found stuck on the door of your kitchen refrigerator. Magnetic materials are valuable not only as magnets but as electronics materials. Manganites have received special attention recently because of their extremely large magnetoresistance, an effect so large that it is called colossal magnetoresistance (CMR). What is the difference between high-temperature superconducting cuprates and CMR manganites? Elements with incomplete d shells in the periodic table are called tran sition elements. Among them, the following eight elements with the atomic numbers from 22 to 29, i. e. , Ti, V, Cr, Mn, Fe, Co, Ni and Cu are the most im portant. These elements make compounds with oxygen and present a variety of properties. High-temperature superconductivity and CMR are examples. Most of the textbooks on magnetism discuss the magnetic properties of transition metal oxides. However, when one studies magnetism using tradi tional textbooks, one finds that the transport properties are not introduced in the initial stages.

On the D-d Transfer in Transition-metal Monoxides and Dihalides

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Publisher :
ISBN 13 :
Total Pages : 17 pages
Book Rating : 4.:/5 (246 download)

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Book Synopsis On the D-d Transfer in Transition-metal Monoxides and Dihalides by : Eero Johannes Ojala

Download or read book On the D-d Transfer in Transition-metal Monoxides and Dihalides written by Eero Johannes Ojala and published by . This book was released on 1985 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Transition Metal Oxides Under X-ray Vision

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Publisher :
ISBN 13 :
Total Pages : 143 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis Transition Metal Oxides Under X-ray Vision by : Georgios Araizi Kanoutas

Download or read book Transition Metal Oxides Under X-ray Vision written by Georgios Araizi Kanoutas and published by . This book was released on 2020 with total page 143 pages. Available in PDF, EPUB and Kindle. Book excerpt: