Synthesis and Chemistry of Yttrium and Lanthanide Metal Complexes. Progress Report, March 15, 1991--March 14, 1992

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ISBN 13 :
Total Pages : 8 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Synthesis and Chemistry of Yttrium and Lanthanide Metal Complexes. Progress Report, March 15, 1991--March 14, 1992 by :

Download or read book Synthesis and Chemistry of Yttrium and Lanthanide Metal Complexes. Progress Report, March 15, 1991--March 14, 1992 written by and published by . This book was released on 1991 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this research project is to determine the special features of complexes of yttrium and the lanthanide metals which will allow the design and synthesis of materials with unique chemical, physical, and catalytic properties. Past studies of yttrium and lanthanide metal alkyl and hydride complexes stabilized by cyclopentadienyl co-ligands have shown that a substantial, often singular, organometallic chemistry is available via these metals. More extensive utilization of the chemical opportunities available through yttrium and the lanthanides would be possible, however, if stabilizing ancillary ligand systems less sensitive to oxidation and protonolysis than cyclopentadienides could be developed. Alkoxide ligands are attractive in this regard and our recent research had focused on alkoxides and the special opportunities they can provide to these metals. 6 refs., 10 figs.

Energy Research Abstracts

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ISBN 13 :
Total Pages : 358 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1992-03 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Government Reports Annual Index

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ISBN 13 :
Total Pages : 1114 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Government Reports Annual Index by :

Download or read book Government Reports Annual Index written by and published by . This book was released on 1992 with total page 1114 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sections 1-2. Keyword Index.--Section 3. Personal author index.--Section 4. Corporate author index.-- Section 5. Contract/grant number index, NTIS order/report number index 1-E.--Section 6. NTIS order/report number index F-Z.

Synthesis and Chemistry of Yttrium and Lanthanide Metal Complexes

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (684 download)

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Book Synopsis Synthesis and Chemistry of Yttrium and Lanthanide Metal Complexes by :

Download or read book Synthesis and Chemistry of Yttrium and Lanthanide Metal Complexes written by and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall objective of this research project is to develop the basic chemistry of complexes of the lanthanide metals which will allow the design and synthesis of materials with unique chemical, physical, and catalytic properties. This report summarizes advances made since the last three year progress report in October 1995. During this time, references 1-16 have been published, references 17-20 have been accepted for publication, and references 21-22 have been submitted for publication. Highlights only of these results are reported here in sections on polymetallic europium chemistry, polymetallic Zirconium chemistry, alkyl alkoxide chemistry, fundamental lanthanide halide chemistry, and arylamido complexes.

Government Reports Announcements & Index

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ISBN 13 :
Total Pages : 576 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Government Reports Announcements & Index by :

Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1992 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organometallic and Surface Chemistry of Mixed-metal Systems. Progress Report, March 15, 1992--March 14, 1993

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ISBN 13 :
Total Pages : 4 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Organometallic and Surface Chemistry of Mixed-metal Systems. Progress Report, March 15, 1992--March 14, 1993 by :

Download or read book Organometallic and Surface Chemistry of Mixed-metal Systems. Progress Report, March 15, 1992--March 14, 1993 written by and published by . This book was released on 1993 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three new SO2 complexes of metal cluster compounds were prepared: [PPN][HFe3(CO)9SO2], and [PPN]2[Ru3CO9SO2] and [PPN]2[Ru3(CO)--(SO2)3]. The x-ray structures were determined for two of these and the transformation of bound SO2 to duster bound SO and S ligands was investigated.

Lanthanides And Actinides, The: Synthesis, Reactivity, Properties And Applications

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Publisher : World Scientific
ISBN 13 : 1800610173
Total Pages : 727 pages
Book Rating : 4.8/5 (6 download)

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Book Synopsis Lanthanides And Actinides, The: Synthesis, Reactivity, Properties And Applications by : Stephen T Liddle

Download or read book Lanthanides And Actinides, The: Synthesis, Reactivity, Properties And Applications written by Stephen T Liddle and published by World Scientific. This book was released on 2021-12-30 with total page 727 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications constitutes an introduction to and comprehensive coverage of f-block chemistry encompassing the following areas: periodicity, natural occurrence and extraction, separations, electronic structure, coordination chemistry, organometallic chemistry, small molecule activation, catalysis, organic synthesis applications, magnetism, spectroscopy, computation, materials, photonics, solar cell technology, biological imaging, and technological applications. Under these subject areas the book provides a broad but deep coverage, providing basic overviews as well as detailed chapters on specific areas.This book, targeted at academics, postgraduates and advanced undergraduates, will serve as an ideal introductory text and key reference work to the Lanthanides and Actinides.

Synthesis, Chemistry, and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report, February 1, 1977--January 31, 1978

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Synthesis, Chemistry, and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report, February 1, 1977--January 31, 1978 by :

Download or read book Synthesis, Chemistry, and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report, February 1, 1977--January 31, 1978 written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Research devoted to synthesis of new classes of lanthanide and actinide complexes is reported. Co-condensation of lanthanide metals with 1,3-butadiene (1,3-C4H6) or 2,3-dimethyl-1,3-butadiene (2,3-(CH3)2-1,3-C4H4) produces three types of organolanthanide complexes differentiated by their solubility in pentane, toluene and tetrahydrofuran (THF). The THF soluble species are formed in highest yield and have been most completely characterized. Elemental analysis shows that when butadiene is the ligand, complexes of empirical formula Ln(C4H6)3 (Ln = Nd, Sm, Er) are obtained. When dimethylbutadiene is used, Ln((CH3)2C4H4)2 is obtained (Ln = La, Nd, Sm, Er). These compounds differ from all other organolanthanide complexes in several respects. First, it is unusual to be able to obtain such good analytical data. Generally, for organolanthanides, incomplete carbon and hydrogen combustion is observed. Second, the stoichiometries are difficult to reconcile with known lanthanide chemistry. If the dienes coordinate as .pi.-ligands, the metals are formally zero-valent. If the dienes coordinate as dialkyl-2-butene moieties, the metals must be in the +6 oxidation state in the butadiene series and the +4 oxidation state in the dimethylbutadiene series. The physical properties of these new complexes are also unusual. The sharp, line-like, 4f-4f optical transitions normally observed for lanthanide complexes are not observed in the visible and near infrared regions. Instead a single broad band dominates the spectrum. The room temperature magnetic moments are similarly not consistent with known Ln/sup 3 +/ species. Most unusual in this respect is the lanthanum complex, which is the first paramagnetic organolanthanum complex ever observed. Further investigations of diene reactions with lanthanides in chemical reduction syntheses are summarized. (JRD).

Synthesis, Chemistry and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report for Period February 1, 1980-January 31, 1981. [none].

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Synthesis, Chemistry and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report for Period February 1, 1980-January 31, 1981. [none]. by :

Download or read book Synthesis, Chemistry and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report for Period February 1, 1980-January 31, 1981. [none]. written by and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Investigations are being conducted on two classes of lanthanide compounds: metal vapor co-condensation reactions with unsaturated hydrocarbons and homoleptic and heteroleptic alkyl lanthanide complexes. Three models have been considered for the interaction of erbium atoms with 3-hexyne. The structure of the heteroleptic alkynide ((C5H5)2ErC triple bond CCMe3)2 was studied. Some new organolanthanides have been prepared. (DLC).

The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)

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Publisher : Springer Science & Business Media
ISBN 13 : 1402035985
Total Pages : 4059 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) by : L.R. Morss

Download or read book The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2007-12-31 with total page 4059 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.

CRC Handbook of Metal Etchants

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Publisher : CRC Press
ISBN 13 : 9781439822531
Total Pages : 1434 pages
Book Rating : 4.8/5 (225 download)

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Book Synopsis CRC Handbook of Metal Etchants by : Perrin Walker

Download or read book CRC Handbook of Metal Etchants written by Perrin Walker and published by CRC Press. This book was released on 1990-12-11 with total page 1434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication presents cleaning and etching solutions, their applications, and results on inorganic materials. It is a comprehensive collection of etching and cleaning solutions in a single source. Chemical formulas are presented in one of three standard formats - general, electrolytic or ionized gas formats - to insure inclusion of all necessary operational data as shown in references that accompany each numbered formula. The book describes other applications of specific solutions, including their use on other metals or metallic compounds. Physical properties, association of natural and man-made minerals, and materials are shown in relationship to crystal structure, special processing techniques and solid state devices and assemblies fabricated. This publication also presents a number of organic materials which are widely used in handling and general processing...waxes, plastics, and lacquers for example. It is useful to individuals involved in study, development, and processing of metals and metallic compounds. It is invaluable for readers from the college level to industrial R & D and full-scale device fabrication, testing and sales. Scientific disciplines, work areas and individuals with great interest include: chemistry, physics, metallurgy, geology, solid state, ceramic and glass, research libraries, individuals dealing with chemical processing of inorganic materials, societies and schools.

Inorganometallic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1489924590
Total Pages : 409 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Inorganometallic Chemistry by : Thomas P. Fehlner

Download or read book Inorganometallic Chemistry written by Thomas P. Fehlner and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a certain fascination associated with words. The manipulation of strings of symbols according to mutually accepted rules allows a language to express history as well as to formulate challenges for the future. But language changes as old words are used in a new context and new words are created to describe changing situations. How many words has the computer revolution alone added to languages? "Inorganometallic" is a word you probably have never encountered before. It is one created from old words to express a new presence. A strange sounding word, it is also a term fraught with internal contradiction caused by the accepted meanings of its constituent parts. "In organic" is the name of a discipline of chemistry while "metallic" refers to a set of elements constituting a subsection of that discipline. Why then this Carrollian approach to entitling a set of serious academic papers? Organic, the acknowledged doyenne of chemistry, is distinguished from her brother, inorganic, by the prefix "in," i. e. , he gets everything not organic. Organometallic refers to compounds with carbon-metal bonds. It is simple! Inorganometallic is everything else, i. e. , compounds with noncarbon-metal element bonds. But why a new term? Is not inorganic sufficient? By virtue of training, limited time, resources, co-workers, and so on, chemists tend to work on a specific element class, on a particular compound type, or in a particular phase. Thus, one finds element-oriented chemists (e. g.

Metal-Organic Framework Materials

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Publisher : John Wiley & Sons
ISBN 13 : 1118931580
Total Pages : 1210 pages
Book Rating : 4.1/5 (189 download)

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Book Synopsis Metal-Organic Framework Materials by : Leonard R. MacGillivray

Download or read book Metal-Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Advances in Fingerprint Technology

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Publisher : CRC Press
ISBN 13 : 1420041347
Total Pages : 457 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Advances in Fingerprint Technology by : Ashim K. Datta

Download or read book Advances in Fingerprint Technology written by Ashim K. Datta and published by CRC Press. This book was released on 2001-06-15 with total page 457 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fingerprints constitute one of the most important categories of physical evidence, and it is among the few that can be truly individualized. During the last two decades, many new and exciting developments have taken place in the field of fingerprint science, particularly in the realm of methods for developing latent prints and in the growth of imag

Hydrogen and Fuel Cells

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Publisher : Simon and Schuster
ISBN 13 : 9264108831
Total Pages : 208 pages
Book Rating : 4.2/5 (641 download)

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Book Synopsis Hydrogen and Fuel Cells by : International Energy Agency

Download or read book Hydrogen and Fuel Cells written by International Energy Agency and published by Simon and Schuster. This book was released on 2004 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen and fuel cells are vital technologies to ensure a secure and CO2-free energy future. Their development will take decades of extensive public and private effort to achieve technology breakthroughs and commercial maturity. Government research programs are indispensable for catalyzing the development process. This report maps the IEA countries' current efforts to research, develop and deploy the interlocking elements that constitute a "hydrogen economy", including CO2 capture and storage when hydrogen is produced out of fossil fuels. It provides an overview of what is being done, and by whom, covering an extensive complexity of national government R & D programs. The survey highlights the potential for exploiting the benefits of the international cooperation. This book draws primarily upon information contributed by IEA governments. In virtually all the IEA countries, important R & D and policy efforts on hydrogen and fuel cells are in place and expanding. Some are fully-integrated, government-funded programs, some are a key element in an overall strategy spread among multiple public and private efforts. The large amount of information provided in this publication reflects the vast array of technologies and logistics required to build the "hydrogen economy."--Publisher description.

The Chemical Bond in Inorganic Chemistry

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Publisher :
ISBN 13 : 0198508700
Total Pages : 289 pages
Book Rating : 4.1/5 (985 download)

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Book Synopsis The Chemical Bond in Inorganic Chemistry by : Ian David Brown

Download or read book The Chemical Bond in Inorganic Chemistry written by Ian David Brown and published by . This book was released on 2002 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the bond valence model, a description of acid-base bonding which is becoming increasingly popular particularly in fields such as materials science and mineralogy where solid state inorganic chemistry is important. Recent improvements in crystal structure determination have allowed the model to become more quantitative. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and can be used for analysing crystal structures and the conceptual modelling of local as well as extended structures. This is the first book to explore in depth the theoretical basis of the model and to show how it can be applied to synthetic and solution chemistry. It emphasizes the separate roles of the constraints of chemistry and of three-dimensional space by analysing the chemistry of solids. Many applications of the model in physics, materials science, chemistry, mineralogy, soil science, surface science, and molecular biology are reviewed. The final chapter describes how the bond valence model relates to and represents a simplification of other models of inorganic chemical bonding.

ACS Style Guide

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Publisher : American Chemical Society
ISBN 13 : 9780841239494
Total Pages : 0 pages
Book Rating : 4.2/5 (394 download)

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Book Synopsis ACS Style Guide by : Anne M. Coghill

Download or read book ACS Style Guide written by Anne M. Coghill and published by American Chemical Society. This book was released on 2006 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the time since the second edition of The ACS Style Guide was published, the rapid growth of electronic communication has dramatically changed the scientific, technical, and medical (STM) publication world. This dynamic mode of dissemination is enabling scientists, engineers, and medicalpractitioners all over the world to obtain and transmit information quickly and easily. An essential constant in this changing environment is the requirement that information remain accurate, clear, unambiguous, and ethically sound.This extensive revision of The ACS Style Guide thoroughly examines electronic tools now available to assist STM writers in preparing manuscripts and communicating with publishers. Valuable updates include discussions of markup languages, citation of electronic sources, online submission ofmanuscripts, and preparation of figures, tables, and structures. In keeping current with the changing environment, this edition also contains references to many resources on the internet.With this wealth of new information, The ACS Style Guide's Third Edition continues its long tradition of providing invaluable insight on ethics in scientific communication, the editorial process, copyright, conventions in chemistry, grammar, punctuation, spelling, and writing style for any STMauthor, reviewer, or editor. The Third Edition is the definitive source for all information needed to write, review, submit, and edit scholarly and scientific manuscripts.