Read Books Online and Download eBooks, EPub, PDF, Mobi, Kindle, Text Full Free.
The Synthesis And Reactions Of Fluorine Containing Organo Silicon Compounds Primary Source Edition
Download The Synthesis And Reactions Of Fluorine Containing Organo Silicon Compounds Primary Source Edition full books in PDF, epub, and Kindle. Read online The Synthesis And Reactions Of Fluorine Containing Organo Silicon Compounds Primary Source Edition ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis The Synthesis and Reactions of Fluorine-Containing Organo-Silicon Compounds - Primary Source Edition by : Charles Tomasino
Download or read book The Synthesis and Reactions of Fluorine-Containing Organo-Silicon Compounds - Primary Source Edition written by Charles Tomasino and published by Nabu Press. This book was released on 2013-10 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a reproduction of a book published before 1923. This book may have occasional imperfections such as missing or blurred pages, poor pictures, errant marks, etc. that were either part of the original artifact, or were introduced by the scanning process. We believe this work is culturally important, and despite the imperfections, have elected to bring it back into print as part of our continuing commitment to the preservation of printed works worldwide. We appreciate your understanding of the imperfections in the preservation process, and hope you enjoy this valuable book.
Book Synopsis The Synthesis and Reactions of Fluorine-Containing Organo-Silicon Compounds by : Charles Tomasino
Download or read book The Synthesis and Reactions of Fluorine-Containing Organo-Silicon Compounds written by Charles Tomasino and published by Sagwan Press. This book was released on 2015-08-25 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Book Synopsis Synthesis and Reactions of Fluorine-containing Organo-silicon Compounds by : Charles 1931- Tomasino
Download or read book Synthesis and Reactions of Fluorine-containing Organo-silicon Compounds written by Charles 1931- Tomasino and published by Hassell Street Press. This book was released on 2021-09-09 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important and is part of the knowledge base of civilization as we know it. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. To ensure a quality reading experience, this work has been proofread and republished using a format that seamlessly blends the original graphical elements with text in an easy-to-read typeface. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Book Synopsis Efficient Preparations of Fluorine Compounds by : Herbert W. Roesky
Download or read book Efficient Preparations of Fluorine Compounds written by Herbert W. Roesky and published by John Wiley & Sons. This book was released on 2012-10-11 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: The definitive guide to creating fluorine-based compounds—and the materials of tomorrow Discovered as an element by the French chemist Henri Moissan in 1886, through electrolysis of potassium fluoride in anhydrous hydrogen fluoride—"le fluor," or fluorine, began its chemical history as a substance both elusive and dangerous. With a slight pale yellow hue, fluorine is at room temperature a poisonous diatomic gas. Resembling a spirit from a chemical netherworld, fluorine is highly reactive, difficult to handle, yet very versatile as a reagent—with the power to form compounds with almost any other element. Comprising 20% of pharmaceutical products and 30% of agrochemical compounds, as well as playing a key role in electric cars, electronic devices, and space technology, compounds containing fluorine have grown in importance across the globe. Learning how to safely handle fluorine in the preparation of innovative new materials—with valuable new properties—is of critical importance to chemists today. Bringing together the research and methods of leading scientists in the fluorine field, Efficient Preparations of Fluorine Compounds is the definitive manual to creating, and understanding the reaction mechanisms integral to a wide variety of fluorine compounds. With sixty-eight contributed chapters, the book's extensive coverage includes: Preparation of Elemental Fluorine Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions Direct Fluorination of Organic Compounds with Elemental Fluorine Efficient Preparations of Bioorganic Fluorine Compounds Asymmetric Fluorocyclization Reactions Preparations of Rare Earth Fluorosulfides and Oxyfluorosulfides The book offers methods and results that can be reproduced by students involved in advanced studies, as well as practicing chemists, pharmaceutical scientists, biologists, and environmental researchers. The only chemical resource of its kind, Efficient Preparations of Fluorine Compounds—from its first experiment to its last—is a unique window into the centuries old science of fluorine and the limitless universe of fluorine-based compounds.
Book Synopsis The Electrochemical Fluorination of Organosilicon Compounds by : Robert E. Seaver
Download or read book The Electrochemical Fluorination of Organosilicon Compounds written by Robert E. Seaver and published by . This book was released on 1961 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organofluorine Chemistry by : Kenji Uneyama
Download or read book Organofluorine Chemistry written by Kenji Uneyama and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: The replacement of hydrogen with fluorine in organic molecules canprofoundly influence their chemical and physical properties,leading to a range of compounds with highly desirable properties.These molecules are of interest across the wide spectrum ofindustrial and academic organic chemistry, so that organofluorinechemistry is economically highly important. Organofluorine Chemistry will help chemists to develop a systematicknowledge of the chemistry of fluorine with a view towards itsapplication in the design of new reactions and syntheses, and thecreation of novel fluorinated molecules and materials. With initialchapters focusing on why fluorine creates such unique properties inorganic compounds, the book then covers general reactions offluorine. Coverage is chosen from the recent research literature,concentrating on the development of novel bioactive compounds andcatalytic ligands, and explaining, in the context of the initialchapters, how and why fluorine is so effective. With a finalchapter covering the general synthetic chemistry of organofluorinecompounds, the book is a cohesive summary of the fundamentalprincipals of organofluorine chemistry.
Book Synopsis The Synthesis and Structure of Some Fluorine-containing Silicon Compounds by : James D. Groves
Download or read book The Synthesis and Structure of Some Fluorine-containing Silicon Compounds written by James D. Groves and published by . This book was released on 1958 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Fluorine Chemistry for Organic Chemists by : Milos Hudlic'ky
Download or read book Fluorine Chemistry for Organic Chemists written by Milos Hudlic'ky and published by Oxford University Press. This book was released on 2000-04-20 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a synthesis of two of Hudlicky's earlier books outlining the many unpredictable properties of fluorine and its compounds that are not analogous to the properties of any other halogens and their compounds. It is divided into two separate sections, the first presenting peculiar reactions as problems to be solved. Each reaction can be analyzed in the lab without the help of the second section, however if a solution is not easily reached, the second section provides discussion of the problems, outlining the products of the reactions and their mechanisms. Among the 105 reactions outlined are the introduction of fluorine into organic molecules, reduction and oxidation of fluorine compounds, reactions of fluorocompounds with halogens and their derivatives, nitration, acid catalyzed reactions, organometallic syntheses, and pyrolyses. The reactions are documented in the experimental material of the earlier volumes and will be important background knowledge for anyone working in organic chemistry.
Book Synopsis Organo-Fluorine Compounds by : Bernd Baasner
Download or read book Organo-Fluorine Compounds written by Bernd Baasner and published by Thieme Medical Publishers. This book was released on 2000-04-12 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume E10 Organo-Fluorine Compounds from the acclaimed Houben-Weyl series is now available in a WORKBENCH EDITION. A unique resource in the field, this 5-volume set provides a comprehensive treatise of the preparation and reactivity of organo-fluorine compounds presented in the high-quality format synonymous with the Houben-Weyl series. Now available in a workbench edition to give a prime source of detailed information directly in the lab. Houben-Weyl Vol. E10 Organo-Fluorine Compounds is a critical survey of the academic and patent literature, organized in a systematic and structured way and presented in 5 volumes. In Volume E10a Section A details the diverse range of fluorinating agents used to make C-F bonds. In Volumes E10b/1 and E10b/2 Section B describes in detail methods for the synthesis of fluorinated compounds from organo-fluorine precursors (the building block approach), while in Section C are outlined general reactions and reactivity of organo-fluorides. A comprehensive index is provided in Volume E10c/1 and E10c/2. Houben-Weyl Vol. E10 Organo-Fluorine Compounds is written by leading experts in the field and will prove to be an invaluable tool for the student and researcher alike well into the next millennium. For full information on the complete Houben-Weyl series, please visit the Houben-Weyl Homepage.
Book Synopsis Organofluorine Chemistry by : V. Prakash Reddy
Download or read book Organofluorine Chemistry written by V. Prakash Reddy and published by Elsevier. This book was released on 2020-03-20 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organofluorine Chemistry: Synthesis and Applications gives a comprehensive outlook on modern synthetic methodologies for organofluorine compounds. It illustrates chemical, biochemical, and materials applications of fluorine-containing compounds, including synthesis and applications of small molecule compounds in drug discovery, positron emission tomography, and fluorinated polymers in solar cells. This book is of use to scientists working in the interdisciplinary areas, such as chemical, biochemical, and biomedical engineering, as well as those involved in materials science and medicinal chemistry. It is also a useful reference for researchers and graduate students interested in organofluorine chemistry. - Provides modern synthetic methods and reactions of organofluorine compounds - Incorporates the synthesis and chemical, biochemical and biomedical applications of fluorine-containing compounds, nanomaterials, PET imaging agents, pharmaceuticals, and polymeric materials - Features emerging "hot" topics, such as late-stage fluorinations and drug discovery
Book Synopsis The Synthesis of Fluorine-containing Organic Compounds by : John Savory
Download or read book The Synthesis of Fluorine-containing Organic Compounds written by John Savory and published by . This book was released on 1961 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Houben-weyl Methods in Organic Chemistry by : Bernd Baasner
Download or read book Houben-weyl Methods in Organic Chemistry written by Bernd Baasner and published by Thieme Medical Publishers. This book was released on 2000-04-12 with total page 3956 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume E10 Organo-Fluorine Compounds from the acclaimed Houben-Weyl series is now available in a WORKBENCH EDITION. A unique resource in the field, this 5-volume set provides a comprehensive treatise of the preparation and reactivity of organo-fluorine compounds presented in the high-quality format synonymous with the Houben-Weyl series. Now available in a workbench edition to give a prime source of detailed information directly in the lab. Houben-Weyl Vol. E10 Organo-Fluorine Compounds is a critical survey of the academic and patent literature, organized in a systematic and structured way and presented in 5 volumes. In Volume E10a Section A details the diverse range of fluorinating agents used to make C-F bonds. In Volumes E10b/1 and E10b/2 Section B describes in detail methods for the synthesis of fluorinated compounds from organo-fluorine precursors (the building block approach), while in Section C are outlined general reactions and reactivity of organo-fluorides. A comprehensive index is provided in Volume E10c/1 and E10c/2. Houben-Weyl Vol. E10 Organo-Fluorine Compounds is written by leading experts in the field and will prove to be an invaluable tool for the student and researcher alike well into the next millennium. For full information on the complete Houben-Weyl series, please visit the Houben-Weyl Homepage
Book Synopsis The Use of Organometallic Derivatives in the Preparation of Some Organic Fluorine Compounds - Primary Source Edition by : Dale Alford Warner
Download or read book The Use of Organometallic Derivatives in the Preparation of Some Organic Fluorine Compounds - Primary Source Edition written by Dale Alford Warner and published by Nabu Press. This book was released on 2013-10 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a reproduction of a book published before 1923. This book may have occasional imperfections such as missing or blurred pages, poor pictures, errant marks, etc. that were either part of the original artifact, or were introduced by the scanning process. We believe this work is culturally important, and despite the imperfections, have elected to bring it back into print as part of our continuing commitment to the preservation of printed works worldwide. We appreciate your understanding of the imperfections in the preservation process, and hope you enjoy this valuable book.
Book Synopsis Organo-Fluorine Compounds Methods Index by : Bernd Baasner
Download or read book Organo-Fluorine Compounds Methods Index written by Bernd Baasner and published by Thieme Medical Publishers. This book was released on 2000-04-12 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume E10 Organo-Fluorine Compounds from the acclaimed Houben-Weyl series is now available in a WORKBENCH EDITION. A unique resource in the field, this 5-volume set provides a comprehensive treatise of the preparation and reactivity of organo-fluorine compounds presented in the high-quality format synonymous with the Houben-Weyl series. Now available in a workbench edition to give a prime source of detailed information directly in the lab. Houben-Weyl Vol. E10 Organo-Fluorine Compounds is a critical survey of the academic and patent literature, organized in a systematic and structured way and presented in 5 volumes. In Volume E10a Section A details the diverse range of fluorinating agents used to make C-F bonds. In Volumes E10b/1 and E10b/2 Section B describes in detail methods for the synthesis of fluorinated compounds from organo-fluorine precursors (the building block approach), while in Section C are outlined general reactions and reactivity of organo-fluorides. A comprehensive index is provided in Volume E10c. Houben-Weyl Vol. E10 Organo-Fluorine Compounds is written by leading experts in the field and will prove to be an invaluable tool for the student and researcher alike well into the next millennium. For full information on the complete Houben-Weyl series, please visit the Houben-Weyl Homepage
Book Synopsis Synthesis of Organo-fluorine Compounds by Metal Complex-mediated and -Catalyzed Transformations of Fluoro-alkenes and Fluoro-arenes by : Nicholas Orlando Andrella
Download or read book Synthesis of Organo-fluorine Compounds by Metal Complex-mediated and -Catalyzed Transformations of Fluoro-alkenes and Fluoro-arenes written by Nicholas Orlando Andrella and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The prevalence of fluorine in natural products is scarce. There are but a handful of compounds that have been discovered to date. This could be largely attributable to the occurrence of fluorine in nature as fluoride (F-). - One might recognize such nomenclature from the ingredients list on a toothpaste tube - In fact, naturally occurring fluoride is most commonly found as fluorite (CaF2) or cryolite (Na3AlF6). As such, the introduction of fluorine via biological pathways has been limited to use of aqueous F- (a very poor nucleophile). This fact - coupled with its naturally low concentration in water - has created the ripe conditions for this shortage. In a way this has proven fertile for synthetic chemists because nature has not yet evolved a method for the deconstruction of partially or fully fluorinated compounds. Considering the above, as synthetic methodologies for the construction of carbon-fluorine bonds became available, so too did the discovery of their valuable properties. So beneficial are these properties that C-F bond-containing compounds have become commonplace in many households throughout the world. For example, practically every home relies on these compounds for use in their refrigerators. Other examples of useful fluorinated materials include blowing agents, non-stick coatings, pharmaceuticals, agrochemicals, liquid crystals, and lubricants. With all these applications and seemingly easy availability of these compounds, it is interesting to learn that original synthetic methods are still being employed today. As such, the objective of this Thesis is to develop 'greener' routes for the synthesis of fluorocarbons. We hypothesized that by studying transition metal-fluoroalkyl complex-mediated reactions, a more efficient catalytic system could be developed. A foreseen complication arises from the thermodynamic stability of C-F, transition metal-F and transition metal-CRF bonds. Improvements to overcome these caveats include the use of first-row late transition metal complexes. Presented herein are additions to this body of knowledge by expanding on the reactivity of nickel, copper and silver fluoroalkyl complexes. The approach applied in this work, in line with 'green' chemistry principles, was to source readily available fluorinated reagents, i.e. fluoroalkenes and fluoroarenes, to reduce the number of steps for the synthesis of new fluorinated compounds. Chapter 2 builds on the well-established oxidative cyclization of C2 fluoroalkenes to nickel (0), which yields new C4 units. The use of a bulky N-heterocyclic carbene ligand was found to enhance reactivity by reducing the coordination number at nickel. Examples of room temperature C?-F and Ni-CF bond activation and functionalization reactions are presented. Chapters 3, 4 and 5 re-examine the insertion of fluoroalkenes into silver and copper fluorides and hydrides. Building on precedent of addition reactions to hexafluoropropene, this fluoroalkene was examined first. In so doing, a versatile and inexpensive copper heptafluoroisopropyl reagent was developed (Cu-F addition to (CF3)CF=CF2. With easy access to new heptafluoroisopropyl complexes, they were systemically studied for their applications in catalysis. This revealed key features, particularly the lability of the M-hfip bond, which could be detrimental to catalytic reactions. As such, a nickel complex-mediated carbonylative heptafluoroisopropylation reaction and copper complex-mediated nucleophilic addition to electrophiles were developed. When a copper hydride was used instead, the in situ generated fluoroalkyl [Cu-H addition to (CF3)CF=CF2] was susceptible to ?-fluoride elimination. Chapter 4 expands this methodology to achieve the catalytic consecutive hydrodefluorination of fluoroalkenes, demonstrating the scope and limitations of this system. Furthermore, the critical role of the phosphine ligand in accessing an L3Cu-H addition and unusual ?-fluoride elimination mechanism is highlighted. However, tetrafluoroethylene proved resistant to this reaction because the fluoroalkyl resting state of this alkene, Cu-CF2CF2H, is unusually robust. Chapter 5 investigates the utility of this fragment and others in C(sp2)-RF cross-coupling and nucleophilic substitutions. With focus on new routes for late stage fluorination and examples of nickel (0) complex-catalyzed selective C-F bond functionalization reactions, Chapter 5, continues studies for low-temperature and DMAP-assisted conditions for aryl-F cross-coupling reactions with boronic acid esters. Lastly, Chapter 6 reviews the advances presented in this Thesis, provides a link to the expected lasting impacts and attempts to provide guidance to future research on transition-metal complexes in the synthesis of C-F or C-RF containing compounds. Moreover, with the introduction of a new hydrodefluorination technology, previously scarce fluoroalkenes (e.g. 1,2-difluoroethylene) can now be used more freely, potentially leading to the development of new refrigerants or materials applications.
Book Synopsis Chemistry of Organic Fluorine Compounds by : Milos Hudlicky
Download or read book Chemistry of Organic Fluorine Compounds written by Milos Hudlicky and published by Prentice Hall. This book was released on 1992 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: This republication of an established classic coincides with a surge in the indistrial development of fluorine chemistry. Comprehensive and authoritative, it provides finger tip access to methods for introducing small or large numbers of fluorine atoms into organic chemistry. Serving as a practical bench manual and source book for theoretical and industrial knowledge, the reference provides 3,857 references to the original literature; 1,520 illustrated equations indicating reactions and yields of fluorinated products; more than 200 detailed experimental procedures indicating types of reagent that can be used, types of compounds with which they react, and types of products that can be prepared; over 200 tables of highly relevant data; and much more.
Book Synopsis New Approaches in the Synthesis of Fluorine Containing Organic Compounds Using Radical Reagents by :
Download or read book New Approaches in the Synthesis of Fluorine Containing Organic Compounds Using Radical Reagents written by and published by . This book was released on 1998 with total page 109 pages. Available in PDF, EPUB and Kindle. Book excerpt:
