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Synthesis And Characterization Of Mixed Transition Metal Carbonyl Clusters And Nickel Germanium And Nickel Tin Carbonyl Clusters
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Book Synopsis Synthesis and Characterization of Mixed-transition Metal Carbonyl Clusters and Nickel-germanium and Nickel-tin Carbonyl Clusters by : Jeffrey Paul Zebrowski
Download or read book Synthesis and Characterization of Mixed-transition Metal Carbonyl Clusters and Nickel-germanium and Nickel-tin Carbonyl Clusters written by Jeffrey Paul Zebrowski and published by . This book was released on 1990 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Book Synopsis Synthesis and Physicochemical Characterization of Large Nickel-carbonyl-arsinidene Clusters and a Novel Au6Ni12 Carbonyl Cluster by : Alison Jane Whoolery
Download or read book Synthesis and Physicochemical Characterization of Large Nickel-carbonyl-arsinidene Clusters and a Novel Au6Ni12 Carbonyl Cluster written by Alison Jane Whoolery and published by . This book was released on 1993 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Isolation, and Characterization of Variety of High Nuclearity Nickel-antimony, Nickel-bismuth, and Nickel-copper Carbonyl Clusters by : Peter D. Mylnek
Download or read book Synthesis, Isolation, and Characterization of Variety of High Nuclearity Nickel-antimony, Nickel-bismuth, and Nickel-copper Carbonyl Clusters written by Peter D. Mylnek and published by . This book was released on 1996 with total page 778 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of High Nuclearity Bimetallic Group 8-Group 10 Transition Metal Cluster Complexes by : Sumit Saha
Download or read book Synthesis and Characterization of High Nuclearity Bimetallic Group 8-Group 10 Transition Metal Cluster Complexes written by Sumit Saha and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In past years bimetallic nanoparticle catalysts have been shown to exhibit superior catalytic properties, due to the presence of different metals such that one metal performs a certain role in a catalytic cycle and the other performs another function. Our goal was to synthesize bimetallic cluster complexes containing cheap metals for the application in heterogeneous catalysis. We have reported the reaction of Fe5(C)(CO)15 with Ni(COD)2, in acetonitrile solvent to afford the nickel-iron complex NiFe5(C)(NCMe)(CO)15. In addition, some chemistry with this compound was studied which gave new Fe-Ni carbide clusters with varying Fe-Ni ratios. Similar chemistry was observed with the reaction of Ru5(C)(CO)15 with Ni(COD)2. Electronic unsaturation in transition metal complexes is induced by bulky ligands. The bulky ligands shield the metal center from the approach of large molecules, leaving enough room for the selective approach of small molecules. Bulky ligands such as phosphines, stananes, germanes and N-heterocyclic carbenes stabilize the reactive intermediates of transition metal complexes. Based on this approach, we have synthesized Ru-Ge cluster complexes from the reaction of bulky tertiary butyl germane, ButGeH3 with ruthenium carbonyl complexes. We have also synthesized Ru-Pt bimetallic transition metal cluster complexes with bulky N-heterocyclic carbene ligand. All the new compounds were structurally characterized by single-crystal X-ray diffraction analyses.
Book Synopsis Synthesis and Characterization of Transition Metal Carbonyl Clusters by : Frederic Roy Furuya
Download or read book Synthesis and Characterization of Transition Metal Carbonyl Clusters written by Frederic Roy Furuya and published by . This book was released on 1986 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :Guillermo Gonzalez-Moraga Publisher :Springer Science & Business Media ISBN 13 :3642859267 Total Pages :310 pages Book Rating :4.6/5 (428 download)
Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga
Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Book Synopsis The Synthesis and Characterization of Nonclassical Transition Metal Carbonyl Complexes by : Jeffrey J. Rack
Download or read book The Synthesis and Characterization of Nonclassical Transition Metal Carbonyl Complexes written by Jeffrey J. Rack and published by . This book was released on 1996 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of New Rhodium/nickel-phosphorus and Nickel-antimony Carbonyl Clusters by : Robert E. DesEnfants
Download or read book Synthesis and Characterization of New Rhodium/nickel-phosphorus and Nickel-antimony Carbonyl Clusters written by Robert E. DesEnfants and published by . This book was released on 1988 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Compounds with Bonds between Tin and Transition Metals of Groups VIII, I, and II by : Herbert Schumann
Download or read book Compounds with Bonds between Tin and Transition Metals of Groups VIII, I, and II written by Herbert Schumann and published by Springer. This book was released on 1995 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Part 22 concludes the description of mononuclear organotin compounds containing bonds between tin and a transition metal. The Group-VIII compounds occupy the largest portion of this volume and are subdivided into the subgroups of iron, cobalt, and nickel. The molecular structure of many of these compounds has been elucidated in addition to the standard spectroscopic methods. Compounds of copper, silver, and gold, although virtually unknown, are included in the present volume, since several organotin cuprates have been prepared intermediately and used in situ as regio- and stereoselective reagents in organic chemistry.
Book Synopsis Synthesis and Structural Characterization of Transition Metal Cluster Compounds of Iron and Nickel by : Candice J. Kreese-Foley
Download or read book Synthesis and Structural Characterization of Transition Metal Cluster Compounds of Iron and Nickel written by Candice J. Kreese-Foley and published by . This book was released on 1985 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 1991 with total page 796 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis New High-nuclearity Nickel-phosphinidene Carbonyl Clusters by : James A. Gavney
Download or read book New High-nuclearity Nickel-phosphinidene Carbonyl Clusters written by James A. Gavney and published by . This book was released on 1992 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of the Mixed-Metal Alkylidyne Clusters RCFeCo2(CO)9H (R by : Ronald A. Epstein
Download or read book Synthesis and Characterization of the Mixed-Metal Alkylidyne Clusters RCFeCo2(CO)9H (R written by Ronald A. Epstein and published by . This book was released on 1978 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction of closed metal carbonyl trimers with carbonylmetalates has been shown to be a useful synthetic route to tetranuclear clusters in which the carbonylmetalate adds to the face of the original trimer. This type of reaction has been particularly useful for the synthesis of mixed-metal clusters. In principle, clusters with more than four framework atoms could be prepared by the addition of carbonylmetalates to the triangular faces of tetranuclear and larger clusters.
Book Synopsis Synthesis of Tetrahedral Mixed-Metal Clusters of the Iron Triad. Preparation and Characterization of H2FeRu2Os(CO)13 and H2FeRuOs2(CO)13 by : Gregory L. Geoffroy
Download or read book Synthesis of Tetrahedral Mixed-Metal Clusters of the Iron Triad. Preparation and Characterization of H2FeRu2Os(CO)13 and H2FeRuOs2(CO)13 written by Gregory L. Geoffroy and published by . This book was released on 1977 with total page 39 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal cluster complexes have become a very important class of compounds, principally because of their potential in catalysis. Clusters have been shown to behave as catalysts in their own right and they hold considerable promise for serving as models for catalytic surfaces. Clusters comprised of two or more different transition metals in the cluster framework are particularly interesting in this regard because of possible bimetallic effects. Further, mixed-metal clusters have non-equivalent bonding sites. As such they are ideally suited for modeling studies which employ variable temperature NMR to follow the movements of substrates over their surfaces. One of the problems which has hampered studies of mixed-metal clusters is their relative lack of availability. Only a very few isostructural series have been achieved, and general synthetic methods for mixed-metal clusters are lacking. Carbonylmetalates have been widely used as synthetic reagents in cluster chemistry and several of the reported reactions appear to be adaptable to design. This is particularly true of the reactions of Knight and Mays who prepared a series of Group 7 - Group 8 tetrameric mixed-metal clusters through the addition of a carbonylmetalate to a closed M3(CO)12 trimer.
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1990 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis, by Rational Means, and Characterization of High Nuclearity Platinum Carbonyl Clusters by : Karl Christopher Cairns Kharas
Download or read book The Synthesis, by Rational Means, and Characterization of High Nuclearity Platinum Carbonyl Clusters written by Karl Christopher Cairns Kharas and published by . This book was released on 1988 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:
