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The Kinetics Of Evolution Of Water Vapor Clusters In Air
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Book Synopsis The Kinetics of Evolution of Water Vapor Clusters in Air by :
Download or read book The Kinetics of Evolution of Water Vapor Clusters in Air written by and published by . This book was released on 1975 with total page 141 pages. Available in PDF, EPUB and Kindle. Book excerpt: The kinetic theory of cluster formation in a condensing gas proposed by Buckle (1) attempts to calculate the course of homogeneous condensation from molecular rather than thermodynamic precepts. Here it is applied to the rapid nonequilibrium expansion of atmospheric water vapor in air. A method is established for demonstrating the validity of this theory, originally proposed for a mono-molecular gas, in the case of a complicated species such as water vapor. Cluster conditions in the temperature range 210-295 K and the vapor pressure are calculated throughout the collapse of a supersaturated metastable vapor. An effective molecular pair interaction energy and nearest neighbor coordination number is found based on the classical zero-point enthalpy of sublimation and by iteration to satisfy initial equilibrium limiting constraints at 273 K. The internal energy redistribution frequency results from close matching of the experimental pressure distribution. A method of determining the cluster size at which macroscopic properties become relevant is described; the size is found to be a cluster of about 122 molecules at 273 K based on a hard sphere model collision cross section. For the water vapor dimer an equilibrium constant of 4 x 10 to the -21st power/cc is found at 273 K compared to 3.1 x 10 to the -21st power/cc obtained from Keyes data. Two models for water vapor clusters result (from satisfying all constraints imposed on the theory) which are given in terms of number of nearest neighbors, pair interaction energy per molecule (2.9kcal/mol at 273 K) and possible structure on a cluster by cluster basis for a classical hard sphere model and for a model approximating a Pauling type clathrate.
Book Synopsis Scientific and Technical Aerospace Reports by :
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Book Synopsis Hydraulic Research in the United States and Canada, 1974 by : Pauline H. Gurewitz
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Book Synopsis Hydraulic Research in the United States and Canada by :
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Book Synopsis Growth Kinetics of Water Clusters by : Jeffrey John Kolstad
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Book Synopsis UTIAS Review by : University of Toronto. Institute for Aerospace Studies
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