Cyclodextrins as Additives for the Synthesis of Zirconia-supported Metal Oxide Catalysts for Formaldehyde Oxidation and Extension to the Preparation of Zirconia

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (986 download)

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Book Synopsis Cyclodextrins as Additives for the Synthesis of Zirconia-supported Metal Oxide Catalysts for Formaldehyde Oxidation and Extension to the Preparation of Zirconia by : Lei Bai

Download or read book Cyclodextrins as Additives for the Synthesis of Zirconia-supported Metal Oxide Catalysts for Formaldehyde Oxidation and Extension to the Preparation of Zirconia written by Lei Bai and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volatile organic compounds, such as formaldehyde are currently health concern and their elimination into harmless compounds is of great importance. Different catalysts metal oxides have been developed to decompose formaldehyde under thermal treatments. The present work aims at developing cobalt and/or manganese oxides catalysts supported on zirconia designed for the deep oxidation of formaldehyde. The catalysts have been synthesized by classical wet impregnation method and the started metal solution has been modified by the controlled addition of cyclodextrins.The influence of different parameters, such as the metal precursor, the nature of the cyclodextrin nature and the amount of the cyclodextrin has been studied. A beneficial effect of cyclodextrins addition on the catalytic activity has been obtained and the role of the cyclodextrins at each stage of the preparation has been investigated (i.e. in impregnating solution, before activation and after activation). Interactions occurring in the aqueous phase between the cyclodextrin and the metal precursor modify the activation process leading to the formation of small particles size more active.As an extension, cyclodextrins have also been used to prepare by simple synthesis procedure of single-phase tetragonal zirconia. The stabilization of the tetragonal phase is suggested to occur via the formation of a composite material precursor composed of incorporated cyclodextrin within the polymeric zirconium hydroxide. Finally, the effect of the cyclodextrin modified zirconium hydroxide was adapted in the preparation of a very efficient mixed oxide MnOx-ZrO2 in the oxidation of formaldehyde.

Cyclodextrins

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Publisher : John Wiley & Sons
ISBN 13 : 3527339809
Total Pages : 334 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Cyclodextrins by : Wanda Sliwa

Download or read book Cyclodextrins written by Wanda Sliwa and published by John Wiley & Sons. This book was released on 2017-04-10 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Authored by two experts working in this important field of research, the timely book covers the latest advances in the synthesis of cyclodextrins, their properties and important industrial applications. To this end, the authors describe covalent and non-covalent assemblies, cyclodextrin inclusion complexes, cyclodextrin polymers, and modified cyclodextrins, resulting in an up-to-date overview of cyclodextrin chemistry. An invaluable reference for organic and polymer chemists in academia as well as those researchers in industry working in polymer, supramolecular and pharmaceutical chemistry, as well as food, textile and cosmetic science.

Cyclodextrins: Preparation And Application In Industry

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Publisher : World Scientific
ISBN 13 : 9813229675
Total Pages : 293 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Cyclodextrins: Preparation And Application In Industry by : Zhengyu Jin

Download or read book Cyclodextrins: Preparation And Application In Industry written by Zhengyu Jin and published by World Scientific. This book was released on 2018-01-10 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cyclodextrins are an extremely versatile class of chemicals highly prized for their ability to incorporate a plethora of organic, inorganic and biologic guest molecules into their hydrophobic cavities and form host-guest inclusion complexes. As excellent molecular receptors, they have long been exploited in many important industries such as food and agriculture, pharmaceuticals, cosmetics, textiles, analytical chemistry and enzyme mimics.Researchers, technicians and application specialists in many industries will appreciate this handy volume that systematically discusses how cyclodextrins are applied in their industries. Special attention is devoted to the preparation of inclusion complexes, novel properties of the resultant complexes, and details on applying those properties to industry.

Cyclodextrins

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Publisher : John Wiley & Sons
ISBN 13 : 1119247543
Total Pages : 320 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Cyclodextrins by : Sahar Amiri

Download or read book Cyclodextrins written by Sahar Amiri and published by John Wiley & Sons. This book was released on 2017-08-30 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The comprehensive resource for understanding the structure, properties, and applications of cyclodextrins Cyclodextrins: Properties and Industrial Applications is a comprehensive resource that includes information on cyclodextrins (CDs) structure, their properties, formation of inclusion complex with various compounds as well as their applications. The authors Sahar Amiri and Sanam Amiri, noted experts in the field of cyclodextrins, cover both the basic and applied science in chemistry, biology, and physics of CDs and offers scientists and engineers an understand of cyclodextrins. Cyclodextrins are a family of cyclic oligosaccharides consisting of (α-1,4)-linked α-D-glucopyranose units. The formation of inclusion complex between CDs as host and guest molecules is based on non-covalent interaction such as hydrogen bonding or van der waals interactions and lead to the formation of supramolecular structures. These supramolecular structures can be used as macroinitiator for initiating various type of reactions. CDs are widely used in many industrial products such as pharmacy, food and flavours, chemistry, chromatography, catalysis, biotechnology, agriculture, cosmetics, hygiene, medicine, textiles, drug delivery, packing, separation processes, environment protection, fermentation, and catalysis. This important resource: Offers a basic understanding of cyclodextrins for researchers and engineers Includes information of the basic structure of cyclodextrins and their properties Reviews how cyclodextrins can be applied in a variety of fields including medicine, chemistry, textiles, packing, and many others Shows how encapsulate corrosion inhibitors became active in corrosive electrolytes to ensure delivery of the inhibitors to corrosion sites and long-term corrosion protection Cyclodextrins offers research scientists and engineers a wealth of information about CDs with particular focus on how cyclodextrins are applied in various ways including in drug delivery, the food industry, and many other areas.

Modified Cyclodextrins: Scaffolds And Templates For Supramolecular Chemistry

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Publisher : World Scientific
ISBN 13 : 1911298860
Total Pages : 305 pages
Book Rating : 4.9/5 (112 download)

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Book Synopsis Modified Cyclodextrins: Scaffolds And Templates For Supramolecular Chemistry by : Chris J Easton

Download or read book Modified Cyclodextrins: Scaffolds And Templates For Supramolecular Chemistry written by Chris J Easton and published by World Scientific. This book was released on 1999-04-29 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Through modification, the natural cyclodextrins are effective templates for the generation of a wide range of molecular hosts. This makes it possible to tailor a cyclodextrin host to a particular guest, to meet specific requirements in the host-guest complex, and opens the way to diverse new areas of supramolecular chemistry. Metallocyclodextrins, rotaxanes and catenanes, as well as surface monolayers of modified cyclodextrins, are readily obtained. The native cyclodextrins serve as scaffolds on which functional groups and other substituents can be assembled, with controlled geometry. This results in substantially improved molecular recognition and procedures for chemical separation, including enantiomer discrimination, through guest binding. Access to the gamut of functional groups greatly expands the utility of cyclodextrins in chemical synthesis and provides catalysts which mimic the entire range of enzymic activity. Modifications to the cyclodextrins also lead to a wide range of photochemistry of cyclodextrin complexes, through which the enhancement of guest reactivity occurs; in addition, light harvesting molecular devices and photochemical frequency switches may be constructed. In solution, modified cyclodextrins have been used to construct molecular reactors, as well as molecular, temperature and pH sensors. At surfaces, they form semipermeable membranes and sensor electrodes. Such exciting fields of chemistry, made possible only through modifications to the natural cyclodextrins, are the subject of this book.

Cyclodextrin Chemistry: Preparation And Application

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Publisher : World Scientific
ISBN 13 : 981443681X
Total Pages : 290 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis Cyclodextrin Chemistry: Preparation And Application by : Zhengyu Jin

Download or read book Cyclodextrin Chemistry: Preparation And Application written by Zhengyu Jin and published by World Scientific. This book was released on 2013-10-07 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cyclodextrin Chemistry covers the preparation of cyclodextrins and cyclodextrin derivatives (CDs), and their applications in industrial and non-industrial areas. An overall theme in the book is the screening of cyclodextrin glycosyltransferase (CGTase), the preparation of sugar-branched cyclodextrins and CDs, and the use of CDs for reconstructing various supermolecule systems. The specific content also includes preparation methods, spectroscopy techniques for CDs analysis, and potential applications in food packaging, nutrient fortification, medicine, cosmetics, textiles, chemicals, feed, agriculture, and environment.It summarizes the research merit of CDs in the past twenty years and also emphasizes hot topics and important areas of cyclodextrin chemistry in the future.

The History of Cyclodextrins

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Publisher : Springer Nature
ISBN 13 : 3030493083
Total Pages : 409 pages
Book Rating : 4.0/5 (34 download)

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Book Synopsis The History of Cyclodextrins by : Grégorio Crini

Download or read book The History of Cyclodextrins written by Grégorio Crini and published by Springer Nature. This book was released on 2020-09-29 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the historical development of Cyclodextrins by scientists who have made outstanding contribution to the field. Cyclodextrins are safe, cage-like molecules that have found major applications in many industrial sectors such as medicine, food, agriculture, environment and chemistry.

Functionality of Cyclodextrins in Encapsulation for Food Applications

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Publisher : Springer Nature
ISBN 13 : 3030800563
Total Pages : 343 pages
Book Rating : 4.0/5 (38 download)

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Book Synopsis Functionality of Cyclodextrins in Encapsulation for Food Applications by : Thao M. Ho

Download or read book Functionality of Cyclodextrins in Encapsulation for Food Applications written by Thao M. Ho and published by Springer Nature. This book was released on 2021-10-06 with total page 343 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cyclodextrins (CD) are cyclic oligosaccharides containing 6, 7 or 8 glucose units (α, β or γ-CD, respectively) in a truncated molecular shape. Their cyclic molecular structure contains a hydrophilic surface and a hydrophobic cavity at the center that can interact (host) with external hydrophobic compounds (guest molecules). Cyclodextrins have been categorized as Generally Recognized As Safe (GRAS) in the USA, “natural products” in Japan, and as “novel food” in Australia, New Zealand and EU countries. They are therefore widely used in food production to encapsulate hydrophobic compounds, including solid, liquid and gas molecules, in order to solubilize, stabilize or control the release rate of these components. To date, there has been no comprehensive review of the very large number of studies performed on encapsulation using cyclodextrin powders for food applications in recent years. This text fills that gap for academics in the encapsulation field and for industry professionals who want to gain a solid understanding of encapsulation functionality of cyclodextrin powders. The book consists of 16 chapters in which chapter 1 introduces cyclodextrin properties and its applications in food processing, and chapters 2-16 explore applications of cyclodextrin in encapsulation for many guest compounds. These compounds include gases, flavors, colors, pigments, polyphenols (plant bioactive compounds), essential oils, lipids (cholesterol and polyunsaturated fatty acids), vitamins, fruit ripening controlling compounds, and antifungal and antimicrobial compounds. These chapters also discuss functionalities of cyclodextrin in packaging, masking off-flavor and off-taste, and as dietary fiber. Covering a broad range of cyclodextrin applications and suitable for both newcomers to encapsulation technology and those with experience, Functionality of Cyclodextrins in Encapsulation for Food Applications is a unique and essential reference on this increasingly important topic.

Cyclodextrin Fundamentals, Reactivity and Analysis

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Publisher : Springer
ISBN 13 : 3319761595
Total Pages : 262 pages
Book Rating : 4.3/5 (197 download)

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Book Synopsis Cyclodextrin Fundamentals, Reactivity and Analysis by : Sophie Fourmentin

Download or read book Cyclodextrin Fundamentals, Reactivity and Analysis written by Sophie Fourmentin and published by Springer. This book was released on 2018-04-26 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is the first volume of two volumes on cyclodextrins published in the series Environmental Chemistry for a Sustainable World. After a brief description of the cyclodextrin fundamentals, the first chapter by Grégorio Crini et al. provides an overview of cyclodextrin research during the last 5 years. The second chapter by Michal Řezanka discusses the synthesis of novel cyclodextrin systems by selective modifications. Then Eric Monflier et al. describes the synthesis of nanostructured porous materials based on cyclodextrins, and applications in heterogeneous catalysis and photocatalysis. The use of thermal analyses for assessing cyclodextrin inclusion complexes is reviewed in chapter 4 by Daniel Hădărugă et al. Experimental methods for measuring binding constants of cyclodextrin inclusion compounds are presented by David Landy. The second volume reviews cyclodextrin applications in medicine, food, environment and liquid crystals.

Cyclodextrins in Pharmacy

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Publisher : Springer Science & Business Media
ISBN 13 : 9401582777
Total Pages : 248 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Cyclodextrins in Pharmacy by : Karl-Heinz Frömming

Download or read book Cyclodextrins in Pharmacy written by Karl-Heinz Frömming and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nearly three thousand papers and patents are dedicated to the actual or potential uses of cyclodextrins in pharmacy and pharmaceutical formulations. This is the first book written for pharmacists and pharmaceutical technologists which not only critically summarizes the enormous amount of literature available, but which can be used as a handbook when looking for solutions to practical problems. The fundamentals -- chemistry of cyclodextrins and their derivatives -- their physical and chemical properties are condensed to the most relevant items in Chapters 1 and 2. Chapter 3 deals with the adsorption, metabolism and toxicological properties of cyclodextrins. Chapter 4 explains the formulation, structure, composition and advantageous effects of the cyclodextrin inclusion complexes. Chapter 5 describes the methods for preparation and characterization of drug/cyclodextrin complexes. Chapters 6 and 7 are dedicated to the pharmacokinetics, biopharmaceutical and technological aspects of drug/CD complexes. Chapter 8 treats the application and effects of cyclodextrins in various drug formulations. The Appendix comprises a collection of recipes for any type of drug formulation. This book is aimed at those who use cyclodextrins in drug formulations, to improve the properties of existing drug formulations, or who want to prepare quite new formulations.

Cyclodextrin

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Publisher : BoD – Books on Demand
ISBN 13 : 1789230683
Total Pages : 334 pages
Book Rating : 4.7/5 (892 download)

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Book Synopsis Cyclodextrin by : Poonam Arora

Download or read book Cyclodextrin written by Poonam Arora and published by BoD – Books on Demand. This book was released on 2018-04-18 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is devoted to the highly versatile and potential ingredient Cyclodextrin, a family of cyclic oligosaccharides composed of ?-(1,4)-linked glucopyranose subunits. Its molecular complexation phenomena and negligible cytotoxic effects attribute toward its application such as in pharmaceuticals, cosmetics, food, agriculture, textile, separation process, analytical methods, catalysis, environment protection, and diagnostics. Efforts have also been made to concentrate on recent research outcomes along with future prospects of cyclodextrins to attract the interest of scientists from the industry and academia. The contributions of the authors are greatly acknowledged, without which this compilation would not have been possible.

Modified Cyclodextrins

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Publisher : Imperial College Press
ISBN 13 : 9781860941443
Total Pages : 293 pages
Book Rating : 4.9/5 (414 download)

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Book Synopsis Modified Cyclodextrins by : Christopher J. Easton

Download or read book Modified Cyclodextrins written by Christopher J. Easton and published by Imperial College Press. This book was released on 1999-01-01 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Through modification, the natural cyclodextrins are effective templates for the generation of a wide range of molecular hosts. This makes it possible to tailor a cyclodextrin host to a particular guest, to meet specific requirements in the host -- guest complex, and opens the way to diverse new areas of supramolecular chemistry. Metallocyclodextrins, rotaxanes and catenanes, as well as surface monolayers of modified cyclodextrins, are readily obtained. The native cyclodextrins serve as scaffolds on which functional groups and other substituents can be assembled, with controlled geometry. This results in substantially improved molecular recognition and procedures for chemical separation, including enantiomer discrimination, through guest binding. Access to the gamut of functional groups greatly expands the utility of cyclodextrins in chemical synthesis and provides catalysts which mimic the entire range of enzymic activity. Modifications to the cyclodextrins also lead to a wide range of photochemistry of cyclodextrin complexes, through which the enhancement of guest reactivity occurs; in addition, light harvesting molecular devices and photochemical frequency switches may be constructed. In solution, modified cyclodextrins have been used to construct molecular reactors, as well as molecular, temperature and pH sensors. At surfaces, they form semipermeable membranes and sensor electrodes. Such exciting fields of chemistry, made possible only through modifications to the natural cyclodextrins, are the subject of this book.

Synthesis and Characterisation of Zirconia Supported Molybdenum Oxide and Molybdenum Carbide Catalysts for Hydroconversion of N-heptane

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (111 download)

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Book Synopsis Synthesis and Characterisation of Zirconia Supported Molybdenum Oxide and Molybdenum Carbide Catalysts for Hydroconversion of N-heptane by : Femi Francis Oloye

Download or read book Synthesis and Characterisation of Zirconia Supported Molybdenum Oxide and Molybdenum Carbide Catalysts for Hydroconversion of N-heptane written by Femi Francis Oloye and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Cyclodextrins

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Publisher : Nova Science Publishers
ISBN 13 : 9781634827881
Total Pages : 0 pages
Book Rating : 4.8/5 (278 download)

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Book Synopsis Cyclodextrins by : Francis G. Ramirez

Download or read book Cyclodextrins written by Francis G. Ramirez and published by Nova Science Publishers. This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cyclodextrins (CDs) are capable of interacting with a large variety of guest molecules to form inclusion complexes. The authors of the chapters that form this book discuss the development of ion-selective electrodes based on selected cyclodextrins and their derivatives as selective ionophores for various drugs and their applications in pharmaceutical research; the wide range of applications of CDs in biomedical electrochemistry, focusing both on their behavior in solutions and embedded in thin films formed at the electrode surface; the general features of CDs and the progress done so far in the field of microencapsulation of pesticides in CDs; cyclodextrins as encapsulating agents for bioactive plant molecules in the pharmaceutical field; the effect of cyclodextrins on the photodegradation profile of drugs when they are used in drug formulations; applications of cyclodextrins in stabilizing or solubilizing ingredients of pharmaceutical relevance used in the food industry (commonly called nutraceuticals); the use and importance of cyclodextrins in the pharmaceutical industry; the main aspects of the crystal structures of the dimeric;-CD inclusion complexes; the influence of biologically active inorganic ions on complex formation of cyclodextrins with some aromatic carboxylic acids possessing pharmacological and biological activity; the importance of detailed characterization of the composition of substituted CDs by the example of sulfobutylether cyclodextrins; the several crystal structures of dye inclusion complexes using cyclodextrin, the preparation of DISC (dye inclusion single crystal); the structural details about the dye inclusion complex analyzed by X-ray and the properties of porphyrin DISC.

Proceedings of the Fourth International Symposium on Cyclodextrins

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Publisher : Springer Science & Business Media
ISBN 13 : 9400926375
Total Pages : 527 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Proceedings of the Fourth International Symposium on Cyclodextrins by : J. Szejtli

Download or read book Proceedings of the Fourth International Symposium on Cyclodextrins written by J. Szejtli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 527 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rapidly growing number of papers and patents on Cyclodextrins and their potential or actual industrial uses raised the idea to organize a Symposium on Cyclodextrins. This Symposium - held in September 1981 in Budapest, with more than 200 participants from 17 countries - proved to be very succesfull in every respect, therefore it has been accepted unanimously to organize the lInd CD-Symposium in 1984, in Tokyo. (The Budapest-Symposium got posteriorly the "First" adjective). The IInd Symposium was held together with the III. Int. Symposium on Chlatrate Compounds and Molecular Inclusion Phenomena. The IIIrd CD-Symposium also was held as a Joint Symposium, with the IVth. Chlatrate Symposium in Lancaster, U. K. ,1986. The limited time however showed, that such a broad field - from calixarenes to zeolites - can not be managed efficiently. Therefore the International Organizing Committee voted for separation of two Symposia in the future. The IVth Int. CD-Symposium was held in the Munich, in April 1988, and the Vth Chlatrate Symposium (called already Vth Int. Symposium on Inclusion Phenomena and Molecular Recognition) was held in Alabama, Sept. 1988. In Munich 220 participants from 21 countries attended 32 verbal lectures and 54 posters. This volume contains the submitted 71 manuscripts of the IVth Cyclodextrin Symposium.

Proceedings of the Ninth International Symposium on Cyclodextrins

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Publisher : Springer Science & Business Media
ISBN 13 : 9401146810
Total Pages : 708 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Proceedings of the Ninth International Symposium on Cyclodextrins by : Juan José Torres Labandeira

Download or read book Proceedings of the Ninth International Symposium on Cyclodextrins written by Juan José Torres Labandeira and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 708 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains the proceedings of the Ninth International Symposium on Cyclodextrins, held in Santiago de Compostela, Spain, May 31 - June 3, 1998. The papers collected represent a summary of the last two years' achievements in the application of cyclodextrins in such diverse fields as pharmaceuticals, biotechnology, textiles, chromatography and environmental sciences. Highlights: Chiral selection of chemicals, nuclear waste management, cyclodextrins in nasal drug delivery, cyclodextrins in pulmonary drug delivery, cyclodextrins as pharmaceutical excipients, pharmacokinetics, stabilization of drugs by cyclodextrins, structural characterization of cyclodextrin complexes by nuclear magnetic resonance and molecular modeling, artificial receptors, large cyclodextrins, cyclodextrins as enzyme models, new cyclodextrin derivatives and potentials. Audience: This book will be of interest to researchers whose work involves biotechnology, pharmaceuticals, food and chemicals and chromatographic methods, as well as fundamental cyclodextrin research.

Cyclodextrins and Their Inclusion Complexes

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Publisher :
ISBN 13 :
Total Pages : 304 pages
Book Rating : 4.:/5 (51 download)

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Book Synopsis Cyclodextrins and Their Inclusion Complexes by : József Szejtli

Download or read book Cyclodextrins and Their Inclusion Complexes written by József Szejtli and published by . This book was released on 1982 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: