An investigation into the chemical speciation of technetium in the environment

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)

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Book Synopsis An investigation into the chemical speciation of technetium in the environment by : S. Nicholson

Download or read book An investigation into the chemical speciation of technetium in the environment written by S. Nicholson and published by . This book was released on 1990 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The chemical speciation of technetium in the environment

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (597 download)

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Book Synopsis The chemical speciation of technetium in the environment by : S. T. Sparkes

Download or read book The chemical speciation of technetium in the environment written by S. T. Sparkes and published by . This book was released on 1987 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Technetium in the Environment

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Publisher : Springer Science & Business Media
ISBN 13 : 9400941897
Total Pages : 416 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Technetium in the Environment by : G. Desmet

Download or read book Technetium in the Environment written by G. Desmet and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of technetium (in 1937, by Perrier and Segre), technetium-99 and technetium-99m have become most familiar in the specialised literature, the behaviour of the former being of concern regarding its health impact, the latter having been used intensively in medical tests for many years. The knowledge of the characteristics and behaviour of this element in nature is currently increasing exponentially. It has become clear, however, that there is still a serious shortage of information needed to assess properly its burden and impact on man and his environment. Technetium may indeed be released from nuclear installations or as a waste product from medical applications. It is generally considered to be highly mobile as the anion TcOi, but it is also suspected to be readily reduced in soils and metabolised in living beings into lower oxidation states. The seminar was planned to analyse thoroughly the experimental results obtained up to now and to make recommendations of specific issues requiring further research. This book presents the papers of the different sessions in the order of presentation, and the conclusions drawn by three discussion groups which dealt separately with: problems of sources and distribution of man-made technetium and its radiological consequences; the chemical behaviour of technetium in different ecosystems; biochemical reactions and binding with macromolecules in various life systems. vi Preface The editors, together with the Programme Committee of the Seminar, wish to express their gratitude to the chairmen of the different sessions for their summary of the group discussions.

The Chemical Speciation of Technetium in the Environment

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ISBN 13 : 9780705810296
Total Pages : 30 pages
Book Rating : 4.8/5 (12 download)

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Book Synopsis The Chemical Speciation of Technetium in the Environment by : S. T. Sparkes

Download or read book The Chemical Speciation of Technetium in the Environment written by S. T. Sparkes and published by . This book was released on 1987 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt:

הקשר בין יציבות לחומרים אנטיביוטיים ובין אלימות אצל חידקי KLEBSIELLA

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (144 download)

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Book Synopsis הקשר בין יציבות לחומרים אנטיביוטיים ובין אלימות אצל חידקי KLEBSIELLA by :

Download or read book הקשר בין יציבות לחומרים אנטיביוטיים ובין אלימות אצל חידקי KLEBSIELLA written by and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Research Program to Investigate the Fundamental Chemistry of Technetium

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ISBN 13 :
Total Pages : 3 pages
Book Rating : 4.:/5 (685 download)

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Book Synopsis Research Program to Investigate the Fundamental Chemistry of Technetium by :

Download or read book Research Program to Investigate the Fundamental Chemistry of Technetium written by and published by . This book was released on 2004 with total page 3 pages. Available in PDF, EPUB and Kindle. Book excerpt: Technetium (99Tc, half-life = 2.13 x 105 years,?-emitter) is one of the radionuclides of major concern for nuclear waste disposal. This concern is due to the long half-life of 99Tc, the ease with which pertechnetate, TcO4−, migrates in the geosphere, difficulties in incorporating technetium into glass waste forms, and the corresponding regulatory considerations. The problem of mobility of pertechnetate in the environment is compounded by the fact that pertechnetate is the thermodynamically stable form of technetium in oxidizing environments. These factors present challenges for the separation and immobilization of technetium. The objective of this research project is to provide new knowledge about the chemical behavior of technetium so that the factors underlying technetium speciation in nuclear waste and in waste forms can be understood and the problems can be addressed. In particular, the behavior of technetium and rhenium in glass will be examined since rhenium is ofte n used as a non-radioactive surrogate to predict the behavior of technetium. In this project, glasses containing both rhenium and technetium will be prepared, so that the behavior of both metals can be compared under identical conditions.

Energy Research Abstracts

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ISBN 13 :
Total Pages : 782 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1995 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Speciation in the Environment

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Publisher : John Wiley & Sons
ISBN 13 : 140514730X
Total Pages : 472 pages
Book Rating : 4.4/5 (51 download)

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Book Synopsis Chemical Speciation in the Environment by : A. M. Ure

Download or read book Chemical Speciation in the Environment written by A. M. Ure and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Considerable recent research has focused on the topic of chemical speciation in the environment. It is increasingly realised that the distribution, mobility and biological availability of chemical elements depend not simply on their concentrations but, critically, on the forms in which they occur in natural systems. Continuing developments in analytical chemistry have made speciation practicable even where analytes are present at trace levels (as is often the case in natural samples). In the second edition of this book, the expertise of scientists involved in chemical speciation in various fields have been brought together to provide an overview of the current status of speciation science and indicate how the field may develop in the future.

Government Publications

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ISBN 13 :
Total Pages : 120 pages
Book Rating : 4.3/5 (243 download)

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Book Synopsis Government Publications by : Great Britain. Her Majesty's Stationery Office

Download or read book Government Publications written by Great Britain. Her Majesty's Stationery Office and published by . This book was released on 1993 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Stobwasser's Bilderkabinet in Berlin

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ISBN 13 : 9780795903571
Total Pages : 52 pages
Book Rating : 4.9/5 (35 download)

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Book Synopsis Stobwasser's Bilderkabinet in Berlin by :

Download or read book Stobwasser's Bilderkabinet in Berlin written by and published by . This book was released on 1986 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Research Program to Investigate the Fundamental Chemistry of Technetium. 1998 Annual Progress Report

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ISBN 13 :
Total Pages : 3 pages
Book Rating : 4.:/5 (871 download)

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Book Synopsis Research Program to Investigate the Fundamental Chemistry of Technetium. 1998 Annual Progress Report by :

Download or read book Research Program to Investigate the Fundamental Chemistry of Technetium. 1998 Annual Progress Report written by and published by . This book was released on 1998 with total page 3 pages. Available in PDF, EPUB and Kindle. Book excerpt: Technetium (99Tc, [beta] emitter, half-life 2.1 x 105 years, spA= 1.7 x 10−2 Ci/g) is one of the radionuclides of major concern because of regulatory considerations for radioactive waste disposal. The propensity of Tc as pertechnetate, TcO4−, to migrate in the geosphere necessitates its safe, long-term immobilization. Technetium is found in the nuclear waste storage tanks at the Hanford and at the Savannah River sites in highly alkaline environments along with multi-molar concentrations of nitrate, nitrite, and Na ions and lesser amounts of organic complexants, phosphate, sulfate chloride, fluoride, and carbonate. It has been assumed that technetium is present in the waste tanks as the pertechnetate ion but a recent study has suggested that at least in part, technetium is present in another form. There is a lack of information on Tc chemistry in oxidation states III-V with simple inorganic (OH−, CO32−, PO43−, SiO44−) and common organic ligands (EDTA, citrate, oxalate) under alkaline conditions. This is essential information needed for pretreatment schemes, processing, and the assessment of stability of Tc in waste form materials. Further complicating the Tc waste tank chemistry is the added effect of an intense radiation field originating from 137Cs and 9°Sr. The interactions of the ionizing radiation with water, nitrate, nitrite, and other minor components create highly reactive species that can strongly perturb the oxidation-reduction conditions. The stability of Tc in waste form materials is of paramount importance for long term storage concerns and the solid state chemical properties of many candidate Tc compounds are unknown. There have been few systematic studies of Tc stability in lower valent solids with the exception of TcO2. Thus, it is not possible at present to assess the long term stability of many Tc compounds relevant to proposed waste form materials. This experimental research program addresses the characterization of the chemistry of technetium pertinent to the waste tank environment and to various waste forms. The solution and solid state chemistry of this element will be studied in aqueous solutions as a function of pH with the various salts added such as nitrate and nitrite, and as a function of radiation dose. The second part of this program is a search for stable, lower valent Tc materials which may prove useful for waste storage. This report summarizes the results after nine months of a three year project.

The Importance of Chemical “Speciation” in Environmental Processes

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Publisher : Springer Science & Business Media
ISBN 13 : 3642704417
Total Pages : 758 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis The Importance of Chemical “Speciation” in Environmental Processes by : M. Bernhard

Download or read book The Importance of Chemical “Speciation” in Environmental Processes written by M. Bernhard and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Report, the editors replaced the term "speciation" wherever it occurred by "identification and quantification," or "description of abundance," or "reactivity," or "transformation" of a chemical species, according to whichever one of the four meanings the author had evidently meant to convey. In line with the Dahlem Workshop Model, this Report comprises the background papers written in advance of the meeting on the current status of problems in environmental research and on advanced analytical tech niques for the identification and quantification of chemical species, as well as the group reports summarizing the results of the discussions held during the meeting. Each group report was prepared during the meeting by one "rapporteur" with the help of members of that group and finalized by the rapporteur (listed as the first author of the group report) after the meeting, taking into account both verbal comments made during the presentation of the reports in the plenary session at the end of the workshop and written comments received afterwards.

Technetium

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Publisher : Wiley-VCH
ISBN 13 : 9783527294961
Total Pages : 0 pages
Book Rating : 4.2/5 (949 download)

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Book Synopsis Technetium by : Klaus Schwochau

Download or read book Technetium written by Klaus Schwochau and published by Wiley-VCH. This book was released on 2000-04-13 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Klaus Schwochau Technetium Chemistry and Radiopharmaceutical Applications This unique handbook provides a comprehensive survey of the present status of Technetium chemistry and its radiopharmaceutical applications. All Technetium aspects such as natural and artificial occurence in the environment, isotopes and isomers, analytical chemistry and electrochemistry, thermodynamic data, stability and reactivity, intermetallic and binary compounds, and predominantly complex chemistry, and radiopharmacy are presented in an clear and precise manner. This outstanding presentation allows both experts and non-experts a quick access to the subject. Therefore this handbook is an indispensable reference for researchers at universities and research centers, in the nuclear mdecine and radiopharmaceutical industries as well as consultants in government and environmental agencies.

Beteckningar och symboler för styranläggningar inom VVS-tekniken

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ISBN 13 :
Total Pages : 31 pages
Book Rating : 4.:/5 (185 download)

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Book Synopsis Beteckningar och symboler för styranläggningar inom VVS-tekniken by :

Download or read book Beteckningar och symboler för styranläggningar inom VVS-tekniken written by and published by . This book was released on 1969 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt:

British Reports, Translations and Theses

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ISBN 13 :
Total Pages : 592 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis British Reports, Translations and Theses by : British Library. Document Supply Centre

Download or read book British Reports, Translations and Theses written by British Library. Document Supply Centre and published by . This book was released on 1991 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Review of the Final Draft Analysis of Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation

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Publisher : National Academies Press
ISBN 13 : 0309495210
Total Pages : 81 pages
Book Rating : 4.3/5 (94 download)

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Book Synopsis Review of the Final Draft Analysis of Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation by : National Academies of Sciences, Engineering, and Medicine

Download or read book Review of the Final Draft Analysis of Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-09-15 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1943, as part of the Manhattan Project, the Hanford Nuclear Reservation was established with the mission to produce plutonium for nuclear weapons. During 45 years of operations, the Hanford Site produced about 67 metric tonnes of plutoniumâ€"approximately two-thirds of the nation's stockpile. Production processes generated radioactive and other hazardous wastes and resulted in airborne, surface, subsurface, and groundwater contamination. Presently, 177 underground tanks contain collectively about 210 million liters (about 56 million gallons) of waste. The chemically complex and diverse waste is difficult to manage and dispose of safely. Section 3134 of the National Defense Authorization Act for Fiscal Year 2017 calls for a Federally Funded Research and Development Center (FFRDC) to conduct an analysis of approaches for treating the portion of low-activity waste at the Hanford Nuclear Reservation intended for supplemental treatment. The third of four, this report provides an overall assessment of the FFRDC team's final draft report, dated April 5, 2019.

Final Review of the Study on Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation

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Publisher : National Academies Press
ISBN 13 : 0309672910
Total Pages : 131 pages
Book Rating : 4.3/5 (96 download)

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Book Synopsis Final Review of the Study on Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation by : National Academies of Sciences, Engineering, and Medicine

Download or read book Final Review of the Study on Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2020-03-30 with total page 131 pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. Department of Energy's Office of Environmental Management is responsible for managing and cleaning up the waste and contamination at the Hanford Nuclear Reservation, the nation's biggest and most complex nuclear cleanup challenge. At the site, 177 underground tanks collectively contain about 211 million liters of waste that includes high-activity and low-activity materials. At the request of Congress, Final Review of the Study on Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation: Review #4 focuses on approaches for treatment and disposal of the supplemental portion of the low-activity waste from the tanks. This review report discusses developments since the publication of Review #3 and provides a summary of public comments on the third committee review report. The authoring committee then shares their views on these comments and whether they change any of the findings or recommendations in the third review report.