Author :
Publisher :
ISBN 13 : 9780542458071
Total Pages : pages
Book Rating : 4.4/5 (58 download)
Book Synopsis The Effects of Particle Anisotropy on the Rheology and Microstructure of Concentrated Colloidal Suspensions Through the Shear Thickening Transition by :
Download or read book The Effects of Particle Anisotropy on the Rheology and Microstructure of Concentrated Colloidal Suspensions Through the Shear Thickening Transition written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Though suspensions comprised of anisotropic particles are ubiquitous in industry, little has been done to elucidate the effects of particle anisotropy on concentrated suspension rheology, or the mechanism responsible for the reversible shear thickening observed in these systems. This dissertation explores the rheology and shear-induced microstructure of anisotropic particle suspensions through the shear thickening transition, and provides the first account of anisotropic particle alignment during shear thickening. For this investigation, Poly(ethylene glycol) (PEG)-based suspensions of acicular precipitated calcium carbonate (PCC) particles of varying particle aspect ratio (nominal L/D & sim; 2, 4, 7) are generated that demonstrate both continuous and discontinuous reversible shear thickening with increasing applied shear rate or stress. The critical volume fraction for the onset of discontinuous shear thickening decreases as the average particle aspect ratio is increased. However, the critical stress for shear thickening is found to be independent of particle anisotropy and volume fraction, and can be predicted based on the minor axis dimension of the particles in agreement with the critical stress scaling for hard-sphere suspensions. Small angle neutron scattering during shear flow (Rheo-SANS) demonstrates that long-axis particle alignment with the flow direction is maintained throughout the range of shear stresses investigated, including the shear thickening regimes for both continuous and discontinuous shear thickening PCC/PEG suspensions. Investigations of particle flow alignment following flow cessation provide evidence that the critical volume fraction for shear thickening may be associated with an isotropic-nematic transition within the anisotropic particle suspensions. Rheo-SANS investigations of concentrated kaolin clay suspensions demonstrate that disk-shaped particles exhibit particle alignment with the face surfaces orthogonal to the gradient direction during both continuous and discontinuous shear thickening. The critical stress at the onset of shear thickening for discontinuous shear thickening clay suspensions is observed to scale with the particle thickness dimension. The rheology and Rheo-SANS observations for both the acicular PCC and disk-like kaolin clay suspensions invalidate earlier hypothesis suggesting that shear thickening behavior in anisotropic particle dispersions results from increased particle rotations out of flow alignment potentially leading to particle jamming. Rather, the observations suggest that shear thickening in anisotropic particle suspensions is a consequence of short range hydrodynamic lubrication forces resulting in the formation of hydroclusters at higher shear rates, analogous to the behavior established for spherical particle suspensions. Lastly, anisotropic particle suspensions are used to successfully develop of shear thickening fluid (STF)/ballistic fabric composites. Shape anisotropy imparts the advantage of lower solids loading required to achieve energy dissipative improvements compared to spherical particle STFs. The observed improvements in ballistic and stab resistance response of these composites over that of ballistic fabrics alone suggests that they could potentially be used in the development of personal body armors with improved, multi-threat protective capabilities.
