Synthesis and Characterization of the Compounds with the Derivatives of Pyridine Or Schiff Bases

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Publisher :
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.:/5 (252 download)

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Book Synopsis Synthesis and Characterization of the Compounds with the Derivatives of Pyridine Or Schiff Bases by : Keping Qian

Download or read book Synthesis and Characterization of the Compounds with the Derivatives of Pyridine Or Schiff Bases written by Keping Qian and published by . This book was released on 1991 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Pyridine and Its Derivatives, Volume 14, Part 1

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Publisher : John Wiley & Sons
ISBN 13 : 0470188146
Total Pages : 626 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Pyridine and Its Derivatives, Volume 14, Part 1 by : Erwin Klingsberg

Download or read book Pyridine and Its Derivatives, Volume 14, Part 1 written by Erwin Klingsberg and published by John Wiley & Sons. This book was released on 2009-09-15 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.

Exploring Chemistry with Pyridine Derivatives

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Publisher : BoD – Books on Demand
ISBN 13 : 1803566620
Total Pages : 251 pages
Book Rating : 4.8/5 (35 download)

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Book Synopsis Exploring Chemistry with Pyridine Derivatives by : Satyanarayan Pal

Download or read book Exploring Chemistry with Pyridine Derivatives written by Satyanarayan Pal and published by BoD – Books on Demand. This book was released on 2023-01-04 with total page 251 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses the chemistry and applications of pyridine derivatives. The library of pyridine derivatives is growing steadily with numerous synthetic analogues already described and the identification of new, naturally occurring pyridine-based compounds. The book includes ten chapters organized into two parts. The first part focuses on the numerous types of reactions that arise from pyridine derivatives. The second part examines the pharmaceutical applications of pyridine derivatives as well as their usefulness as sensors for metal cations and extracting agents for platinum group metals.

Synthesis & Characterization of Complexes of Pyridine Derivatives

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Publisher :
ISBN 13 : 9783659295607
Total Pages : 72 pages
Book Rating : 4.2/5 (956 download)

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Book Synopsis Synthesis & Characterization of Complexes of Pyridine Derivatives by : Alina Murtaza

Download or read book Synthesis & Characterization of Complexes of Pyridine Derivatives written by Alina Murtaza and published by . This book was released on 2018-05-27 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hydrogen Bonded Supramolecular Materials

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Publisher : Springer
ISBN 13 : 3662457806
Total Pages : 238 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Hydrogen Bonded Supramolecular Materials by : Zhan-Ting Li

Download or read book Hydrogen Bonded Supramolecular Materials written by Zhan-Ting Li and published by Springer. This book was released on 2015-01-05 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an up-to-date text covering topics in utilizing hydrogen bonding for constructing functional architectures and supramolecular materials. The first chapter addresses the control of photo-induced electron and energy transfer. The second chapter summarizes the formation of nano-porous materials. The following two chapters introduce self-assembled gels, many of which exhibit unique functions. Other chapters cover the advances in supramolecular liquid crystals and the versatility of hydrogen bonding in tuning/improving the properties and performance of materials. This book is designed to bring together in a single volume the most important and active fields of hydrogen bonding strategy for designing supramolecular materials. The book will be a valuable resource for graduates and researchers working in the fields of supramolecular chemistry and materials sciences. Zhan-Ting Li, PhD, is a Professor of Organic Chemistry at the Department of Chemistry, Fudan University, China Li-Zhu Wu, PhD, is a Professor of Organic Chemistry at the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China

La, Nd and Er Complexes of Schiff Bases Derived from Benzopyran-4-one

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Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659488436
Total Pages : 240 pages
Book Rating : 4.4/5 (884 download)

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Book Synopsis La, Nd and Er Complexes of Schiff Bases Derived from Benzopyran-4-one by : Nora S. Abdel-Kader

Download or read book La, Nd and Er Complexes of Schiff Bases Derived from Benzopyran-4-one written by Nora S. Abdel-Kader and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff bases have played an important role in the development of coordination chemistry. The growing importance of the Schiff bases in modern coordination chemistry is attributable to recent observations about their antibacterial and antifungal properties. Lanthanide coordination compounds are the subject of intense research efforts owing to their unique structures and their potential applications. Accordingly, this book contains preparation and characterization of a series of Schiff bases derived from the condensation of benzopyran-4-one derivatives with aliphatic diamines (ethylenediamine and trimethylenediamine), aromatic diamines (o-phenylenediamine and p-phenylene-diamine) and 2-aminopyridine and their antimicrobial activities were screened. The mode of chelation of La(III), Nd(III), Er(III) with these Schiff bases was elucidated by different techniques. The luminescence properties of the prepared Schiff bases and their complexes with Nd(III) and Er(III) ions are also discussed. The book is a valuable study to inorganic chemists those research coordination compounds as well as those looking for a novel approach in drug development.

Chemistry with Schiff Bases of Pyridine Derivatives

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (139 download)

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Book Synopsis Chemistry with Schiff Bases of Pyridine Derivatives by : Kaushal Kumar Joshi

Download or read book Chemistry with Schiff Bases of Pyridine Derivatives written by Kaushal Kumar Joshi and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pyridine is a valuable nitrogen based heterocyclic compound which is present not only in large number of naturally occurring bioactive compounds, but widely used in drug designing and development in pharmaceuticals as well as a precursor to agrochemicals and chemical-based industries. Pyridine derivatives bearing either formyl or amino group undergo Schiff base condensation reaction with appropriate substrate and under optimum conditions resulting in Schiff base as product which behave as a flexible and multidentate bioactive ligand. These Schiff bases are of great interest in medicinal chemistry as they can exhibit physiological effects similar to pyridoxal-amino acid systems which are considered to be very important in numerous metabolic reactions. They possess an interesting range of bioactivities including antibacterial, antiviral, antitubercular, antifungal, antioxidant, anticonvulsants, antidepressant, anti-inflammatory, antihypertensive, anticancer activity etc. and considered as a versatile pharmacophore group. Further, several pyridine-based Schiff bases show very strong binding abilities towards the various cations and anions with unique photophysical properties which can be used in ion recognition and they are extensively used in development of chemosensors for qualitative and quantitative detection of selective or specific ions in various kinds of environmental and biological media. These chapter insights the bioactivity and ion recognition ability of Schiff bases derived from pyridine derivatives.

Structural and Biological Applications of Schiff Base Metal Complexes

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Publisher : CRC Press
ISBN 13 : 1000865444
Total Pages : 265 pages
Book Rating : 4.0/5 (8 download)

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Book Synopsis Structural and Biological Applications of Schiff Base Metal Complexes by : Pallavi Jain

Download or read book Structural and Biological Applications of Schiff Base Metal Complexes written by Pallavi Jain and published by CRC Press. This book was released on 2023-05-31 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination compounds have been well-known for their wide variety of applications for over a century, as well as enhancing the researcher’s interest and concern in evaluating their action mechanism. It is certainly one of the most intensely discussed research topics. Coordination compounds involve different metal-ion-ligand phenomenon. The involved metal ions play a significant role in structural association and functioning of several processes in the genetic and metabolism system. In recent years, Schiff base ligands have gained significant interest and received a keen interest of many researchers. Schiff’s base ligands have been recognized to hold a wide variety of biological and medicinal activities due to the presence of donor atoms. They have proved exceptional pharmalogical actions such as antimicrobial, anti-tuberclosis, antiplatelet, antidiabetic, antiarthritis, antioxidant, anti-inflammatory, anticancer, antiviral, antimalarial, and analgesic. These biologically active Schiff base ligands have also been shown to inhibit enzyme mobilization and, when bound to a metal ion, exhibit enhanced biological activity, making them useful in a number of fields. As a result, metal complexes of Schiff base ligands are gaining popularity due to their unique properties and functionalities. Schiff base complex-based research for educational and industrial purposes is booming, and the number of publications is gradually increasing. Despite these interests, there is currently no detailed book on Schiff base metal complexes that covers the structures, biological activities, and other non-biological perspectives. This book delves into the structures of Schiff base metal complexes, which are critical in assessing the biological viability of any complex. It also highlights their biological significance in pharma and drug discovery like antibacterial, antifungal, anticancer, anti-inflammatory, anti-arthritis, anti-diabetic, antioxidants, anti-proliferative, antitumor, anticancer, antiviral. The fundamentals of metal complexes are described, as well as an up-to-date outline of developments in synthesis, characterization methods, properties- chemical, thermal, optical, structural, and applications. This book also discusses the other applications of Schiff base metal complexes: as sensor (luminescent, electrochemical, and biosensor), as pigments in dying and paint industries, as photocatalyst to improve the degradation rate. Features : This book would be useful for academia, researchers and engineers working in the area of Schiff base and their metal complexes. This book will give an in-depth account of the properties of Schiff base and their metal complexes. This book will discuss the details of synthesis methods for Schiff base and their metal complexes. This book will cover emerging trends in the use of Schiff base metal complexes in the industry. This book will provide an overview of the wider biological applications of Schiff base metal complexes

Synthesis,characterization of Azetidinone Based Pyrazoline Derivatives

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Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659500893
Total Pages : 256 pages
Book Rating : 4.5/5 (8 download)

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Book Synopsis Synthesis,characterization of Azetidinone Based Pyrazoline Derivatives by : Shailesh Shah

Download or read book Synthesis,characterization of Azetidinone Based Pyrazoline Derivatives written by Shailesh Shah and published by LAP Lambert Academic Publishing. This book was released on 2014-05-21 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contain brief note of azetidin-2-one based pyrazoline like acetyl pyrazoline, benzoyl pyrazoline, phenyl sulfonyl pyrazoline derivatives and cyno-pyridine from Chalcones. it is helpful for those researcher who works on pyrazoline derivatives, this book is also helpful for young researcher as well as PhD students. schiff base and azetidin-2-one prepared from different aromatic aldehydes and then convert into Chalcones. pyrazoline is made from chalcones.

Beauty in Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642283411
Total Pages : 180 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Beauty in Chemistry by : Luigi Fabbrizzi

Download or read book Beauty in Chemistry written by Luigi Fabbrizzi and published by Springer Science & Business Media. This book was released on 2012-02-22 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Beauty of Chemistry in the Words of Writers and in the Hands of Scientists, by Margherita Venturi, Enrico Marchi und Vincenzo Balzani Living in a Cage Is a Restricted Privilege, by Luigi Fabbrizzi Inner and Outer Beauty, by Kenneth N. Raymond und Casey J. Brown The Mechanical Bond: A Work of Art, by Carson J. Bruns und J. Fraser Stoddart The Beauty of Knots at the Molecular Level, by Jean-Pierre Sauvage und David B. Amabilino

Pyridine and Its Derivatives, Volume 14, Part 1

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Publisher : Wiley-Interscience
ISBN 13 : 9780470379172
Total Pages : 0 pages
Book Rating : 4.3/5 (791 download)

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Book Synopsis Pyridine and Its Derivatives, Volume 14, Part 1 by : Erwin Klingsberg

Download or read book Pyridine and Its Derivatives, Volume 14, Part 1 written by Erwin Klingsberg and published by Wiley-Interscience. This book was released on 1960-01-15 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.

Design and Strategy in Organic Synthesis

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Publisher : Wiley-VCH
ISBN 13 : 9783527319640
Total Pages : 0 pages
Book Rating : 4.3/5 (196 download)

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Book Synopsis Design and Strategy in Organic Synthesis by : Stephen Hanessian

Download or read book Design and Strategy in Organic Synthesis written by Stephen Hanessian and published by Wiley-VCH. This book was released on 2013-09-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This long-awaited graduate level book, written by one of the world's leading organic chemists in collaboration with two of his former and present coworkers, adopts a refreshingly unique approach to synthesis planning and execution. Following an introductory look at the concept of synthesis, the authors discuss the Why, What, and How of organic synthesis as they apply to natural products. Although emphasis is on the Chiron Approach utilizing amino-acids, carbohydrates, hydroxy acids, terpenes, lactones and other naturally occurring small molecules as starting materials, catalytic asymmetric methods are also included as a corollary whenever relevant. A must-have source of first class information for everyone working in organic synthesis, be it in academia or industry. With a foreword by Larry E. Overman and David W. C. MacMillan

Rational Design, Synthesis and Characterization of Amide Functionalized Pyridine and Benzimidazole Transition Metal Complexes

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Publisher :
ISBN 13 :
Total Pages : 576 pages
Book Rating : 4.:/5 (81 download)

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Book Synopsis Rational Design, Synthesis and Characterization of Amide Functionalized Pyridine and Benzimidazole Transition Metal Complexes by : Samuel S. K. Asem

Download or read book Rational Design, Synthesis and Characterization of Amide Functionalized Pyridine and Benzimidazole Transition Metal Complexes written by Samuel S. K. Asem and published by . This book was released on 2011 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study expands our efforts to make a new class of Pt (II) compounds analogous to cisplatin and its derivatives using sterically hindered ligands. Pt compounds in this series have been synthesized using specially designed pyridine and benzimidazole ligands. These heterocycles, amide functionalized at position 2 with aryl and alkyl pendants, rapidly change their mode of coordination depending on the pH of the medium. These ligands, synthesized using condensation chemistry, also coordinate to Co(II), Ni(H), Cu(lI), and Zn(1I) generally as anionic bis-chelates through the benzimidazole nitrogen and the carbonyl oxygen, creating a four-coordinate complex with the exception of an unusual trigonal bipyramidal Zn(H) complex. I H NMR temperature studies reveal that these ligands interconvert between imide and amide isomers and that electron withdrawing pendants favor amide isomers. Crystal structures of Co(II) and Ni(1I) complexes of N-( I-methylbenzimidazol-2-yl)cyclohexanecarboxamide, for example, show two ligands bind per metal ion when reacted with acetate and nitrate salts. The bischelates of these Ni(1I) complexes also show expansions of their coordination spheres from four to five-coordinate. Furthermore, these Ni(II) bis-chelated complexes possess square planar or distorted 4-coordinate geometries. The synthesis and properties of several new Pt (II) complexes containing these ligands will be presented. A second generation and novel complex class containing metal-binding, linker and recognition domains is reported. Both classes of Pt complexes were obtained using a synthetic methodology which favors the cis isomers. The second generation complex crystallizes in the monoclinic space group P2dn with lattice dimensions a = 17.7393(5) A, b = 11.4632(3) A, c = 19.3959(5) A and ~ = 99.794(3)°. These complexes have been characterized using physical methods that include X-ray crystallography, IH &13C NMR, Mass spectrometry, UV and IR spectroscopies. Complexes similar in structure to cisplatin and carboplatin show varying cytotoxic properties toward different cancer cell lines. Additionally, some of these new Pt complexes show comparable and promising cytotoxicity against prostate cancer cell lines.

Advances in Heterocyclic Chemistry

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Publisher : Elsevier
ISBN 13 : 0080464505
Total Pages : 279 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Advances in Heterocyclic Chemistry by : Alan R. Katritzky

Download or read book Advances in Heterocyclic Chemistry written by Alan R. Katritzky and published by Elsevier. This book was released on 2011-07-29 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt: Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area-one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties. - Up-to-date results in the subject which continues to gain importance and expand - Makes available to graduate students and research workers in academic and industrial laboratories the latest reviews on wide variety of heterocyclic topics - The series forms a very substantial database covering wide areas of heterocyclic chemistry

Synthesis and Characterization of Some Fused Ring Pyridine Compounds

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Publisher :
ISBN 13 :
Total Pages : 190 pages
Book Rating : 4.:/5 (359 download)

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Book Synopsis Synthesis and Characterization of Some Fused Ring Pyridine Compounds by : Lucy Ellen Shanaman

Download or read book Synthesis and Characterization of Some Fused Ring Pyridine Compounds written by Lucy Ellen Shanaman and published by . This book was released on 1996 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Corrosion Inhibitors

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Publisher : John Wiley & Sons
ISBN 13 : 1119794501
Total Pages : 530 pages
Book Rating : 4.1/5 (197 download)

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Book Synopsis Organic Corrosion Inhibitors by : Chandrabhan Verma

Download or read book Organic Corrosion Inhibitors written by Chandrabhan Verma and published by John Wiley & Sons. This book was released on 2021-09-11 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of organic corrosion inhibitors used in modern industrial platforms, including current developments in the design of promising classes of organic corrosion inhibitors Corrosion is the cause of significant economic and safety-related problems that span across industries and applications, including production and processing operations, transportation and public utilities infrastructure, and oil and gas exploration. The use of organic corrosion inhibitors is a simple and cost-effective method for protecting processes, machinery, and materials while remaining environmentally acceptable. Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications provides up-to-date coverage of all aspects of organic corrosion inhibitors, including their fundamental characteristics, synthesis, characterization, inhibition mechanism, and industrial applications. Divided into five sections, the text first covers the basics of corrosion and prevention, experimental and computational testing, and the differences between organic and inorganic corrosion inhibitors. The next section describes various heterocyclic and non-heterocyclic corrosion inhibitors, followed by discussion of the corrosion inhibition characteristics of carbohydrates, amino acids, and other organic green corrosion inhibitors. The final two sections examine the corrosion inhibition properties of carbon nanotubes and graphene oxide, and review the application of natural and synthetic polymers as corrosion inhibitors. Featuring contributions by leading researchers and scientists from academia and industry, this authoritative volume: Discusses the latest developments and issues in the area of corrosion inhibition, including manufacturing challenges and new industrial applications Explores the development and implementation of environmentally-friendly alternatives to traditional toxic corrosion inhibitors Covers both established and emerging classes of corrosion inhibitors as well as future research directions Describes the anticorrosive mechanisms and effects of acyclic, cyclic, natural, and synthetic corrosion inhibitors Offering an interdisciplinary approach to the subject, Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications is essential reading for chemists, chemical engineers, researchers, industry professionals, and advanced students working in fields such as corrosion inhibitors, corrosion engineering, materials science, and applied chemistry.

The Design, Synthesis and Characterization of New Building Blocks for the Preparation of Molecule-based Magnetic Materials

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (124 download)

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Book Synopsis The Design, Synthesis and Characterization of New Building Blocks for the Preparation of Molecule-based Magnetic Materials by : Jian Wang

Download or read book The Design, Synthesis and Characterization of New Building Blocks for the Preparation of Molecule-based Magnetic Materials written by Jian Wang and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Two new families of building blocks have been prepared and fully characterized and their coordination chemistry exploited for the preparation of molecule-based magnetic materials. The first class of compounds were prepared by exploiting the chemistry of 3,3'-diamino-2,2'-bipyridine together with 2-pyridine carbonyl chloride or 2-pyridine aldehyde. Two new ligands, 2,2'-bipyridine-3,3'-[2-pyridinecarboxamide] (Li, 2.3) and N'-6/s(2-pyridylmethyl) [2,2'bipyridine]-3,3'-diimine (L2, 2.7), were prepared and characterized. For ligand L4, two copper(II) coordination compounds were isolated with stoichiometrics [Cu2(Li)(hfac)2] (2.4) and [Cu(Li)Cl2] (2.5). The molecular structures of both complexes were determined by X-ray crystallography. In both complexes the ligand is in the dianionic form and coordinates the divalent Cu(II) ions via one amido and two pyridine nitrogen donor atoms. In (2.4), the coordination geometry around both Cu11 ions is best described as distorted trigonal bipyramidal where the remaining two coordination sites are satisfied by hfac counterions. In (2.5), both Cu(II) ions adopt a (4+1) distorted square pyramidal geometry. One copper forms a longer apical bond to an adjacent carbonyl oxygen atom, whereas the second copper is chelated to a neighboring Cu-Cl chloride ion to afford chloride bridged linear [Cu2(Li)Cl2]2 tetramers that run along the c-axis of the unit cell. The magnetic susceptibility data for (2.4) reveal the occurrence of weak antiferromagnetic interactions between the copper(II) ions. In contrast, variable temperature magnetic susceptibility measurements for (2.5) reveal more complex magnetic properties with the presence of ferromagnetic exchange between the central dimeric pair of copper atoms and weak antiferromagnetic exchange between the outer pairs of copper atoms. The Schiff-base bis-imine ligand (L2, 2.7) was found to be highly reactive; single crystals grown from dry methanol afforded compound (2.14) for which two methanol molecules had added across the imine double bond. The susceptibility of this ligand to nucleophilic attack at its imine functionality assisted via chelation to Lewis acidic metal ions adds an interesting dimension to its coordination chemistry. In this respect, a Co(II) quaterpyridine-type complex was prepared via a one-pot transformation of ligand L2 in the presence of a Lewis acidic metal salt. The rearranged complex was characterized by X-ray crystallography and a reaction mechanism for its formation has been proposed. Three additional rearranged complexes (2.13), (2.17) and (2.19) were also isolated when ligand (L2, 2.7) was reacted with transition metal ions. The molecular structures of all three complexes have been determined by X-ray crystallography. The second class of compounds that are reported in this thesis, are the two diacetyl pyridine derivatives, 4-pyridyl-2,6-diacetylpyridine (5.5) and 2,2'-6,6'-tetraacetyl-4,4'-bipyridine (5.15). Both of these compounds have been designed as intermediates for the metal templated assembly of a Schiff-base N3O2 macrocycle. From compound (5.15), a covalently tethered dimeric Mn(II) macrocyclic compound of general formula {[Mn^C^XJCl-FkO^Cl-lO.SFbO (5.16) was prepared and characterized. The X-ray analysis of (5.16) reveals that the two manganese ions assume a pentagonal-bipyramidal geometry with the macrocycle occupying the pentagonal plane and the axial positions being filled by a halide ion and a H2O molecule. Magnetic susceptibility data reveal the occurrence of antiferromagnetic interactions between covalently tethered Mn(II)-Mn(II) dimeric units. Following this methodology a Co(II) analogue (5.17) has also been prepared which is isostructural with (5.16).