Using Mass Spectrometry and Ftir to Characterize Atmospherically-relevant Particles Generated in Laboratory Systems

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ISBN 13 : 9781267057884
Total Pages : 166 pages
Book Rating : 4.0/5 (578 download)

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Book Synopsis Using Mass Spectrometry and Ftir to Characterize Atmospherically-relevant Particles Generated in Laboratory Systems by : Emily Anne Bruns

Download or read book Using Mass Spectrometry and Ftir to Characterize Atmospherically-relevant Particles Generated in Laboratory Systems written by Emily Anne Bruns and published by . This book was released on 2011 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric aerosols are known to have multifaceted effects on human health, visibility and climate. To understand these effects, characterization of aerosol properties is necessary. This dissertation focuses on several specific topics with the overall goal of improving our understanding of aerosols in the atmosphere. One area of importance is particulate organic nitrates, which are known to be ubiquitous in the atmosphere; however, there is a lack of proven analytical techniques for their measurement. The qualitative and quantitative response of a high resolution time of flight aerosol mass spectrometer to particulate organic nitrates was studied by analyzing secondary organic aerosol (SOA) from NO3 radical reactions with [Alpha]- and [Beta]-pinene, 3-carene, limonene, and isoprene. Extensive fragmentation of the organic nitrate products was observed in the mass spectra, which precluded molecular speciation. Another area of interest is the recent development of a number of ambient ionization techniques, which are promising for aerosol characterization. One such technique, atmospheric solids analysis probe mass spectrometry (ASAP-MS), was applied for the first time to the identification of organics in SOA, which was generated in the laboratory from the ozonolysis of & alpha;-pinene and isoprene, and from the NO3 oxidation of & alpha;-pinene. Also, ambient samples were collected from a forested and a suburban location. ASAP-MS data for the laboratory-generated samples showed peaks corresponding to well-known products of these reactions, and higher molecular weight oligomers were present in all samples. This is consistent with previously published studies of similar systems and shows that ASAP-MS should have wide applicability in both laboratory and field studies. Vapor pressures of low volatility compounds are important parameters in several atmospheric processes, including the formation of new particles and the partitioning of compounds between the gas-phase and particles. However, vapor pressures of low volatility compounds are challenging to measure and reported values vary significantly, illustrating the need for new approaches. ASAP-MS was applied for the first time to the measurement of vapor pressures and heats of sublimation. The measured heats of sublimation were in good agreement with published values. The vapor pressures were typically within a factor of three of published values made at similar temperatures. This study establishes that ASAP-MS is a promising new technique for vapor pressure and heat of sublimation measurements of low volatility compounds. To further understand new particle formation, laboratory and field measurements were made to identify gas-phase amines, which could play a role in new particle formation, from previously unknown sources using proton transfer reaction mass spectrometry. The work presented in this dissertation advances our understanding of aerosols and explores novel methods for their characterization.

Development and Characterization of Two Versions of a New Single Particle Mass Spectrometer for Organic Aerosol Analysis that Incorporate a 3D Ion Trap

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (68 download)

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Book Synopsis Development and Characterization of Two Versions of a New Single Particle Mass Spectrometer for Organic Aerosol Analysis that Incorporate a 3D Ion Trap by :

Download or read book Development and Characterization of Two Versions of a New Single Particle Mass Spectrometer for Organic Aerosol Analysis that Incorporate a 3D Ion Trap written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol particles are ubiquitous throughout the atmosphere and play an important role in human health, climate, and the chemistry of the atmosphere. A significant mass fraction of these particles is composed of organic species, which remain poorly characterized due to the number and diversity of species present. This thesis describes the development and characterization of two versions of a new single particle mass spectrometer with a 3D ion trap for organic aerosol studies. Version I combines CO2 laser desorption and electron impact ionization in an ion trap. Mass spectra obtained for four species are comparable to NIST EI spectra. Tandem mass spectrometry studies are also demonstrated. The effects of vaporization energy, ionization delay time, and electron pulse width on the mass spectra and fragmentation patterns are examined. The detection limit of the instrument is found to be ~1x108 molecules (350 nm diameter particle) for 2,4-dihydroxybenzoic acid. Version II integrates CO2 laser desorption and tunable VUV ionization in an ion trap and was used for a detailed study of oleyl alcohol, oleic acid and mixtures thereof. Both the degree of fragmentation in the mass spectra and the translational energy of the vaporized molecules are found to vary as a function of desorption energy in the pure particles and as a function of composition in the mixed particles. These changes can be described by the energy absorbed per particle during desorption. We show that these effects hinder the quantitative response of the instrument and have important implications for other two step laser desorption/ionization systems. The final part of this thesis presents preliminary results from atmospherically relevant particles. Mass spectra of cigarette sidestream smoke, fulvic acid, meat cooking, and ammonium bisulfate aerosols are collected using both versions of the instrument. The two step desorption/ionization process only worked for two types of aerosols, while CO2 only mass spectra w.

Mass Spectrometry of Atmospherically-Relevant Soot and Black-Carbon Particles

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (916 download)

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Book Synopsis Mass Spectrometry of Atmospherically-Relevant Soot and Black-Carbon Particles by : Joel Christopher Corbin

Download or read book Mass Spectrometry of Atmospherically-Relevant Soot and Black-Carbon Particles written by Joel Christopher Corbin and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fundamentals and Applications in Aerosol Spectroscopy

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Publisher : CRC Press
ISBN 13 : 142008562X
Total Pages : 513 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Fundamentals and Applications in Aerosol Spectroscopy by : Ruth Signorell

Download or read book Fundamentals and Applications in Aerosol Spectroscopy written by Ruth Signorell and published by CRC Press. This book was released on 2010-12-20 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: Helping you better understand the processes, instruments, and methods of aerosol spectroscopy, Fundamentals and Applications in Aerosol Spectroscopy provides an overview of the state of the art in this rapidly developing field. It covers fundamental aspects of aerosol spectroscopy, applications to atmospherically and astronomically relevant problem

Infrared and Raman Spectroscopy

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Publisher : Elsevier
ISBN 13 : 0128042095
Total Pages : 288 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Infrared and Raman Spectroscopy by : Peter Larkin

Download or read book Infrared and Raman Spectroscopy written by Peter Larkin and published by Elsevier. This book was released on 2017-11-13 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Infrared and Raman Spectroscopy, Principles and Spectral Interpretation, Second Edition provides a solid introduction to vibrational spectroscopy with an emphasis on developing critical interpretation skills. This book fully integrates the use of both IR and Raman spectroscopy as spectral interpretation tools, enabling the user to utilize the strength of both techniques while also recognizing their weaknesses. This second edition more than doubles the amount of interpreted IR and Raman spectra standards and spectral unknowns. The chapter on characteristic group frequencies is expanded to include increased discussions of sulphur and phosphorus organics, aromatic and heteroaromatics as well as inorganic compounds. New topics include a discussion of crystal lattice vibrations (low frequency/THz), confocal Raman microscopy, spatial resolution in IR and Raman microscopy, as well as criteria for selecting Raman excitation wavelengths. These additions accommodate the growing use of vibrational spectroscopy for process analytical monitoring, nanomaterial investigations, and structural and identity determinations to an increasing user base in both industry and academia. - Integrates discussion of IR and Raman spectra - Pairs generalized IR and Raman spectra of functional groups with tables and text - Includes over 150 fully interpreted, high quality IR and Raman reference spectra - Contains fifty-four unknown IR and Raman spectra, with a corresponding answer key

Air Quality in the Mexico Megacity

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Publisher : Springer Science & Business Media
ISBN 13 : 9401004544
Total Pages : 401 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Air Quality in the Mexico Megacity by : L. Molina

Download or read book Air Quality in the Mexico Megacity written by L. Molina and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, experts in atmospheric sciences, human health, economics, social and political sciences contribute to an integrated assessment of the complex elements needed to structure air quality policy in the 21st century. The analysis is developed through a case study of the Mexico City Metropolitan Area - one of the world's largest megacities in which air pollution grew unchecked for decades. The international research team is led by Luisa T. and Mario J. Molina, Nobel Laureate in Chemistry. Improvements in Mexico City's air quality in the last decade testifies to the power of determined and enlightened policy making, and throws into relief the tough problems that remain to be solved. The volume's first six chapters, including the contributions of over 50 distinguished scholars from Mexico and the US, outline the fundamental areas of knowledge policy makers must accommodate. The message is that only good science and well-chosen technologies can direct the way to corrective regulatory measures; but without strong commitment from government, no amount of science or technology can help.

Modern Molecular Photochemistry

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Publisher : University Science Books
ISBN 13 : 9780935702712
Total Pages : 644 pages
Book Rating : 4.7/5 (27 download)

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Book Synopsis Modern Molecular Photochemistry by : Nicholas J. Turro

Download or read book Modern Molecular Photochemistry written by Nicholas J. Turro and published by University Science Books. This book was released on 1991 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades the photochemistry of organic molecules has grown into an important and pervasive branch of organic chemistry. In Modern Molecular Photochemistry, the author brings students up to date with the advances in this field - the development of the theory of photoreactions, the utilization of photoreactions in synthetic sequences, and the advancement of powerful laser techniques to study the mechanisms of photoreactions.

Stimulated Raman Scattering Microscopy

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Publisher : Elsevier
ISBN 13 : 0323903371
Total Pages : 612 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Stimulated Raman Scattering Microscopy by : Ji-Xin Cheng

Download or read book Stimulated Raman Scattering Microscopy written by Ji-Xin Cheng and published by Elsevier. This book was released on 2021-12-04 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stimulated Raman Scattering Microscopy: Techniques and Applications describes innovations in instrumentation, data science, chemical probe development, and various applications enabled by a state-of-the-art stimulated Raman scattering (SRS) microscope. Beginning by introducing the history of SRS, this book is composed of seven parts in depth including instrumentation strategies that have pushed the physical limits of SRS microscopy, vibrational probes (which increased the SRS imaging functionality), data science methods, and recent efforts in miniaturization. This rapidly growing field needs a comprehensive resource that brings together the current knowledge on the topic, and this book does just that. Researchers who need to know the requirements for all aspects of the instrumentation as well as the requirements of different imaging applications (such as different types of biological tissue) will benefit enormously from the examples of successful demonstrations of SRS imaging in the book. Led by Editor-in-Chief Ji-Xin Cheng, a pioneer in coherent Raman scattering microscopy, the editorial team has brought together various experts on each aspect of SRS imaging from around the world to provide an authoritative guide to this increasingly important imaging technique. This book is a comprehensive reference for researchers, faculty, postdoctoral researchers, and engineers. - Includes every aspect from theoretic reviews of SRS spectroscopy to innovations in instrumentation and current applications of SRS microscopy - Provides copious visual elements that illustrate key information, such as SRS images of various biological samples and instrument diagrams and schematics - Edited by leading experts of SRS microscopy, with each chapter written by experts in their given topics

Atmospheric Chemistry

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Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 1164 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Atmospheric Chemistry by : Barbara J. Finlayson-Pitts

Download or read book Atmospheric Chemistry written by Barbara J. Finlayson-Pitts and published by Wiley-Interscience. This book was released on 1986 with total page 1164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of the new and emerging discipline of atmospheric chemistry. Starting with the fundamentals of kinetics and photochemistry, it shows how the experimental techniques in these areas are applied to the study and control of chemical reactions in the troposphere. Gives detailed analysis of such major societal issues as smog, acid rain and volatile toxic organics, and treats the seven criteria pollutants considered by the U.S. Environmental Protection Agency to be hazardous, as well as a variety of trace non-criteria pollutants, such as those cited in the Clean Air Act of 1977. Also included is a comprehensive bibliography and over 340 illustrations.

Atmospheric Aerosols

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Publisher : Scitus Academics LLC
ISBN 13 : 9781681171326
Total Pages : 0 pages
Book Rating : 4.1/5 (713 download)

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Book Synopsis Atmospheric Aerosols by : Rekha Kale

Download or read book Atmospheric Aerosols written by Rekha Kale and published by Scitus Academics LLC. This book was released on 2015-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric Aerosols is a vital problem in current environmental research due to its importance in atmospheric optics, energetics, radiative transfer studies, chemistry, climate, biology and public health. Aerosols can influence the energy balance of the terrestrial atmosphere, the hydrological cycle, atmospheric dynamics and monsoon circulations. Because of the heterogeneous aerosol field with large spatial and temporal variability and reduction in uncertainties in aerosol quantification is a challenging task in atmospheric sciences. Keeping this in view the present study aims to assess the impact of aerosols on coastal Indian station Visakhapatnam and the adjoining Bay of Bengal. An aerosol is a colloid of fine solid particles or liquid droplets, in air or another gas. Aerosols can be natural or not. Examples of natural aerosols are fog, forest exudates and geyser steam.

Aerosol Technology

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Publisher : John Wiley & Sons
ISBN 13 : 1118591976
Total Pages : 411 pages
Book Rating : 4.1/5 (185 download)

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Book Synopsis Aerosol Technology by : William C. Hinds

Download or read book Aerosol Technology written by William C. Hinds and published by John Wiley & Sons. This book was released on 2012-12-06 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: The #1 guide to aerosol science and technology -now better than ever Since 1982, Aerosol Technology has been the text of choice among students and professionals who need to acquire a thorough working knowledge of modern aerosol theory and applications. Now revised to reflect the considerable advances that have been made over the past seventeen years across a broad spectrum of aerosol-related application areas - from occupational hygiene and biomedical technology to microelectronics and pollution control -this new edition includes: * A chapter on bioaerosols * New sections on resuspension, transport losses, respiratory deposition models, and fractal characterization of particles * Expanded coverage of atmospheric aerosols, including background aerosols and urban aerosols * A section on the impact of aerosols on global warming and ozone depletion. Aerosol Technology, Second Edition also features dozens of new, fully worked examples drawn from a wide range of industrial and research settings, plus new chapter-end practice problems to help readers master the material quickly.

Heterogeneous NOx Chemistry in Polluted Urban Atmospheres

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Publisher :
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Heterogeneous NOx Chemistry in Polluted Urban Atmospheres by : Barbara J. Finlayson-Pitts

Download or read book Heterogeneous NOx Chemistry in Polluted Urban Atmospheres written by Barbara J. Finlayson-Pitts and published by . This book was released on 2004 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ocean-Atmosphere Interactions of Gases and Particles

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Publisher : Springer
ISBN 13 : 3642256430
Total Pages : 366 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Ocean-Atmosphere Interactions of Gases and Particles by : Peter S. Liss

Download or read book Ocean-Atmosphere Interactions of Gases and Particles written by Peter S. Liss and published by Springer. This book was released on 2013-12-18 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.

CRC Handbook of Fundamental Spectroscopic Correlation Charts

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Publisher : CRC Press
ISBN 13 : 1420037684
Total Pages : 241 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis CRC Handbook of Fundamental Spectroscopic Correlation Charts by : Thomas J. Bruno

Download or read book CRC Handbook of Fundamental Spectroscopic Correlation Charts written by Thomas J. Bruno and published by CRC Press. This book was released on 2005-10-31 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: From forensics and security to pharmaceuticals and environmental applications, spectroscopic detection is one of the most cost-effective methods for identifying chemical compounds in a wide range of disciplines. For spectroscopic information, correlation charts are far more easily used than tables, especially for scientists and students whose own a

Scientific and Technical Aerospace Reports

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Publisher :
ISBN 13 :
Total Pages : 1008 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1978 with total page 1008 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.

Multiphase Environmental Chemistry in the Atmosphere

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Publisher : ACS Symposium
ISBN 13 : 9780841233638
Total Pages : 0 pages
Book Rating : 4.2/5 (336 download)

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Book Synopsis Multiphase Environmental Chemistry in the Atmosphere by : Sherri W. Hunt

Download or read book Multiphase Environmental Chemistry in the Atmosphere written by Sherri W. Hunt and published by ACS Symposium. This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights new cross-disciplinary advances in aerosol chemistry that involve more than one phase, for example, unique chemical processes occurring on gas-solid and liquid-solid interfaces.

Interpretation of MS-MS Mass Spectra of Drugs and Pesticides

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Publisher : John Wiley & Sons
ISBN 13 : 1118500180
Total Pages : 421 pages
Book Rating : 4.1/5 (185 download)

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Book Synopsis Interpretation of MS-MS Mass Spectra of Drugs and Pesticides by : Wilfried M. A. Niessen

Download or read book Interpretation of MS-MS Mass Spectra of Drugs and Pesticides written by Wilfried M. A. Niessen and published by John Wiley & Sons. This book was released on 2017-01-30 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of the interpretation of LC–MS–MS mass spectra of 1300 drugs and pesticides Provides a general discussion on the fragmentation of even-electron ions (protonated and deprotonated molecules) in both positive-ion and negative-ion modes This is the reference book for the interpretation of MS–MS mass spectra of small organic molecules Covers related therapeutic classes of compounds such as drugs for cardiovascular diseases, psychotropic compounds, drugs of abuse and designer drugs, antimicrobials, among many others Covers general fragmentation rule as well as specific fragmentation pathways for many chemical functional groups Gives an introduction to MS technology, mass spectral terminology, information contained in mass spectra, and to the identification strategies used for different types of unknowns