Transformation Of Organometallics Into Common And Exotic Materials Design And Activation

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Transformation of Organometallics into Common and Exotic Materials: Design and Activation

Author : R.M. Laine
Publisher : Springer Science & Business Media
ISBN 13 : 9400913931
Total Pages : 297 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Transformation of Organometallics into Common and Exotic Materials: Design and Activation by : R.M. Laine

Download or read book Transformation of Organometallics into Common and Exotic Materials: Design and Activation written by R.M. Laine and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 297 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design, -synthesis, and selective pyrolytic conversion of organo metallic precursdrs to materials of high purity or specific morphology (for electronic or optical applications), high strength and/or high-temperature stability (for structural or refractory applications) represents a poten tial area of extreme growth at the overlap of chemistry and materials science (materials chemistry). Research in this area is likely to have considerable impact at both the academic and societal levels because it will require development of scientific expertise in areas currently not well understood. Examples include: (1) The thermodynamics of molecular rearrangements in organometallic molecules at temperatures above 200°C; (2) The electronic properties of amorphous ceramic materials; (3) The phys icochemical properties of ceramic molecular composites; and (4) The optical properties of multicomponent glasses made by sol-gel processing. The opportunity to establish the scientific principles needed to pursue useful research goals in "materials chemistry" requires communica tion between chemists, ceramists, metallurgists, and physicists. To date, there have been few opportunities to create an environment where such communication might occur. The objective of this NATO Advanced Research Workshop was to promote discussions between experts in the varibus disci plines aligned with "materials chemistry. " These discussions were intended to identify the scope and potential rewards of research efforts in the development of: Custom-designed precursors to common and exotic materials, methods of selectively transforming these precursors in high yield to the desired material, and methods of characterizing the final products.

Transformation of Organometallics Into Common and Exotic Materials

Author : R M Laine
Publisher :
ISBN 13 : 9789400913943
Total Pages : 312 pages
Book Rating : 4.9/5 (139 download)

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Book Synopsis Transformation of Organometallics Into Common and Exotic Materials by : R M Laine

Download or read book Transformation of Organometallics Into Common and Exotic Materials written by R M Laine and published by . This book was released on 1988-02-29 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Design, Activation and Selective Transformation of Organometallic Compounds Into Common and Exotic Materials

Author : Richard M. Laine
Publisher :
ISBN 13 :
Total Pages : 27 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis The Design, Activation and Selective Transformation of Organometallic Compounds Into Common and Exotic Materials by : Richard M. Laine

Download or read book The Design, Activation and Selective Transformation of Organometallic Compounds Into Common and Exotic Materials written by Richard M. Laine and published by . This book was released on 1988 with total page 27 pages. Available in PDF, EPUB and Kindle. Book excerpt: Future directions in Materials Chemistry research are identified based on the NATO/ONR Advanced Research Workshop 'The Design, Activation and Selective Transformation of Organometallic Compounds into Common and Exotic Materials'. Specific problems and research needs in the fields of: (1) Premetallic and preceramic organometallics; (2) Chemical Vapor deposition precursors; and, (3) Sol-gel chemistry are discussed. Fundamental problems at the interfaces of chemistry, physics, and materials science are also considered. Keywords: Polymers, Molecular structure, Thermodynamics, Chemical engineering, Monomers, Reaction kinetics, Catalysis, Pyrolysis. (aw).

NATO Workshop on the Design, Activation and Transformation of Organometallics Into Common and Exotic Materials

Author : Robert W. Vests
Publisher :
ISBN 13 :
Total Pages : 18 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis NATO Workshop on the Design, Activation and Transformation of Organometallics Into Common and Exotic Materials by : Robert W. Vests

Download or read book NATO Workshop on the Design, Activation and Transformation of Organometallics Into Common and Exotic Materials written by Robert W. Vests and published by . This book was released on 1987 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this workshop was to identify the scope and potential rewards of research efforts in the development of methods of transforming organometallic compounds into useful materials. This report covers the presentations in chemical vapor deposition, sol-gel processing, and preceramic polymers. Keywords: Ceramic materials; Ceramic coatings; Metal coatings; Metallic crystals; Organic coatings.

Inorganic and Organometallic Polymers with Special Properties

Author : R.M. Laine
Publisher : Springer Science & Business Media
ISBN 13 : 9401126127
Total Pages : 431 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Inorganic and Organometallic Polymers with Special Properties by : R.M. Laine

Download or read book Inorganic and Organometallic Polymers with Special Properties written by R.M. Laine and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop, Cap d'Agde, France, September 9-14, 1990

Macromolecular Design of Polymeric Materials

Author : Hatada
Publisher : CRC Press
ISBN 13 : 9780824794651
Total Pages : 900 pages
Book Rating : 4.7/5 (946 download)

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Book Synopsis Macromolecular Design of Polymeric Materials by : Hatada

Download or read book Macromolecular Design of Polymeric Materials written by Hatada and published by CRC Press. This book was released on 1997-01-02 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a range of information on polymers and polymerization techniques, this text covers the gamut of polymer science from synthesis, structure and properties to function and applications. It analyzes speciality polymers, including acrylics, fluoropolymers, polysiplanes, polyphosphazenes, and inorganic and conducting polymers. The book examines the stereochemistry of polymerization and the stereoregularity of polymers.

Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis

Author : Michel Chanon
Publisher : Springer Science & Business Media
ISBN 13 : 9400908776
Total Pages : 568 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis by : Michel Chanon

Download or read book Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis written by Michel Chanon and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,"Advanced Organic Chemistry", J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, "Advanced Inorganic Chemistry", Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, "Principles and Applications of Organotransition Metal Chemistry", University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry.

Inorganometallic Chemistry

Author : Thomas P. Fehlner
Publisher : Springer Science & Business Media
ISBN 13 : 1489924590
Total Pages : 409 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Inorganometallic Chemistry by : Thomas P. Fehlner

Download or read book Inorganometallic Chemistry written by Thomas P. Fehlner and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a certain fascination associated with words. The manipulation of strings of symbols according to mutually accepted rules allows a language to express history as well as to formulate challenges for the future. But language changes as old words are used in a new context and new words are created to describe changing situations. How many words has the computer revolution alone added to languages? "Inorganometallic" is a word you probably have never encountered before. It is one created from old words to express a new presence. A strange sounding word, it is also a term fraught with internal contradiction caused by the accepted meanings of its constituent parts. "In organic" is the name of a discipline of chemistry while "metallic" refers to a set of elements constituting a subsection of that discipline. Why then this Carrollian approach to entitling a set of serious academic papers? Organic, the acknowledged doyenne of chemistry, is distinguished from her brother, inorganic, by the prefix "in," i. e. , he gets everything not organic. Organometallic refers to compounds with carbon-metal bonds. It is simple! Inorganometallic is everything else, i. e. , compounds with noncarbon-metal element bonds. But why a new term? Is not inorganic sufficient? By virtue of training, limited time, resources, co-workers, and so on, chemists tend to work on a specific element class, on a particular compound type, or in a particular phase. Thus, one finds element-oriented chemists (e. g.

Physical Properties of Polymers Handbook

Author : James E. Mark
Publisher : Springer Science & Business Media
ISBN 13 : 0387690026
Total Pages : 1050 pages
Book Rating : 4.3/5 (876 download)

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Book Synopsis Physical Properties of Polymers Handbook by : James E. Mark

Download or read book Physical Properties of Polymers Handbook written by James E. Mark and published by Springer Science & Business Media. This book was released on 2007-03-21 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers concise information on the properties of polymeric materials, particularly those most relevant to physical chemistry and chemical physics. Extensive updates and revisions to each chapter include eleven new chapters on novel polymeric structures, reinforcing phases in polymers, and experiments on single polymer chains. The study of complex materials is highly interdisciplinary, and new findings are scattered among a large selection of scientific and engineering journals. This book brings together data from experts in the different disciplines contributing to the rapidly growing area of polymers and complex materials.

Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis

Author : Jean-Marie Basset
Publisher : Springer Science & Business Media
ISBN 13 : 9400929714
Total Pages : 340 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis by : Jean-Marie Basset

Download or read book Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis written by Jean-Marie Basset and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.

Activation of Hormone and Growth Factor Receptors

Author : Michael N. Alexis
Publisher : Springer Science & Business Media
ISBN 13 : 9400919360
Total Pages : 320 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Activation of Hormone and Growth Factor Receptors by : Michael N. Alexis

Download or read book Activation of Hormone and Growth Factor Receptors written by Michael N. Alexis and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains the papers presented in the NATO Advanced Research Workshop "Activation of Hormone and Growth Factor Receptors: Molecular Mechanisms and Consequences" held in Nafplion, Greece on September 25-30, 1988. The objective of NATO ARW is to assess the state of-the-art in a given scientific area and to formulate recommendations for future research in emerging areas of science by promoting international scientific contacts. In the Nafplion meeting this objective was reached by an international group of speakers, senior Greek scientists and graduates involved in relevant research areas. The Workshop was made possible by the generous support of the Scientific Council of NATO. We thank Drs. G. Sinclair and L.V. daCunha, Directors of the NATO ARW's and ASI's (Advanced Study Institutes) respectively, for their wholehearted support and advice. The International Union of Biochemistry awarded additional travel grants leading to increased international participation. Furthermore, the Secretariat of Science and Technology, the Ministry of Culture and Sciences and the National Hellenic Research Foundation contributed financially and by supporting personnel. We sincerely thank all these organizations for their support. Our heartful thanks are also extended to the Mayor of the Municipality of Nafplion, Mr.

Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials

Author : J.F. Harrod
Publisher : Springer Science & Business Media
ISBN 13 : 9401103372
Total Pages : 352 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials by : J.F. Harrod

Download or read book Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials written by J.F. Harrod and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.

Inorganic and Organometallic Oligomers and Polymers

Author : J.F. Harrod
Publisher : Springer Science & Business Media
ISBN 13 : 9401132143
Total Pages : 316 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Inorganic and Organometallic Oligomers and Polymers by : J.F. Harrod

Download or read book Inorganic and Organometallic Oligomers and Polymers written by J.F. Harrod and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although, carbon is only one of one hundred plus elements, the polymer science lit erature consists primarily of studies on carbon based polymers. In part, this reflects the varied feedstock sources and in part, the type of bonds and bond forming reactions avail able to form organic polymers that are not available to the inorganic and organometallic chemist. However, recent intense interest in polymers with novel optical, electronic or magnetic properties or polymers that can serve as precursors to ceramic, semiconductor, metallic or superconductor materials has served as a driver for the development of novel synthetic routes and characterization techniques that have launched many new inorganic and organometallic oligomers and polymer systems. The following chapters represent an effort to provide an overview of several new and continuing areas of development in inorganic and organometallic polymer science. This book represents the second in a series of books we have edited on inorganic and organometallic polymer chemistry (1. Transformation of Organo-metallics into Common and Exotic Materials, NATO ASI Series Vol 141. 3. Inorganic and Organometallic Polymers with Special Properties, NATO ASI Series in press). In this series, we attempt to develop, for the reader, an understanding of the breadth, depth and potential of inorganic and organometallic polymer science.

Scientific and Technical Aerospace Reports

Author :
Publisher :
ISBN 13 :
Total Pages : 984 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1989 with total page 984 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organosilicon Compounds

Author : Vladimir Ya Lee
Publisher : Academic Press
ISBN 13 : 0128019913
Total Pages : 758 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Organosilicon Compounds by : Vladimir Ya Lee

Download or read book Organosilicon Compounds written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-08-22 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Inorganic and Metal-Containing Polymeric Materials

Author : Charles E. Carraher Jr.
Publisher : Springer Science & Business Media
ISBN 13 : 1461306698
Total Pages : 506 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Inorganic and Metal-Containing Polymeric Materials by : Charles E. Carraher Jr.

Download or read book Inorganic and Metal-Containing Polymeric Materials written by Charles E. Carraher Jr. and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.

Free Radicals in Synthesis and Biology

Author : F. Minisci
Publisher : Springer Science & Business Media
ISBN 13 : 9400908970
Total Pages : 487 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Free Radicals in Synthesis and Biology by : F. Minisci

Download or read book Free Radicals in Synthesis and Biology written by F. Minisci and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free-radical reactions have been for long time the domain of the physical chemists and the basic chemical industry (polymerization of vinyl monomers, oxidation by molecular oxygen, chlorination of methane etc.), where the use of simple molecules and the possibility of partial conversions without heavy problems of product separations makes less dramatic the aspects of regio and chemoselectivity. As synonym of unselectivity, free radical reactions were considered of poor use in the synthesis of fine chemicals or sophisticated molecules, where a high selectivity is an essential condition for the success, or in the involvement of biological processes. Within the last 15 years, however, an authentic explosion of synthetic applications of free radical reactions occurred; they have gained a remarkable position among the selective methods of synthesis. At the same time the great importance of free radical reactions in fundamental biological processes and in the metabolism of drugs has been recognized. Thus a specialized meeting on these topics was generally felt appropriate. I had the honour and the onus to organize this workshop because for more than 30 years I have been involved in the research of free radical reactions. Thanks to a generous grant from NATO Scientific Affairs Division and the financial support of CNR and chemical industry (Montedison, Enichem, Zambon) such a meeting among almost 50 specialists and 15 observers of sufficient standard to take advantage of the discussion, became possible at Bardolino (Italy).