Chiral Lewis Acids in Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527802134
Total Pages : 399 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Chiral Lewis Acids in Organic Synthesis by : Jacek Mlynarski

Download or read book Chiral Lewis Acids in Organic Synthesis written by Jacek Mlynarski and published by John Wiley & Sons. This book was released on 2017-06-26 with total page 399 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete overview covering the application of metal-based chiral Lewis acids from all parts of the periodic table, the Author emphasizes the most recent contributions to the field as well as prominent direction of development. The book discusses the design of chiral complexes as well as a wide spectrum of reactions promoted by various chiral Lewis acids, including water-compatible acids as well as the most important applications in the chemical and pharmaceutical industries. A must-have for catalytic and organic chemists working in the field, both in academia and industry, as well as pharmaceutical and medicinal chemists.

Environmentally Sustainable Catalytic Asymmetric Oxidations

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Publisher : CRC Press
ISBN 13 : 1466588578
Total Pages : 166 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Environmentally Sustainable Catalytic Asymmetric Oxidations by : Konstantin Bryliakov

Download or read book Environmentally Sustainable Catalytic Asymmetric Oxidations written by Konstantin Bryliakov and published by CRC Press. This book was released on 2014-09-17 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis plays a vital role in chemical, petroleum, agriculture, polymer, electronics, pharmaceutical, and other industries. Over 90 percent of chemicals originate from catalytic processes. Toughening economic and environmental constraints have proven to be a challenge for meeting the demand of novel efficient and sustainable regio- and stereoselective catalyst systems. Environmentally Sustainable Catalytic Asymmetric Oxidations provides a comprehensive overview of existing ecologically friendly catalyst systems for various asymmetric oxidation processes. Topics include: A survey of existing transition metal-based catalyst systems for asymmetric epoxidations (AEs) with O2 and H2O2 Asymmetric sulfoxidations with H2O2 on chiral metal complexes An overview of various transition metal-catalyzed oxidative transformations with H2O2 or O2 used as the terminal oxidant Organocatalytic asymmetric oxidations Catalytic processes of stereospecific oxidations of C-H functional groups The role that oxoiron(V) intermediates play in chemo- and stereoselective oxidations catalyzed by non-heme iron complexes The book concludes with a discussion of the opportunities and problems associated with the industrial application of stereoselective processes of catalytic oxidation with H2O2 and O2. It also provides examples of processes with industrial potential. Some of the catalysts presented in this book may serve as promising alternatives for existing catalysts—progressively replacing them in manufacturing processes and ultimately making the chemical industry greener and cleaner.

Comprehensive Chirality

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Author :
Publisher : Newnes
ISBN 13 : 0080951686
Total Pages : 5635 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Chirality by :

Download or read book Comprehensive Chirality written by and published by Newnes. This book was released on 2012-12-31 with total page 5635 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although many books exist on the subject of chiral chemistry, they only briefly cover chiral synthesis and analysis as a minor part of a larger work, to date there are none that pull together the background information and latest advances in one comprehensive reference work. Comprehensive Chirality provides a complete overview of the field, and includes chiral research relevant to synthesis, analytic chemistry, catalysis, and pharmaceuticals. The individual chapters in each of the 9 volumes provide an in depth review and collection of references on definition, technology, applications and a guide/links to the related literature. Whether in an Academic or Corporate setting, these chapters will form an invaluable resource for advanced students/researchers new to an area and those who need further background or answers to a particular problem, particularly in the development of drugs. Chirality research today is a central theme in chemistry and biology and is growing in importance across a number of disciplinary boundaries. These studies do not always share a unique identifying factor or subject themselves to clear and concise definitions. This work unites the different areas of research and allows anyone working or researching in chiral chemistry to navigate through the most essential concepts with ease, saving them time and vastly improving their understanding. The field of chirality counts several journals that are directly and indirectly concerned with the field. There is no reference work that encompasses the entire field and unites the different areas of research through deep foundational reviews. Comprehensive Chirality fills this vacuum, and can be considered the definitive work. It will help users apply context to the diverse journal literature offering and aid them in identifying areas for further research and/or for solving problems. Chief Editors, Hisashi Yamamoto (University of Chicago) and Erick Carreira (ETH Zürich) have assembled an impressive, world-class team of Volume Editors and Contributing Authors. Each chapter has been painstakingly reviewed and checked for consistent high quality. The result is an authoritative overview which ties the literature together and provides the user with a reliable background information and citation resource.

Schiff Base Metal Complexes

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Publisher : John Wiley & Sons
ISBN 13 : 3527350705
Total Pages : 229 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Schiff Base Metal Complexes by : Pranjit Barman

Download or read book Schiff Base Metal Complexes written by Pranjit Barman and published by John Wiley & Sons. This book was released on 2023-05-15 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: A systematic and organized structure designed to make information instantly accessible Detailed coverage of thermal synthesis, photochemical synthesis, and more Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.

Beauty in Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642283411
Total Pages : 180 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Beauty in Chemistry by : Luigi Fabbrizzi

Download or read book Beauty in Chemistry written by Luigi Fabbrizzi and published by Springer Science & Business Media. This book was released on 2012-02-22 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Beauty of Chemistry in the Words of Writers and in the Hands of Scientists, by Margherita Venturi, Enrico Marchi und Vincenzo Balzani Living in a Cage Is a Restricted Privilege, by Luigi Fabbrizzi Inner and Outer Beauty, by Kenneth N. Raymond und Casey J. Brown The Mechanical Bond: A Work of Art, by Carson J. Bruns und J. Fraser Stoddart The Beauty of Knots at the Molecular Level, by Jean-Pierre Sauvage und David B. Amabilino

Asymmetric Synthesis

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Author :
Publisher : CRC Press
ISBN 13 : 9789056991524
Total Pages : 408 pages
Book Rating : 4.9/5 (915 download)

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Book Synopsis Asymmetric Synthesis by : Tamio Hayashi

Download or read book Asymmetric Synthesis written by Tamio Hayashi and published by CRC Press. This book was released on 1998-06-09 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides a comprehensive overview of the rapidly developing field of asymmetric synthesis. Using easy to understand graphical abstracts it presents 348 important catalytic and stoichiometric reactions leading to the synthesis of optically active chiral compounds. The first part of the book covers reactions related to reductions, oxidations, carbon-carbon bond formation and carbon-heteroatom bond formation. Each graphical abstract is accompanied by a list of important keywords and references to assist the reader. The second part concentrates on experimental aspects, describing synthetic procedures for selected chiral reagents and chiral auxiliaries, and provides an invaluable reference tool for laboratory work. Written with both the graduate student and professional organic chemist in mind, this book will serve as an important resource for the synthetic organic chemist.

Comprehensive Inorganic Chemistry II

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Publisher : Newnes
ISBN 13 : 0080965296
Total Pages : 7694 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Inorganic Chemistry II by :

Download or read book Comprehensive Inorganic Chemistry II written by and published by Newnes. This book was released on 2013-07-23 with total page 7694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

The Chemical Transformations of C1 Compounds

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Publisher : John Wiley & Sons
ISBN 13 : 3527831894
Total Pages : 1780 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis The Chemical Transformations of C1 Compounds by : Xiao-Feng Wu

Download or read book The Chemical Transformations of C1 Compounds written by Xiao-Feng Wu and published by John Wiley & Sons. This book was released on 2022-01-14 with total page 1780 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemical Transformations of C1 Compounds A comprehensive exploration of one-carbon molecule transformations The chemistry of one-carbon molecules has recently gained significant prominence as the world transitions away from a petroleum-based economy to a more sustainable one. In The Chemical Transformations of C1 Compounds, an accomplished team of chemists delivers an in-depth overview of recent developments in the field of single-carbon chemistry. The three-volume book covers all major C1 sources, including carbon monoxide, carbon dioxide, methane, methanol, formic acid, formaldehyde, carbenes, C1 halides, and organometallics. The editors have included resources discussing the main reactions and transformations into feedstock chemicals of each of the major C1 compounds reviewed in dedicated chapters. Readers will discover cutting-edge material on organic transformations with MeNO2, DMF, DCM, methyl organometallic reagents, CCl4, CHCl3, and CHBr3, as well as recent achievements in cyanation reactions via cross-coupling. The book also offers: Thorough introductions to chemical transformations of CH4, methods of CH4 activation, chemical transformations of CH3OH and synthesis alkenes from CH3OH Comprehensive explorations of the carbonylation of MeOH, CH2O in organic synthesis, organic transformations of HCO2H, and hydrogen generation from HCO2H Practical discussions of the carbonylation of unsaturated bonds with heterogeneous and homogeneous catalysts, as well as the carbonylation of C(sp2)-X bonds and C(sp3)-X bonds In-depth examinations of carbonylative C-H bond activation and radical carbonylation Perfect for organic and catalytic chemists, The Chemical Transformations of C1 Compounds is also an ideal resource for industrial chemists, chemical engineers, and practitioners at energy supply companies.

Enantioselective Chemical Synthesis

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Author :
Publisher : Elsevier
ISBN 13 : 0128001518
Total Pages : 334 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Enantioselective Chemical Synthesis by : Elias J. Corey

Download or read book Enantioselective Chemical Synthesis written by Elias J. Corey and published by Elsevier. This book was released on 2013-10-23 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by world-renowned and best-selling experts, Nobel Laureate E. J. Corey and Laszlo Kurti, Enantioselective Chemical Synthesis offers an authoritative and comprehensive overview of the field's progress; the processes and tools for key formations; future development for complex, stereocontrolled (enantiomeric or diastereoisomeric) molecules; and valuable examples of multi-step syntheses. Utilizing a color-coded scheme to illustrate chemical transformations, Enantioselective Chemical Synthesis provides clear explanation and guidance through vital asymmetrical syntheses and insight into the next steps for the field. Researchers, professionals, and academics will benefit from this valuable, thorough, and unique resource. - In Part I, the authors present clearly, comprehensively and concisely the most useful enantioselective processes available to synthetic chemists. - Part II provides an extensive discussion of the most logical ways to apply these new enantioselective methods to the planning of syntheses of stereochemically complex molecules. This hitherto neglected area is essential for the advancement of enantioselective synthesis to a more rational and powerful level. - Part III describes in detail many reaction sequences which have been used successfully for the construction of a wide variety of complex target molecules - Clearly explains stereochemical synthesis in theory and practice - Provides a handy tool box for scientists wishing to understand and apply chiral chemical synthesis - Describes almost 50 real life examples of asymmetric synthesis in practice and examines how the chiral centers were introduced at key synthetic stages

Frontiers of Green Catalytic Selective Oxidations

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Publisher : Springer Nature
ISBN 13 : 9813297514
Total Pages : 298 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Frontiers of Green Catalytic Selective Oxidations by : Konstantin P. Bryliakov

Download or read book Frontiers of Green Catalytic Selective Oxidations written by Konstantin P. Bryliakov and published by Springer Nature. This book was released on 2019-10-02 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.

Modern Surface Organometallic Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527627103
Total Pages : 725 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Modern Surface Organometallic Chemistry by : Jean-Marie Basset

Download or read book Modern Surface Organometallic Chemistry written by Jean-Marie Basset and published by John Wiley & Sons. This book was released on 2009-07-10 with total page 725 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering everything from the basics to recent applications, this monograph represents an advanced overview of the field. Edited by internationally acclaimed experts respected throughout the community, the book is clearly divided into sections on fundamental and applied surface organometallic chemistry. Backed by numerous examples from the recent literature, this is a key reference for all chemists.

Solvents as Reagents in Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 352780563X
Total Pages : 740 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Solvents as Reagents in Organic Synthesis by : Xiao-Feng Wu

Download or read book Solvents as Reagents in Organic Synthesis written by Xiao-Feng Wu and published by John Wiley & Sons. This book was released on 2017-09-28 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations.

Deuterium

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Publisher : Elsevier
ISBN 13 : 0128110414
Total Pages : 132 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Deuterium by : Jaemoon Yang

Download or read book Deuterium written by Jaemoon Yang and published by Elsevier. This book was released on 2016-05-15 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: Deuterium: Discovery and Applications in Organic Chemistry provides a well-illustrated overview of the discovery of 2H or heavy hydrogen, the stable hydrogen isotope with both a proton and a neutron in its nucleus. The work introduces the isotope, its discovery, physical properties, nomenclature, and common compounds, also exploring its application in organic chemistry through classic and recent examples from literature. Finally, the book devotes one chapter to Deuterium in medicinal chemistry and the biological effects of Deuterium Oxide, better known as D2O. - Provides unique coverage not found elsewhere that is presented in an accessible, dedicated short work - Contains practical information and examples on the use of Deuterium (D or 2H, Heavy Hydrogen) in organic synthesis - Presents a detailed description of Deuterium's discovery and applications in the pharmaceutical industry

Enantioselective Titanium-catalysed Transformations

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Author :
Publisher : World Scientific
ISBN 13 : 1783268964
Total Pages : 278 pages
Book Rating : 4.7/5 (832 download)

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Book Synopsis Enantioselective Titanium-catalysed Transformations by : Helene Pellissier

Download or read book Enantioselective Titanium-catalysed Transformations written by Helene Pellissier and published by World Scientific. This book was released on 2016-01-15 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chiral titanium complexes are low-cost, low-toxicity and high-efficiency catalysts. Impressive progress on enantioselective titanium-catalysed transformations has been achieved in the past seven years, with exciting new discoveries ranging from basic reactions to novel methodologies. Despite this, the field has not been substantially reviewed since 2008.This book contains up to date research and covers all types of enantioselective transformations using chiral titanium catalysts. It illustrates the economic, health, and environmental benefits of chiral titanium catalysts, showing the types of highly enantioselective reactions that they are able to induce are unlimited.Work presented here is aimed at researchers in organic and catalytic chemistry, and has been carefully curated to encourage future research possibilities.

Enantioselective Homogeneous Supported Catalysis

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849733422
Total Pages : 301 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Enantioselective Homogeneous Supported Catalysis by : Radovan Sebesta

Download or read book Enantioselective Homogeneous Supported Catalysis written by Radovan Sebesta and published by Royal Society of Chemistry. This book was released on 2011-11-02 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: Immobilization of chiral catalysts is an important tool for improving overall efficiency of catalytic processes. However, heterogeneous catalysts often suffer from decreased activities and supported but still homogeneous catalysts can help overcome this issue. This book covers the most important concepts of homogeneous supported catalysis with an emphasis on enantioselective processes. It describes the state-of-the-art and latest developments in each area whilst critically evaluating the strengths and weaknesses of this important method. The book encompasses ionically-tagged catalysts, supported organocatalysts, supported ionic liquid phases, catalysis using soluble polymers, catalytic dendrimers, fluorous catalysts, water soluble catalysts and non-covalent immobilization methods. Potential developments and ideas for the future are also highlighted. There is a growing demand for effective and recyclable catalysts so this book, covering all the important methods in the field of supported homogeneous catalysis, will appeal to many researchers in academia and industry.

Organic Reaction Mechanisms 2004

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Publisher : John Wiley & Sons
ISBN 13 : 9780470066607
Total Pages : 712 pages
Book Rating : 4.0/5 (666 download)

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Book Synopsis Organic Reaction Mechanisms 2004 by : A. C. Knipe

Download or read book Organic Reaction Mechanisms 2004 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2008-05-23 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 40th annual volume in this highly successful and unique series surveying the advances in the understanding of organic reaction mechanisms. In every volume the content is divided in the different classes of organic reaction mechanisms, including: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Elimination Reactions Radical Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. As a new service to the reader all reaction mechanisms leading to stereospecific products are highlighted. This reflects the needs of the organic synthetic community with leads to chiral reactions.

Addition Reactions with Unsaturated Hydrocarbons

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 352780482X
Total Pages : 452 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Addition Reactions with Unsaturated Hydrocarbons by : Ruimao Hua

Download or read book Addition Reactions with Unsaturated Hydrocarbons written by Ruimao Hua and published by John Wiley & Sons. This book was released on 2022-02-28 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Addition Reactions with Unsaturated Hydrocarbons Provides comprehensive coverage of the atom-economic approach to functionalized molecules using unsaturated hydrocarbons as starting materials Unsaturated hydrocarbons have emerged as an important class of fundamental starting materials in organic synthesis. Synthetic methodologies incorporating unsaturated hydrocarbons continue to expand due to their numerous applications in the synthesis of a vast array of chemicals. Addition Reactions with Unsaturated Hydrocarbons presents an up-to-date overview of modern methods that utilize reactions of unsaturated hydrocarbons as building blocks of organic synthesis, covering the conceptual and practical knowledge required for designing atom-efficient reactions to synthesize functionalized molecules. This authoritative volume discusses homo-dimerization and cross-dimerization of alkynes and/or alkenes, synthesis of carbonyl compounds from the hydration of alkynes, cycloadditions of alkynes and alkenes for the synthesis of carbocycles and heterocycles, double functionalization of alkynes and alkenes by addition reactions of element-element bonds, and more. Summarizes the most recent developments in the reactions of unsaturated hydrocarbons Features more than 600 schemes describing typical reactions starting from unsaturated hydrocarbons Covers topics such as alkynylated reactions, addition and cycloaddition reactions of alkynes and alkenes, and carbonylation of alkynes and alkenes with carbon monoxide Includes examples of synthesis procedures of natural products involving alkyne transformation With comprehensive coverage of important reactions of unsaturated hydrocarbons, Addition Reactions with Unsaturated Hydrocarbons is a valuable resource for organic chemists, pharmaceutical chemists, and biochemists in both academia and industry as well as an excellent reference text for graduate students in relevant areas of chemistry.