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Synthesis And Catalytic Application Of Functional Transition Metal Oxides
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Book Synopsis Synthesis and Catalytic Application of Functional Transition Metal Oxides by : Patrick Mountapmbeme Kouotou
Download or read book Synthesis and Catalytic Application of Functional Transition Metal Oxides written by Patrick Mountapmbeme Kouotou and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Design, Synthesis, and Characterization of Transition Metal Oxide Based Functional Materials for Multi-phase Catalytic Applications by : Chung-Hao Kuo
Download or read book Design, Synthesis, and Characterization of Transition Metal Oxide Based Functional Materials for Multi-phase Catalytic Applications written by Chung-Hao Kuo and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Application of Transition Metal Catalysts in Organic Synthesis by : L. Brandsma
Download or read book Application of Transition Metal Catalysts in Organic Synthesis written by L. Brandsma and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.
Book Synopsis New Pathways for Organic Synthesis by : H.M. Colquhoun
Download or read book New Pathways for Organic Synthesis written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.
Book Synopsis Design, Synthesis, and Characterization of Transition Metal Oxide Nanomaterials as Efficient Sorbents and Multifunctional Catalysts for Oxidation, Dehydrogenative Coupling, and Desulfurization Reactions by : Chandima Weerakkody
Download or read book Design, Synthesis, and Characterization of Transition Metal Oxide Nanomaterials as Efficient Sorbents and Multifunctional Catalysts for Oxidation, Dehydrogenative Coupling, and Desulfurization Reactions written by Chandima Weerakkody and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The research work presented here is focused on nanotechnological synthetic approaches for transition metal oxide nanomaterials and their applications in heterogeneous catalysis and adsorptive desulfurization reactions. Here, we discuss the controllable synthesis of functional nanomaterials and investigation of their structure-activity relationship in multiphase catalytic and sorption reactions. Among transition metal oxides, Co3O4 is well known for the presence of mobile oxygen, and thus is more reactive towards oxidation reactions. Aerobic oxidation under additive free conditions is highly desirable in organic synthesis reactions, from the viewpoint of green and sustainable chemistry. We demonstrate the activity enhancement of mesoporous cobalt oxide materials by substitutional doping of molybdenum ions. We discuss the surface chemistry in the production of active metal oxide nanoparticles and effect of lattice deformation on creating surface defects. High conversion and selectivity was achieved by controlling the surface area, Lewis acidity, and oxygen vacancy density of the solid catalyst in the liquid phase dehydrogenative coupling reactions. Synthesis of high surface area mesoporous cobalt molybdenum mixed metal oxide materials was accomplished using surfactant assisted inverse micelle method. The cobalt molybdenum oxide materials were investigated as a efficient desulfurization sorbent in a fixed bed reactor at low temperatures ( C).
Download or read book Metal Oxides written by J.L.G. Fierro and published by CRC Press. This book was released on 2005-08-24 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of metals has traditionally been more understood than that of its oxides. As catalytic applications continue to grow in a variety of disciplines, Metal Oxides: Chemistry and Applications offers a timely account of transition-metal oxides (TMO), one of the most important classes of metal oxides, in the context of catalysis. The
Download or read book Nanocasting written by An-Hui Lu and published by Royal Society of Chemistry. This book was released on 2010 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured materials with tailored properties are regarded as a fundamental element in the development of future science and technology. Research is still ongoing into the nanosized construction elements required to create functional solids. The recently developed technique, nanocasting, has great advantage over others in terms of the synthesis of special nanostructured materials by the careful choice of suitable elements and nanoengineering steps. This new book summarizes the recent developments in nanocasting, including the principles of nanocasting, syntheses of novel nanostructured materials, characterization methods, detailed synthetic recipes and further possible development in this area. The book focuses on the synthesis of porous solids from the viewpoint of methodology and introduces the science of nanocasting from fundamental principles to their use in synthesis of various materials. It starts by outlining the principles of nanocasting, requirements to the templates and precursors and the tools needed to probe matter at the nanoscale level. It describes how to synthesize nano structured porous solids with defined characteristics and finally discusses the functionalization and application of porous solids. Special attention is given to new developments in this field and future perspectives. A useful appendix covering the detailed synthetic recipes of various templates including porous silica, porous carbon and colloidal spheres is included which will be invaluable to researchers wanting to follow and reproduce nanocast materials. Topics covered in the book include: * inorganic chemistry * organic chemistry * solution chemistry * sol-gel and interface science * acid-base equilibria * electrochemistry * biochemistry * confined synthesis The book gives readers not only an overview of nanocasting technology, but also sufficient information and knowledge for those wanting to prepare various nanostructured materials without needing to search the available literature.
Book Synopsis Synthesis, Characterization, and Applications of Nano-functional Transition Metal Oxides Materials and Graphite Anode Modified by Cvd Carbon Coating by : Yunshuang Ding
Download or read book Synthesis, Characterization, and Applications of Nano-functional Transition Metal Oxides Materials and Graphite Anode Modified by Cvd Carbon Coating written by Yunshuang Ding and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This research consists of two major sections. The first section of this research is focused on developing novel synthesis methods, characterization, and catalytic applications of multi-functional transition metal oxides including manganese oxide nano-materials (2x2 tunel structured manganese oxide octahedral molecular sieve), 3D hierarchical nano-architecture -MnO2 and cobalt oxides, and cobalt based materials. Manganese oxide octahedral molecula sieves (OMS) have ID open framework structures with various theoretical nano-scale tunnel size materials have been investigated extensively as low cost and environmentally benign ionic and molecular sieves and efficient redox catalysts. A novel and efficient solvent-free method has been developed to synthesize manganese oxides with 2 x 2 tunnel structures. The properties of the synthesized OMS-2 materilas have been compared with that synthesized by conventional reflux and hydrothermal methods. Epsilon manganese dioxides with controlled novel 3D architectures have been fabricated via a hydrothermal chemical reaction. The effects of reaction time and reaction temperature on the morphology of the final -MnO2 are investigated, and the formation mechanisms of the hierarchical nano-architectures are proposed. The magnetic properties of -MnO2 are also studied. Resides manganese oxides, a microwave-heating reflux route has been used to synthesize 3D flower like cobalt hydrotalcite-like compounds with layered structure and these compounds can be transferred into spinel structure of Co3O 4. Both materials show the electrocatalytic activity and stability for the electrochemical reduction of oxygen. Therefore these materials have the potential to be electrocatyltic catalysts. The second section of the research is to study the microstructure of carbon films coated on the iron and graphite particles by a Chemical Vapor Deposition (CVD) method and the relationship between the microstructure of the carbon coatings and their effects on electrochemical properties.
Book Synopsis Synthesis, Characterization, and Catalytic Applications of Transition Metal Oxide/carbonate Nanomaterials by : Lei Jin
Download or read book Synthesis, Characterization, and Catalytic Applications of Transition Metal Oxide/carbonate Nanomaterials written by Lei Jin and published by . This book was released on 2011 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Tailored Functional Oxide Nanomaterials by : Chiara Maccato
Download or read book Tailored Functional Oxide Nanomaterials written by Chiara Maccato and published by John Wiley & Sons. This book was released on 2022-03-02 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tailored Functional Oxide Nanomaterials A comprehensive exploration of the preparation and application of metal oxide nanomaterials Tailored Functional Oxide Nanomaterials: From Design to Multi-Purpose Applications delivers a one-of-a-kind discussion of the fundamentals and key applications of metal oxide nanomaterials. The book explores everything from their preparation to the mastering of their characteristics in an interdisciplinary view. The distinguished authors address theoretical research and advanced technological utilizations, illustrating key issues for the understanding and real-world end-uses of the most important class of inorganic materials. The interplay between the design, preparation, chemico-physical characterization, and functional behaviors of metal oxide nanomaterials in a variety of fields is presented. Up-to-date work and knowledge on these materials is also described, with fulsome summaries of important applications that are relevant to researchers pursuing safety, sustainability, and energy end-uses. Readers will also find: A thorough introduction to vapor phase growth of metal oxide thin films and nanostructures Comprehensive explorations of addressing complex transition metal oxides at the nanoscale, including bottom-up syntheses of nano-objects and properties Practical discussions of nanosized oxides supported on mats of carbon nanotubes, including synthesis strategies and performances of Ti/CNT systems In-depth examinations of computational approaches to the study of oxide nanomaterials and nanoporous oxides Perfect for materials scientists, inorganic chemists, physicists, catalytic chemists, and chemical engineers, Tailored Functional Oxide Nanomaterials will also earn a place in the libraries of solid-state chemists.
Book Synopsis Metal Oxide Catalysis, 2 Volume Set by : S. David Jackson
Download or read book Metal Oxide Catalysis, 2 Volume Set written by S. David Jackson and published by John Wiley & Sons. This book was released on 2008-11-24 with total page 916 pages. Available in PDF, EPUB and Kindle. Book excerpt: With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.
Book Synopsis Synthesis, Characterization, and Applications of Nano-functional Transition Metal Oxides Materials and Graphic Anode Modified by CVD Carbon Coating by : Yunshuang Ding
Download or read book Synthesis, Characterization, and Applications of Nano-functional Transition Metal Oxides Materials and Graphic Anode Modified by CVD Carbon Coating written by Yunshuang Ding and published by . This book was released on 2007 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Transition Metal Oxide Catalysts for Environmental and Energy Storage Applications by : Wenqiao Song
Download or read book Synthesis and Characterization of Transition Metal Oxide Catalysts for Environmental and Energy Storage Applications written by Wenqiao Song and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Nowadays, environmental concerns and the global energy crisis have become two of our greatest challenges. The main purpose of this dissertation research is to design highly active mesoporous materials that can efficiently catalyze environmental and energy related reactions. Surface properties can be easily tuned by thermal treatment and cation doping, resulting in improved catalytic activities. Synthesis and characterization of the materials, catalytic activities for carbon monoxide oxidation, oxygen reduction and oxygen evolution reactions, and mechanistic studies are covered in this thesis. The first part describes the synthesis of mesoporous cobalt oxides through an inverse micelle route for low temperature carbon monoxide oxidation applications. The prepared material showed much better activity and stability compared with commercial cobalt oxide due to its nanoparticle nature and porous structure. The catalytic performance under both dry and moisture rich conditions were tested. Detailed characterization of the materials suggested that high surface areas and the presence of surface oxygen vacancies were critical for enhanced activities. In real systems, structured catalysts such as monolithic substrates coated with a layer of active material are used instead of powder form catalysts. To evaluate the potential of our catalysts to be used in practical catalytic devices, mesoporous metal oxides (MnOx, Co3O4, CeO2) were coated on cordierite substrate by dip coating and in-situ growth and were used as low temperature diesel oxidation catalysts. The resulting materials showed promising catalytic performance. The effect of particle size, loading amount and Cu doping on the catalytic performance are discussed in detail. In the last part, mesoporous cobalt oxides were used as bifunctional catalysts for oxygen reduction and oxygen evolution reactions. If a catalyst can catalyze both reactions, it will have great potential in the application of rechargeable metal air batteries. Ni and Mn doping were introduced into the cobalt oxide material to increase the conductivity and active site population. The Ni incorporated cobalt oxide exhibited the best activity, which can be considered as a potential substituent for precious metal catalysts (Pt, Ir, Ru). Furthermore, the intrinsic structure-property relationships of the materials were established.
Book Synopsis Green Catalytic Applications of Functional Nanomaterials and Design, Synthesis, and Structure - Property Relationships of Sodium Tungsten Bronze Thin Films by : Niluka D Wasalathanthri
Download or read book Green Catalytic Applications of Functional Nanomaterials and Design, Synthesis, and Structure - Property Relationships of Sodium Tungsten Bronze Thin Films written by Niluka D Wasalathanthri and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The research presented here is focused on design, synthesis, and characterization of transition metal oxides for catalytic and energy applications. The first part is devoted to discuss catalytic applications of mesoporous manganese oxides and the second part is devoted to discuss novel solvent driven synthesis of sodium tungsten bronze nanomaterials for energy applications. From the standpoint of green chemistry, the investigation of simple, low cost, stable, environmentally friendly, and potentially active materials for complete oxidation reactions at low temperatures is highly desirable. In recent years, green chemical approaches have become an integrated part of daily life and implementation of this modern discipline led to momentous ecological benefits, innovations and a strengthened economy. My research is devoted to investigate potential materials in oxidative catalysts that resonate with the concepts in green chemistry. The first part of this thesis will discuss the importance of catalytic oxidation reactions, synthesis, and characterization of the mesoporous manganese oxide materials and their applications in a series of complete oxidation reactions. The projected decline in fossil fuels and growing global energy consumption demands alternatives for petroleum feedstock and sustainable conversion processes for energy production. Thus, applicability of mesoporous manganese oxides on complete catalytic oxidation of methane has been discussed. Secondly, complete catalytic oxidation of diesel particulate matter (DPM) which is an unsolicited byproduct emitted by diesel exhaust engines is discussed. In the second part of this thesis, design of novel, solvent driven in situ synthesis method of sodium tungsten bronze is discussed. Tungsten bronzes are well defined, unique class of non-stoichiometric compounds with exclusive characteristic properties. They have attracted much attention in the past few decades due to their wide variety of crystal structures and interesting electro-optic, photochromic, and super-conducting properties However, the synthesis of cubic sodium tungsten bronze nanomaterials with high conductivity is not much reported due to the limitations of high temperature synthetic approaches.
Book Synopsis Nanostructured Catalysts by : Christian Hess
Download or read book Nanostructured Catalysts written by Christian Hess and published by Royal Society of Chemistry. This book was released on 2011-07-22 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book gives a comprehensive up-to-date summary of the existing information on the structural/electronic properties, chemistry and catalytic properties of vanadium and molybdenum containing catalysts. It discusses the importance of nanoscience for the controlled synthesis of catalysts with functional properties and introduces the necessary background regarding surface properties and preparation techniques, leading from a textbook level to the current state of knowledge. Then follows an extensive survey and analysis of the existing open and patent literature - an essential knowledge source for the development of the new generation of partial oxidation catalysts. Important examples from current research on partial oxidation reactions are reviewed from experts in the field. The next chapter discusses the importance of 2- and 3-dimensional model systems for a fundamental understanding of the structure of transition metal oxide catalysts and its correlation to reactivity. Finally, an outlook on research opportunities within the area of partial oxidation reactions is presented.
Book Synopsis Metal Oxides in Heterogeneous Catalysis by : Jacques C. Vedrine
Download or read book Metal Oxides in Heterogeneous Catalysis written by Jacques C. Vedrine and published by Elsevier. This book was released on 2018-01-11 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. Presents case studies in each chapter that provide a focus on the industrial applications Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications
Book Synopsis Design, Synthesis and Characterization of Transition Metal Oxide Nanomaterials for Emerging Catalytic Applications by : Dharmarathna Arachchige Saminda Dharmarathna
Download or read book Design, Synthesis and Characterization of Transition Metal Oxide Nanomaterials for Emerging Catalytic Applications written by Dharmarathna Arachchige Saminda Dharmarathna and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
