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Chemistry Of Lower Valent Actinide Halides Final Report
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Book Synopsis Chemistry of Lower Valent Actinide Halides. Final Report by :
Download or read book Chemistry of Lower Valent Actinide Halides. Final Report written by and published by . This book was released on 1992 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research effort was concerned almost entirely with the first two members of the actinide series, thorium and uranium, although the work was later extended to some aspects of the neptunium-fluorine system in a collaborative program with Los Alamos National Laboratory. Detailed information about the lighter actinides will be helpful in modeling the properties of the heavier actinide compounds, which will be much more difficult to study experimentally. In this program, thermochemical information was obtained from high temperature equilibrium measurements made by effusion-beam mass spectrometry and by effusion-pressure techniques. Data were derived primarily from second-law analysis so as to avoid potential errors in third-law calculations resulting from uncertainties in spectroscopic and molecular constants. This approach has the additional advantage of yielding reaction entropies that can be checked for consistency with various molecular constant assignments for the species involved. In the U-F, U-Cl, and U-Br systems, all of the gaseous species UX, UX2, UX3, UX4, and UX5, where X represents the halogen, were identified and characterized; the corresponding species ThX, ThX2, ThX3, and ThX4 were studied in the Th-F, Th-Cl, and Th-Br systems. A number of oxyhalide species in the systems U-0-F, U-0-Cl, Th-0-F, and Th-O-Cl were studied thermochemically. Additionally, the sublimation thermodynamics of NpF4(s) and NpO2F2(s) were studied by mass spectrometry.
Book Synopsis Chemistry of Lower Valent Actinide Halides by :
Download or read book Chemistry of Lower Valent Actinide Halides written by and published by . This book was released on 1992 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research effort was concerned almost entirely with the first two members of the actinide series, thorium and uranium, although the work was later extended to some aspects of the neptunium-fluorine system in a collaborative program with Los Alamos National Laboratory. Detailed information about the lighter actinides will be helpful in modeling the properties of the heavier actinide compounds, which will be much more difficult to study experimentally. In this program, thermochemical information was obtained from high temperature equilibrium measurements made by effusion-beam mass spectrometry and by effusion-pressure techniques. Data were derived primarily from second-law analysis so as to avoid potential errors in third-law calculations resulting from uncertainties in spectroscopic and molecular constants. This approach has the additional advantage of yielding reaction entropies that can be checked for consistency with various molecular constant assignments for the species involved. In the U-F, U-Cl, and U-Br systems, all of the gaseous species UX, UX2, UX3, UX4, and UX5, where X represents the halogen, were identified and characterized; the corresponding species ThX, ThX2, ThX3, and ThX4 were studied in the Th-F, Th-Cl, and Th-Br systems. A number of oxyhalide species in the systems U-0-F, U-0-Cl, Th-0-F, and Th-O-Cl were studied thermochemically. Additionally, the sublimation thermodynamics of NpF4(s) and NpO2F2(s) were studied by mass spectrometry.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1993 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book ERDA Energy Research Abstracts written by and published by . This book was released on 1989 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1993 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Government reports annual index by :
Download or read book Government reports annual index written by and published by . This book was released on 199? with total page 1362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Government Reports Announcements & Index by :
Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1993 with total page 1258 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book INIS Atomindex written by and published by . This book was released on 1987 with total page 1136 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1988 with total page 908 pages. Available in PDF, EPUB and Kindle. Book excerpt: Includes all works deriving from DOE, other related government-sponsored information and foreign nonnuclear information.
Author :United States. Congress. House. Committee on Science and Technology. Subcommittee on Energy Development and Applications Publisher : ISBN 13 : Total Pages :1160 pages Book Rating :4.:/5 (319 download)
Book Synopsis Fiscal Year 1986 Department of Energy Authorization (basic Research Programs) by : United States. Congress. House. Committee on Science and Technology. Subcommittee on Energy Development and Applications
Download or read book Fiscal Year 1986 Department of Energy Authorization (basic Research Programs) written by United States. Congress. House. Committee on Science and Technology. Subcommittee on Energy Development and Applications and published by . This book was released on 1985 with total page 1160 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mass Spectrometry Bulletin written by and published by . This book was released on 1994 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) by : L.R. Morss
Download or read book The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2010-10-21 with total page 4511 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts. The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements contain partially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.
Book Synopsis The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) by : L.R. Morss
Download or read book The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2007-12-31 with total page 4059 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.
Book Synopsis Government Reports Annual Index: Keyword A-L by :
Download or read book Government Reports Annual Index: Keyword A-L written by and published by . This book was released on 1984 with total page 1092 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemistry of the Actinide Elements by : G.T. Seaborg
Download or read book The Chemistry of the Actinide Elements written by G.T. Seaborg and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 905 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first edition of this work appeared almost thirty years ago, when, as we can see in retrospect, the study of the actinide elements was in its first bloom. Although the broad features of the chemistry of the actinide elements were by then quite well delineated, the treatment of the subject in the first edition was of necessity largely descriptive in nature. A detailed understanding of the chemical consequences of the characteristic presence of Sf electrons in most of the members of the actinide series was still for the future, and many of the systematic features of the actinide elements were only dimly apprehended. In the past thirty years all this has changed. The application of new spectroscopic techniques, which came into general use during this period, and new theoretical insights, which came from a better understanding of chemical bonding, inorganic chemistry, and solid state phenomena, were among the important factors that led to a great expansion and maturation in actinide element research and a large number of new and important findings. The first edition consisted of a serial description of the individual actinide elements, with a single chapter devoted to the six heaviest elements (lawrencium, the heaviest actinide, was yet to be discovered). Less than 15 % of the text was devoted to a consideration of the systematics of the actinide elements.
Book Synopsis Government Reports Annual Index: Corporate author by :
Download or read book Government Reports Annual Index: Corporate author written by and published by . This book was released on 1987 with total page 1028 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Radiochemistry and Nuclear Chemistry - Volume II by : Sandor Nagy
Download or read book Radiochemistry and Nuclear Chemistry - Volume II written by Sandor Nagy and published by EOLSS Publications. This book was released on 2009-08-24 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radiochemistry and Nuclear Chemistry theme is a component of Encyclopedia of Chemical Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. The content of the Theme on Radiochemistry and Nuclear Chemistry provides the essential aspects and a myriad of issues of great relevance to our world such as: Isotope Effects, Isotope Separation and Isotope Fractionation; Radiometric Dating and Tracing; Radiochemical Techniques; Radionuclides in Chemical Research; Nuclear Methods in Material Research; Radiation Chemistry; Radiation Biology and Radiation Protection; Radiochemistry and Radiopharmaceutical Chemistry for Medicine; Chemistry of the Actinide Elements; Production And Chemistry Of Transactinide Elements; Nuclear Waste Management and the Nuclear Fuel Cycle; High-intensity Lasers in Nuclear Science; Nuclear Forensics; Nuclear Processes in Nature; Subatomic Particles, Nuclear Structure and Stability. These two volumes are aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs.
