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Synthesis And Characterization Of Transition Metal Carbonyl Clusters
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Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Book Synopsis Synthesis and Characterization of Transition Metal Carbonyl Clusters by : Frederic Roy Furuya
Download or read book Synthesis and Characterization of Transition Metal Carbonyl Clusters written by Frederic Roy Furuya and published by . This book was released on 1986 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Mixed-transition Metal Carbonyl Clusters and Nickel-germanium and Nickel-tin Carbonyl Clusters by : Jeffrey Paul Zebrowski
Download or read book Synthesis and Characterization of Mixed-transition Metal Carbonyl Clusters and Nickel-germanium and Nickel-tin Carbonyl Clusters written by Jeffrey Paul Zebrowski and published by . This book was released on 1990 with total page 594 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Structural Characterization of Transition Metal Selenido-carbonyl Clusters by : Chiara Massera
Download or read book Synthesis and Structural Characterization of Transition Metal Selenido-carbonyl Clusters written by Chiara Massera and published by . This book was released on 2000 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis, by Rational Means, and Characterization of High Nuclearity Platinum Carbonyl Clusters by : Karl Christopher Cairns Kharas
Download or read book The Synthesis, by Rational Means, and Characterization of High Nuclearity Platinum Carbonyl Clusters written by Karl Christopher Cairns Kharas and published by . This book was released on 1988 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Transition Metal Complexes for Oxidation, Reduction, and Carbonylation Reactions by : Cassandra P. Lilly
Download or read book Synthesis and Characterization of Transition Metal Complexes for Oxidation, Reduction, and Carbonylation Reactions written by Cassandra P. Lilly and published by . This book was released on 2014 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization, and Reactivity of Transition Metal Complexes Containing Multi-donor Ligands by : John C. Linehan
Download or read book Synthesis, Characterization, and Reactivity of Transition Metal Complexes Containing Multi-donor Ligands written by John C. Linehan and published by . This book was released on 1986 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Transition Metal Clusters by : Allan George Hee
Download or read book Synthesis and Characterization of Transition Metal Clusters written by Allan George Hee and published by . This book was released on 2004 with total page 562 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of New CN-based Transition Metal Complexes by : Omar Mowafaq Younis Al-Ramadhani
Download or read book Synthesis and Characterization of New CN-based Transition Metal Complexes written by Omar Mowafaq Younis Al-Ramadhani and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis and Characterization of Oligocyclopentadienyl and Oligoalkynyl Transition Metal Complexes by : Ian Martin Wasser
Download or read book The Synthesis and Characterization of Oligocyclopentadienyl and Oligoalkynyl Transition Metal Complexes written by Ian Martin Wasser and published by . This book was released on 1998 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands by :
Download or read book Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of transition metal chalcogenide polynuclear clusters is a rapidly expanding area. The increasing interest is due to the search for structural models and precursors of extended inorganic solids with novel electronic, magnetic and optical properties. Our interest for the synthesis of a variety of transition - etal clusters is due to their use as a model and precursors for materials and catalyst. Synthesis and study of a variety of ligand substituted iron carbonyl cluster has been carried out to understand the reactivity features and structural variety. The main focus has been on the transition metal clusters containing chalcogens which act as bridges between different metal fragments and are helpful in cluster growth reactions and maintains the cluster integrity. A synthetic strategy has been developed to prepare a mixed metal cluster when a dichloromethane solution of [Fe3Y2(CO)6], Y=S, Se, Te and ML4 (M=Pd, L=PPh3) was reacted at room temperature in presence of trimethylamine-N-oxide. Substitution reaction of carbonyl groups by triphenylphosphine and bis(diphenylphosphino)methane ligands results in the formation of different types of trinuclear clusters. Homo metallic cluster as well mixed metal clusters with phosphine ligands has been synthesized by a room temperature reaction and characterized by FTIR, proton and 31P NMR spectroscopy. Some of the transition metal cluster contains chelating phosphine ligands which stabilizes the cluster integrity.
Book Synopsis Synthesis, Characterization, and Reactivity of Metal Carbonyl Clusters Containing Small Nitrogeneous Ligands by : Joanne Agnes Smieja
Download or read book Synthesis, Characterization, and Reactivity of Metal Carbonyl Clusters Containing Small Nitrogeneous Ligands written by Joanne Agnes Smieja and published by . This book was released on 1986 with total page 478 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :Guillermo Gonzalez-Moraga Publisher :Springer Science & Business Media ISBN 13 :3642859267 Total Pages :310 pages Book Rating :4.6/5 (428 download)
Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga
Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Book Synopsis Synthesis and Characterization of High Nuclearity Bimetallic Group 8-Group 10 Transition Metal Cluster Complexes by : Sumit Saha
Download or read book Synthesis and Characterization of High Nuclearity Bimetallic Group 8-Group 10 Transition Metal Cluster Complexes written by Sumit Saha and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In past years bimetallic nanoparticle catalysts have been shown to exhibit superior catalytic properties, due to the presence of different metals such that one metal performs a certain role in a catalytic cycle and the other performs another function. Our goal was to synthesize bimetallic cluster complexes containing cheap metals for the application in heterogeneous catalysis. We have reported the reaction of Fe5(C)(CO)15 with Ni(COD)2, in acetonitrile solvent to afford the nickel-iron complex NiFe5(C)(NCMe)(CO)15. In addition, some chemistry with this compound was studied which gave new Fe-Ni carbide clusters with varying Fe-Ni ratios. Similar chemistry was observed with the reaction of Ru5(C)(CO)15 with Ni(COD)2. Electronic unsaturation in transition metal complexes is induced by bulky ligands. The bulky ligands shield the metal center from the approach of large molecules, leaving enough room for the selective approach of small molecules. Bulky ligands such as phosphines, stananes, germanes and N-heterocyclic carbenes stabilize the reactive intermediates of transition metal complexes. Based on this approach, we have synthesized Ru-Ge cluster complexes from the reaction of bulky tertiary butyl germane, ButGeH3 with ruthenium carbonyl complexes. We have also synthesized Ru-Pt bimetallic transition metal cluster complexes with bulky N-heterocyclic carbene ligand. All the new compounds were structurally characterized by single-crystal X-ray diffraction analyses.
Book Synopsis Metal Clusters in Chemistry by : Pierre Braunstein
Download or read book Metal Clusters in Chemistry written by Pierre Braunstein and published by Wiley-VCH. This book was released on 2000-01-11 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.
Download or read book Active Metals written by Alois Fürstner and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactions with metals are ubiquitous in organic synthesis and, particularly in the last few years, a large repertoire of methods for the activation of metals and for their use in organic synthesis has been developed. In Active Metals, topics ranging from morphology of metal clusters and nanometallurgy to organometallic chemistry, catalysis and the use of activated metals in natural product synthesis are authoritatively discussed by leading experts in the field. Active Metals will allow you to fully benefit from the recent advances in the field by giving: * Detailed experimental procedures * Guidance on manipulation of active metals under inert atmosphere * Valuable information for planning syntheses * Extensive tables of typical conversions with yields * Critically selected, up-to-date references This handbook is a unique source of 'hands-on' information which will allow you to expand the scope of your research.
Book Synopsis Studies in Transition Metal Chemistry by : Allen Capron Sievert
Download or read book Studies in Transition Metal Chemistry written by Allen Capron Sievert and published by . This book was released on 1980 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt:
