Synthesis, Characterization and Photophysical Studies of RU(II) Bipyridyl-dithiocarbamate Complexes as Sensitizers for Dye Sensitized Solar Cells

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ISBN 13 :
Total Pages : 254 pages
Book Rating : 4.:/5 (15 download)

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Book Synopsis Synthesis, Characterization and Photophysical Studies of RU(II) Bipyridyl-dithiocarbamate Complexes as Sensitizers for Dye Sensitized Solar Cells by : Zintle Fudo

Download or read book Synthesis, Characterization and Photophysical Studies of RU(II) Bipyridyl-dithiocarbamate Complexes as Sensitizers for Dye Sensitized Solar Cells written by Zintle Fudo and published by . This book was released on 2018 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and characterization of cyanuric-based dye-sensitizer for solar cells, their photo-response in the visible Region and chemosensing properties

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ISBN 13 :
Total Pages : 96 pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Synthesis and characterization of cyanuric-based dye-sensitizer for solar cells, their photo-response in the visible Region and chemosensing properties by : Dan Simasiku Mabuku

Download or read book Synthesis and characterization of cyanuric-based dye-sensitizer for solar cells, their photo-response in the visible Region and chemosensing properties written by Dan Simasiku Mabuku and published by . This book was released on 2021 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis, characterization and photoresponse properties of ruthenium-based dye sensitizers for solar cells

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ISBN 13 :
Total Pages : 236 pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Synthesis, characterization and photoresponse properties of ruthenium-based dye sensitizers for solar cells by : Paulina Tuulikefo Endjala

Download or read book Synthesis, characterization and photoresponse properties of ruthenium-based dye sensitizers for solar cells written by Paulina Tuulikefo Endjala and published by . This book was released on 2020 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis of Photosensitizing Molecules and Fabrication of Inorganic Nanostructures for Dye-Sensitized Solar Cell

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Publisher : Open Dissertation Press
ISBN 13 : 9781361309025
Total Pages : pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Synthesis of Photosensitizing Molecules and Fabrication of Inorganic Nanostructures for Dye-Sensitized Solar Cell by : Hung-Tat Chan

Download or read book Synthesis of Photosensitizing Molecules and Fabrication of Inorganic Nanostructures for Dye-Sensitized Solar Cell written by Hung-Tat Chan and published by Open Dissertation Press. This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Synthesis of Photosensitizing Molecules and Fabrication of Inorganic Nanostructures for Dye-sensitized Solar Cell" by Hung-tat, Chan, 陳鴻達, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Dye-sensitized solar cells (DSSC) have drawn much attention due to their higher versatility and lower production cost compared to inorganic photovoltaics. The top performers of DSSC have achieved power conversion efficiency over 10%, which is comparable to amorphous silicon solar cells. In this work, new photosensitizers and nanostructure for improving the photovoltaic performance of DSSC were developed and evaluated. Two series of cyclometalated ruthenium(II) complex photosensitizer were presented and their photosensitizing properties in DSSC were studied. Eight cyclometalated ruthenium(II) terpyridine complexes with three carboxylic acid groups on the terpyridine ligand were synthesized. Series A (M1 to M4) consist of C, N, N' ligands substituted with phenyl group whereas series B (M5 to M8) consist of C, N, N' ligands substituted with m-fluorophenyl group. All of the complexes exhibited broad aborption spectra covering the whole visible spectrum. The complexes in series B generally showed better photovoltaic performance than those in series A in the DSSCs. DSSC fabricated from M7 achieved the highest Voc, Jsc and power conversion efficiency among other DSSC, which were 0.56 V, 7.30 mAcm-2 and 2.63 % respectively. Truxene-core donor--acceptor dyes were presented and their photosensitizing properties in DSSC were studied. Eight dyes with either one donor two acceptors system (T2, B2, T2R and B2R) or two donor one acceptor system (T1, B1, T1R and B1R) were synthesized. Dyes with two acceptors have high molar extinction coefficients originated from the charge-transfer transition band, which are almost two times higher than those with only one accceptors. Both the enhanced absorption and better anchoring geometry on TiO2 contribute to the better photovoltaic performance of the two acceptors dyes in the DSSCs. Devices fabricated from B2 and volatile solvent electrolyte exhibited the best photovoltaic performance among the truxene-core dyes. The Voc, Jsc, FF and power conversion efficiency of the device were 0.59 V, 9.69 mAcm-2, 0.63 and 3.62 % respectively. Dyes based on cyanoacrylic acid anchoring groups (T1, T2, B1 and B2) were found to perform better than those based on rhodanine-3-acetic acid dyes (T1R, T2R, B1R and B2R) in both donor--acceptor configurations. ITO nanorod/TiO2 nanoparticle composite films with the three different types of ITO nanorod with different length (150 nm, 600 nm and 1.5 μm) were fabricated on FTO glass substrate. The transmittance and sheet resistance of the ITO nanorod array on the FTO glass substrate were found decreased with increasing the length of the ITO nanorod. When the ITO nanorod/TiO2 nanoparticle composite films were applied as the anode in DSSCs, the device fabricated from 600 nm ITO nanorod with TiO2 'double layer' film showed enhanced photocurrent generation. The improved photocurrent generation is suggested to be due to an improved charge collection efficiency at the ITO nanorod back electrode. DOI: 10.5353/th_b4784934 Subjects: Nanostructured materials - Synthesis Dye-sensitized solar cells

Synthesis and Evaluation of Novel Sensitizers for Dye-sensitized Solar Cells

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ISBN 13 :
Total Pages : 98 pages
Book Rating : 4.:/5 (926 download)

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Book Synopsis Synthesis and Evaluation of Novel Sensitizers for Dye-sensitized Solar Cells by : Boyang Chu

Download or read book Synthesis and Evaluation of Novel Sensitizers for Dye-sensitized Solar Cells written by Boyang Chu and published by . This book was released on 2015 with total page 98 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of Organic Ligands and the Corresponding Ru Dyes for Dye-Sensitized Solar Cells

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Synthesis and Characterization of Organic Ligands and the Corresponding Ru Dyes for Dye-Sensitized Solar Cells by : Baharak Bakhshaei

Download or read book Synthesis and Characterization of Organic Ligands and the Corresponding Ru Dyes for Dye-Sensitized Solar Cells written by Baharak Bakhshaei and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Heteroleptic Ru(II) Bipyridyl Complexes with Asymmetric Bis Ancillary Ligands for Dye-Sensitized Solar Cells

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ISBN 13 :
Total Pages : 119 pages
Book Rating : 4.:/5 (112 download)

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Book Synopsis Heteroleptic Ru(II) Bipyridyl Complexes with Asymmetric Bis Ancillary Ligands for Dye-Sensitized Solar Cells by : Mira K Abed

Download or read book Heteroleptic Ru(II) Bipyridyl Complexes with Asymmetric Bis Ancillary Ligands for Dye-Sensitized Solar Cells written by Mira K Abed and published by . This book was released on 2019 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Design and Synthesis of Core-modified Porphyrin Sensitizers for Dye-sensitized Solar Cells

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (895 download)

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Book Synopsis Design and Synthesis of Core-modified Porphyrin Sensitizers for Dye-sensitized Solar Cells by : Sandeep Baruwahan Mane

Download or read book Design and Synthesis of Core-modified Porphyrin Sensitizers for Dye-sensitized Solar Cells written by Sandeep Baruwahan Mane and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of Transition Metal Based Dyes for the Application in Dye Sensitized Solar Cells

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ISBN 13 :
Total Pages : 34 pages
Book Rating : 4.:/5 (915 download)

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Book Synopsis Synthesis and Characterization of Transition Metal Based Dyes for the Application in Dye Sensitized Solar Cells by :

Download or read book Synthesis and Characterization of Transition Metal Based Dyes for the Application in Dye Sensitized Solar Cells written by and published by . This book was released on 2014 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Synthesis of Solar Cell Dyes

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis The Synthesis of Solar Cell Dyes by : Yasmeen Abdullah Hameed

Download or read book The Synthesis of Solar Cell Dyes written by Yasmeen Abdullah Hameed and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Copper(I) Polypyridine Complexes

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ISBN 13 :
Total Pages : 240 pages
Book Rating : 4.:/5 (69 download)

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Book Synopsis Copper(I) Polypyridine Complexes by : Ana Hernández Redondo

Download or read book Copper(I) Polypyridine Complexes written by Ana Hernández Redondo and published by . This book was released on 2009 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Investigation of Dibenzo[b, J][1,10]phenanthroline and N-Propanoic Acid Spiropyrans and Spirooxazines for Use in Dye-Sensitized Solar Cells

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ISBN 13 :
Total Pages : 276 pages
Book Rating : 4.:/5 (972 download)

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Book Synopsis Investigation of Dibenzo[b, J][1,10]phenanthroline and N-Propanoic Acid Spiropyrans and Spirooxazines for Use in Dye-Sensitized Solar Cells by : Noah Johnson

Download or read book Investigation of Dibenzo[b, J][1,10]phenanthroline and N-Propanoic Acid Spiropyrans and Spirooxazines for Use in Dye-Sensitized Solar Cells written by Noah Johnson and published by . This book was released on 2016 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Finding alternative energy sources is one of the great problems of science today. One potential solution, the dye-sensitized solar cell (DSSC) has been studied thoroughly since its discovery in 1991. They are composed of a sensitizing dye adsorbed on to the surface of a semiconducting metal oxide. Much research has been done trying to improve the DSSC efficiency, mainly by creating new derivatives of the sensitizing dye. However, despite the large number of derivatives made, most have utilized the same strategy of extending conjugation to increase overall efficiency. In this work, I investigated a different class of compounds, the dibenzo[b, j][1,10]phenanthrolines, which highlight the effect of extended aromaticity on the properties of ruthenium-based DSSCs. First, I developed a synthetic scheme which improves upon those used before, opening up the possibility of creating a library of compounds to be used for future investigations. Second, the chemistry of these compounds was investigated, which was shown to be different from the [1,10]phenanthrolines. Specifically, they were shown to be more sensitive to oxidative, reductive, and alkaline conditions, along with being more resistant to formation via the Pd-catalyzed dehydrogenation. Finally, these compounds were evaluated for their ability to form a DSSC, showing low conversion efficiencies, but with promise for better results in the future. This lays the groundwork for the creation of a library of DSSCs based on this backbone. As well, we report the creation of color-changing dye-sensitized solar cells (DSSCs) using N-propanoic functionalized spiropyrans and spirooxazines. We investigated the photophysical properties of these compounds in various solvents and pH conditions using UV-Vis spectroscopy, and their behavior on a TiO2 surface using a combination of UV-Vis and FT-IR. Their performance as sensitizing dyes for DSSCs was analyzed. This study reveals a number of properties for this class of compounds that affect their performance as both photochromic compounds and DSSC sensitizers, which allow for future creation of an efficient photochromic DSSC.

Inorganic Photochemistry

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Publisher : Academic Press
ISBN 13 : 0123859050
Total Pages : 461 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Inorganic Photochemistry by :

Download or read book Inorganic Photochemistry written by and published by Academic Press. This book was released on 2011-07-14 with total page 461 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. Features comprehensive reviews on the latest developments Includes contributions from leading experts in the field Serves as an indispensable reference to advanced researchers

Macromolecular Syntheses

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ISBN 13 :
Total Pages : 180 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Macromolecular Syntheses by : Charles Gilbert Overberger

Download or read book Macromolecular Syntheses written by Charles Gilbert Overberger and published by . This book was released on 2002 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an up-to-date collection of presentations and posters given at a tutorial and workshop sponsored by the Polymer Division of the American Chemical Society. The material included encompasses recent research results, overviews of critical areas and short presentations in the form of posters and preprints. The book is targeted at established workers in the field of fluoropolymers as well as those wishing to develop a quick understanding of current knowledge and trends in this important field.

Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science

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Publisher : Springer Nature
ISBN 13 : 3030548511
Total Pages : 249 pages
Book Rating : 4.0/5 (35 download)

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Book Synopsis Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science by : Lai Chung Liu

Download or read book Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science written by Lai Chung Liu and published by Springer Nature. This book was released on 2020-09-10 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: The thesis provides the necessary experimental and analytical tools to unambiguously observe the atomically resolved chemical reactions. A great challenge of modern science has been to directly observe atomic motions during structural transitions, and while this was first achieved through a major advance in electron source brightness, the information content was still limited and new methods for image reconstruction using femtosecond electron diffraction methods were needed. One particular challenge lay in reconciling the innumerable possible nuclear configurations with the observation of chemical reaction mechanisms that reproducibly give the same kind of chemistry for large classes of molecules. The author shows that there is a simple solution that occurs during barrier crossing in which the highly anharmonic potential at that point in nuclear rearrangements couples high- and low-frequency vibrational modes to give highly localized nuclear motions, reducing hundreds of potential degrees of freedom to just a few key modes. Specific examples are given in this thesis, including two photoinduced phase transitions in an organic system, a ring closure reaction, and two direct observations of nuclear reorganization driven by spin transitions. The emerging field of structural dynamics promises to change the way we think about the physics of chemistry and this thesis provides tools to make it happen.

Energy Efficiency and Renewable Energy Through Nanotechnology

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Publisher : Springer Science & Business Media
ISBN 13 : 0857296388
Total Pages : 937 pages
Book Rating : 4.8/5 (572 download)

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Book Synopsis Energy Efficiency and Renewable Energy Through Nanotechnology by : Ling Zang

Download or read book Energy Efficiency and Renewable Energy Through Nanotechnology written by Ling Zang and published by Springer Science & Business Media. This book was released on 2011-09-06 with total page 937 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reflecting the rapid growth of nanotechnology research and the potential impact of the growing energy crisis, Energy Efficiency and Renewable Energy Through Nanotechnology provides comprehensive coverage of cutting-edge research in the energy-related fields of nanoscience and nanotechnology, which aim to improve energy efficiency and the generation of renewable energy. Energy Efficiency and Renewable Energy Through Nanotechnology tightly correlates nanotechnology with energy issues in a general, comprehensive way that makes it not only suitable as a desk reference for research, but also as a knowledge resource for the non-expert general public. Readers will find Energy Efficiency and Renewable Energy Through Nanotechnology useful in a variety of ways, ranging from the creation of energy policy, to energy research development, and to education in nanotechnology and its application to energy-related problems. It can also be used as a primary or supplementary textbook for energy-related courses for advanced undergraduate and graduate students.

Immobilized Catalysts

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540209157
Total Pages : 354 pages
Book Rating : 4.2/5 (91 download)

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Book Synopsis Immobilized Catalysts by : Andreas Kirschning

Download or read book Immobilized Catalysts written by Andreas Kirschning and published by Springer Science & Business Media. This book was released on 2004-11-22 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: R. Haag, S. Roller: Polymeric Supports for the Immobilisation of Catalysts .- J. Horn, F. Michalek, C.C. Tzschucke, W. Bannwarth: Non-Covalently Solid-Phase Bound Catalysts for Organic Synthesis .- Y. Uozumi: Recent Progress in Polymeric Palladium Catalysts for Organic Synthesis .- D.E. Bergbreiter, J. Li: Applications of Catalysts on Soluble Supports .- B. Desai, C.O. Kappe: Microwave-Assisted Synthesis Involving Immobilized Catalysts .- A. Kirschning, G. Jas: Applications of Immobilized Catalysts in Continuous Flow Processes .- N. End, K.-U. Schöning: Immobilized Catalysts in Industrial Research and Application .- N. End, K.-U. Schöning: Immobilized Biocatalysts in Industrial Research and Production