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Synthesis And Characterization Of Novel Carbosilane Dendrimers As Supports
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Book Synopsis Synthesis and Characterization of Novel Carbosilane Dendrimers as Supports by : Luke C. De Selm
Download or read book Synthesis and Characterization of Novel Carbosilane Dendrimers as Supports written by Luke C. De Selm and published by . This book was released on 2004 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and characterization of carbosilane dendrimers with perfluoroalkyl end groups by : Matthew Paul Cashion
Download or read book Synthesis and characterization of carbosilane dendrimers with perfluoroalkyl end groups written by Matthew Paul Cashion and published by . This book was released on 2004 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization and Group Modification of Carbosilane Based Dendrimers by : Richard Hooper
Download or read book Synthesis, Characterization and Group Modification of Carbosilane Based Dendrimers written by Richard Hooper and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbosilane dendrimers have been prepared via iterative hydrosilylation/alkenylation reactions using a variety of chlorosilanes (HSiMe3−nC1n)and alkenyl nucleophiles (CH2=CHCH2MgBr and CH2=CHMgBr). Characterization by multinuclear NMR spectroscopy of the stepwise trifurctate dendrimers RED3 (E=Si; R=Ph; D=Dendritic carbosilane fragment) assists end-group counting (NMR, R vs D) and can be related to analogous spheroidal ED4 and hexafunctional E2D6 systems (E=Si or Ge). Typical D units contain (prnSiMe3−n)N Nb linkers; where pr=(CH2)3, N=generation number, Nb=branch multiplicity at silicon. For higher symmetry ED4 and E2D6 systems (and also trifurcate) the Nb=1 (1B series) or Nb=2 (2B series) also allows for end-group counting by proton NMR spectroscopy (Ph:D:Me). 29Si NMR chemical shifts have been developed for topographical mapping of dendritic structure. Peripheral and core substitution reactions have been examined for a series of trifurcate and related Ge2D6 'masked trifurcate' dendrimers. Replacement of end groups with a range of substrates is facilitated by the reactivity of the intermediate silicon chlorine bonds formed by hydrosilylation reactions. Selective removal of the core phenyl group (via triflic acid), or alternatively oxidative Ge-Ge cleavage, allows for unprecedented 'bifunctionalization'; offering routes into dendrimer periphery:core electron transfer ('photon-harvesting') processes. Methodology for a 'rapid-synthesis' of hyperbranched structures has been developed and examined on a range of initial core molecules. Use of multinuclear NMR spectroscopy via comparison with step-wise products, as well as GPC chromatography, gives some insight into the overall architectures produced. Alteration of Si branch point from Nb=2 to Nb=3, using presynthesised 'hypercores' facilitates an alternate method of end group counting for higher symmetry cores. This methodology allows for population counting at large N in dendrimer generation G(N) (D interior vs D periphery).
Book Synopsis Dendrimer Chemistry by : Fritz Vögtle
Download or read book Dendrimer Chemistry written by Fritz Vögtle and published by John Wiley & Sons. This book was released on 2009-03-09 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by internationally acclaimed authors, this textbook contains everything you need to know about this versatile class of compounds. Starting with a historical overview, definitions and other fundamentals, it goes on to look at characterization, analysis and properties of dendrimers. While the focus is on synthesis and applications, it also contains chapters on analytics and other applications. Essential reading for organic and polymer chemists, undergraduate and graduate students, students and lecturers in chemistry.
Book Synopsis Synthesis, Characterization and Group Modification of Carbosilane Based Dendrimers by :
Download or read book Synthesis, Characterization and Group Modification of Carbosilane Based Dendrimers written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Novel BINOL-based Symmetrical and Asymmetrical Axially Chiral Dendrimers by : Adil Abdullah Gobouri
Download or read book Synthesis and Characterization of Novel BINOL-based Symmetrical and Asymmetrical Axially Chiral Dendrimers written by Adil Abdullah Gobouri and published by . This book was released on 2011 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Novel BINOL-based Symmetrical and Asymmetrical Axially Chiral Dendrimers by : Adil A. Gobouri
Download or read book Synthesis and Characterization of Novel BINOL-based Symmetrical and Asymmetrical Axially Chiral Dendrimers written by Adil A. Gobouri and published by . This book was released on 2011 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis and Characterization of Unsaturated Carbosilane Polymers by : Steven Jeffry Sargeant
Download or read book The Synthesis and Characterization of Unsaturated Carbosilane Polymers written by Steven Jeffry Sargeant and published by . This book was released on 1993 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis 'Dialyzable' Carbosilane Dendrimers as Soluble Supports in Organic Synthesis by : M. Wander
Download or read book 'Dialyzable' Carbosilane Dendrimers as Soluble Supports in Organic Synthesis written by M. Wander and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dendrimers and Dendronized Polymers by : Andreas Nyström
Download or read book Dendrimers and Dendronized Polymers written by Andreas Nyström and published by . This book was released on 2006 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis and Characterization of Photoresponsive Dendrimers by : Denise Marie Junge
Download or read book The Synthesis and Characterization of Photoresponsive Dendrimers written by Denise Marie Junge and published by . This book was released on 1998 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Dendrimer Rods by : Peter I. Carver
Download or read book Synthesis and Characterization of Dendrimer Rods written by Peter I. Carver and published by . This book was released on 2002 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Silicon-Containing Dendritic Polymers by : Petar R. Dvornic
Download or read book Silicon-Containing Dendritic Polymers written by Petar R. Dvornic and published by Springer Science & Business Media. This book was released on 2009-01-09 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades silicon-containing dendritic polymers have become one of the fastest growing areas of development in polymer science. The eruption of interest in these new polymers stems from their unprecedented molecular architecture, unique resulting properties and the realization that they represent ideal building blocks for chemical nanotechnology. This is the first book to solely focus on silicon-containing dendritic polymers. The contributions of those experts who originally introduced each field or played a major role in its progress are reported. The developments in all major areas of this field are presented from their origins to the present. It is anticipated that this text will become an invaluable guide and vanguard of reference for experienced scientists interested in the fields of polymer and material science, synthetic chemistry, and nanotechnology. It will also serve advanced graduate students either as a source of creative inspiration or as a textbook for appropriate courses.
Book Synopsis Carbosilane Containing Polymers by : Zhizhong Wu
Download or read book Carbosilane Containing Polymers written by Zhizhong Wu and published by . This book was released on 2005 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Novel Carboranes and Polyborane Compounds by : Mitchel Decastro Millan
Download or read book Synthesis and Characterization of Novel Carboranes and Polyborane Compounds written by Mitchel Decastro Millan and published by . This book was released on 1996 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Chiral, Non-racemic Dendrimers from Stilbene Precursors by : Mu-Jen Wu
Download or read book Synthesis and Characterization of Chiral, Non-racemic Dendrimers from Stilbene Precursors written by Mu-Jen Wu and published by . This book was released on 1997 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dendrimers II written by Fritz Vögtle and published by Springer. This book was released on 2003-07-01 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second volume on dendrimers is again written by pioneers in the field. Their contributions illuminate the aspects of dendrimers mentioned in the subtitle, and also touch on areas beyond chemistry, namely material sciences as well as biological, medicinal, analytical, and nano aspects.