Water-in-oil Microemulsions as Soft-templates to Mediate Nanoparticle Interfacial Assembly Into Hybrid Nanostructures

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Water-in-oil Microemulsions as Soft-templates to Mediate Nanoparticle Interfacial Assembly Into Hybrid Nanostructures by : Rebeca Fortes Martín

Download or read book Water-in-oil Microemulsions as Soft-templates to Mediate Nanoparticle Interfacial Assembly Into Hybrid Nanostructures written by Rebeca Fortes Martín and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hybrid nanomaterials offer the combination of individual properties of different types of nanoparticles. Some strategies for the development of new nanostructures in larger scale rely on the self-assembly of nanoparticles as a bottom-up approach. The use of templates provides ordered assemblies in defined patterns. In a typical soft-template, nanoparticles and other surface-active agents are incorporated into non-miscible liquids. The resulting self-organized dispersions will mediate nanoparticle interactions to control the subsequent self-assembly. Especially interactions between nanoparticles of very different dispersibility and functionality can be directed at a liquid-liquid interface. In this project, water-in-oil microemulsions were formulated from quasi-ternary mixtures with Aerosol-OT as surfactant. Oleyl-capped superparamagnetic iron oxide and/or silver nanoparticles were incorporated in the continuous organic phase, while polyethyleneimine-stabilized gold nanoparticles were confined in the dispersed water droplets. Each ...

Microemulsion

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Publisher : BoD – Books on Demand
ISBN 13 : 1789845017
Total Pages : 148 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Microemulsion by : Juan Mejuto

Download or read book Microemulsion written by Juan Mejuto and published by BoD – Books on Demand. This book was released on 2019-09-18 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to provide readers with some of the current trends in microemulsions as scalable chemical nanoreactors. The chapters include discussions on microemulsions as reaction media, taking advantage of both the special behavior of trapped water inside their microdroplets and their potential use as a template for nanomaterials. The information contained in this book covers topics that will be of interest to students and researchers in physical chemistry, chemical engineering, and material science. In addition, this book will serve as a tribute in memoriam to Prof. Julio Casado, Professor of Physical Chemistry at the Universities of Santiago de Compostela and Salamanca and Doctor Honoris Causa from the University of Vigo, who died on April 2, 2018. Sit tibi terra levis.

Microemulsions Theory and Practice

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Publisher : Elsevier
ISBN 13 : 0323160409
Total Pages : 192 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Microemulsions Theory and Practice by : Leon Prince

Download or read book Microemulsions Theory and Practice written by Leon Prince and published by Elsevier. This book was released on 2012-12-02 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microemulsions: Theory and Practice covers the development of the theory and practice of microemulsion systems. This book is divided into seven chapters that explore the physics and chemistry of microemulsions. This book deals first with the commercial history of microemulsions, from the discovery of carnauba wax emulsions to polymer emulsions. This topic is followed by discussions on the theoretical aspects of microemulsion formulation techniques and the design of other products. The subsequent chapter describes the microemulsion formulation with less solubilizer or emulsifier together with their optical properties. A chapter examines the mixed film theory that explains the dispersions, oil-water interface, and inferences in microemulsions. Another chapter considers the role of microemulsions in micellar solutions and their relations to the concentrations of different compounds. This chapter also looks into the association phenomena of three-component phase equilibria diagrams and liquids crystals to microemulsions. The concluding chapter discusses the role of the capillary and hydrostatic forces on the entrapment of oil in the reservoir and the necessary conditions for the displacement of entrapped oil. The important properties and economic aspects of a microemulsion slug required for the tertiary oil recovery are also covered in this chapter.

Industrial Applications of Microemulsions

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Publisher : CRC Press
ISBN 13 : 9780824797959
Total Pages : 424 pages
Book Rating : 4.7/5 (979 download)

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Book Synopsis Industrial Applications of Microemulsions by : Conxita Solans

Download or read book Industrial Applications of Microemulsions written by Conxita Solans and published by CRC Press. This book was released on 1996-11-27 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Fills a void in the literature by presenting the basic concepts of microemulsions, essential to understanding their industrial significance, and comprehensive descriptions of the most useful commerical applications. Discusses important issues related to enzymatic reactions and nanoparticle formation. Charts the enormous advances that have occurred in the field over the past decade."

Ethyl Cellulose Nanoparticles in Multiphase Systems

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Publisher :
ISBN 13 :
Total Pages : 150 pages
Book Rating : 4.:/5 (1 download)

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Book Synopsis Ethyl Cellulose Nanoparticles in Multiphase Systems by : Navid Bizmark

Download or read book Ethyl Cellulose Nanoparticles in Multiphase Systems written by Navid Bizmark and published by . This book was released on 2017 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption-mediated self-assembly of ethyl cellulose (EC) nanoparticles at fluid interfaces, driven by reduction in interfacial energy, is shown to lead to stabilization of emulsions and foams. A multiscale approach is followed to address a number of fundamental and practical questions for application of EC nanoparticles in multiphase flows through porous media. At the nanoscale, the effects of pair interactions between EC nanoparticles suspended in water, between an EC nanoparticle and a fluid interface (oil-water or air-water), and between EC nanoparticles adsorbed at a fluid interface are studied by extended-DLVO computations and dynamic surface (interfacial) tension measurements with emphasis on - the dependence of colloidal suspension stability on ionic strength - the kinetics of nanoparticle adsorption at the air-water and alkane-water interfaces - the nature and extent of coverage of fluid interfaces by nanoparticles In the absence of salt, EC nanoparticle suspensions are stable at neutral pH as a result of electrostatic repulsion, but colloidal stability is lost by the addition of salt at or beyond a concentration of 0.05 M (the critical coagulation concentration or CCC). Regardless of ionic strength, however, hydrophobic attraction dominates the interactions between EC nanoparticles and fluid interfaces, resulting in barrier-less irreversible adsorption at both the air-water and alkane-water interfaces. Ionic strength is also found to have insignificant effect on the coverage of either kind of interface at steady-state, which approaches the jamming limit of 91% corresponding to a tight hexagonal packing for any value of the ionic strength in the range of 0 M to 0.1 M. Nonetheless, subtle effects of the ionic strength are observed on the rate of approach to steady state, during the later stages of adsorption, which is accelerated by the addition of salt in the case of the alkane-water interface, but apparently unaffected in the case of the air-water interface. Above the CCC, alkane-water and air-water interfaces behave similarly, in that the approach to steady state is decelerated as a result of increased surface blocking and competition for adsorbing species between coagulation in the bulk and attachment at the interface. These findings lead to new insights into the way in which EC nanoparticles stabilize emulsions and foams. The extent to which EC nanoparticles may be used to stabilize so-called Pickering emulsions is investigated as a function of phase volume ratio, ionic strength and nanoparticle concentration. Both oil-in-water (O/W) and water-in-oil (W/O) Pickering emulsions are observed, their stability is quantified and explained theoretically. The most stable O/W Pickering emulsion is obtained at an ionic strength slightly below the CCC with at least 70% volume fraction for the internal phase, an observation which opens the path for the utilization of EC nanoparticles as stabilizers of high internal phase Pickering emulsions (HIPPE). Such a HIPPE is shown to act as a template to fabricate a polymeric porous material made of EC. This material is demonstrated to selectively adsorb oil from the surface of water, suggesting potential applications in the field of oil-water separations. In line with theoretical expectation, flow and transport tests in transparent glass micromodels demonstrate that EC nanoparticles in stable colloidal suspensions (i.e., below CCC) move through silica-based porous media as a conservative tracer (e.g. NaCl). The convection-dispersion equation adequately describes this process with transport parameter (dispersivity and dispersion coefficient) values which agree with established models. Above the CCC convection accelerates the coagulation of EC nanoparticles, resulting in very rapid clogging of the porous medium and effective filtration of the nanoparticles. Lastly, it is demonstrated that foam can be generated in situ during the co-injection of gas and EC nanoparticle suspensions in glass micromodels, suggesting the possibility to engineer new foam flooding technologies for the recovery of hydrocarbons from subsurface porous media.

Nanoemulsions

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Publisher : Academic Press
ISBN 13 : 0128118393
Total Pages : 665 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Nanoemulsions by : Seid Mahdi Jafari

Download or read book Nanoemulsions written by Seid Mahdi Jafari and published by Academic Press. This book was released on 2018-02-24 with total page 665 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoemulsions: Formulation, Applications, and Characterization provides detailed information on the production, application and characterization of food nanoemulsion as presented by experts who share a wealth of experience. Those involved in the nutraceutical, pharmaceutical and cosmetic industries will find this a useful reference as it addresses findings related to different preparation and formulation methods of nanoemulsions and their application in different fields and products. As the last decade has seen a major shift from conventional emulsification processes towards nanoemulsions that both increase the efficiency and stability of emulsions and improve targeted drug and nutraceutical delivery, this book is a timely resource. Summarizes general aspects of food nanoemulsions and their formulation Provides detailed information on the production, application, and characterization of food nanoemulsion Reveals the potential of nanoemulsions, as well as their novel applications in functional foods, nutraceutical products, delivery systems, and cosmetic formulations Explains preparation of nanoemulsions by both low- and high-energy methods

Bijels

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788015207
Total Pages : 266 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Bijels by : Paul S Clegg

Download or read book Bijels written by Paul S Clegg and published by Royal Society of Chemistry. This book was released on 2020-03-27 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bicontinuous interfacially jammed emulsion gels, now commonly termed 'bijels', are a class of soft materials, in which interpenetrating, continuous domains of two immiscible fluids are maintained in a rigid arrangement by a jammed layer of colloidal particles at their interface. Such gels have unusual material properties that promise exciting applications across diverse fields from energy materials and catalysis, to food science. This is the first book on the subject and provides the reader with a fundamental introduction. Edited by a recognised authority on bijels, the reader will learn about the bijel and its formation. Bringing together current understanding, this book aims to bring the potential application of bijels to diverse materials challenges closer to fruition. This is a must-have resource for anyone working in soft matter and applied fields.

Colloidal Particles at Liquid Interfaces

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Publisher : Cambridge University Press
ISBN 13 : 1139458183
Total Pages : 500 pages
Book Rating : 4.1/5 (394 download)

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Book Synopsis Colloidal Particles at Liquid Interfaces by : Bernard P. Binks

Download or read book Colloidal Particles at Liquid Interfaces written by Bernard P. Binks and published by Cambridge University Press. This book was released on 2006-08-17 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: The understanding of how small solid particles operate at liquid interfaces is minimal. This book brings together the topics actively being investigated, with contributions from experts in the field. It will be of interest to researchers in chemistry, physics, chemical engineering, pharmacy, food science and materials science.

Metal Nanoparticles in Microbiology

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Publisher : Springer Science & Business Media
ISBN 13 : 3642183123
Total Pages : 306 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Metal Nanoparticles in Microbiology by : Mahendra Rai

Download or read book Metal Nanoparticles in Microbiology written by Mahendra Rai and published by Springer Science & Business Media. This book was released on 2011-04-02 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Following an introduction to biogenic metal nanoparticles, this book presents how they can be biosynthesized using bacteria, fungi and yeast, as well as their potential applications in biomedicine. It is shown that the synthesis of nanoparticles using microbes is eco-friendly and results in reproducible metal nanoparticles of well-defined sizes, shapes and structures. This biotechnological approach based on the process of biomineralization exploits the effectiveness and flexibility of biological systems. Chapters include practical protocols for microbial synthesis of nanoparticles and microbial screening methods for isolating a specific nanoparticle producer as well as reviews on process optimization, industrial scale production, biomolecule-nanoparticle interactions, magnetosomes, silver nanoparticles and their numerous applications in medicine, and the application of gold nanoparticles in developing sensitive biosensors.

Anisotropic Particle Assemblies

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Publisher : Elsevier
ISBN 13 : 0128041099
Total Pages : 368 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Anisotropic Particle Assemblies by : Ning Wu

Download or read book Anisotropic Particle Assemblies written by Ning Wu and published by Elsevier. This book was released on 2018-07-12 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anisotropic Particle Assemblies: Synthesis, Assembly, Modeling, and Applications covers the synthesis, assembly, modeling, and applications of various types of anisotropic particles. Topics such as chemical synthesis and scalable fabrication of colloidal molecules, molecular mimetic self-assembly, directed assembly under external fields, theoretical and numerical multi-scale modeling, anisotropic materials with novel interfacial properties, and the applications of these topics in renewable energy, intelligent micro-machines, and biomedical fields are discussed in depth. Contributors to this book are internationally known experts who have been actively studying each of these subfields for many years.This book is an invaluable reference for researchers and chemical engineers who are working at the intersection of physics, chemistry, chemical engineering, and materials science and engineering. It educates students, trains the next generation of researchers, and stimulates continuous development in this rapidly emerging area for new materials and innovative technologies. Provides comprehensive coverage on new developments in anisotropic particles Features chapters written by emerging and leading experts in each of the subfields Contains information that will appeal to a broad spectrum of professionals, including but not limited to chemical engineers, chemists, physicists, and materials scientists and engineers Serves as both a reference book for researchers and a textbook for graduate students

Calcium Orthophosphates

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Publisher : CRC Press
ISBN 13 : 9814364177
Total Pages : 863 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis Calcium Orthophosphates by : Sergey V. Dorozhkin

Download or read book Calcium Orthophosphates written by Sergey V. Dorozhkin and published by CRC Press. This book was released on 2012-06-04 with total page 863 pages. Available in PDF, EPUB and Kindle. Book excerpt: Due to a great chemical similarity with the biological calcified tissues, many calcium orthophosphates possess remarkable biocompatibility and bioactivity. Materials scientists use this property extensively to construct artificial bone grafts that are either entirely made of or only surface-coated with the biologically relevant calcium orthophospha

Magnetic Nanoparticles in Biosensing and Medicine

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Publisher : Cambridge University Press
ISBN 13 : 1107031095
Total Pages : 317 pages
Book Rating : 4.1/5 (7 download)

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Book Synopsis Magnetic Nanoparticles in Biosensing and Medicine by : Nicholas J. Darton

Download or read book Magnetic Nanoparticles in Biosensing and Medicine written by Nicholas J. Darton and published by Cambridge University Press. This book was released on 2019-02-14 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: Drawing together topics from a wide range of disciplines, and featuring up-to-date examples of clinical usage and research applications, this text provides a comprehensive insight into the fundamentals of magnetic biosensors and the applications of magnetic nanoparticles in medicine.

Food Emulsions and Foams

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Publisher : Elsevier
ISBN 13 : 1845698304
Total Pages : 299 pages
Book Rating : 4.8/5 (456 download)

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Book Synopsis Food Emulsions and Foams by : E. Dickinson

Download or read book Food Emulsions and Foams written by E. Dickinson and published by Elsevier. This book was released on 1987-02-01 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text explains how properties of the system are affected by such factors as the crystallisation of the fat, the surface behaviour of the proteins, and presence of various small molecules and ions in the aqueous phase.

Metallic Nanoparticles

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Publisher : Elsevier
ISBN 13 : 0080559697
Total Pages : 402 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Metallic Nanoparticles by :

Download or read book Metallic Nanoparticles written by and published by Elsevier. This book was released on 2008-11-21 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metallic nanoparticles display fascinating properties that are quite different from those of individual atoms, surfaces or bulk rmaterials. They are a focus of interest for fundamental science and, because of their huge potential in nanotechnology, they are the subject of intense research effort in a range of disciplines. Applications, or potential applications, are diverse and interdisciplinary. They include, for example, use in biochemistry, in catalysis and as chemical and biological sensors, as systems for nanoelectronics and nanostructured magnetism (e.g. data storage devices), where the drive for further miniaturization provides tremendous technological challenges and, in medicine, there is interest in their potential as agents for drug delivery.The book describes the structure of metallic nanoparticles, the experimental and theoretical techniques by which this is determined, and the models employed to facilitate understanding. The various methods for the production of nanoparticles are outlined. It surveys the properties of clusters and the methods of characterisation, such as photoionization, optical spectroscopy, chemical reactivity and magnetic behaviour, and discusses element-specific information that can be extracted by synchrotron-based techniques such as EXAFS, XMCD and XMLD. The properties of clusters can vary depending on whether they are free, deposited on a surface or embedded in a matrix of another material; these issues are explored. Clusters on a surface can be formed by the diffusion and aggregation of atoms; ways of modelling these processes are described. Finally we look at nanotechnology and examine the science behind the potential of metallic nanoparticles in chemical synthesis, catalysis, the magnetic separation of biomolecules, the detection of DNA, the controlled release of molecules and their relevance to data storage.The book addresses a wide audience. There was a huge development of the subject beginning in the mid-1980s where researchers began to study the properties of free nanoparticle and models were developed to describe the observations. The newcomer is introduced to the established models and techniques of the field without the need to refer to other sources to make the material accessible. It then takes the reader through to the latest research and provides a comprehensive list of references for those who wish to pursue particular aspects in more detail. It will also be an invaluable handbook for the expert in a particular aspect of nanoscale research who wishes to acquire knowledge of other areas.The authors are specialists in different aspects of the subject with expertise in physics and chemistry, experimental techniques and computational modelling, and in interdisciplinary research. They have collaborated in research. They have also collaborated in writing this book, with the aim from the outset of making it is a coherent whole rather than a series of independent loosely connected articles. * Appeals to a wide audience* Provides an introduction to established models and techniques in the field* Comprehensive list of references

Nanocatalysis

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Publisher : John Wiley & Sons
ISBN 13 : 1118609808
Total Pages : 670 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Nanocatalysis by : Vivek Polshettiwar

Download or read book Nanocatalysis written by Vivek Polshettiwar and published by John Wiley & Sons. This book was released on 2013-09-06 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors’ first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book’s nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.

Metal Oxide Nanoparticles, 2 Volume Set

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Publisher : John Wiley & Sons
ISBN 13 : 1119436745
Total Pages : 903 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Metal Oxide Nanoparticles, 2 Volume Set by : Oliver Diwald

Download or read book Metal Oxide Nanoparticles, 2 Volume Set written by Oliver Diwald and published by John Wiley & Sons. This book was released on 2021-09-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Nanoparticles A complete nanoparticle resource for chemists and industry professionals Metal oxide nanoparticles are integral to a wide range of natural and technological processes—from mineral transformation to electronics. Additionally, the fields of engineering, electronics, energy technology, and electronics all utilize metal oxide nanoparticle powders. Metal Oxide Nanoparticles: Formation, Functional Properties, and Interfaces presents readers with the most relevant synthesis and formulation approaches for using metal oxide nanoparticles as functional materials. It covers common processing routes and the assessment of physical and chemical particle properties through comprehensive and complementary characterization methods. This book will serve as an introduction to nanoparticle formulation, their interface chemistry and functional properties at the nanoscale. It will also act as an in-depth resource, sharing detailed information on advanced approaches to the physical, chemical, surface, and interface characterization of metal oxide nanoparticle powders and dispersions. Addresses the application of metal oxide nanoparticles and its economic impact Examines particle synthesis, including the principles of selected bottom-up strategies Explores nanoparticle formulation—a selection of processing and application routes Discusses the significance of particle surfaces and interfaces on structure formation, stability and functional materials properties Covers metal oxide nanoparticle characterization at different length scales With this valuable resource, academic researchers, industrial chemists, and PhD students can all gain insight into the synthesis, properties, and applications of metal oxide nanoparticles.

Interfacial Catalysis

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Publisher : CRC Press
ISBN 13 : 9780203910429
Total Pages : 690 pages
Book Rating : 4.9/5 (14 download)

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Book Synopsis Interfacial Catalysis by : Alexander G. Volkov

Download or read book Interfacial Catalysis written by Alexander G. Volkov and published by CRC Press. This book was released on 2002-12-12 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfacial catalysis in metal complexation, the role of water molecules in ion transfer at the oil/water interface, and ultrathin films in enhanced oil recovery.