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Author : Qi Su
Publisher :
ISBN 13 :
Total Pages : 404 pages
Book Rating : 4.:/5 (346 download)
Download or read book Competition Kinetic Studies of Radical Addition to Olefins written by Qi Su and published by . This book was released on 1996 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Lan-Yuh Yang Chuang
Publisher :
ISBN 13 :
Total Pages : 126 pages
Book Rating : 4.:/5 (241 download)
Download or read book The Kinetic Study of the Addition Reactions of the Cyclopropyl Radical to Olefins written by Lan-Yuh Yang Chuang and published by . This book was released on 1966 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Eric Jacob Simon
Publisher :
ISBN 13 :
Total Pages : 184 pages
Book Rating : 4.:/5 (438 download)
Download or read book The Relative Reactivites of Olefins with Respect to Free Radical Addition written by Eric Jacob Simon and published by . This book was released on 1951 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael Silaev
Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659373565
Total Pages : 60 pages
Book Rating : 4.3/5 (735 download)
Download or read book The Kinetic Investigation of the Free-Radical Addition written by Michael Silaev and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: Five reaction schemes are suggested for the initiated nonbranched-chain addition of free radicals to the multiple bonds of the unsaturated compounds. The proposed schemes include the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in these schemes involves three or four types of free radicals. One of them is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. Based on the suggested schemes, nine rate equations (containing one to three parameters to be determined directly) are deduced using quasi-steady-state treatment. These equations provide good fits for the nonmonotonic (peaking) dependences of the formation rates of the molecular products (1:1 adducts) on the concentration of the unsaturated component in binary systems consisting of a saturated component (hydrocarbon, alcohol, etc.) and an unsaturated component (olefin, allyl alcohol, formaldehyde, or dioxygen). The unsaturated compound in these systems is both a reactant and an autoinhibitor generating low-reactive free radicals. The energetics of the key radical-molecule reactions is considered.
Author : A. C. Knipe
Publisher : John Wiley & Sons
ISBN 13 : 0470066709
Total Pages : 600 pages
Book Rating : 4.4/5 (7 download)
Download or read book Organic Reaction Mechanisms 1983 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1983 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1983. The 19th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Author : Brian Walton Harris
Publisher :
ISBN 13 :
Total Pages : 200 pages
Book Rating : 4.:/5 (731 download)
Download or read book Some Free Radical Addition Reactions of Olefins written by Brian Walton Harris and published by . This book was released on 1962 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : G. Porter
Publisher : Elsevier
ISBN 13 : 1483213722
Total Pages : 524 pages
Book Rating : 4.4/5 (832 download)
Download or read book Progress in Reaction Kinetics written by G. Porter and published by Elsevier. This book was released on 2013-09-11 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Reaction Kinetics, Volume 3 presents articles about advances in reaction kinetics. The book begins with a theoretical review of bimolecular reactions, such as the relation between free energy and potential energy surfaces. The text describes reactions of hydrogen atoms in the gas phase; the hot atom chemistry of gas-phase systems; the inhibition of gaseous free radical chain reactions; and vibrational relaxation in gases. Articles about pulse radiolysis; the effects of dose-rate and linear energy transfer in radiation chemistry; and the electronic spectra and kinetics of aromatic free radicals are also considered. The book further tackles the kinetics of polymerization of vinyl monomers by lithium alkyls as well as radical polymerization in solutions. Chemists and professionals dealing with radiation, physical, and industrial chemistry will find the book invaluable.
Author : Richard D. Chambers
Publisher : Springer Science & Business Media
ISBN 13 : 9783540631712
Total Pages : 268 pages
Book Rating : 4.6/5 (317 download)
Download or read book Organofluorine Chemistry written by Richard D. Chambers and published by Springer Science & Business Media. This book was released on 1997-09-18 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: The excitement of the chemistry of organofluorine compounds stems from the unique reactions that arise and the "special effects" that introduction of fluorine impart on a molecule. Indeed, these effects are now exploited in a remarkable array of applications the whole of the chemical, pharmaceutical, and plant-protection industries. In this two-volume set, we have gathered authors with immense experience in various aspects of their fields and each is a world-authority on the important topics which they have described. The first volume treats the chemistry of fluorinated alkenes, which are important "building-blocks" for the synthesis of a range of fluorinated systems and are used widely in industry. The second volume is directed to techniques and synthons for obtaining fluorinated compounds.
Author : R. Gregory
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (643 download)
Download or read book Free-radical Addition to Olefins written by R. Gregory and published by . This book was released on 1966 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 492 pages
Book Rating : 4.:/5 (318 download)
Download or read book Kinetics and Catalysis written by and published by . This book was released on 1986 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Samir Z. Zard
Publisher : Oxford University Press, USA
ISBN 13 : 9780198502401
Total Pages : 276 pages
Book Rating : 4.5/5 (24 download)
Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford University Press, USA. This book was released on 2003 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction and some general concepts. -- General principles: chain reactions based on stannane chemistry. -- Further chain reactions of stannanes. -- Organo-silicon, -germanium, and -mercury hydrides. -- The Barton decarboxylation and related reactions. -- Atom and group transfer reactions. -- The persistent radical effect: non-chain processes. -- Redox processes. -- Some concluding remarks.
Author : D. C. Nonhebel
Publisher : CUP Archive
ISBN 13 : 9780521201490
Total Pages : 620 pages
Book Rating : 4.2/5 (14 download)
Download or read book Free-Radical Chemistry written by D. C. Nonhebel and published by CUP Archive. This book was released on 1974-01-31 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Roy John Gritter
Publisher :
ISBN 13 :
Total Pages : 310 pages
Book Rating : 4.:/5 (168 download)
Download or read book Studies with Optically Active Butanol-2 written by Roy John Gritter and published by . This book was released on 1955 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Arkadi Vigalok
Publisher : Springer
ISBN 13 : 3642120733
Total Pages : 198 pages
Book Rating : 4.6/5 (421 download)
Download or read book C-X Bond Formation written by Arkadi Vigalok and published by Springer. This book was released on 2010-06-30 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Kilian Muñiz: Transition Metal Catalyzed Electrophilic Halogenation of C-H bonds in alpha-Position to Carbonyl Groups; Arkadi Vigalok * and Ariela W Kaspi: Late Transition Metal-Mediated Formation of Carbon-Halogen Bonds; Paul Bichler and Jennifer A. Love*: Organometallic Approaches to Carbon-Sulfur Bond Formation; David S. Glueck: Recent Advances in Metal-Catalyzed C-P Bond Formation; Andrei N. Vedernikov: C-O Reductive Elimination from High Valent Pt and Pd Centers; Lukas Hintermann: Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes; Moris S. Eisen: Catalytic C-N, C-O and C-S bond formation promoted by organoactinide complexes.
Author : American Chemical Society. Meeting
Publisher :
ISBN 13 :
Total Pages : 900 pages
Book Rating : 4.:/5 (6 download)
Download or read book Abstracts of Papers - American Chemical Society written by American Chemical Society. Meeting and published by . This book was released on 1968 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : B. Marciniec
Publisher : Elsevier
ISBN 13 : 0080912435
Total Pages : 767 pages
Book Rating : 4.0/5 (89 download)
Download or read book Comprehensive Handbook on Hydrosilylation written by B. Marciniec and published by Elsevier. This book was released on 2013-10-22 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook provides an up-to-date account of hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding. The book consists of two parts: the first is descriptive, presenting the catalytic, mechanistic, structural and synthetic aspects of hydrosilylation, as well as its application in organic and organosilicon chemistry. The second part, presented in tabular form sets out encyclopedic information concerning reaction conditions taken from more than 2000 papers and patents in the period 1965 - 1990.
Author : Angelo Albini
Publisher : John Wiley & Sons
ISBN 13 : 1118689305
Total Pages : 491 pages
Book Rating : 4.1/5 (186 download)
Download or read book Photochemically-Generated Intermediates in Synthesis written by Angelo Albini and published by John Wiley & Sons. This book was released on 2013-07-01 with total page 491 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examines the latest applications of photochemistry to generate important intermediates Presenting the latest breakthroughs in the field of organic photochemistry, this book offers tested and proven photochemical approaches to synthesis, creating promising new possibilities and applications for photochemical reactions. It focuses on photoreactions involving an intermediate where mechanistic aspects control the course of the reaction and its synthetic value. Readers will discover new insights into the mechanisms and nature of photo-produced reactive intermediates for organic synthesis as well as the methods to generate them. Moreover, by focusing on highly efficient techniques for producing such species, the authors enable researchers to design and perform photoreactions within the framework of green, sustainable chemistry. Photochemically-Generated Intermediates in Synthesis begins with a discussion of the principles and practice of photo-generated intermediates. Next, the book explores: Photogeneration of carbon-centered radicals Photogeneration of heteroatom-centered radicals Photogeneration of biradicals and radical pairs Photochemical generation of radical ions Photogeneration of carbocations and carbanions Photogeneration of carbenes and nitrenes The book's final chapter is dedicated to the photochemical manipulation of intermediates. Each chapter includes key kinetic data for typical intermediates as well as detailed case examples, giving readers all the tools needed to perform their own photochemical reactions. Comparisons to non-photochemical methods are offered whenever possible. Photochemically-Generated Intermediates in Synthesis sets the stage for greater collaboration among photochemists and synthetic organic chemists, enabling these two research communities to fully leverage photochemistry in order to generate key intermediates needed for a broad range of synthetic reactions in organic chemistry.
