Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel

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Publisher : Springer Science & Business Media
ISBN 13 : 3642276792
Total Pages : 185 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel by : Bruce L. Yoder

Download or read book Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel written by Bruce L. Yoder and published by Springer Science & Business Media. This book was released on 2012-02-03 with total page 185 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bruce Yoder’s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas.

Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel

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Publisher : Springer
ISBN 13 : 9783642276804
Total Pages : 192 pages
Book Rating : 4.2/5 (768 download)

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Book Synopsis Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel by :

Download or read book Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel written by and published by Springer. This book was released on 2012-02-05 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Methane Conversion by Oxidative Processes

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Publisher : Springer Science & Business Media
ISBN 13 : 9401574499
Total Pages : 556 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Methane Conversion by Oxidative Processes by : Wolf

Download or read book Methane Conversion by Oxidative Processes written by Wolf and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.

Methane Conversion Routes

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788014308
Total Pages : 377 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Methane Conversion Routes by : Vladimir Galvita

Download or read book Methane Conversion Routes written by Vladimir Galvita and published by Royal Society of Chemistry. This book was released on 2023-09-29 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Methane Biocatalysis: Paving the Way to Sustainability

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Publisher : Springer
ISBN 13 : 3319748661
Total Pages : 310 pages
Book Rating : 4.3/5 (197 download)

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Book Synopsis Methane Biocatalysis: Paving the Way to Sustainability by : Marina G. Kalyuzhnaya

Download or read book Methane Biocatalysis: Paving the Way to Sustainability written by Marina G. Kalyuzhnaya and published by Springer. This book was released on 2018-06-20 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides in-depth insights into the most recent developments in different areas of microbial methane and methanol utilization, including novel fundamental discoveries in genomics and physiology, innovative strategies for metabolic engineering and new synthetic approaches for generation of feedstocks, chemicals and fuels from methane, and finally economics and the implementation of industrial biocatalysis using methane consuming bacteria. Methane, as natural gas or biogas, penetrates every area of human activity, from households to large industries and is often promoted as the cleanest fuel. However, one should not forget that this bundle of energy, carbon, and hydrogen comes with an exceptionally large environmental footprint. To meet goals of long-term sustainability and human well-being, all areas of energy, chemicals, agriculture, waste-management industries must go beyond short-term economic considerations and target both large and small methane emissions. The search for new environment-friendly approaches for methane capture and valorization is an ongoing journey. While it is not yet apparent which innovation might represent the best solution, it is evident that methane biocatalysis is one of the most promising paths. Microbes are gatekeepers of fugitive methane in Nature. Methane-consuming microbes are typically small in number but exceptionally big in their impact on the natural carbon cycle. They control and often completely eliminate methane emission from a variety of biological and geothermal sources. The tremendous potential of these microbial systems, is only now being implemented in human-made systems. The book addresses professors, researchers and graduate students from both academia and industry working in microbial biotechnology, molecular biology and chemical engineering.

Direct Methane to Methanol

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Author :
Publisher : Elsevier
ISBN 13 : 0444632514
Total Pages : 321 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Direct Methane to Methanol by : Vladimir Arutyunov

Download or read book Direct Methane to Methanol written by Vladimir Arutyunov and published by Elsevier. This book was released on 2014-01-30 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Methane to Methanol: Foundations and Prospects of the Process offers a state-of-the-art account of one of the most interesting and potentially commercial technologies for direct conversion of natural gas into valuable chemicals. The book thoroughly explains the complex and unusual chemistry of the process, as well as possible applications for direct methane to methanol (DMTM). It covers topics involving thermokinetics, pressure, direct oxidation of heavier alkanes, and more, and provides detailed appendices with experimental data and product yields. This book provides all those who work in the field of gas processing and gas chemistry with the theory and experimental data to develop and apply new processes based on direct oxidation of natural gas. All those who deal with oil and natural gas production and processing will learn about this promising technology for the conversion of gas into more valuable chemicals. - Reviews more than 350 publications on high-pressure, low-temperature oxidation of methane and other gas phase hydrocarbons - Contains rare material available for the first time in English - Explains the reasons of previous failure and outlines the way forward for commercial development of the conversion technology - Presents a deep theoretical knowledge of this complex conversion process

Methane Conversion by Oxidative Processes

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Author :
Publisher : Springer
ISBN 13 :
Total Pages : 566 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Methane Conversion by Oxidative Processes by : Eduardo E. Wolf

Download or read book Methane Conversion by Oxidative Processes written by Eduardo E. Wolf and published by Springer. This book was released on 1992 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.

Methanation Catalysts

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Publisher :
ISBN 13 : 9789290290537
Total Pages : 56 pages
Book Rating : 4.2/5 (95 download)

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Book Synopsis Methanation Catalysts by : G. H. Watson

Download or read book Methanation Catalysts written by G. H. Watson and published by . This book was released on 1980 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Methane and Alkane Conversion Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1461518075
Total Pages : 338 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Methane and Alkane Conversion Chemistry by : M.M. Bhasin

Download or read book Methane and Alkane Conversion Chemistry written by M.M. Bhasin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural gas, an abundant natural energy and chemical resource, is underutilized. Its inherent high energy content is compromised by its volatility. Storage and transportation problems abound for liquified natural gas. Several of the drawbacks of the utilization of natural gas, particularly its high volatility, could be offset by development of an economical and efficient process for coupling and/or further homologation of its principal component, methane. Alternatively, other conversion strategies such as partial oxidation to methanol and syngas, to oxygenates or conversion to such products via the intermediacy of chlorides should also be considered. Given the energy-intensive regimes necessary for the likely activation of methane, it was inevitable that researchers would tum to the use of heterogeneous catalysts. Heterogeneous catalysis is now a relatively mature discipline with numerous and diverse reactions being explored alongside informative studies on surface characterization, mechanism, and theory. Relationships to important related areas such as homogeneous catalysis, organometallic chemistry, and inorganic chemistry have become firmly established within this discipline. The field of methane and alkane activation is now over ten years old. The first decade of investigation produced results plagued by low yields and low-moderate conversions with well-articulated mechanistic limitations. As we begin the second decade of inquiry, novel strategies have brought increasing yields and conversions to such products as ethane, ethylene, methanol, and formaldehyde. These new approaches utilize separation of products via membranes or adsorbents. Moreover, additional mechanistic insight has been forthcoming from theoretical and computational examination as well as experimental investigation.

Methane Activation and Utilization in the Petrochemical and Biofuel Industries

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Author :
Publisher : Springer Nature
ISBN 13 : 3030884244
Total Pages : 264 pages
Book Rating : 4.0/5 (38 download)

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Book Synopsis Methane Activation and Utilization in the Petrochemical and Biofuel Industries by : Hua Song

Download or read book Methane Activation and Utilization in the Petrochemical and Biofuel Industries written by Hua Song and published by Springer Nature. This book was released on 2021-11-15 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses effective and alternative uses for natural gas (NG) and highlights the utilization of NG in the field of methane activation and chemical production. It details the techniques used during the reforming process of petrochemical and bio-derived fuels and it presents cutting-edge research that describes the utilization of NG that enables it to be more cost-effective and eliminate the expensive greenhouse gas emitting process of hydrogen production. The book addresses three major topics: NG use in upstream heavy oil and bitumen upgrading, NG and its use in downstream oil refining through co-aromatization of various feeds in the petrochemical industry, and NG use in the upgrading of bio-derived fuels and discusses alternative uses of NG. In-depth chapters demonstrate uses for NG beyond heating homes, through catalysis and in-situ hydrogen donation, and its potential applications for the petrochemical and biofuel industries.

Methane Conversion

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Author :
Publisher : Elsevier Publishing Company
ISBN 13 : 9780444429353
Total Pages : 741 pages
Book Rating : 4.4/5 (293 download)

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Book Synopsis Methane Conversion by : David M. Bibby

Download or read book Methane Conversion written by David M. Bibby and published by Elsevier Publishing Company. This book was released on 1988-01-01 with total page 741 pages. Available in PDF, EPUB and Kindle. Book excerpt: This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered. The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.

Methods in Methane Metabolism, Part A

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Author :
Publisher : Academic Press
ISBN 13 : 0123851130
Total Pages : 420 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Methods in Methane Metabolism, Part A by : Amy Rosenzweig

Download or read book Methods in Methane Metabolism, Part A written by Amy Rosenzweig and published by Academic Press. This book was released on 2011-05-11 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: Produced by microbes on a large scale, methane is an important alternative fuel as well as a potent greenhouse gas. This volume focuses on microbial methane metabolism, which is central to the global carbon cycle. Both methanotrophy and methanogenesis are covered in detail. Topics include isolation and classification of microorganisms, metagenomics approaches, biochemistry of key metabolic enzymes, gene regulation and genetic systems, and field measurements. The state-of-the-art techniques described here will both guide researchers in specific pursuits and educate the wider scientific community about this exciting and rapidly developing field. - Topics include isolation and classification of microorganisms, metagenomics approaches, biochemistry of key metabolic enzymes, gene regulation and genetic systems, and field measurements - The state-of-the-art techniques described here will both guide researchers in specific pursuits and educate the wider scientific community about this exciting and rapidly developing field

Methane Conversion

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Author :
Publisher : Elsevier
ISBN 13 : 0080960707
Total Pages : 759 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Methane Conversion by : D.M. Bibby

Download or read book Methane Conversion written by D.M. Bibby and published by Elsevier. This book was released on 1988-03-01 with total page 759 pages. Available in PDF, EPUB and Kindle. Book excerpt: This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered.The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.

Chemicals from Synthesis Gas

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Publisher : Springer Science & Business Media
ISBN 13 : 9401710198
Total Pages : 234 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Chemicals from Synthesis Gas by : R.A. Sheldon

Download or read book Chemicals from Synthesis Gas written by R.A. Sheldon and published by Springer Science & Business Media. This book was released on 2013-04-18 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: The origins of the petrochemical industry can be traced back to the 1920s when simple organic chemicals such as ethanol and isopropanol were first prepared on an industrial scale from by-products (ethylene and propylene) of oil refining. This oil-based petrochemical industry, with lower olefms and aromatics as the key building blocks, rapidly developed into the enormous industry it is today. A multitude of products that are indispensible to modern day society, from plastics to pharmaceuticals, are derived from oil and natural gas-based hydro carbons. The industry had its heyday in the '50s and '60s when predictions of future growth rates tended to be exponential curves. However, two developments that took place in the early '70s disturbed this simplistic and optimistic view of the future. Firstly, the publication of the report for the Cub of Rome on the 'Limits to Growth' emphasized the finite nature of non-renewable fossil fuel resources. Secondly, the Oil Crisis of 1973 emphasized the vulnerability of an energy and chemicals industry that is based largely on a single raw material.

Methane Combustion over Lanthanum-based Perovskite Mixed Oxides

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Publisher : Springer
ISBN 13 : 366246991X
Total Pages : 123 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Methane Combustion over Lanthanum-based Perovskite Mixed Oxides by : Hamidreza Arandiyan

Download or read book Methane Combustion over Lanthanum-based Perovskite Mixed Oxides written by Hamidreza Arandiyan and published by Springer. This book was released on 2015-04-30 with total page 123 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents current research into the catalytic combustion of methane using perovskite-type oxides (ABO3). Catalytic combustion has been developed as a method of promoting efficient combustion with minimum pollutant formation as compared to conventional catalytic combustion. Recent theoretical and experimental studies have recommended that noble metals supported on (ABO3) with well-ordered porous networks show promising redox properties. Three-dimensionally ordered macroporous (3DOM) materials with interpenetrated and regular mesoporous systems have recently triggered enormous research activity due to their high surface areas, large pore volumes, uniform pore sizes, low cost, environmental benignity, and good chemical stability. These are all highly relevant in terms of the utilization of natural gas in light of recent catalytic innovations and technological advances. The book is of interest to all researchers active in utilization of natural gas with novel catalysts. The research covered comes from the most important industries and research centers in the field. The book serves not only as a text for researcher into catalytic combustion of methane, 3DOM perovskite mixed oxide, but also explores the field of green technologies by experts in academia and industry. This book will appeal to those interested in research on the environmental impact of combustion, materials and catalysis.

Methods in Methane Metabolism, Part B

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Author :
Publisher : Academic Press
ISBN 13 : 0123869064
Total Pages : 361 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Methods in Methane Metabolism, Part B by : Amy Rosenzweig

Download or read book Methods in Methane Metabolism, Part B written by Amy Rosenzweig and published by Academic Press. This book was released on 2011-03-17 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Produced by microbes on a large scale, methane is an important alternative fuel as well as a potent greenhouse gas. This volume focuses on microbial methane metabolism, which is central to the global carbon cycle. Both methanotrophy and methanogenesis are covered in detail. Topics include isolation and classification of microorganisms, metagenomics approaches, biochemistry of key metabolic enzymes, gene regulation and genetic systems, and field measurements. The state of the art techniques described here will both guide researchers in specific pursuits and educate the wider scientific community about this exciting and rapidly developing field. - Topics include isolation and classification of microorganisms, metagenomics approaches, biochemistry of key metabolic enzymes, gene regulation and genetic systems and field measurements - The state-of-the-art techniques described here will both guide researchers in specific pursuits and educate the wider scientific community about this exciting and rapidly developing field

Realizing the Energy Potential of Methane Hydrate for the United States

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Author :
Publisher : National Academies Press
ISBN 13 : 0309148898
Total Pages : 204 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Realizing the Energy Potential of Methane Hydrate for the United States by : National Research Council

Download or read book Realizing the Energy Potential of Methane Hydrate for the United States written by National Research Council and published by National Academies Press. This book was released on 2009-07-30 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural gas, composed mostly of methane, is the cleanest of all the fossil fuels, emitting 25-50% less carbon dioxide than either oil or coal for each unit of energy produced. In recent years, natural gas supplied approximately 20-25% of all energy consumed in the United States. Methane hydrate is a potentially enormous and as yet untapped source of methane. The Department of Energy's Methane Hydrate Research and Development Program has been tasked since 2000 to implement and coordinate a national methane hydrate research effort to stimulate the development of knowledge and technology necessary for commercial production of methane from methane hydrate in a safe and environmentally responsible way. Realizing the Energy Potential of Methane Hydrate for the United States evaluates the program's research projects and management processes since its congressional re-authorization in 2005, and presents recommendations for its future research and development initiatives.