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Synthesis And Characterization Of Hydrido Ruthenium And Platinum Carbonyl Complexes
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Book Synopsis Synthesis and Characterization of Hydrido-ruthenium and Platinum Carbonyl Complexes by : Rosemarie Szostak
Download or read book Synthesis and Characterization of Hydrido-ruthenium and Platinum Carbonyl Complexes written by Rosemarie Szostak and published by . This book was released on 1982 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Ruthenium(II) and Platinum(IV) Complexes with Anionic Heteroatomic Ligands by :
Download or read book Synthesis and Characterization of Ruthenium(II) and Platinum(IV) Complexes with Anionic Heteroatomic Ligands written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Isolated and fully characterized complexes of late transition metals in low oxidation states possessing amido and alkoxo ligands are relatively rare. These ligands often exhibit nucleophilic and/or basic reactivity. This reactivity is due, at least in part, to the disruption of ligand to metal à â'Ơ-bonding. Reports of early transition metals with low d-electron counts with imido ligands facilitating C-H activation suggest that if later transition metals with amido or aryloxo ligands can be isolated, C-H activation reactivity may be observed. Ruthenium(II) complexes that catalyze the H/D exchange of N-H and O-H protons at anilido and hydroxo ligands, respectively, with deuterated solvents have been reported, and studies of related systems could shed significant light on C-H activation in these types of reactions. Observing changes in the rate of C-H activation based on specific changes to transition metal complexes could give insight into the creation of highly active C-H activation catalysts. Presented here are synthetic efforts toward late transition metal complexes with formally anionic heteroatomic ligands. The synthesis and initial characterization of [EpRu(Cl)(PPh3)(NCMe)][Cl], [EpRu(py)2Cl][Cl], [EpRu(py)2Cl][Cl], [EpRu(OHMe)(PMe3)(Cl)][BArÃØâ'Ơâ"Ø4] are reported {Ep = 1,1,1-tris(pyrazolyl)ethane, py = N-pyridine, ArÃØâ'Ơâ"Ø = 3,5-(CF3)-C6H3}. The lack of solubility yielded these complexes ineffective for further synthetic manipulation. Additionally presented is the synthesis and characterization of (tbpy)Pt(Me)2(I)2 and (tbpy)Pt(Me)(NHPh)(I)2 (tbpy = 4,4ÃØâ'Ơâ"Ø-tert-butyl-2,2ÃØâ'Ơâ"Ø-bipyridine). Attempted syntheses of (tbpy)Pt(NHPh)2(I)2 and (tbpy)Pt(Cl)(NHPh)(I)2 are also reported. Initial reactivity of (tbpy)Pt(Me)2(I)2 and the decomposition of (tbpy)Pt(Me)(NHPh)(I)2 are further re.
Book Synopsis Synthesis and Characterization of Ruthenium(II) and Platinum(IV) Complexes with Anionic Heteroatomic Ligands by : Joshua Taylor Gurkin
Download or read book Synthesis and Characterization of Ruthenium(II) and Platinum(IV) Complexes with Anionic Heteroatomic Ligands written by Joshua Taylor Gurkin and published by . This book was released on 2009 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: Keywords: platinum(IV), ruthenium(II), C-H activation, pyrazolyl alkanes.
Book Synopsis The Synthesis, by Rational Means, and Characterization of High Nuclearity Platinum Carbonyl Clusters by : Karl Christopher Cairns Kharas
Download or read book The Synthesis, by Rational Means, and Characterization of High Nuclearity Platinum Carbonyl Clusters written by Karl Christopher Cairns Kharas and published by . This book was released on 1988 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Ruthenium(II)-hispolon Complexes by : Carmen Kloer
Download or read book Synthesis and Characterization of Ruthenium(II)-hispolon Complexes written by Carmen Kloer and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Ruthenium Complexes with (N-N)(P-P) and (N-P)2 Donor Sets by : Xinwei Yang
Download or read book Synthesis and Characterization of Ruthenium Complexes with (N-N)(P-P) and (N-P)2 Donor Sets written by Xinwei Yang and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of nonlinear effects, both the theory and measurement techniques have been developed significantly, especially since the invention of the laser. However, structure-NLO property relationships for organometallics as well as their NLO mechanisms are far less explored than those of organic molecules and inorganic salts. The greater flexibility and exceptionally large NLO responses of organometallic compounds attracts chemists to this field. Modification of coordinated co-ligands in organometallic systems has influence on the NLO merit by introducing new electronic charge-transfer transitions, oxidation state and coordination sphere of the metal centers. In this work, the donor sets of the ruthenium complexes were modified from the most investigated (P-P)(P-P) to (N-N)(P-P) and (N-P)2 and a series of ruthenium complexes were synthesized and characterized. In Chapter 2, the study of the Ru(N-N)(P-P) complexes is detailed. Three bidentate diphosphine ligands (dppe, dppb and dppf) and one diimine ligand (tert-Bu-bpy) were selected for this study as the diphosphine and diimine ligands, respectively. Ruthenium halide and mono-alkynyl complexes were obtained successfully. Their optical, electrochemical and spectroelectrochemical properties were examined and are discussed. The formation of eta3- and eta1-butenynyl complexes was confirmed by single-crystal X-ray diffraction. Attempts towards bis-alkynyl complexes were made, but no conclusive evidence could be obtained to confirm the successful synthesis of this species. In Chapter 3, the focus of the work is the study of ruthenium complexes with a (N-P)2 donor set. Two iminophosphine ligands, 2-(diphenylphosphino)pyridine (PPh2py) and 8-(diphenylphosphino)quinoline (PPh2qn), were selected for this study. The cis-RuCl2(N-P) complexes and the corresponding dimers were synthesized and characterized. Their optical and electrochemical properties were measured and are discussed. In Chapter 4, the quadratic and cubic nonlinear optical properties of organometallic complexes were explored by hyper-Rayleigh scattering (HRS) and frequency-depentdent Z-scan techniques, respectively. The first hyperpolarizabilities of the ruthenium halide and mono-alkynyl complexes described in Chapter 2 were determined by HRS measurements. The second hyperpolarizabilities of some organometallic complexes synthesized by the Humphrey group and the collaborators were measured by the Z-scan technique.
Book Synopsis Homogeneous Catalytic Oxidation with Cluster Metal Carbonyl Compounds by : Mark Kevin Dickson
Download or read book Homogeneous Catalytic Oxidation with Cluster Metal Carbonyl Compounds written by Mark Kevin Dickson and published by . This book was released on 1982 with total page 191 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization, and Biological Activity of Hydroxylated Diphosphine Complexes of Ruthenium, Platinum, and Palladium by : Ana Clara Zampirolli Leal
Download or read book Synthesis, Characterization, and Biological Activity of Hydroxylated Diphosphine Complexes of Ruthenium, Platinum, and Palladium written by Ana Clara Zampirolli Leal and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Rhenium Carbonyl Complexes Obtained by Ligand Exchange Reactions by : Franklin R. Beckles Araque
Download or read book Synthesis and Characterization of Rhenium Carbonyl Complexes Obtained by Ligand Exchange Reactions written by Franklin R. Beckles Araque and published by . This book was released on 2005 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization and Reactivity of Ruthenium Porphyrin Complexes Containing Metal-carbon Bonds [microform] by : Mingzhe Ke
Download or read book Synthesis, Characterization and Reactivity of Ruthenium Porphyrin Complexes Containing Metal-carbon Bonds [microform] written by Mingzhe Ke and published by National Library of Canada. This book was released on 1988 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Ruthenium Complex Using Hypoxanthine as Ligand by : Chakravarthy B. Koricheria
Download or read book Synthesis and Characterization of Ruthenium Complex Using Hypoxanthine as Ligand written by Chakravarthy B. Koricheria and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Ruthenium (II) Polypyridyl Complexes by : Youxiang Wang
Download or read book Synthesis and Characterization of Ruthenium (II) Polypyridyl Complexes written by Youxiang Wang and published by . This book was released on 1994 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Survey of the Synthesis, Characterization, and Utilization of Hydride Complexes of Ruthenium, Rhodium, and Iridium by : Jeffrey Richard Lehman
Download or read book A Survey of the Synthesis, Characterization, and Utilization of Hydride Complexes of Ruthenium, Rhodium, and Iridium written by Jeffrey Richard Lehman and published by . This book was released on with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization, and Reactivity of the Half-sandwich Ruthenium (II) Hydride Complexes of 1,3,5-triaza-7-phosphaadamantane by : Jocelyn Pineda Lanorio
Download or read book Synthesis, Characterization, and Reactivity of the Half-sandwich Ruthenium (II) Hydride Complexes of 1,3,5-triaza-7-phosphaadamantane written by Jocelyn Pineda Lanorio and published by . This book was released on 2014 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Ruthenium Lewis Acid-amide Complexes by : Ann Wawrukiewicz
Download or read book Synthesis and Characterization of Ruthenium Lewis Acid-amide Complexes written by Ann Wawrukiewicz and published by . This book was released on 1993 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ruthenium in Organic Synthesis by : Shun-Ichi Murahashi
Download or read book Ruthenium in Organic Synthesis written by Shun-Ichi Murahashi and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)
Book Synopsis Synthesis and Characterization of Ruthenium Complexes with a Tridentate, Binucleating Ligand by : Amy E. Frost
Download or read book Synthesis and Characterization of Ruthenium Complexes with a Tridentate, Binucleating Ligand written by Amy E. Frost and published by . This book was released on 1984 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: