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Chemistry Of Transuranium Elements In Salt Base Repository
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Book Synopsis Chemistry of Transuranium Elements in Salt-base Repository by :
Download or read book Chemistry of Transuranium Elements in Salt-base Repository written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The mobility and potential release of actinides into the accessible environment continues to be the key performance assessment concern of nuclear repositories. Actinide, in particular plutonium speciation under the wide range of conditions that can exist in the subsurface is complex and depends strongly on the coupled effects of redox conditions, inorganic/organic complexation, and the extent/nature of aggregation. Understanding the key factors that define the potential for actinide migration is, in this context, an essential and critical part of making and sustaining a licensing case for a nuclear repository. Herein we report on recent progress in a concurrent modeling and experimental study to determine the speciation of plutonium, uranium and americium in high ionic strength Na-CI-Mg brines. This is being done as part of the ongomg recertification effort m the Waste Isolation Pilot Plant (WIPP). The oxidation-state specific solubility of actinides were established in brine as function of pC{sub H+}, brine composition and the presence and absence of organic chelating agents and carbonate. An oxidation-state invariant analog approach using Nd{sup 3+} and Th{sup 4+} was used for An{sup 3+} and An{sup 4+} respectively. These results show that organic ligands and hydrolysis are key factors for An(III) solubility, hydrolysis at pC{sub H+} above 8 is predominate for An(IV) and carbonates are the key factor for U(VI) solubility. The effect of high ionic strength and brine components measured in absence of carbonates leads to measurable increased in overall solubility over analogous low ionic strength groundwater. Less is known about the bioreduction of actinides by halo-tolerant microorganisms, but there is now evidence that bioreduction does occur and is analogous, in many ways, to what occurs with soil bacteria. Results of solubility studies that focus on Pitzer parameter corrections, new species (e.g. borate complexation), and the thermodynamic parameters for modeling are discussed.
Book Synopsis Proceedings of the Moscow Symposium on the Chemistry of Transuranium Elements by : V. I. Spitsyn
Download or read book Proceedings of the Moscow Symposium on the Chemistry of Transuranium Elements written by V. I. Spitsyn and published by Elsevier. This book was released on 2018-03-06 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the Moscow Symposium on the Chemistry of Transuranium Elements
Book Synopsis The Transuranium Elements by : Glenn Theodore Seaborg
Download or read book The Transuranium Elements written by Glenn Theodore Seaborg and published by . This book was released on 1946 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Transuranium Elements by : V. I. Gol danskii
Download or read book The Transuranium Elements written by V. I. Gol danskii and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nearly three years have passed since the publication of the original Russian edition, in which time there have appeared various papers on recent research on the transuranium elements, of which the most notable concern the production of element 105 at Dubna and Berkeley. There has also been much fresh information on elements 104 (kurchatovium) and 103 (lawrencium). Our knowledge of shell effects in the fission barrier has been extended. Hopes of finding relatively stable superheavy elements have stimulated searches for such elements in nature as well as rapid development in heavy ion acceleration. We may see some very considerable discoveries in the next few years. The new results vary in reliability, and so it is not surprising that some papers on the properties of the heaviest elements have given rise to vigorous debates, whose value lies in the way they ad vance the subject. We have not attempted to give an exhaustive survey of recent papers and have merely added brief sections to reflect what we con sider to be the most important points from these. So far, the United states and the USSR have made the most considerable contributions to the synthesis, study, and use of the transuranium elements, so it is especially welcome to us that this book, first published in our country, should now appear in the USA in an English translation.
Book Synopsis The Transuranium Elements by : Glenn Theodore Seaborg
Download or read book The Transuranium Elements written by Glenn Theodore Seaborg and published by . This book was released on 1949 with total page 896 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Elements Beyond Uranium by : Glenn T. Seaborg
Download or read book The Elements Beyond Uranium written by Glenn T. Seaborg and published by John Wiley & Sons. This book was released on 1991-01-16 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by Glenn T. Seaborg, Nobel Laureate and pre-eminent figure in the field, with the assistance of Walter D. Loveland, it covers all aspects of transuranium elements, including their discovery, chemical properties, nuclear properties, nuclear synthesis reactions, experimental techniques, natural occurrence, superheavy elements, and predictions for the future. Published on the fiftieth anniversary of the discovery of transuranium elements, it conveys the essence of the ideas and distinctive blend of theory and experiment that has marked their study.
Book Synopsis Transuranium Elements by : Lester R. Morss
Download or read book Transuranium Elements written by Lester R. Morss and published by . This book was released on 1992 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Papers from an international symposium to commemorate the discovery of transuranium elements, held at the 200th ACS National Meeting in Washington, DC, August 1990. Many of the pioneers of transuranium research in the 1940s present papers in a section devoted to historical viewpoints. Contemporary research is addressed with articles in the areas of: spectroscopy, photophysics, and photochemistry; chemistry; separations and thermodynamics; nuclear physics and chemistry; materials physics; materials chemistry; and analytical/chemistry. Acidic paper. Annotation copyrighted by Book News, Inc., Portland, OR
Book Synopsis The Chemistry of the Transuranium Elements by : Cornelius Keller
Download or read book The Chemistry of the Transuranium Elements written by Cornelius Keller and published by Wiley-VCH. This book was released on 1971-01-01 with total page 675 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transuranium People, The: The Inside Story by : Darleane C Hoffman
Download or read book Transuranium People, The: The Inside Story written by Darleane C Hoffman and published by World Scientific. This book was released on 2000-01-21 with total page 563 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this highly interesting book, three pioneering investigators provide an account of the discovery and investigation of the nuclear and chemical properties of the twenty presently known transuranium elements. The neutron irradiation of uranium led to the discovery of nuclear fission in 1938 and then to the first transuranium element, neptunium (atomic number 93), in 1940. Plutonium (94) quickly followed and the next nine elements completed the actinide series by 1961. Investigation of the chemical properties of the actinides was followed more recently by chemical studies of the first three transactinides — rutherfordium (104), hahnium (105), and seaborgium (106). Recent discoveries have extended the known elements to 112./a
Book Synopsis Chemistry of Transuranium Elements by :
Download or read book Chemistry of Transuranium Elements written by and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transuranium Elements by : Glenn Theodore Seaborg
Download or read book Transuranium Elements written by Glenn Theodore Seaborg and published by Hutchinson Ross Publishing Company. This book was released on 1978 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Transuranium Elements--the Mendeleev Centennial by :
Download or read book The Transuranium Elements--the Mendeleev Centennial written by and published by . This book was released on 1970 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthetic Transuranium Elements by : Earl K. Hyde
Download or read book Synthetic Transuranium Elements written by Earl K. Hyde and published by . This book was released on 1964 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Complex Compounds of Transuranium Elements by : Anna D. Gelʹman
Download or read book Complex Compounds of Transuranium Elements written by Anna D. Gelʹman and published by . This book was released on 1962 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemistry of Transuranium Elements by : Joseph Jacob Katz
Download or read book Chemistry of Transuranium Elements written by Joseph Jacob Katz and published by . This book was released on 1976 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Transuranium Elements by : Glenn Theodore Seaborg
Download or read book The Transuranium Elements written by Glenn Theodore Seaborg and published by . This book was released on 2003-01-01 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Selected Topics, Transuranium Elements in the General Environment by :
Download or read book Selected Topics, Transuranium Elements in the General Environment written by and published by . This book was released on 1978 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:
